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Material and Energy Balance Analysis

This document provides an overall material and energy balance for a refinery process with multiple distillation columns. It includes: 1) Material and energy balances across each unit with feed and product stream compositions and flow rates. 2) Temperature, pressure, and enthalpy values for the feed, products, and side streams of each unit. 3) Equations showing the enthalpy balances across each distillation unit balance the energy of the feeds and products with the duties of the reboiler and condenser.

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Ahmed Hassan
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17 views13 pages

Material and Energy Balance Analysis

This document provides an overall material and energy balance for a refinery process with multiple distillation columns. It includes: 1) Material and energy balances across each unit with feed and product stream compositions and flow rates. 2) Temperature, pressure, and enthalpy values for the feed, products, and side streams of each unit. 3) Equations showing the enthalpy balances across each distillation unit balance the energy of the feeds and products with the duties of the reboiler and condenser.

Uploaded by

Ahmed Hassan
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd

Chapter # 4

MATERIAL AND
ENERGY BALANCE:
MATERIAL AND ENERGY
BALANCE:

BASIS :
25°C of Temperature
1atm of pressure
FEED FLOW RATE = 9881kg/hr
OVERALL MATERIAL AND ENERGY BALANCE:

46

STREAMS(kg/hr) IN OUT
1 (FEED) 9881 _

1-A (SOLVENT) 3006 _

5 (C-2 non aro) _ COMP. FEED3615


SOL. EXT. RAF.
(kg/hr) (1) (3) (2) (4)
24 (V-1 non aro) _ 4308

C6H6 1258 _ 1240 17


29 (BENZENE) _ 1193

C7H8 1613 _ 1589 23


36 (TOLUENE) _ 1554

C8H10 2130 _ 2088 43


43 (XYLENE) _ 1981

C9H12 492 _ 464 33


46 (C-8 BOT) _ 153

C6H14 884 _ 504 379


TOTAL 12887 12804
C7H16 1484 _ 266 1218

C8H18 1194 _ 0 1194

C9H20 826 _ 0 826


ACROSS EXTRACTOR:
SOLVEN _ 19860 18264 1596
T

OVERAL 9881 19860 24415 5331

T (°C) 25 100 90 90
P (atm) 1 0.51 0.68 1

H (kJ/hr) 0 3.2×106 2.5×106 5×105


ACROSS WATER WASH
COMP. FEED WATER RAF EXT.
(kg/hr) (4) (7) (5) (6)

C6H6 18 _ 15 2

C7H8 24 _ 22 2

C8H10 44 _ 35 8

C9H12 34 _ 32 2

C6H14 379 _ 352 27

C7H16 1218 _ 1183 36


C8H18 1194 1163 31

C9H20 827 _ 810 17

SOLVEN 1596 _ 0 1596


T

WATER _ 0 1620

OVERALL 5334 _ 3615 3340

T(°C) 90 _ 72 61

P(atm) 1 _ 1 _

H(kJ/hr) 5×10 2.15×10 3.1×10 3.8×10


5 5 5 5

ACROSS STRIPPER
COMP. FEED (8+9) BOT. O-H
(kg/hr) (14) (12)

C6H6 1240 1171 69

C7H8 1589 1559 30

C8H10 2086 2059 26

C9H12 464 458 6

C6H14 504 86 503

C7H16 266 2 264

SOLVENT 20256 20040 168

OVERALL 26406 25291 1068

T(°C) 121 178 121

P(atm) 42 1.7 1.4


H(kJ/hr) 2.5×105 2.9×106 2.5×105

ENTHALPY OF (9+8) + REBOILER DUTY ~ENTHALPY OF (14+12) + CONDENSER


DUTY

5.2×106 + 2.6×105 ~ 3.15×106 + 2.25×106

RECOVERY COLUMN
RECOVERY COLUMN RECEIVER
COMP FEED STEAM(17 O-H BOT.
(kg/hr) (14) ) (15) (18)

COMP. FEED BOT.


C6H6 1171 _ TOP. 117 0
(kg/hr) (22) (21) (7) 1
C7H8 1159 _ 115 0
C6H6 1171 1171 0 9
C8H10 2059 _ 201 48
C7H8 1559 1559 0 2
C9H12 458 _ 149 309
C8H10 2008 2008 0
SOLVEN 2013 _ 0 2013
C9H12 148 T 148 6 0 6

STEAM 1620 STEAM _ 1843 1620 162 25

OVERALL 6509 4889


OVERAL 2498 1843 0 611 2051
L 6 1 8
T(°C) 50 50 50
T(°C) 178 _ 184 145
P(atm) _ _ _
P(atm) 1.7 _ _ 1.5
H(kJ/hr) 2.2×105 -_ _-
H(kJ/hr) _ _ _ _
WATER STRIPPER
COMP. FEED O-H BOT. (17)
(kg/hr) (6) (13)

C6H6 2 2 0

C7H8 1.8 1.8 0

C8H10 8.4 8.4 0

C9H12 2.4 2.4 0


C6H14 26 0

C7H16 26 35 0
35
C8H18 30 30 0

C9H20 16 16 0

SOLVENT 1764 84 1680

WATER 1764 140 1620

OVERALL 3652 348 3300

T(°C) 61 110 145

P(atm) _ 1.2 1.5

H(kJ/hr) 3.8×105 5.7×104 5.1×106


ENTHALPY OF (6+25) + REBOILER DUTY ~ENTHALPY OF (13+18+17)
5.92 ×106 ~ 5.91×106

BENZENE COLUMN COMP. FEED O-H BOT.


(kg/hr) (20) (29) (32)

C6H6 1171 1171 0

C7H8 1559 22 1528

C8H10 2008 0 2008

C9H12 1488 0 1488

OVERAL 4908 1193 3705

T(°C) 50 85 145

P(atm) 1.5 1 1.2

H(kJ/hr) 1.8×105 3.3×104 1.06×105

ENTHALPY OF (20) + REBOILER DUTY ~ENTHALPY OF (27+32)+COND. DUTY


5.78×106 ~ 5.76×106
TOLUENE COLUMN
COMP. FEED O-H BOT.
(kg/hr) (32) (36) (39)

C7H8 1528 1528 0

C8H10 2011 26 1985

C9H12 148 0 148


OVERALL 2134

T(°C) 145 1554 160

P(atm) 1.2 1.2 _

H(kJ/hr) 1.06×105 2.2×105 3×105

ENTHALPY OF (32) + REBOILER DUTY ~ENTHALPY OF (34+39)+COND. DUTY


8.86×105 ~ 8.85×105

XYLENE COLUMN
COMP. FEED O-H BOT.
(kg/hr) (39) (43) (46)

C8H10 1985 1977 8

C9H12 149 4 145

OVERALL 2134 1981 153

T(°C) 160 139 175

P(atm) _ _ 1

H(kJ/hr) 3×105 5.2×105 2.7×105

ENTHALPY OF (39) + REBOILER DUTY ~ENTHALPY OF (41+46)+COND. DUTY

9.5×105 ~ 9.48×105

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