CONFIDENTIAL TOT1/FEB2020/CHE553
UNIVERSITI TEKNOLOGI MARA
TUTORIAL 1
COURSE : CHEMICAL ENGINEERING THERMODYNAMICS
COURSE CODE : CHE553
DATE : 25/2/2020
TIME : 1 WEEK
INSTRUCTIONS TO CANDIDATES
1. This question paper consists of two (2) questions.
2. Answer ALL questions in the Answer Booklet. Start each answer on a new page.
3. Do not bring any material into the examination room unless permission is given by the
invigilator.
1.
Name:
2.
1
Student No.:
2
Group:
Question 1 /4
Question 2 a) / 10
Question 2 b) / 10
Marks:
Total / 24
Date of submission: 10th March 2017 before 5.00 pm
1. Using your own word, explain in detail the following item:
a. Three dimensional VLE phase diagram for a binary system
b. Azeotrope condition
2. A process stream contains light species 1 and heavy species 2. A relatively pure liquid stream
containing mostly species 2 is desired, obtained by a single-stage liquid/vapor separation. The
Date of submission: 10th March 2017 before 5.00 pm
equilibrium compositions are x1 = 0.002 and y1 = 0.950. Determine T(K) and P(bar) for the
separator. Assume that modified Raoult’s law applies. Use data given below. The calculated P
should validate this assumption.
For the liquid phase,
ln 1 0.93x22 ln 2 0.93x12
B
ln Pi sat bar Ai i
T K
A1 10.08, B1 2572, A2 11.63, B2 6254
3. A feed containing equimolar amounts of acetone(1)and acetonitrile(2) is throttled to pressure P
and temperature T. For what temperature range will two phases (liquid and vapor) be formed for
P = 1 bar. Assume that modified Raoult’s law applies. Activity coefficients are given by:
ln 1 Ax22 ln 2 Ax12 where A 2.573 0.00126T
(Show details calculation. Calculate pressure and temperature to two decimal places; A, and
mole fraction to four decimal places. )
4. The stream from a reactor is a mixture of 388 kmol/h methane, 388 kmol/h propane and 55
kmol/h cyclohexane. This stream is fed into a partial condenser maintained at a pressure of 17
bar, where its temperature is brought to 30°C (303.15 K). Determine the flow rate of the vapor
that condenses and the compositions of the vapor phase leaving the condenser.
5. An equimolar stream containing ethanol and methanol is fed to a flash separator operating at 75 oC
(348.15 K). Assuming the fraction of liquid produced at the exit stream is 40% from the feed in one
mole basis,
a) Determine the pressure at which this separator should be operated. [Hint the pressure is
between 113 kPa and 115 kPa]
b) Determine the composition of liquid and vapor phases at the exit stream.
Date of submission: 10th March 2017 before 5.00 pm