A piston-cylinder device initially contains 2L of air at 100 kPa and 25C.
Air is now
compressed to a final state of 600 kPa and 150C. The useful work input is 1.2 kJ.
Assuming the surroundings are at 100 kPa and 25C, determine (a) the availability of the air
at the initial and final states, (b) the minimum work that must be supplied to accomplish the
compression process, and (c) the second-law efficiency of this process.
P1 100 kPa
Pcrut air 3.76 MPa
P2 600 kPa
Air can be treated as ideal
T1 298 K
Tcrut air 133 K
T2 423 K
mass of air in system
P2 = 600 kPa
P11 100 2 10 3
m T2 = 423 K
RT1 0.287 298
m 0.00234 kg Air System boundary
1 =2L
P1 = 100 kPa
T1 = 25C = 298 K
specific volumes
RT2 0.287 423 RT0 0.287 298
v2 0.2023 m 3 / kg , v 0 0.8553 m 3 / kg
P2 600 P0 100
internal energies
u 2 300.73
308.03 300.73423 420 302.92 kJ / kg
430 420
(214.09 206.92)( 298 290)
u 0 206.92 212.66 kJ / kg
(300 290)
Entropy difference
P2
s 2 s 0 s 2 s 0 Rn
P0
(7.0651 7.0412)( 423 420)
s 2 7.0412 7.0484 kJ / kg K
(430 420)
(6.7018 6.678)( 298 290)
s 0 6.6678 6.6950 kJ / kg K
(300 290)
600
s 2 s 0 7.0484 6.6950 0.287 n 0.1608 kJ / kg K
100
Availabilities
(a) 1 m1 m(u 1 u 0 ) P0 (v1 v 0 ) T0 (s1 s 0 )
P1 = P0 , u1 = u0 , v1 = v0 , s1 = s0 (i.e. system is at the dead state) 1 0
2 m(u 2 u 0 ) P0 (v 2 v 0 ) T0 (s 2 s 0 ) m 2
(0.00234)(302.92 212.66) 100(0.2023 0.8553) 29(0.1608)
2 0.1705 kJ
Minimum work to accomplish compression
– minimum will be supplied if the compression process is internally reversible
(b) Wrev 1 2 m(1 2 ) (0 0.1705) Wrev 0.1705 kJ
Indicates work input
(c) Second-Law Efficiency
Wrev 0.1705
compression 0.142 (14.2%)
Wusesful 1.2