Extended Aeration in Sugar Wastewater Treatment
Extended Aeration in Sugar Wastewater Treatment
Submitted By:
MEMBERS
Mora, Roxan B.
Tangonan, Visitacion D.
Ventula, Lea B.
Submitted To:
DECEMBER 2017
TABLE OF CONTENTS
I. Introduction .......................................................................................................................... 3
1
NOMENCLATURE
Q Volumetric flowrate
X Denoted as MLVSS
S BOD Initial
V Volume
Y Yield Velocity
h Effective Depth
2
I. INTRODUCTION
The extended aeration process is one modification of the activated sludge process which
provides biological treatment. The process maximizes the stability of the operating
environment and provides high efficiency treatment. The system utilizes a longer sludge age
than other aerobic systems. Sludge age, also known as SRT (Solids Retention Time) or
MCRT (Mean Cell Residence Time), defines the operating characteristics of any aerobic
biological treatment system. A longer sludge age dramatically lowers effluent BOD and
ammonia levels, especially in colder climates. The systems long sludge age process produces
BOD levels of less than 10 mg/L and complete nitrification (less than 1 mg/L ammonia).
Minor modifications to the system will extend its capabilities to denitrification and biological
phosphorus removal. The large quantity of biomass treats widely fluctuating loads with very
few operational changes. Extreme sludge stability allows sludge wasting to non-aerated
sludge ponds or basins and long storage times.
The effluent generated from sugar processing industry has miscellaneous quality because
it contains high BOD and constitutes a number of chemical pollutants, such as oil and grease,
carbonate, bicarbonate, nitrite, phosphate, leading to high COD, in addition to total
suspended solids, dissolved solids, volatiles and scopes of other toxicants. These can harm
the environment if discharged irresponsibly.
This paper will give emphasis on the process of activated sludge using extended retention
of biological solids to create an extremely stable, easily operated system. It will discuss the
advantages of the process as well as the functionality of the treatment process under extended
aeration activated sludge such as aeration and clarification in the wastewater treatment plant.
Moreover, calculations in the process and mechanical designs of this treatment processes
were also included in the plant design.
II. OBJECTIVES
Generally, this section aims to develop a design in the process of an extended aeration to
be used in the secondary treatment of the sugar industry wastewater. Specifically,
1. The process to be used must lower the biodegradable organic matter and suspended
solids to an effluent quality standard of 50 mg/L and 100 mg/L, respectively;
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2. The equipment to be used must be able to cater the influent flow rate of 750 m3/day;
and,
3. The process and design of conventional activated sludge must be able to achieve the
effluent standards at the most desirable time.
A. PRINCIPLE
4
b. Constant Food to Microorganism
This method, the MLVSS concentration is increased or decreased to match an
increase or decrease in the BOD entering a plant, so as to maintain a certain desired
F/M ratio. The use of this method presupposes the knowledge of the organic (BOD)
load present and the MLVSS concentration. While the latter parameter could be
measured readily at any time, real-time data regarding the former parameter are not
available (BOD7 analysis takes 7 days). This organic load can sometimes be
approximated by making use of chemical oxygen demand (COD) or total organic
carbon (TOC) measurements combined with BOD/COD or BOD/TOC correlations.
As can be imagined this method requires a large amount of laboratory work. An
additional disadvantage of this method is that the MLVSS is not an accurate measure
of active mass of microorganisms, among other' things, dead cells (unlysed once) are
registered in volatile solids test. As a result, even with a constant BOD7/MLVSS ratio,
there is no assurance that the F/M ratio is constant.
5
sample easily can establish the desired waste flow rate to be used to accomplish the
wasting of a certain quantity of sludge solids.
Another way of control of a plant through MCRT is by wasting sludge direct
from the aeration tank. This process of wasting mixed liquor rather than return sludge
is called hydraulic control of the activated sludge system.
This control method is easier yet than the previous one. If a steady state is
achieved i.e. solids produced equal those wasted both intentionally and
unintentionally, control through MCRT could be achieved by simply wasting a
constant percentage of the mixed liquor in the aeration tank (reactor) each day.
The hydraulic control system is self-regulating. As the concentration of the
MLSS increases, the mass of solids wasted also increases, lowering the MLVSS
concentration over a period of time. If the MLSS concentration decreases below the
level dictated by the selected MCRT, the mass of solids wasted decreases, raising the
MLVSS concentration over time. The hydraulic control system lends itself to
automation readily and is the simplest system to control. This method of controlling a
treatment process results in stable operation of the process because there will be less
variation in the F/M ratio and MCRT than the other control methods.
6
According to McCarty and Brodersen, the sludge recycle rate may be formulated as
follows:
R V
R 1 1000
Where; f.
2. Substrate Stabilization
The biological removal and stabilization of organic wastes in an activated sludge
process is shown in Figure III.1, this conversion of organic wastes into end-products
can be thought to take place in two different stages, which occur simultaneously in the
same tank.
CO2 +H2O
+
Degradable Energy
Organic Waste
New Bacterial
Cells Inert Organic
Residue
7
First the degradable organic wastes are metabolized and partially used for
energy and partially synthesized into new microbial cells. With continued aeration, in
the second stage, the microbial cells formed (their protoplasm) are metabolized for
further energy (this so-called endogenous phase takes place when substrate
concentration is at a minimum). The active biological solids utilize oxygen while
undergoing endogenous respiration to oxidize the degradable portion of their cells to
carbon dioxide and water with a resulting decrease in sludge mass. Ideally, with
extended aeration this sludge mass would continue to oxidize itself to carbon dioxide
and water so that no net sludge accumulation would occur in the system. However, it
has been found out that some of the biological solids produced are relatively inert to
biological oxidation and so accumulate in the system. As a result, with continuous
operation and no sludge wasting intentional or unintentional (controlled sludge
wastage or loss of biological solids to the effluent), from an extended aeration system
an increase in mixed liquor volatile solids (MLVSS) will result.
The total accumulation of sludge in the system will be equal to the
accumulation of biological solids plus the accumulation of biologically degradable
suspended solids which were originally present in the influent waste.
In extended aeration plants where controlled sludge wasting is not practiced,
the solids will increase until the system capacity to settle and retain the solids is
exceeded. The excess solids produced will then be discharged to the effluent, resulting
in an increase in effluent BOD and as a consequence a decrease in overall efficiency.
3. Nutrient Removal
a. Nutrient Requirements
Domestic wastewater contains more than a sufficient amount of nitrogen and
phosphorus, compared with carbon, for the correct balance of nutrients required for
bacterial growth. The question of nitrogen and phosphorus utilization must be
considered from two viewpoints; the minimal requirement and the extent of removal
in biological treatment.
To ensure maximum removal of carbon (and therefore BOD) from a given
substrate, carbon must be made the limiting nutrient, while nitrogen and phosphorus
(and other nutrients also) must be present in at least the minimum required proportion
for cell growth.
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Nutrient requirements in the conventional activated sludge process are higher
than those of the extended aeration process since, in the latter, there is more recycling
and less sludge withdrawal. It is suggested that the ratio of BOD7: N: P should be
about 100:5:1.
b. Phosphorus Removal
Phosphorus removal in biological treatment is due mainly to the removal of
microbial solids from the system. At steady state, the surplus microbial solids
removed equal those produced per unit time. Thus, it is necessary to estimate the net
volatile solids produced, and to know the phosphorus content of the solids.
Phosphorus removal from a given wastewater is a function of the MCRT of
the system. As MCRT increases, the phosphorus removal rate decreases since less
surplus sludge is removed from such a system. Thus, due to a higher MCRT, an
extended aeration process should give less phosphorus removal than conventional
activated sludge. Conversely when treating phosphorus-deficient wastewater, the
extended aeration process should require less artificial phosphorus addition than the
activated sludge process.
Generally, chemical precipitation is found to be a more efficient method of
phosphorus removal than biological treatment.
c. Nitrification
Most of the nitrogen in treated wastewater is in the form of ammonia.
Consequently, when wastewater containing ammonia is discharged to the
environment, depletion of recipient-water oxygen can occur as the ammonia is
oxidized to nitrate. This depletion of oxygen can be avoided if the ammonia is first
oxidized to nitrate before it is discharged Nitrification, which is the bio-oxidation of
ammonia to nitrate, is the process used to accomplish this objective. This conversion
of ammonia to nitrate is performed by nitrifying micro-organisms (either
heterotrophic or autotrophic) which are present in almost all aerobic biological
treatment processes, but usually their numbers are limited. In spite of the fact that
over one hundred species have been cited as forming nitrite (NO2-) from ammonia, it
is doubtful that significant quantities of nitrate are generated heterotrophically in
natural systems. Consequently, most research into nitrification in waste-water
treatment systems has concentrated on the autotrophic micro-organisms.
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The major nitrifying bacteria are thought genera Nitrosomonas and
Nitrobacter. These organisms obtain their cell carbon from carbon dioxide and energy
from the oxidation of inorganic compounds ammonia and nitrite/. Nitrosomonas
oxidizes ammonia nitrogen (NH4+-N) to nitrite (NO2- -N) through complex pathway
which is not yet completely understood, and remains largely speculative. Nitrobacter
oxidizes NO2- -N to nitrate nitrogen (NO3--N) in a single step. The theoretical
stoichiometric equations for the growth of Nitrosomonas and Nitrobacter are:
For Nitrosomous:
55 NH 4 76O2 109 HCO3 C 5 H 7 O2 N 54 NO2 57 H 2 O 104 H 2 CO3
For Nitrobacter:
400 NO2 NH 4 4 H 2 CO3 HCO3 195O2 C 5 H 7 O2 N 3H 2 O 400 NO3
These equations are important for two reasons. First, they tell us that a large
amount of alkalinity(HCO3-) will be utilized during the oxidation of NH4+-N: 8.64 mg
HCO3-/mg oidized NH4+-N. A small part of this will be incorporated into the cell
material, but the majority will be used to neutralize the hydrogen ions (pH) released
during the oxidation. If the water contains insufficient alkalinity, nitrification will be
retarded because of the unavailability of a needed reactant and the deleterious effect
of the resulting low pH. Efficient nitrification usually consumes alkalinity and
consequently causes pH depression. Secondly, they tell us that approximately 3.22 mg
O2 will be required for each mg oxidized NH4+-N to NO2- -N, and 1.11 mg O2 will be
needed for each mg NO2- -N of oxidized to NO3--N for a total of 4.33 mg 0 2 per mg
of oxidized NH4+-N all the way to NO3--N.
The nitrifying organisms are sensitive to their environment, and even under
favorable conditions they are slower growing than the usual BOD-removing micro-
organisms (heterotrophs). The former has a doubling time of 1 - 2 days while the
latter have typical doubling time of 0.25 - 1.5 hours 12.21. Since the growth rate of
Nitrosomonas is lower than that of Nitrobacter, it is the one that determines the rate of
nitrification.
It has been found out that the following factors have a significant effect on the
nitrification process: ammonia concentration, BOD/Total Kjeldahl Nitrogen (TKN)
ratio TKN NH 4 N N organic dissolved oxygen concentration, pH, temperature and
MCRT.
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Ammonia concentration in a reactor affects the growth rate of the nitrifying
organisms. It has been found out that the reaction that determines the growth of the
organisms proceeds at a constant rate (zero-order reaction) till the concentration of
ammonia reduces to about 1.5 to 2 mg/liter, below which the nitrification rate is
reported to drop off rapidly. When the wastewater to be treated contains a very high
concentration of NH4+-N, the concentrations of NO2- -N and NO3--N formed are likely
to be high enough to inhibit the organisms so that complete nitrification cannot occur,
even at very long MCRT’s. Jenkins and Garrison report that previous work has shown
that the rate of NH4+-N oxidation by Nitrosomonas is not limited by NH4+-N
concentration above 1 to 3 mg/L, the exact value depending on the temperature.
The choice of MCRT for an activated sludge treatment plant must take into
account the actual growth rate of nitrifiers at field conditions. Unless the MCRT is
somewhat greater than the cell doubling time, cell washout would occur.
1
MCRT
Where: µ is the growth rate for Nitrosomonas at the worst operating temperature and
other conditions.
Activated sludge plants in cold climates designed for MCRT less than 10 days
may show relatively poorer nitrification in winter. Extended aeration plants generally
designed for MCRT greater than 10 days may show nitrification uniformly over all
seasons. Even activated sludge plants in warm climates may show nitrification
uniformly, provided sufficient aeration capacity is available to meet the total oxygen
demand and maintain required high dissolved oxygen levels in mixed liquors.
Contact time between incoming ammonia and micro-organisms in the mixed
liquor must also be sufficient, besides appropriate MCRT, for successful nitrification.
Nitrifying bacteria are very sensitive to pH. The effects of pH on nitrifiers in
mixed cultures, such as activated sludge, are not quite as severe. A wide range of pH
optima have been reported, but most researchers agree that as the pH moves to the
acid range the rate of ammonia oxidation declines. pH ranges of 7.8 to 9.2 and 8.5 to
9.2 are thought to be optimum for Nitrosomonas and Nitrobacter respectively.
Temperature has a strong influence on the nitrification process. It affects the
growth rate of nitrifying bacteria just as it does heterotrophs.
Dissolved oxygen concentration (DO) in a reactor is one of the parameters that
could determine the extent of nitrification. Jenkins and Garrison reported that work by
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Garret and a group at the British Water Pollution Research Laboratory showed that
the rate of NH4+-N oxidation by Nitrosomonas was dependent on the DO below levels
of about 3.0 mg/L. It is assumed that a DO concentration greater or equal to 1 - 2 mg
O2/1 is required for the nitrification process.
It should be mentioned here that nitrification could be a major problem in
extended aeration plants. Due to the large excess of air and low organic loadings
normally used in extended aeration plants, the condition becomes favorable for. The
growth of nitrifying bacteria pH depression (mentioned earlier) in aeration tanks and
rising sludge in settling tanks are frequent problems.
Another problem of importance is the effect of nitrification on measurement of
effluent BOD and evaluation of efficiency of operation. Effluent samples taken from
highly nitrifying activated sludge plants exhibit higher BOD values than would be
caused by the carbonaceous demand alone. This has been shown to be due to the
nitrifying organisms present in these effluents, which caused nitrification to take place
immediately in the BOD test.
4. Dissolved Oxygen
12
air/m3wastewater was considered adequate, but later, 30 to 55m3 air/kg BOD5 was
used. Values ranging from 43 to 123 m3 of air/kg of BOD5 treated have been used. For
extended aeration systems, the air supplied may range up to 125 m 3/kg BOD5
removed in those cases where the effects of endogenous respiration and nitrification
are significant. It should be noted that these “rules of thumb” are generally
conservative in that they include the air needed for mixing as well as for biological
needs and presume a fixed transfer efficiency of the aeration device.
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liquor by an updraft or downdraft pump or turbine (see Figure III.4). This action
produces surface and subsurface turbulence, at the same time diffusing air through the
liquid mass.
Rotating brushes or blades partially submerged are used in oxidation ditch
plants (see Figure III.5). The turbulence produced entrains the air bubbles and keeps
the mixed liquor in motion.
Turbulence of the mixed liquor, as mentioned above, is one of the main factors
that determine the transfer of oxygen in the aforementioned aeration systems.
However, excessive turbulence (mixing of the mixed liquor) can damage the floe
particles of the mixed liquor, causing poor sedimentation and loss of solids in the
effluent.
14
Figure III.8: Brush Aerator
B. Process Flow
Influent and
Infiltration Effluent
Return Sludge
Flow Chlorine
Aeration Basin Clarifier Dechlorination
Equalization Contact Tank
At the end of the aeration period the wastewater biological mass mixture (mixed
liquor) reaches the effluent end of the chamber and flows in a trough to the clarifier. Here the
suspended solids (MLSS) and liquid are separated by gravity. The separated solids are
returned to the aeration compartment as return sludge while the liquid flows over weirs into
the chlorine contact tank for disinfection. Foam control sprays are provided to control
frothing in the aeration chamber and skimmers are provided to remove floating material from
the surface of the clarifiers.
The settled sludge and scum are returned to the aeration chambers by air lifts. The
extended aeration system is quite simple in concept. The maintenance of a favourable
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environment for the activated sludge (oxygen and complete mixing) and good solids
separation (clarifier) are readily accomplished. The MLSS is a well operating system and
should have a brown colour and settle well, and have an earthy odour.
C. Disadvantages
1. Extended aeration plants do not achieve denitrification or phosphorus removal
without additional unit processes because of flexibility is limited to adapt to the
changing effluent requirements resulting from regulatory changes.
2. The longer aeration period requires more energy therefore; systems require a
larger amount of space and tankage then other “higher rate” processes, which have
shorter aeration detention times.
D. Advantages
1. Extended aeration process is often better at handling organic loading and flow
fluctuations, as there is greater detention time for the nutrients to be assimilated by
microbes.
2. This plant is easy to operate and systems are easy to install as they are shipped inn
one or two pieces and then mounted on an onsite concrete pad, above or below
grade.
3. The systems are odor free, can be installed in most locations, have a relatively
small footprint, and can be landscaped to match the surrounding area.
Design an extended aeration activated sludge process given the pre-treated wastewater
treatment characteristics.
Based upon flow and organic loading the design factors determining the size and
volume of an activated sludge unit are the aeration volume, the total mixed liquor volume
necessary to handle the biological load, and the clarification area required to obtain solids
separation.
Since this unit is an extended aeration system, its BOD5/MLSS (F/M) loading is in the
range of 0.042 to 0.153. Under normal conditions an average range of 0.042 to 0.096 should
be used. The optimum ratio of F/M for the system must be determined by direct operation of
the unit and evaluation of the results. This F/M ratio establishes the MLSS concentration in
the range of 2,500 to approximately 6,000 mg/L.
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Aeration compartment volume has been established to provide a detention period of
24 hours at design flow. This volume, in turn, determines the BOD5 loading to the plant at 15
lbs. BOD5/day1,[Link]. This loading is within the normal range for extended aeration
plants.
The clarifiers have been sized to produce solids separation under all hydraulic loading
conditions. A good overflow rate is 520 GPD/sq ft at design [Link] is supplied to the
diffusers by positive displacement blowers. These blowers were designed to provide
sufficient air to ensure that the dissolved oxygen content of the aeration chambers can always
be maintained within of 1.0 to 2.0 mg/L.
V. DESIGN PROBLEM
Design the aeration tank and secondary clarifier to be used in an extended aeration
activated sludge process given the pre-treated wastewater characteristics and effluent
characteristics tabulated in Table V.1.
Parameter Concentration
A. Material Balance
F/M = 0.14
mg
MLVSS 0.5 5000 4000
L
YQ S0 S C
VX EQ.2
1 kd C
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Table V.3: Table of Values for Domestic Wastewater Values are for 20°C
Value
Parameter Basis
Range Typical
Ks mg/l BOD5 25-100 60
kd d-1 0-030 0.10
µm d-1 1-8 3
Y mg VSS/mg BOD5 0.4-0.8 0.6
From Table V.4, the values of Y, kd, are taken as the average of their range. The
values, Y=0.6 and kd= 0.03, are substituted to equation to solve for the value of θc.
(0.6)(750)300 30 C
(402)( 4000)
1 0.03C
C 21.95 22days
Solving for the Volumetric Loading
Q( S )
Volumetric Loading
V
750 m3 day300 mg L 1g 1000mg 1g 1000 g
Volumetricloading
402m3
kgBOD kg
0.56 0.3 0.7 3
Volumetric loading m3day within the range of m day
19
Volume
L
Area
402
L 29.78 m or 30 m
4 .5 3
Providing continuous chambers with 3 aeration chambers each length is 10 m.
0.6 3 3.6 m or 4m
Overall dimensions of aeration tank 10m 19m 4m
Provide 2 tanks
3
V (volume of tan k ) 375 47 m 3
24
750
Surface area 25 m 2
30
47m 3
Effective Depth 1.88 m
25m 2
V 4 47 4
Diameter 5.64 m
h 1.88
20
C. Specifications
21
Figure V.3: Dimensions of Secondary Clarifier
The design of this wastewater treatment is locally available, thus, can be adopted and
constructed at the local sugar industry. However, further studies are required to test the
effectiveness of the developed treatment method along with costing reports and selection
of materials to be used for each unit. It is also important to consider that the processes in a
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sugar industry are seasonal, making the characteristics as well as the quantity and quality
of the proposed design are needed.
The treatment method is also suitable for other types of wastewater which has a high
predominantly organic pollutant load that is biodegradable but short study is required to
determine the bio-reaction and contact times for each step.
VII. References
(n.d.).
Blevins, J. (2017, December 18). Activated Sludge Process-6, Extended Aeration Activated
Sludge. Retrieved from [Link]: [Link]
Davis, M. L. (2010). Water and Wastewater Engineering Design Principles and Practice.
New York: The McGraw-Hill Companies, Inc.
Lin, S. D. (2007). Water and Wastewater Calculations Manual. New York: The McGraw-
Hill Companies, Inc.
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