GRIGNARD REAGENT
THEORY AND EXERCISE BOOKLET
CONTENTS
[Link]. TOPIC PAGE NO.
1. THEORY WITH SOLVED EXAMPLES ...................................... 03 14
2. EXERCISE - I .................................................................. 15 25
3. EXERCISE - II ................................................................. 26 30
4. ANSWER-KEY .................................................................. 31 32
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www. [Link], email-info@[Link]
IIT-JEE Syllabus :
GRIGNARD REAGENT
Grignard reactions, nucleophilic substitution reactions; Alcohols: esterification, dehydration
and oxidation, reaction with sodium, phosphorus halides, ZnCl2/conc.-HCl, conversion
of alcohols into aldehydes and ketones; Aldehydes and Ketones: oxidation, reduction,
oxime and hydrazone formation; aldol condensation, Perkin reaction; Cannizzaro
reaction; haloform reaction and nucleophilic addition reactions (Grignard addition);
Carboxylic acids: formation of esters, acid chlorides and amides, ester hydrolysis;
Amines: basicity of substituted anilines and aliphatic amines, preparation from nitro
compounds, reaction with nitrous acid, azo coupling reaction of diazonium salts of
aromatic amines, Sandmeyer and related reactions of diazonium salts; carbylamine
reaction; Haloarenes: nucleophilic aromatic substitution in haloarenes and substituted
haloarenes - (excluding Benzyne mechanism and Cine substitution).
394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, [Link], email-info@[Link]