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Clinker Composition and Reaction Analysis

This document analyzes the components of a clinker sample weighing 100 kg. It lists the components, their masses, molecular masses, and moles. It then shows reactions to calculate the molar masses of compounds in the clinker, including 4CaO*Al2O3*Fe2O3, 3CaO*Al2O3, and remaining CaO. The final section lists the components, moles, molar masses, masses, and percentages of the compounds in the clinker.

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Florence
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23 views2 pages

Clinker Composition and Reaction Analysis

This document analyzes the components of a clinker sample weighing 100 kg. It lists the components, their masses, molecular masses, and moles. It then shows reactions to calculate the molar masses of compounds in the clinker, including 4CaO*Al2O3*Fe2O3, 3CaO*Al2O3, and remaining CaO. The final section lists the components, moles, molar masses, masses, and percentages of the compounds in the clinker.

Uploaded by

Florence
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd

Clinker Analysis:

Basis: 100 kg
Components Mass Molecular Mass kmole
CaO 63.42 56.0774 1.130937
MgO 3.28 40.3044 0.081381
Fe2 O 3 0.5053 159.69 0.003164
Al2 O3 11.42 101.96 0.112005
S iO2 20.80 60.08 0.346205
S O2 0.63 64.066 0.009834

Reaction:
11
2 Fe S 2+ O → Fe 2 O 3 +4 S O 2
2 2

1 kmol Fe S 2 1kmol Fe 2 O 3 159.69 kg Fe2 O3


[
Fe2 O3 mass= 0.0056 (135.589) kg Fe S 2
( 119.98 kg Fe S 2 )( 2 kmol Fe S2 )( 1 kmol Fe2 O3 )]
Fe2 O 3 mass=¿ 0.5053 kg

4CaO * Al2O3 * Fe2O3 mol = 0.003164 mol


3CaO * Al2O3 mol = 0.112005-0.003164 = 0.108841 mol
Remaining CaO mol = 1.130937 – 3[(0.108841) – 4(0.003164) = 0.791758 mol
3 x+ 2 y =0.79175 8
x + y=0.346205
x=0.09934 8
y=0.246857
Components Mole Molar Mass Mass % Mass
3CaO * SiO2 0.099348 228.3122 22.6824 22.67
2CaO * SiO2 0.246857 172.2348 42.5174 42.49
3CaO * Al2O3 0.108839 270.1922 29.40745 29.39
4CaO * Al2O3 * 0.003166 485.9596 1.538548 1.54
Fe2O3
MgO 3.28 3.28
S O2 0.63 0.63
In Clinker:
Solve for 4CaO * Al2O3 * Fe2O3 kmol:
1 kmol Fe2 O 3
0.5056 kg Fe 2 O 3 ( 159.69 kg Fe2 O 3 )
=0.003166 kmol 4 CaO∗Al 2 O 3∗Fe2 O 3

Solve for kmol of 3CaO * Al2O3 mol:

1 kmol Al 2 O3
[ 0.1088 41 kg Al2 O3
( )
101.96 kg Al 2 O3 ( )]
−0.00316 4 kmol Fe2 O3
1
1
=0.00209 7 kmol 3 CaO∗Al 2O 3

Solve for remaining CaO:

[ 1.130 937 kmol CaO−0.00209 7 kmol 3 CaO∗Al 2O 3 ( 1 kmol33kmol CaO


CaO∗Al 2O 3 )
−0.00316 4 kmol 4 CaO∗Al O ∗F
2 3

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