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Pxy Diagram for Acetonitrile/Nitromethane

The document contains equations for calculating vapor pressure and temperature for mixtures of acetonitrile and nitromethane. Tables of parameters A, B, C are provided for each component, along with saturation pressure and temperature values at 348.15K and sample vapor-liquid equilibrium data including mole fraction and vapor phase composition for various total pressures.

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38 views4 pages

Pxy Diagram for Acetonitrile/Nitromethane

The document contains equations for calculating vapor pressure and temperature for mixtures of acetonitrile and nitromethane. Tables of parameters A, B, C are provided for each component, along with saturation pressure and temperature values at 348.15K and sample vapor-liquid equilibrium data including mole fraction and vapor phase composition for various total pressures.

Uploaded by

adevirgie
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd

ln⁡〖���� (𝑘��)=𝐴⁡−⁡𝐵/(𝑇(𝐾)+𝐶) 〗

(1) Acetonitrile (2) Nitromethane


A 14.2724 A 14.2043
B 2945.47 B 2972.64
C -49.15 C -64.15

T 348.15 K
P1sat 83.2068574651 kPa P2sat 41.982704946 kPa

x1 �=�2���+(�1���⁡−�2���)𝑥1 y1 = x1P1sat/P
0 41.9827049461 0 Pxy diagram for acetonitrile(1)/nitromethane(2) at
0.1 46.105120198 0.1804720541 90
0.2 50.2275354499 0.3313196904 80
0.3 54.3499507018 0.4592838985
70
0.4 58.4723659537 0.5692046566
60
0.5 62.5947812056 0.6646469231
0.6 66.7171964575 0.7482945497 50

P(kPa)
0.7 70.8396117094 0.8222066556 40
0.8 74.9620269613 0.8879894084 30
0.9 79.0844422132 0.9469140785
20
1 83.2068574651 1
10
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1,y1
〖𝑇��� (𝐾) 〗 〖 =�/(𝐴⁡−ln⁡〖� (𝑘��) 〗 ) 〗 − C

(1) Acetonitrile (2) Nitromethane


A 14.2724 A 14.2043
B 2945.47 B 2972.64
C -49.15 C -64.15

P 70 kPa
T1sat 342.9946 K T2sat 362.73359744 K

Set T 351.15 K
P1sat 91.76107 ln⁡〖���� (𝑘��)=𝐴⁡−⁡𝐵/(𝑇(𝐾)+𝐶) 〗
P2sat 46.83681
x1 0.515605 x1⁡〖 =⁡(�−�2���)/(�1���−�2���) 〗
y1 = x1P1sat/P 0.675893
365
T P1sat P2sat x1 y1
362.733597436 131.5604 70 0 0 360
360.733597436 123.8628 65.45472 0.07781931 0.1376988298
358.733597436 116.5248 61.14881 0.15983805 0.2660727649 355
356.733597436 109.5345 57.07305 0.24640882 0.3855750837
354.733597436 102.8801 53.21839 0.3379183 0.4966440054 350
352.733597436 96.55031 49.57599 0.43479096 0.5997028861
350.733597436 90.53365 46.13721 0.53749328 0.6951604223 345
349.571223792 87.17634 44.22885 0.60006192 0.7473028524
348.733597436 84.81903 42.8936 0.6465384 0.7834108628 340
346.733597436 79.39551 39.83689 0.76249142 0.8648342285
344.733597436 74.25236 36.95905 0.88597535 0.9397965399 335
342.994571664 70 34.59598 1 1
330
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.5 0.6 0.7 0.8 0.9 1

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