CONV(PROP) INPUT(PROP)

0.801 337.79

PRODUCT

C3H3N 270.57
H2O 811.71

PRODUCT

C2H3N 10.641
C3H3N H2O 21.282
ATERIAL C3H6
ALANCE NH3 PRODUCT

ON O2 HCN 27.36

ACTOR C2H3N
H2O 54.72

LUID BED) H2O PRODUCT

C3H4O CO2 108.432

H2O 108.432
HCN
PRODUCT
N2
C3H4O 9.12
HCN H2O 9.12

converision product
0.005
1.353 C4H4N2 1.353

1.353

a 1.353
 y1 0.0016026
y2 0.0018032

0.019
0.018
0.017
0.016
0.015
0.014
0.013
0.012
0.011
0.01
0.009
0.008
0.007
0.006
0.005
0.004
0.003
0.002
0.001
 0.008
0.007
0.006
0.005
0.004
0.003
0.002
0.001
0
0 0.0005 0.001 0.0015 0.002 0.0025 0.003 0.0035

eq.c

ABSORBER MATERIAL BALNCE

total input kmol/h

total inpu kg/h total out kg/h
Tot(out)
20521.095 539949.58 539950.46 20521.1

BSORBER(KG/H)
 kmol/h kg/h
HCN 25.74693 697.278
CO2 0.005 0.22005
C3H3N 2.689 142.689
NH3 96.777 1648.499
C3H6 1.444 60.761
C2H3N 10.53459 432.48706
total total
137.19652 2981.9341

O.M.B
component input(Kmol) out(kmol) IN OUT
C3H3N 0 266.55441 0 14144.443
C3H6 337.79 8.40459 14213.528 353.64834
O2 3209.005 2593.381 102688.16 82988.192
N2 12071.97 12071.971 338256.6 338256.63
H2O 0 952.61225 17162.262
NH3 405.348 96.777 6904.6978 1648.4994
C3H4O 0 9.12 510.73824
HCN 0 25.74693 697.27836
C2H3N 0 0.1053459 4.3248706
CO2 0 108.432 4772.0923
C4H4N2 0 1.353 108.35906

16024.113 16134.458 462063 460645.67

‫الكلي لمعدات‬
O.M.B KG/H
IN 539949.58
OUT 539950.45

16024.114
16602.048
uction capacity(ton/year) operating time(day) production(kg/h) production(kmol/h)
350 14285.714 269.217
supplied
337.79
405.348
3209.005
CONVERSION out
0.801 can 270.57

CONVERSION
0.021
7.094
10.641
10.641
MATERIAL
CONVERSION
C3H6
BALANCE
0.027
9.12 NH3 ON
27.36
27.36 O2 REACTOR
(FLUID BED)
CONVERSION
0.107
36.144
162.648

CONVERSION
0.027

reaction6
[Link](G/MOL) NAME
C3H3N
42.078 PROPENE
53.064 ACRYLONITRILE HCN
32 OXYGEN
28.02 NITROGEN
41.054 ACETONITRILE
44.01 CARBON DIOXIDE
18.016 WATER
 17.034 AMMOUNIA
56.002 ACROLEIN
27.082 HYDROGEN CYANIDE
80.088

IN (KMOL/H)
IN(KG/H) OUT(KMOL/H) OUT (KG/H)

0 269.217 14285.731
337.79 14213.528 5.742 241.612
3209.005 102688.16 2593.381 82988.192
12071.971 338256.627 12071.971 338256.63
0 1005.264 18110.836
405.348 6904.698 96.777 1648.499
0 9.12 510.738
0 0 26.007 704.322
0 0 10.641 436.856
0 108.432 4772.092
0 1.353 108.359
TOTAL INPUT(KMOL/H)
TOTAL INPUT(KG/H) TOT(KMOL/H) TOTAL OUTPUT(KG/H)
16024.114 462063 16197.905 462063

aterial balance on Absorber

5.4434
y X Y
0 0 0 x1 0.008785961
0.0054434 0.001001001 0.0054731928 x2 0.009895073
0.0059877 0.0011012113 0.006024
0.0065321 0.0012014417 0.0065750286 slope 0.180939346
0.0070764 0.0013016922 0.0071268526
0.0076208 0.0014019627 0.007679282
0.0081651 0.0015022534 0.0082323177 0.019
0.0087094 0.0016025641 0.0087859608 0.018
0.0092538 0.0017028949 0.0093402123 0.017
0.0097981 0.0018032458 0.0098950731 0.016
0.0103425 0.0019036169 0.0104505443 0.015
0.0108868 0.002004008 0.0110066269 0.014
0.0114311 0.0021044193 0.011563322
0.013
0.0119755 0.0022048507 0.0121206304
0.012
0.0125198 0.0023053022 0.0126785532
0.011
0.0130642 0.0024057739 0.0132370915
0.01
0.0136085 0.0025062657 0.0137962462
0.009
0.0141528 0.0026067776 0.0143560184
0.008
0.0146972 0.0027073097 0.0149164092
0.0152415 0.002807862 0.0154774194 0.007
0.0157859 0.0029084345 0.0160390502 0.006
0.0163302 0.0030090271 0.0166013026 0.005
0.004
0.003
0.002
0.001
 0.008
0.007
0.006
0.005
0.0168745 0.0031096399 0.0171641776 0.004
0.0174189 0.0032102729 0.0177276763 0.003
0.002
0.001
0
0 0.0005

Gm(2) Kmol/h y(1) Y(1) kg/h

C3H3N 0.269 1.8177061E-05 1.818E-05 14.274
H2O 10.053 0.0006793085 0.0006798 181.115
N2 12071.971 0.8157358885 4.4269928 338256.627

CO2 108.427 0.0073267071 0.0073808 4771.872

C4H4N2 1.353 9.1425887E-05 9.143E-05 108.359
O2 2593.381 0.1752418022 0.2124766 82988.192
C3H6 4.298 0.0002904275 0.0002905 180.851
C3H4O 9.12 0.0006162632 0.0006166 510.738

tot total (kg/h)

14798.872 427012.028

water out 5328.45 error% 0.4

‫التقريب مرتبتين‬

Lm(1) Kmol/h x(1) X(1) BOTTOM ABSORBER(KG/H)

C3H3N 268.948 0.047000615 0.0493186205 14271.457
HCN 26.007 0.004544912 0.0045656625 704.322
C2H3N 10.641 0.001859592 0.0018630565 436.856
H2O 5318.401 0.9294291746 13.170161606 95816.312
NH3 96.777 0.0169124831 0.017203436 1648.499
CO2 0.005 8.7378629E-07 8.7378705E-07 0.22
C3H6 1.444 0.0002523495 0.0002524132 60.761

total kg/h
 112938.43
1
Tot(out)
5722.223

kg/h
4.3248706 TOTAL 952.9063653
948.58149

componentamount %
C3H6 1.444
H2O 53.18401
HCN 26.007
C3H3N 268.948 Distillation
CO2 0.005 (3)
NH3 96.777
c2h3n 10.53459
total kmol/h totalout d3
456.8996 456.8996

kg/h
93909.568 total

0.0436856

total
93909.612

kmol/h kg/h
C3H3N 263.59641 13987.48

H2O 0.5318401 9.582

total total kg/h
264.1282501 13997.062

269.217

kmol/h kg/h
C3H3N 2.66259 141.28767576
H2O 52.6521699 948.581
HCN 0.26007 7.04321574
total
TOTAL 1096.9118915
55.5748299

462063
462063.87003
production capacity(ton/year)
120000
composition
C3H6 1
NH3 1.2
O2 9.5
REACTION(1)

C3H6 270.57
NH3 270.57
O2 405.855

REACTION2

C3H6
NH3
O2

REACTION3

C3H6
NH3
O2

REACTION4

C3H6
O2

REACTION5

C3H6 9.12
O2 9.12

COMPONENT

C3H6
C3H3N
O2
N2
C2H3N
CO2
H2O
 NH3
C3H4O
HCN
C4H4N2

COMPONENT

C3H3N
C3H6
O2
N2
H2O
NH3
C3H4O
HCN
C2H3N
CO2
C4H4N2

Material balance on
H
x
0
0.001
op.l 0.0011
Y1 0.01688 0.0012
Y2 0.0000166 0.0013
X1 0.0031096399 0.0014
X2 0 0.0015
0.0016
0.0017
0.0018
0.0019
0.002
0.0021
0.0022
0.0023
0.0024
0.0025
0.0026
0.0027
0.0028
0.0029
0.003
 0.0031
0.0032

X(2) Lm(2)
1 water 4323.1896

WATER(KG/H)
77886.584

Absorb
er
water in 5328.454

INPUT kh/h Gm(1) kmol/h y(1) Y(1)

C3H3N 269.217 0.0166205 0.016901392
C3H6 5.742 0.0003545 0.000354616
O2 2593.381 0.160106 0.1906263681
N2 12071.971 0.7452798 2.925875935
H2O 1005.264 0.0620614 0.0661678243
NH3 96.777 0.0059747 0.0060105727
 C3H4O 9.12 0.000563 0.000563353
HCN 26.007 0.0016056 0.00160816
C2H3N 10.641 0.0006569 0.0006573687
CO2 108.432 0.0066942 0.0067393133
C4H4N2 1.353 8.353E-05 8.35363E-05
tota in absorber (kg/h)Gm(tot) 16197.905

kmol/h
CRUDE C2H3N 0.1053459
h20 52.65217
0.99 total
52.757516

weight
60.761
958.163
704.322
14271.457
Distillation 0.22
weight componentAmount % (2) 1648.499

4.3685561 C2H3N 0.10641 2.020959E-05

94858.149 H2O 5265.217 0.9999798683
totl in kmol 1.0000000779
5265.323

total out d2 kmol/h

5265.3234

H2O kmol/h
5212.5648
C2H3N
0.0010641

total
5212.5659

C3H3N
 Distillation
(4)

total out d4

IMPURITIES
 y1 0.0166204827
y2 1.6620483E-05

Gm" 15928.688

slop=lm(min)/Gm" lm(min)(kmol/h) 2882.1264

Lm(act) 4323.1895857

n(solute)⁼(wt*Mwt of H2O*nH2O)/100*Mwt of solute

3321.7674 33.217674
0.4 0.0071426
coponent boiling poit
C3H3N 350.15
HCN 299.15 INPUT kh/h
C2H3N 355.15 14285.731
H2O 373.15 241.612
NH3 239.75 82988.192
CO2 194.65 338256.63
C3H6 225.15 18110.836
1648.499
 510.738
704.322
436.856
4772.092
108.359
tota in absorber (kg/h
462063

Distillation
WEIGHT(kg/h)
component amount(kmol/h) % (1)
0.22 CO2 0.005 8.7378629E-07
60.761 C3H6 1.444 0.0002523495
1648.499 NH3 96.777 0.0169124831
14271.457 C3H3N 268.948 0.047000615
436.856 C2H3N 10.641 0.001859592
704.322 HCN 26.007 0.004544912
95816.312 H2O 5318.401 0.9294291746
TOT inpt kmol/h
5722.223 1

total out kml/h

5722.22301
 kmol/h
C3H3N 266.259
H2O 53.18401

HCN 0.26007
total in
319.70308

total out d4
319.70308
component solubility H2O(gm)
C3H3N soluble 77817413 77817.413
C3H6 44.6 cc
O2 3.36cc
N2 insoluble
H2O -
NH3 72.7125ppm
C3H4O 40 cc
HCN soluble
C2H3N soluble
CO2 0.1688cc
C4H4N2 insoluble

n(solute)⁼(wt*Mwt of H2
density of gas⁼p*Mwt/R*T

d(C3H6) 1.7502257 v(C3H6) 34706566 34.706566 n(NH3)

d(O2) 1.3310334 v(O2) 2614665 2.6146651 n(C3H4O)
d(Co2) 1.8305869 v(co2) 131355.79 0.1313558
wt(C3H6) 60.744324 n 1.4436124
wt(o2) 3.4802065 n 3.4802065
wt(CO2) 0.2404582 n 0.0054637