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Answer Key (First Term Examination 2015-2016)
Class-XI
Subject - Chemistry
1. i) 5 ii) 16 (}2+}2)
2. a) CI b)Ar (}2 +}2)
3. CH4 > NH3> H20 (1)
4. Boyle's Law: The volume of a given mass of a gas is inversely proportional to its pressure at constant
temperature. (}2 + }2)
5.n-land 0-7 (}2 +}2)
OR
[Defi nitio n] (1)
6.40 g O2 :::(40/32) = 1.25 moles
1 mole of CO2::: 1 mole of O2
1.25 mole of CO2::: 1.25 mole of O2
1.25 x 44 = 55 g (2)
7. a) Electronegativity: F > CI > Br (1)
b) Atomic Size: Na' < Mg2+< A13+ (1)
8. [Structure (1)]
In NF3, both 3 bond pair and 1 lone pair while in BF3, only bond pairs (1)
9. T1 = 23.4+ 273 = 296.4 K; V1 = 600 mL
V2 = x mL; T2 = 26.1 + 273 = 299.1 K
Vl V
2
T = - [Constant p]
1 T2 (1)
2 x
296.4 299.1
x = 2.018 L (1)
(2)
OR
p
Total = R )( T )( [n N + nH ].
V 2 2
.083 )( 298 x 4 b
------ = 9.89 ar
10 (2)
10. Type of reaction where a particular element undergoes simultaneous oxidation a nd reduction. (1)
CI2+ 2NaOH -7 NaCI + NaCIO + H20 (1)
1
.\
. Ins =+-
. 11.(i) 2
Na' _ls22s 2p6; 2 (1)
(iilLet the total mass = 100 g
l\I1ass of KI = 20 g
(I..I1ass of H20 = 80 g
ci : (M/V) = 100/1.202 = 83.194 mL
r...
1= ·••• eight of sol\ne x' ~
Molecuh.1 M:-.ss (Solute) Vol\llne of Solution {IllLI (1)
20 'jl}l}l}
,;:-x-
166 83.194 = 1.448 M (1)
12.
E =(2:IS
1\
xJ'II}_H) J ••tom
-'1
,,-
H =E - E
=
¢<> 2/
I} - (-2:IS \11)
_'1)
\. J- .
(1.5)
= S.4S x .tI} -'I-l htOJl{1
~E=~
1.
he
1.= -
ftE
(..(,2(, x '11}-34 x ~ x 'II}S
5.4~ x '11)-'I-t
= 3.647 X 10 -7 m
(1.5)
5
= 3.647 X 10- cm
B.(a) Na_1s22s22p6351.
Na+ - 1s22s22p6 (1)
Effective nuclear charge increases, therefore size shrinks (1)
(b) Shells increase on going down the group & IE decreases (1)
, (c) 4th period subshel\s are 45, 4p & 4d (2 + 6 + 10 18 electrons) = hence 18 elements
(1)
14. i) 1- sp & 2_Sp2
(I
____ - I~.
He = (J - eH -cH - c - OH
'1' 2 2, 2
ii) In this type of hydrogen bonding, the hydrogen atom and the electronegative atom are present in the
bonds belonging to the same molecule. E.g. o-nitropheno\' (1)
2
:+:. • -
"(i'
i
-: () \: ():
iii) - Formal Charge = VE - LP - (J.-iBP)= 6-6 - (J.-ix 2) =-1 (1)
15. (i) H2< He < O2 < CO because size increases in the same order (1)
(ii) CH4 > O2 > H2 intermolecular attractions are the highest in CH4 and lowest in H2 because
intermolecular forces increase with number of electrons in a molecule. (1)
(1)
16.(a) Energy is quantized and in electron intertransition jumps; emissions are quantized and discrete.
(1)
(b) For bodies visible with naked eye, A is negligible. (1)
1o
(c) Completely filled 3d configuration has greater stability and greater exchanges possible i.e. more
exchange energy stabilization. (1)
OR
~IEIH ~IE2H ~e~H
p 419 3051 -48
Q 1681 3374 -328
R 2372 5251 48
i) Metal- P ii) Non-metal- Q iii) NobleGas-R (1 each)
17. The change in enthalpy which takes place when a gaseous atom gains an extra electron to
form monovalent anion also in the gaseous state (1)
(a) CI; because electron- electron repulsion decreases EGE in 2p subshell for Fluorine (1)
(b) 0; because in 0-; electron gets added to an anion (1)
I'
i ··f
.-1
i
1-8. (a) a-) (:'1 Trigonal Bipyramidal
~
3
\}
S~~~
'.~.', .".
F----v.-50F
0·•.••..
1016 ....
,
F F See-saw
c)
F T-shaped (1/2 each)
(b)
4
[Link]
pi - honrl
Orbital structure of ethene
(1.5)
19_ (a) 2 + x - 8 = 0; x = 6 (1)
(b) Yes; Na + ZnCI2 ~ NaCI + Zn
Na is getting oxidized & Zn is reduced (1)
(c)
Reduction
r+
2't F2
'1+
- - > 2K F -
-12 l'
Oxidation
(1)
e
20. (a) is azimuthal quantum number and Lis second shell. (1)
(b) The ejection of electrons from the surface of a metal under the influence of striking photons
(1)
(c) When more than one orbitals of equal energies are available, the electrons will first occupy
these orbitals singly with parallel spins, then pairing of electrons will take place
2 2
N- Is 2s 2p/2p/2p/ (Correct method)
N- 1S22s22p/2p/2pzo (Incorrect method) (1)
5
21. (i)
Sigma Pi
Bond is formed by
the sidewise
Bond is formed by the axial overlap of the
1 overlap of the atomic orbitals atomic orbitals
Overlap is less and
the bond is
Overlap is quite large and the comparitively
2 bond is quite strong. weak.
(1)
(ii) Bond Order = 2
(1)
(ii) LiF [Fazan's rule] (1)
22. i) 2H+ + H202 + 2Fe2+ -7 2Fe3+ + 2H20 (1.5)
ii) 2Mn04- +6\" + 4H20 -7 2Mn02 + 312 + SOH- (1.5)
23. i) Sohan because in pressure cooker, temperature is more than 1000C and latenet heat of
steam is also used in cooking.
ii) The atmospheric pressure is less at hill station due to which water boils below 1000C and
vegetables and pulses take long time in cooking.
iii) Sohan is using scientific method to save time, money and energy.
iv) Sohan needs less fuel as pressure cooker helps in cooking at faster rate. (1 each)
24. (i)They are same. (1)
(ii) Nodes = 3 (1)
(c) Mass of electron = 9.1 x 10-31kg; velocity of electron = 300 ms'
{).V = 0.0001% of 300 = 3 X 10-3 ms' (1)
{).X x m {).V = (h/4n) = [(6.6 x 10-34)/(4 x 3.14 x 9.1 x 10-31x 3 x 10-3)] = 1.92 x 10-2 m (2)
OR
a) Limitations of Bohr's model:
i) The theory could not explain the atomic spectra of the atoms containing more than one
electron or multielectron atoms.
ii) Bohr's theory could not explain Zeeman effect & Stark effect. (1 each)
!.. = u = RH[!; 2 - .!21
1 1 n~
b)
1
1 =
-
u = 109618
[112 - ;2J
11
11.= 1.0257 X 10-7 m (1.5)
Calculation of Frequency
6
1"-
c
u= -
). = [(3 x 108)/(1.0257 X 10-7)] = 2.9248 X 1015 s' (1.5)
25. (a)
,;r;'J-"
\~
Atomic Atomic
o('blta!s orbfW;
(2)
Magnetic behavior isdiarnagnetic.
N2(BO = 3); N2+(BO = 2.5), N2- (BO = 2.5), N/- (BO = 3) (Bond dissociation enthalpy a Bond
Order); N/ < N2+ = N2- < N2 (1)
(b) Dipole moment for NH3 > NF3
7
•• ••
f 1 tf
N. N
7~~ # ~;;;~
H F F
J.1= e' 6 J.1= .2 '.
)
(1)
Since resultant of 3 bond pair vectors & Lone pair dipole is in the same direction, overall dipole
moment for NH3 increases. However, for NF3, resultant of 3 bond pair vectors & Lone pair dipole
is in the opposite direction, overall dipole moment for NF3decreases. (1)
OR
(a) N03-= 32; NH/= 10 (1 each)
(b) MgO has stronger lattice due to small size of Mg (1)
(c)
Atomic Orbital Molecular Orbital
The electron The electron cloud
cloud extends extends around the
around the nuclei of the bonded
nucleus of a atoms in the
1 single atom molecule
It is monocentric It is polycentric in
2 in nature nature
(1 each)
26. (a) The reactant which is present in lesser amount is known as Limiting Reagent since it limits
the participation of the other reactants I the reaction. (1)
(b) 22400 ern" (1)
(c)We shall convert the masses into moles
2 g of Mg = (2/24) = 0.0833 moles of Mg
2 g of S = (2/32) = 0.0625 moles of Mg (1)
From the equation,
Mg + S ~ MgS
8
It follows that one mole of Mg reacts with one mole of S. We are given more mole of Mg than 5,
therefore 5 is the limiting reagent. (1)
From equation, one mole of S gives one mole of MgS, so, 0.0625 mole of S ill react with 0.0625
mole of Mg to form 0.0625 mole of MgS.
Molar mass of MgS = 56 g
Therefore, mass of MgS formed = 0.0625 x 56g = 3.5 g
. Mole of Mg left unreacted = 0.0833 - 0.0625 mole of Mg = 0.0208 x 24 = 0.4992 g of Mg = 0.5
g Mg (approx.) (1)
OR
a) 0.5 mole of NaOH and 0.5 M means 0.5 moles of NaOH in 1 L of solution (1)
b) If two elements combine to form two or more compounds, the weights of one of the
elements which combine with a fixed weight of the other in these compounds, bear simple
whole number ratio by weight. (1)
c) Calculation of Mass% of C & H:
CO2:::: C
44 g:::: 12 g
3.38 g ::: 0.9218 g of C
H20:::: 2H
18g:::: 2 g
0.690 g ::::0.0766 g of H
Total Mass = 0.9218 + 0.0766 = 0.9984 g
% of C = [(Mass
of carbon)/(Mass of Fuel Gas)] x 100
=
[(0.9218)/(0.9984)) x 100 = 92.33%
=
% of H [(Mass of hydrogen)/(Mass of Fuel Gas)] x 100
= [(0.0766)/(0.9984)] x 100 = 7.67%
Empirical Formula: CH (1)
Calculation of Molecular Mass
10 L of the fuel gas at NTP weigh = 11.6 g
22.4 L of fuel gas at NTP weigh = [(11.6)/(10)] x 22.4 = 25.98 g = 26 g (approx.) (1)
Calculation of Molecular formula
Empirical Mass = 13
Molecular Mass = 26
n=2
Molecular Formula = C2H2 (1)