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VLE and Enthalpy Data for Distillation

The document contains data and calculations for vapor-liquid equilibrium (VLE) of a distillation system. Tables provide mole fraction (x,y) data, boiling point and enthalpy values across the range of x from 0 to 1. The relative volatility of the system, heat capacities, latent heats and reference temperatures are entered. A plot of concentration versus enthalpy is shown, along with the vapor-liquid equilibrium curve and its fitted equation.

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akhil
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28 views8 pages

VLE and Enthalpy Data for Distillation

The document contains data and calculations for vapor-liquid equilibrium (VLE) of a distillation system. Tables provide mole fraction (x,y) data, boiling point and enthalpy values across the range of x from 0 to 1. The relative volatility of the system, heat capacities, latent heats and reference temperatures are entered. A plot of concentration versus enthalpy is shown, along with the vapor-liquid equilibrium curve and its fitted equation.

Uploaded by

akhil
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLS, PDF, TXT or read online on Scribd

Data to be entered

Calculated values.
All data are for the more volatile I.e low boiling component

Enter the relative volatility of the system to be distilled = A = 2.5


Table for VLE Plot
x y x y y x
0.00 0.00 0.00 0.00 0.00 0.00
0.10 0.22 0.10 0.10 0.12 0.10
0.20 0.38 0.20 0.20 0.18 0.20
0.30 0.52 0.30 0.30 0.22 0.30
0.40 0.63 0.40 0.40 0.23 0.40
0.50 0.71 0.50 0.50 0.21 0.50
0.60 0.79 0.60 0.60 0.19 0.60
0.70 0.85 0.70 0.70 0.15 0.70
0.80 0.91 0.80 0.80 0.11 0.80
0.90 0.96 0.90 0.90 0.06 0.90
1.00 1.00 1.00 1.00 0.00 1.00

Enter the value of specific heat of [Link] = cp = 0.38 Kcal/Kg.C


Enter the value of specific heat of [Link] = cp = 0.4 Kcal/Kg.C
Latent heat of vaporization of MVC = L1 = 95 Kcal/Kg
Latent heat of vaporization of LVC = L2 = 86 Kcal/Kg
Boling point temp of pure LVC. = 110
Boling point temp of pure MVC. = 80 C
Reference temp. = 0 C

Table for enthalpy calculation

x y Ki Bub point Dew point Hl Hg


0.00 0.00 0 110 110 44 130
0.10 0.22 2.17391 108 105 43 130
0.20 0.38 1.92308 106 102 42 129
0.30 0.52 1.72414 103 98 41 129
0.40 0.63 1.5625 100 94 39.2 128
0.50 0.71 1.42857 97 88 38 126
0.60 0.79 1.31579 94 89 36 127
0.70 0.85 1.21951 90 86 35 127
0.80 0.91 1.13636 87 85 33 127
0.90 0.96 1.06383 83 84 32 127
1.00 1.00 1 80 80 30.4 125.4

Conc. vs. Enthalpy plot.


200

150
Conc. vs. Enthalpy plot.
200

150

H (Enthalpy)

100

50

0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

vap-liq equilibria

1.00
f(x) = - 0.6950971233x^4 + 2.1635002374x^3 - 2.8846809046x^2 + 2.4147700572x + 0.0008446558
f(x) = x - 1.33897934774369E-16
0.90
0.80
0.70
0.60
0.50
y

0.40
0.30
0.20
0.10
0.00 x
[Link].[Link].[Link]
0.50
0.40
0.30
0.20
0.10
0.00 x
[Link].[Link].[Link]
12/3/2003

ot.
ot.

0.70 0.80 0.90 1.00

+ 2.4147700572x + 0.0008446558
-16

[Link].00
[Link].00
data to be entered
Calculated values.

x y
0.1
0.2
0.3
x-y PLOT
0.4 1
0.5 0.9
0.6
0.8
0.7
0.8 0.7
0.9 0.6
1.0
0.5 Colum
y
0.4
0.3
0.2
0.1
0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x
12/3/2003

Column C

.7 0.8 0.9 1

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