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Chapter 5 Chemical Bonding:
The Covalent Bond Model
Atoms with similar ionization energy
and electronegativity DO NOT form
ionic bonds.
There is NO electron transfer!
Electron pairs are shared to form a
covalent bond.
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A covalent bond is a chemical bond resulting from
two _______ attracting the same shared _________.
Fig 5.1 Electron sharing can occur only when electron orbitals
from two different atoms overlap.
H + H H:H
HH
H2
Each atom in H2 has the electron configuration of ____
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Ch 5.2 Lewis Structures for Molecular Compounds
.. .. ..
H + F: H:F: or H - F :
. . . . . .
bonding nonbonding
electrons electrons
F, with ___ valence electrons, forms 1 covalent bond.
O, with ___ valence electrons, forms 2 covalent bonds.
Nonbonding electrons are also called _______ _______ .
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N ___ valence electron 3 covalent bonds
C ___ valence electron 4 covalent bonds
The number of covalent bonds formed by a
nonmetallic element is directly correlated with the
number of electrons it must share in order to obtain
an ___________ of electrons.
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Ch 5.3 Single, Double, and Triple Covalent Bonds
Some atoms must share _______ than one pair of
electrons to obtain an octet of electrons.
Single bond - 2 atoms share 1 pair of e
Double bond - 2 atoms share 2 pairs of e
Triple bond - 2 atoms share 3 pairs of e
. .
:N N : : N ::: N :
. .
:NN: 1 triple bond
each N in N2 has an _______
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Carbon dioxide has ____ double bonds
.. . .. .. ..
:O :C O: : O :: C :: O :
. .
.. ..
:O=C=O:
each atom in CO2 has a complete octet
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Supplemental material
Covalent bonds, bond energy, and bond length
Single Double Triple
bond energy increases
bond length ________
ethane ethylene acetylene
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Supplemental material: Sigma and Pi Bonds
ethylene
double bond = 1 sigma () bond & ___ pi () bond
bond
bond, 2 overlapping p
orbitals (2 lobes/orbital)
restricted motion
acetylene
triple bond = 1 bond & ____ bonds
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Ch 5.4 Valence Electrons and Number of Covalent
Bonds Formed
Group VIIA - 7 valence electrons - 1 covalent bond
& ____ lone pairs
..
: Cl 1 single bond
..
Group VIA - 6 valence electrons - 2 covalent bonds
& ____ lone pairs
:O :O
2 single bonds 1 double bond
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Group VA - 5 valence electrons - 3 covalent bonds
& ____ lone pair
:N :N :N
3 single 1 single 1 triple
& 1 double
Group IV - 4 valence electrons - 4 covalent bonds
& _____ lone pairs
C C C C
4 single 2 single 2 double 1 single
& 1 double & __________
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Ch 5.5 Coordinate Covalent Bonds
In a coordinate covalent bond ______ electrons of a
shared pair come ____________ of the two atoms in
the bond.
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Ammonia shares its________ with the hydrogen ion.
H H +
+
H N: H H NH
H no electrons H
8 electrons 1 coordinate
covalent bond
+ +
NH3 + H NH4
ammonia ____________ ion
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Ch 5.6 Systematic Procedures for Drawing Lewis Structures
Bottom Line
All valence electrons must be shown.
All atoms must have an octet of electrons.
(common exceptions include H)
Strategy
6 steps (slightly modified here)
Example A
Ammonia _______
Step 1. Sum up all valence e (adjust for charge if necessary)
N in VA = 5 valence e
H in IA = 1 valence e
1 x 5e + 3 x 1e = ____ valence e (there is no charge)
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Step 2. Draw skeleton structure and connect atoms by
__________ covalent bonds.
NH3 the central atom is often written first
H
HNH
Step 3. Subtract the number of e used in skeletal structure
bonds from valence e of step 1.
8 valence e from step 1
- 6 e used in step 2 (2 e per bond)
2 e left
Step 4. Count number of e needed in skeletal structure
(step 2) to give each atom an octet (2 e for H).
If that number = e left in step 3, distribute them.
all H are _____ H
N needs 2 e for octet
2 e left in step 3 HNH
add as lone pair on ____
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Example B Hydrogen cyanide HCN (written in order bonded)
Step 1 total valence e = 1 + 4 + 5 = 10 e (no charge)
Step 2 HCN
Step 3 10 e available
- __ e used in step 2
6 e left
Step 4 H has 2 e = complete
C in step 2 needs 4 e
N in step 2 needs 6 e
need 10 e to complete all octets
We are short ____ e
Step 5 For each 2 e short, share one more pair by
forming multiple bonds. Add 2 more bonds.
HCN
Step 6 Distribute remaining e to complete octets.
10 e available (step 1)
- __ e used (step 5)
2 e remain
HCN:
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-
Example C (drill problem) Chlorite ion ClO2
valence e : 7 + 2(6) + 1 = 20 e
- 4 e used
16 e left
: O Cl complete this structure
emcompleteember the charge!
:O:
O needs _____
Cl needs _____
___ e needed
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Ch 5.7 Bonding in Compounds with Polyatomic Ions Present
Both ionic and covalent bonds are present.
.. .. _
K+ : O Cl :
:O:
___________ ___________
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Supplemental Material Resonance Structures
A single Lewis structure does not always adequately represent a
substance and the concept of resonance is used to describe the
bonding in such molecules.
Resonance structures are two or more Lewis structures that
represent the same ion or molecule equally well.
Examples:
_____ion NO2-
ozone O3 __________ ion CO32-
benzene
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Ch 5.8 Molecular Geometry is the 3-D
arrangement of atoms within a molecule
Molecular models of methane
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We can predict the molecular geometry using a molecules
Lewis structure and the Valence Shell Electron-Pair Repulsion
theory (____________ theory)
Electrons repel each other
Electrons tend to be as far apart as possible
Electron pairs control ____________
2 electron pairs or VSEPR groups
3 electron pairs or VSEPR groups
4 electron pairs or VSEPR groups
Figure 5.8
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Steps in predicting molecular geometry
draw a Lewis structure
determine the number of VSEPR groups
bonding and nonbonding pairs count equally
single, double, and triple bonds count equally as one group
predict which arrangement of VSEPR groups
minimizes repulsion
A. Molecules with two VSEPR groups are linear
.. ..
:O=C=O: 2 VSEPR groups around the
central atom
bond angle _____
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B. Molecules with three VSEPR groups are either
trigonal planar or angular
H2CO (formaldehyde)
:O:
HCH
3 VSEPR groups
Trigonal planar
bond angle ~______
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.. .. .. -
NO2- nitrite ion :O NO:
____ VSEPR groups around N
2 bonding, 1 nonbonding
bent or angular shape
bond angle ~120o
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C. Molecules with four VSEPR groups have three
possible geometries:
Tetrahedral (no nonbonding e pairs)
Trigonal pyramidal (___ nonbonding e pair)
Angular or bent (____ nonbonding e pairs)
109.5o 107o 104.5o
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Molecules with more than one central atom
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Ethane
4 VSEPR groups for _____
carbon atom
Tetrahedral arrangement around each carbon atom.
ball-and-stick model of
Ethane
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Ch 5.9 Electronegativity
Electronegativity is a measure of the relative attraction
that an atom has for the _________ electrons in a bond.
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Ch 5.10 Bond Polarity
pure covalent polar covalent ionic
Differences in Electronegativity
____________ covalent bonds (similar values) < 0.4
0.4 < __________ covalent bonds < 1.5
1.5 < Borderline area < 2.0 (ionic or polar covalent)
________ bonds > 2.0
Depicting bond polarity
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Ch 5.11 Molecular Polarity depends on two factors:
Bond polarity
Molecular ___________
A. Polar bond + unsymmetrical distribution of
electronic charge = __________ molecule
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B. Polar bond + symmetrical distribution of
electronic charge = ____________ molecule
Polarity cancels
Polarity cancels in a trigonal planar
molecule with 3 identical atoms or
groups attached.
Polarity cancels in a tetrahedral
molecule with 4 identical atoms or
groups attached.
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Examples of polar and nonpolar molecules
(all contain __________ bonds)
NH3 is trigonal
pyramidal, not planar
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Ch 5.12 Naming Binary Molecular Compounds
Different compounds exist for most pairs of ______________.
Examples of N-O compounds: NO NO2 N2O3 N2O4 N2O5
N2O3
dinitrogen trioxide
1. prefix + full name of least electronegative nonmetal
2. prefix + stem name of more electronegative nonmetal
+ suffix of ide
Table 5.1 Common numerical
prefixes for 1 -10
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Table 5.2 Accepted Common Names
Memorize?
Yes
Yes
Yes
No
Yes
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