DOW CORNING CORPORATION
Material Safety Data Sheet
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Version: 1.6
Revision Date: 2008/09/09
MOLYKOTE(R) G-RAPID PLUS SPRAY
1. PRODUCT AND COMPANY IDENTIFICATION
Dow Corning Corporation 24 Hour Emergency Telephone: (989) 496-5900
South Saginaw Road Customer Service: (989) 496-6000
Midland, Michigan 48686 Product Disposal Information: (989) 496-6315
CHEMTREC: (800) 424-9300
MSDS No.: 01685392 Revision Date: 2008/09/09
Generic Description: Molybdenum disulfide aerosol
Physical Form: Aerosol
Color: Black
Odor: Solvent odor.
NFPA Profile: Health 2 Flammability 4 Instability/Reactivity 0
Note: NFPA = National Fire Protection Association
2. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Acute Effects
Eye: Direct contact may cause mild irritation.
Skin: May cause mild irritation.
Inhalation: Vapor and/or mist may irritate nose and throat. Overexposure by inhalation may cause
drowsiness, dizziness, confusion or loss of coordination.
Oral: Low ingestion hazard in normal use.
Prolonged/Repeated Exposure Effects
Skin: Repeated or prolonged contact may cause defatting and drying of skin which may result in
skin irritation and dermatitis.
Inhalation: Exposures to high concentrations may cause cardiac sensitization. Overexposure by
inhalation may injure the following organ(s): Nervous system.
Oral: No known applicable information.
Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
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No known applicable information.
The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions,
component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS Number Wt % Component Name
106-97-8 30.0 - 60.0 Butane
64742-48-9 15.0 - 40.0 Hydrotreated heavy petroleum naphtha
1305-62-0 5.0 - 10.0 Calcium hydroxide
74-98-6 5.0 - 10.0 Propane
The above components are hazardous as defined in 29 CFR 1910.1200.
4. FIRST AID MEASURES
Eye: Immediately flush with water for 15 minutes.
Skin: Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get
medical attention if irritation or other ill effects develop or persist.
Inhalation: Remove to fresh air. Get immediate medical attention.
Oral: No first aid should be needed.
Notes to Physician: Treat according to person's condition and specifics of exposure.
5. FIRE FIGHTING MEASURES
Flash Point: Not applicable.
Autoignition Temperature: Not determined.
Flammability Limits in Air: Not determined.
Extinguishing Media: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.
Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting large
fires involving chemicals. Use water spray to keep fire exposed containers cool. Determine
the need to evacuate or isolate the area according to your local emergency plan.
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Material Safety Data Sheet
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Unusual Fire Hazards: Vapors are heavier than air and may travel to a source of ignition and flash back. Static
electricity will accumulate and may ignite vapors. Prevent a possible fire hazard by bonding
and grounding or inert gas purge.
6. ACCIDENTAL RELEASE MEASURES
Containment/Clean up: Remove possible ignition sources. Determine whether to evacuate or isolate the area
according to your local emergency plan. Observe all personal protection equipment
recommendations described in Sections 5 and 8. Local, state and federal laws and
regulations may apply to releases and disposal of this material, as well as those materials and
items employed in the cleanup of releases. You will need to determine which federal, state
and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide
information regarding certain federal and state requirements.
Note: See section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is
required.
7. HANDLING AND STORAGE
Use with adequate ventilation. Avoid eye contact. Avoid skin contact. Do not breathe mist. Keep container closed.
Contents under pressure. Do not store above 120F/49C or in direct sunlight. Static electricity will accumulate and may
ignite vapors. Prevent a possible fire hazard by bonding and grounding or inert gas purge. Keep container closed and
away from heat, sparks, and flame.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Component Exposure Limits
CAS Number Component Name Exposure Limits
106-97-8 Butane OSHA PEL (final rule): TWA 800 ppm, 1900 mg/m3.
ACGIH TLV: TWA 1000 ppm.
64742-48-9 Hydrotreated heavy petroleum naphtha Observe petroleum distillates limits. OSHA PEL (final rule):
TWA 400 ppm.
1305-62-0 Calcium hydroxide ACGIH TLV: TWA 5 mg/m3.
74-98-6 Propane OSHA PEL (final rule): TWA 1000 ppm, 1800 mg/m3.
ACGIH TLV: TWA 1000 ppm.
Engineering Controls
Local Ventilation: Recommended.
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General Ventilation: Recommended.
Personal Protective Equipment for Routine Handling
Eyes: Use proper protection - safety glasses as a minimum.
Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.
Suitable Gloves: Neoprene Rubber(R). Polyvinylalcohol. Nitrile Rubber. Polyvinylchloride. Viton(R). Silver
Shield(R). 4H(R).
Inhalation: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure
assessment demonstrates that exposures are within recommended exposure guidelines. IH
personnel can assist in judging the adequacy of existing engineering controls.
Suitable Respirator: General and local exhaust ventilation is recommended to maintain vapor exposures below
recommended limits. Where concentrations are above recommended limits or are unknown,
appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29
CFR 1910.134) and use NIOSH/MSHA approved respirators.
Personal Protective Equipment for Spills
Eyes: Use full face respirator.
Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.
Inhalation/Suitable Respiratory protection recommended. Follow OSHA Respirator Regulations (29 CFR
Respirator: 1910.134) and use NIOSH/MHSA approved respirators. Protection provided by air purifying
respirators against exposure to any hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled release, exposure levels are
unknown, or any other circumstance where air purifying respirators may not provide adequate
protection.
Precautionary Measures: Avoid eye contact. Avoid skin contact. Do not breathe mist. Keep container closed. Use
reasonable care.
Comments: When heated to temperatures above 150 degrees C in the presence of air, product can form
formaldehyde vapors. Formaldehyde is a potential cancer hazard, a known skin and
respiratory sensitizer, and an irritant to the eyes, nose, throat, skin, and digestive system.
Safe handling conditions may be maintained by keeping vapor concentrations within the
OSHA Permissible Exposure Limit for formaldehyde.
Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require
added precautions.
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Material Safety Data Sheet
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9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Aerosol
Color: Black
Odor: Solvent odor.
Specific Gravity @ 25°C: 0.74
Viscosity: Not determined.
Freezing/Melting Point: Not determined.
Boiling Point: Not determined.
Vapor Pressure @ 25°C: Not determined.
Vapor Density: Not determined.
Solubility in Water: Not determined.
pH: Not determined.
Volatile Content: Not determined.
Flash Point: Not applicable.
Autoignition Temperature: Not determined.
Flammability Limits in Air: Not determined.
Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing
specifications.
10. STABILITY AND REACTIVITY
Chemical Stability: Stable.
Hazardous Hazardous polymerization will not occur.
Polymerization:
Conditions to Avoid: None.
Materials to Avoid: Oxidizing material can cause a reaction.
Hazardous Decomposition Products
Thermal breakdown of this product during fire or very high heat conditions may evolve the following decomposition
products: Carbon oxides and traces of incompletely burned carbon compounds. Metal oxides. Sulfur oxides.
Formaldehyde.
11. TOXICOLOGICAL INFORMATION
Special Hazard Information on Components
No known applicable information.
12. ECOLOGICAL INFORMATION
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Material Safety Data Sheet
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Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.
Ecotoxicity Classification Criteria
Hazard Parameters (LC50 or EC50) High Medium Low
Acute Aquatic Toxicity (mg/L) <=1 >1 and <=100 >100
Acute Terrestrial Toxicity <=100 >100 and <= 2000 >2000
This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.
This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the
section concerning the overall ecological safety of this material.
13. DISPOSAL CONSIDERATIONS
RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received, is it classified as a hazardous waste? Yes
Characteristic Waste:
Ignitable: D001
State or local laws may impose additional regulatory requirements regarding [Link] (989) 496-6315, if additional
information is required.
14. TRANSPORT INFORMATION
DOT Road Shipment Information (49 CFR 172.101)
Proper Shipping Name: Consumer Commodity
Hazard Class: ORM
Hazard Label(s): ORM-D (Other Regulated Materials)
Ocean Shipment (IMDG)
Proper Shipping Name: AEROSOLS
Hazard Class: 2.1
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Material Safety Data Sheet
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UN/NA Number: UN 1950
Air Shipment (IATA)
Proper Shipping Name: Aerosols, flammable
Hazard Class: 2.1
UN/NA Number: UN 1950
Hazard Label(s): Flammable Gas
Apply Gross Wt Supplemental Label to Outer Package if shipping Limited Quantity
Call Dow Corning Transportation, (989) 496-8577, if additional information is required.
15. REGULATORY INFORMATION
Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.
EPA SARA Title III Chemical Listings
Section 302 Extremely Hazardous Substances (40 CFR 355):
None.
Section 304 CERCLA Hazardous Substances (40 CFR 302):
None.
Section 311/312 Hazard Class (40 CFR 370):
Acute: Yes
Chronic: Yes
Fire: Yes
Pressure: Yes
Reactive: No
Section 313 Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities.
Note: Chemicals are listed under the 313 Toxic Chemicals section only if they meet or exceed a reporting threshold.
Supplemental State Compliance Information
California
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Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water
and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other
reproductive harm.
None known.
Massachusetts
CAS Number Wt % Component Name
106-97-8 30.0 - 60.0 Butane
1317-33-5 7.0 - 13.0 Molybdenum disulfide
1305-62-0 5.0 - 10.0 Calcium hydroxide
74-98-6 5.0 - 10.0 Propane
7782-42-5 3.0 - 7.0 Graphite
New Jersey
CAS Number Wt % Component Name
106-97-8 30.0 - 60.0 Butane
64742-48-9 15.0 - 40.0 Hydrotreated heavy petroleum naphtha
8042-47-5 10.0 - 30.0 Mineral oil
1317-33-5 7.0 - 13.0 Molybdenum disulfide
1305-62-0 5.0 - 10.0 Calcium hydroxide
74-98-6 5.0 - 10.0 Propane
Pennsylvania
CAS Number Wt % Component Name
106-97-8 30.0 - 60.0 Butane
64742-48-9 15.0 - 40.0 Hydrotreated heavy petroleum naphtha
8042-47-5 10.0 - 30.0 Mineral oil
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1317-33-5 7.0 - 13.0 Molybdenum disulfide
1305-62-0 5.0 - 10.0 Calcium hydroxide
74-98-6 5.0 - 10.0 Propane
7782-42-5 3.0 - 7.0 Graphite
16. OTHER INFORMATION
Prepared by: Dow Corning Corporation
These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or
implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the specific context of the intended use and
determine whether they are appropriate.
(R) indicates Registered Trademark