*Acidimetry, Alkalimetry, Non-Aqueous Titrimetry
______1. Indicators which can be used in the titration of weak bases and their salts.
a. Crystal violet c. Methyl Red e. Quinaldine red
b. Methylrosaniline chloride d. Malachite green
______2. Indicators which can be used in the titration of relatively stronger bases:
a. Methyl red b. Phenolphthalein c. Methyl orange d. Thymol blue
______3. The measurement of a base of a given sample by titration with a standard acid is:
a. acidimetry b. complexometry c. alkalimetry d. cerimetry
______4. The measurement of acids by titrating acid, acid salt, or other acidic substances with standard alkali.
a. acidimetry b. complexometry c. alkalimetry d. cerimetry
______5. Standard solutions are also known as:
a. Test solutions Volumetric solutions c. Saturated solutions d. none of the choices
______6. The Kjeldahl method of analysis is used to determine:
a. Lipids b. Carbohydrates c. Nitrogen d. Oxygen
______7. The chemical factor used in calculation of percent (%) purity of a substance in volumetric analysis:
a. mEq weight b. Molarity c. Titer d. a & c
______8. The components of a blank used in the assay of a substance are, except:
a. Solvent b. reagent c. indicator d. analyte
______9. The terms used when equivalent amounts of each reactant have reacted are the following, except:
a. End point c. Stoichiometric point
b. Equivalence point d. Theoretical point
______10. The experimental way of determining when equivalent amounts of reactants have reacted together is:
a. Titration b. Stoichiometric point c. Standardization d. Equivalence point
______11. The process by which the exact concentration of a solution is determined is:
a. Standardization b. Neutralization c. Titration d. Dissolution
______12. The concentration referring to the number of equivalents of solute per liter of solution is:
a. Normality b. Molarity c. Molality d. Formality
______13. The weight of the substance chemically equivalent to 1mL of the standard solution:
a. Titrand b. Equivalence point c. Titer d. End point
______14. A macromethod of nitrogen determination in which the ammonia is distilled into excess boric acid solution:
a. Method I b. Method II c. Kjeldahl method d. all of the choices
______15. The process by which the exact concentration of a solution is determined is:
a. Standardization b. Neutralization c. Titration d. Dissolution
______16. The strongest of the known common acids which gives excellent results with practically all the known weak
bases.
a. Hydrochloric acid b. Sulfuric acid c. Perchloric acid d. Phosphoric acid
______17. Standard solution in non-aqueous titrimetric analysis-acidimetry:
a. Perchloric acid c. both a & b
b. Hydrogen bromide d. none of the choices
______18. Reasons why non-aqueous titration os performed:
a.
b.
c.
______19. Sulfamic acid (H3NSO3) is a pimary standard that can be used to standardize NaOH. What is the molarity if
34.26mL reacts with 0.3337g of sulfamic acid. MW =97
______20. A 10mL sample of H2SO4 solution required 16.85mL of NaOH solution in titration. Each mL of the NaOH
solution was equivalent to 0.2477g of potassium hydrogen phthalate. Calculate the H2SO4 content in %w/v. MW H2SO4
=98.
Quiz
Quiz on Precipitation Method of Analysis:
1. Fajans titration uses _______ indicator.
a. Acid-base c. Metal- ion
b. Adsorption d. NOTA
_____2. Other name of ferric ammonium sulfate
a. Ferric alum c. Fe (NH4)2 (SO4)2
b. Fe NH4 (SO4)2 d. A and B
_____3. Standard solutions are also known as:
a. Test solutions c. Saturated solutions
b. Volumetric solutions d. NOTA
_____4. The end point in using ferric ammonium sulfate is:
a. White precipitate c. Pink color
b. Red-brown color d. Blue color
_____5. The name of originator who introduced the adsorption dyes as an indicator in volumetric precipitation
method:
a. Volhard b. Liebig c. Mohr d. Fajans
_____6. Ferric alum TS is used as indicator in volumetric precipitation method if the titrant is:
a. AgNO3 b. BaCl2 c. NH4SCN d. NH4Cl
_____7. This is an absorption indicator method where the endpoint reaction occurs on the surface of the AgCl
precipitate.
a. Mohr Method b. Fajan’s Method c. Volhard Method d. None of the choices
_____8. Indicator used in Fajan’s method
I. Eosin Y
II. Dichlorofluoroscein
III. Tetrabromofluroscein
IV. Dithizone
a. I and III b. I and II c. I, II and III d. I, II, III and IV
_____9. The endpoint in Fajan’s method is
a. Change in color of solution c. Appearance of turbidity
b. Change in color of ppt d. Cessation of turbidity
_____10. Sodium chloride (MW:58.44) is assayed using the Volhard method of USP IX. Fifty mL of 0.1 N Silver nitrate
VS was delivered. The back titration involved 26.50 m: of 0.1 N Ammonium thiocynate VS. Determine the % purity
If the sample weighs 0.1853 g.
a. 83.53 b.74.11 c. 37.06 d. 50.32
(N x ml)agno3 - (n x ml) nh4scn) x meq. wt Nacl x100 / sample weight
(0.1 N x 50 mL) - (0.1 N x 26.50 mL ) x 0.058441x 100 / 0.1853
= 74.1
_____ [Link] following indicators are used in volumetric precipitation except:
a. Tetrabromophenolphthalein ethyl ester TS (TEE) c. Ferric alum
b. K2CrO4 d. None of the above
_____ 12. In the Volhard method of precipitation of mercury compounds, nitric acid is used to acidify the solution.
Why is this so?
a. To prevent the hydrolysis of ferric salts c. To prevent the hydrolysis of the ferrous ion
b. To promote the hydrolysis of ferric salts d. To promote the hydrolysis of ferrous ion
_____ 13. Adsorption indicators are used in:
a. Complexation reaction c. Acidimetry
b. Volumetric precipitation d. Alkalimetry
_____ 14. Silver nitrate (169.87) is used to precipitate silver chloride (143.32) in the gravimetric assay of NaCI
(58.44). What is the gravimetric factor?
a. 2.4524 b. 0.3440 c. 0.8347 d. 0.4078
_____ 15. Precipitation method using potassium chromate test solution as indicator and silver nitrate standard
solution:
a. Volhard b. Fajan c. Mohr d. None of the above
For nos. 16-20: Match the use/s of the following with their corresponding chemical substance/s in the Assay of
Sodium Lauryl Sufate for NaCl Content:
a. primary standard c. indicator e. secondary standard
b. neutralizing agent d. Solvent
A 16. Sodium lauryl sulfate
D 17. Distilled water
B 18. Dilute nitric acid
C 19. Potassium chromate TS
E 20. Standard silver nitrate solution
Quiz on REDOX
Direction: Write letter only for multiple choice questions, for problem solving, please include
your solution/s / computations according to our format (a) given; b) formula/s c) solution/s d)
final answer
1. An oxidizing agent:
1. Gain Electron c. Loss Electron
2. Valence Decrease d. Involves reduction
2. To compute for the equivalent weight of an oxidizing agent, divide the Molecular weight
by its:
a. # of electrons gained
b. # of electrons lost c. sodium thiosulfate d. ceric sulfate
3. A reducing agent:
a. potassum dichromate
b. potassium ferricyanide
c. valence of cation
d. # of replaceable H+
c. sodium thiosulfate d. ceric sulfate
4. To compute for the milliequivalent weight of TiCl3, divide the Molecular weight by:
a. 1000 c. 4000
b. 2000 d. 5000
5. The number of electrons gained by KBrO3 as an oxidizing agent:
a. 2000 c. 5000
b. 4000 d. 6000
6. Assay of Hydrogen peroxide involved this method of analysis:
a. Direct titration c. Permanganometry
b. Residual titration d.a&c e.b&c
7. In the assay of cherry juice for malic acid, this ion was liberated and oxidized with
KMnO4:
a. Ca+2 c. Oxalate
b. Malate d. MnO4
8. Assay of Ferrous Sulfate Tablets involves this method of analysis:
a. Cerimetry c. Iodimetry
b. Permanganometry d. Iodometry
9. The primary standard used to standardize a solution of dichlorophenol-indophenol:
a. NaNO2 c. H2O2
b. Ascorbic acid RS d. Sulfathiazole
[Link] this method of analysis, the sample of oxidizing agent is reduced with excess potassium
iodide and an equivalent amount of iodine is produce:
a. Cerimetry c. Iodimetry
b. Permanganometry d. Iodometry
11. The interaction of iodine and iodide ion with the colloidal beta-amylose in starch, result in
the production of an intensely blue-colored sol. The disappearance of blue color during
titration is due to the oxidation of iodine with __?__ or another reducing agent.
A. Potassium permanganate c. oxalic acid
B. sodium thiosulfate d. potassium bromate
12. The primary standard used in the standardization of Iodine solution:
A. Arsenic trioxide c. Sodium bicarbonate
B. Potassium iodide d. Potassium dichromate
13. The following compounds are assayed indirectly (iodometry):
A. Assay of Selenium Sulfide c. Assay of Ascorbic acid
B. Assay of Sodium Hypochlorite Solution d. Assay of Cupric Sulfate
14. The secondary standard used in the assay of ascorbic acid:
a. Na2S2O3 b. I2 solution
c. KMnO4
d. Br2 solution
c. Direct - Iodometry
d. Residual - Iodometry
15. Assay a. b.
16. Assay a. b.
of phenol involved: Direct – Iodimetry Residual – Iodimetry
of the sulfa drugs and other compounds containing an aryl amino group by:
a. Cerimetry c. Diazotization
b. Permanganometry d. Iodometry
17. The primary standard in the standardization of 0.1M Sodium Nitrite Solution:
1. Sulfanilamide RS c. Ascorbic acid RS
2. Sulfathiazole RS d. FeSO4 RS
18. Chemical reactions that involves a change in the valence number of reacting substances:
a. Neutralization b. Complexation c. Precipitation
19. Malic acid present in apple juice may be determined by: a. Indirect permanganate oxidation
method
b. Direct permanganate oxidation method
20. Iodimetry is an indirect analysis of:
a. Reducing agents b. Oxidizing agents
d. Oxidation-Reduction
c. Alkalimetry d. Acidimetry
c. Acids d. Bases
21. In the given reaction, what is the valence of Cr before and after the chemical
reaction?
K2Cr2O7 + 6KI +14 HCl 3I2 + 2CrCl3 + 8KCl + 7H2O
a. +5; +2 c.+6 ;+3 b. +6; +2 d.+7 ;+3
22. What is the valence of I after the chemical reaction? HOCl + 2KI + CH3COOHI2 +
CH3COOK + H2O
a. 0 b.+1 c.-1 d.+2
23. What is the valence of I after the reaction? I2 + C6H8O6 2HI + C6H6O6 a. 0 b.+1 c.-
1 d.+2
24. A 1100mg sample of sodium nitrite was dissolved in sufficient water to make 100ml. A 10ml
sample of the solution was added to 50.00 ml of 0.1N potassium permanganate in the presence
of sulfuric acid. The mixture was treated with 25.00ml of 0.0975N oxalic acid and titrated with
4.58ml of 0.1N potassium permanganate. Calculate the % NaNO2 in the sample.
Na = 23 N = 14 O = 16
25. A. 5.00 ml sample of hydrogen peroxide solution required 21.25ml of a permanganate
solution in titration. If each ml of the permanganate solution is equivalent to 0.007295g of Fe,
what % w/v of H2O2 was in the sample?
Fe= 55.86 H=1 O=16
For nos. 26-27: How much oxalic acid (H2C2O4 with 2H2O) is required to prepare 1000ml of
solutions of the following respective normalities:
H = 1 C = 12 O = 16 _____ 26. 0.5000N
_____ 27. 0.2500N _____ 28. 0.200N
1. Spearmint belong to which division of volatile oil? KETONE
3. Specific gravities of oils may be influenced by what factors?:
i) the maturity of the plant from which the oils is obtained,
ii) the age of the oil, and
iii) the methods of preparation and purification.
3. Examples of Oils lighter than water: Orange, Caraway, Coriander, Lemon, Turpentine, and
Rosemary oils.
4. The rotatory power of volatile oils is measured using Laurent half-shadow polarimeter
5. The property of volatile oil which serve in the detection of extraneous matter in the oil
sample: Refractive index.
For nos. 6-7: (10pts)
Problem: If a 7.120g sample of peppermint oil, refluxed w/ 25mL of about 0.5N
alcoholic KOH, required 20.32mL of 0.4900N HCl for the residual
titration. The blank was run using the same volume of 0.5N alcoholic
KOH and required 24mL of 0.4900N HCl to bring about the end point.
(Menthyl acetate = 0.19831g/meq)
Calculate the following:
(Show the 2 methods of computations for #6-7)
6. The number of meq of KOH required to saponify the total esters calculated as
menthyl acetate:
7. The percent menthyl salicylate.
8. 6-7. Given: Wt of peppermint oil sample= 7.120g, vol KOH= 25mL N KOH= 0.5N, vol HCl actual=
20.32mL, vol HCl blank= 24mL N HCl= 0.4900N, Menthyl acetate = 0.19831g/Meq
1st Method
i) 24ml x 0.4900N = 11.76meq HCl 20.32ml x 0.4900N = 9.9568 meq HCl 11.76 meq - 9.9568 meq
= 1.8032 meq of KOH
ii) 1.8032 meq x 0.19831g/meq = 0.3576g menthyl acetate
iii) 0.3576g / 7.120g x 100 = 5.02% w/w
iv) [(24ml - 20.32ml) x 0.4900N x 0.19831g/ Meq] /7.120g x 100 = 5.02% w/w
2nd Method
i) (24ml x 0.4900N)/ 0.500N = 23.52ml (20.32ml x 0.4900N)/ 0.500N = 19.91ml 23.52ml -19.91ml =
3.61ml
ii) 3.61ml x 0.09916g/ml = 0.3580g
iii) 0.3580g / 7.120g x 100 = 5.03% w/w
iv) [(24ml - 20.32ml) x 0.4900N x 0.19831g/ Meq] /7.120g x 100 = 5.03% w/w
For Nos. 8-15. Determine the method/s of Assay of Volatile Oil component
of the following sample:
Method of Assay
8. Cardamon Seeds STEAM DISTILLATION
9. Lemon Oil STEAM DISTILLATION
10. Menthol DIRECT STEAM DISTILLATION
11. Myristica oil REFLUX
12. Eucalyptus DIRECT STEAM DISTILLATION
13. Oil of wintergreen STEAM DISTILLATION
14. Thymol WATER AND STEAM DISTILLATION
15. Orange Oil STEAM DISTILLATION
