Module 8 - 1
Module 8
Welding Metallurgy for
the Welding Inspector
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Module 8 - 2
Metallurgy
“The science dealing with the internal
structure of metals and metal properties ”
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Welding Metallurgy
“Concerned with the changes occurring in
metals during welding”
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Module 8 - 4
Discussion Topics
Structures
Changes on heating
Changes on cooling
Heat treatments
Alloying
Phases
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Module 8 - 5
Atomic Structure
Matter made up of atoms
Atoms are very small
Electrons orbit atomic nuclei
Have a home location in solids
Oscillate around home position
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Module 8 - 6
Atomic Structure - Simple Cubic
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Home Location
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Solids
Minimum internal energy
Atoms fixed in place
Atoms have ‘home’ position
Atoms vibrating
Orbiting electrons
Crystalline structure
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Module 8 - 9
Liquids
Higher internal energy
Atoms free to move
Atoms vibrating more
Orbiting electrons
No fixed structure
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Module 8 - 10
Solid vs Liquid
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Thermal
expansion on
Heating
Thermal
contraction on
Cooling
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Welding Stresses (Tensile)
Remain after welding is completed (residual stress)
Can cause distortion
– (welding stress exceeds yield strength of material)
Can cause cracking
– (welding stress exceeds tensile strength of material)
Residual stress can be as high as yield strength
Relieved by three methods
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Stress Relieving
Thermally
Vibratory
Peening
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Crystal Structures
BCC - Body Centered Cubic
FCC - Face Centered Cubic
HCP - Hexagonal Close Packed
BCT - Body Centered Tetragonal
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Common
Crystal
Structures
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Metal
Solidification
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Grain Size Effects
Fine grained materials
– Have good tensile strength
– Have good ductility
– Have good low temperature properties
Coarse grained materials
– Have slightly lower strength
– Are slightly less ductile
– Have good high temperature properties
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Alloying
“Adding elements to change mechanical or
physical properties”
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Interstitial
Alloying
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Interstitial Alloying -
Module 8 - 20
Results in Lattice Distortion
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Substitutional
Alloying
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Substitutional Alloying -
Module 8 - 22
Results in Lattice Distortion
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Microstructures
Metals composed of grains (crystals)
Very small
Separated by grain boundaries
Different phases within grains
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Microstructure
of Iron
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Iron-Carbon
Phase Diagram
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Phases in Steel
Ferrite
Cementite
Austenite
Bainite
Pearlite
Martensite
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Module 8 - 27
Cooling Rates
Slow - Pearlite - softest
Moderate - Bainite
Fast - Martensite - hardest
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Lamellar Appearance of Pearlite
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Martensite
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Tempering
“Restores ductility and toughness and reduces
strength and hardness”
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Effects of Tempering
Module 8 - 31
Temperatures
Alloy is AISI 4142
Tempering temperature
is in degrees F
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Effects of Tempering
Module 8 - 32
Temperatures
Alloy contains 12% Cr
Note reduction in impact
strength at 885 F (475 C)
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Continuous Cooling
Diagram & Jominy
Hardenability Diagram
for 8630 steel. Phase
formed on cooling
varies with cooling
rate.
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Weld Area & Fe - Fe3C Diagram
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Heat Input
Joules/inch = current x voltage x 60
travel speed (in./min)
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Preheat
Slows cooling rate
Produces less martensite
Reduces risk of cracking
Reduces distortion
Reduces hydrogen
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Carbon Equivalent
Module 8 - 37
( CE )
CE = % C + % Mn + % Ni + % Cr + % Cu + % Mo
6 15 5 13 4
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Examples of Preheating vs C.E.
C.E. Preheat Temperature
< 0.45 Optional
0.45 - 0.60 2000 - 4000 F
>0.60 4000 - 7000 F
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Module 8 - 39
Heat Treatments for Steels
Super-critical - above transformation temp.
– Annealing
– Normalizing
– Quenching (to harden)
Sub-critical - below transformation temp.
– Tempering
– Stress Relieving
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Diffusion
“Movement of atoms within a solution, be it a
solid, liquid or gas”
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Diffusion of Lead and Gold Atoms
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Solubility
Dissolving Salt into Water
Solid into liquid
Diffusion mechanism
Solubility limit
Temperature effects
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Solid Solubility
Unique to metals
Solid into solid
Solubility limit
Temperature effects
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Examples of Solid Solubility
Gold and lead bars
Carburizing
Nitriding
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Stainless Steels
Ferritic
Martensitic
Austenitic
Precipitation Hardening (PH)
Duplex
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Sensitization of Austenitic Alloys
“Formation of chromium carbides between
800 - 1600 degrees F”
(Sensitization reduces the corrosion resistance
in many environments)
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Corrosion Attack of Austenitic
Module 8 - 47
Stainless Steel
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Avoiding Sensitization
Heat treatment ( SAWQ )
Stabilized grades
Low carbon grades
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Module 8 - 49
Other Common Alloys
Aluminum
– Pure aluminum
– Aluminum-copper
– Aluminum-magnesium
Copper
– Pure copper
– Brasses
– Bronzes
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