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Experimental Data Analysis of GE/RT

The document contains experimental data from a study measuring the properties of a liquid phase including pressure (P), mole fractions (x1 and y1), and excess Gibbs free energy (GE/RT) at varying compositions. A total of 21 data points are reported for P, x1, y1, lnΥ1, lnΥ2, and GE/RT. The data is plotted on graphs comparing the experimental and calculated values based on Margules and Barker methods. Residuals are also calculated and plotted for pressure and mole fraction y1.

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5 views10 pages

Experimental Data Analysis of GE/RT

The document contains experimental data from a study measuring the properties of a liquid phase including pressure (P), mole fractions (x1 and y1), and excess Gibbs free energy (GE/RT) at varying compositions. A total of 21 data points are reported for P, x1, y1, lnΥ1, lnΥ2, and GE/RT. The data is plotted on graphs comparing the experimental and calculated values based on Margules and Barker methods. Residuals are also calculated and plotted for pressure and mole fraction y1.

Uploaded by

Bunga Mega Putu
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd

P

experimen/Kp
x1
a
experimen
68.728
0.0000
72.278
0.0287
75.279
0.0570
77.524
0.0858
78.951
0.1046
82.528
0.1452
86.762
0.2173
90.088
0.2787
93.206
0.3579
95.017
0.4050
96.365
0.4480
97.646
0.5052
98.462
0.5432
99.811
0.6332
99.95
0.6605
100.278
0.6945
100.467
0.7327
100.999
0.7752
101.059
0.7922
99.877
0.9080
99.799
0.9448
96.885
1.0000
Metode Margules

y1
experime
n
0.0000
0.0647
0.1295
0.1848
0.2190
0.2694
0.3633
0.4184
0.4779
0.5135
0.5512
0.5844
0.6174
0.6772
0.6926
0.7124
0.7383
0.7729
0.7876
0.8959
0.9336
1.0000

ln 1
experimen
0.520
0.568
0.544
0.534
0.458
0.404
0.334
0.250
0.218
0.202
0.153
0.144
0.097
0.079
0.060
0.044
0.039
0.036
0.017
0.018
0.000

ln 2
experime
n
0.000
0.013
0.011
0.006
0.002
0.026
0.027
0.055
0.098
0.123
0.131
0.177
0.182
0.245
0.275
0.317
0.358
0.395
0.407
0.497
0.558

GE/RT
experime
n
0.000
0.027
0.043
0.052
0.058
0.089
0.108
0.133
0.152
0.161
0.163
0.165
0.162
0.151
0.145
0.139
0.128
0.119
0.113
0.061
0.048
0.000

GE/x1x2RT
experimen
0.974
0.796
0.663
0.616
0.714
0.638
0.661
0.663
0.669
0.658
0.660
0.651
0.652
0.648
0.653
0.654
0.681
0.689
0.733
0.911

Propertri fase liquid dari data EXPERIMEN


1.20
1.00
0.80
0.60

ln 1
GE/RT

f(x) = - 0.01x + 0.71


R = 0

GE/x1x2RT
Linear (GE/x1x2RT)
GE/RT

0.40
0.20
0.00
0.00

0.20

0.40

0.60
x1

0.80

1.00

1.20

Data Calculation
x1

P cal/KPa

y1 cal

0.0000

2.025

1.000

68.728

0.0000

0.0287

1.944

1.001

72.200

0.0749

0.0570

1.870

1.002

75.287

0.1371

0.0858

1.799

1.005

78.121

0.1915

0.1046

1.756

1.008

79.820

0.2230

0.1452

1.669

1.015

83.123

0.2825

0.2173

1.534

1.034

87.943

0.3673

0.2787

1.437

1.057

91.200

0.4255

0.3579

1.332

1.095

94.507

0.4886

0.4050

1.278

1.123

96.087

0.5220

0.4480

1.235

1.152

97.317

0.5507

0.5052

1.184

1.197

98.674

0.5874

0.5432

1.155

1.231

99.414

0.6113

0.6332

1.097

1.325

100.682

0.6683

0.6605

1.082

1.358

100.932

0.6862

0.6945

1.066

1.401

101.152

0.7091

0.7327

1.050

1.455

101.271

0.7361

0.7752

1.035

1.520

101.232

0.7679

0.7922

1.030

1.548

101.161

0.7814

0.9080

1.006

1.771

99.677

0.8876

0.9448

1.002

1.855

98.764

0.9287

1.0000

1.000

1.995

96.885

1.0000

(P)2
0
0.006
0.000
0.357
0.755
0.353
1.395
1.236
1.692
1.144
0.905
1.056
0.906
0.759
0.964
0.763
0.647
0.054
0.010
0.040
1.072
0

14.115

Grafik Perbandingan P-x-y Data Eksperimen dan Perhitungan


105.00
P vs100.00
x1 (Calculation)

P vs y1 (Calculation)

P vs x1 experimen

95.00
90.00
P/KPa

85.00
80.00

75.00
P vs y1
(experimen)
70.00
65.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
x1,y1

Metode Barker
Dari trial didapat :
A12 = 0.644
A21 = 0.672
P
exp/K
Pa

x1

68.72
8

0.000
0

72.27
8

0.028
7

75.27
9

0.057
0

77.52
4

0.085
8

78.95
1

0.104
6

82.52
8

0.145
2

86.76
2

0.217
3

90.08
8

0.278
7

93.20
6

0.357
9

95.01
7

0.405
0

96.36
5

0.448
0

97.64
6

0.505
2

98.46
2

0.543
2

99.81
1

0.633
2

99.95

0.660
5

100.2
78
100.4
67

0.694
5
0.732
7

y1
0.00
00
0.06
47
0.12
95
0.18
48
0.21
90
0.26
94
0.36
33
0.41
84
0.47
79
0.51
35
0.55
12
0.58
44
0.61
74
0.67
72
0.69
26
0.71
24
0.73

Pcal/K
Pa

y1 cal

(P)2

y1

0.0000

0.0000

0.0000

0.0000

0.1402

0.3745

0.0032

0.1213

0.2671

0.5168

0.0082

77.4181
1

0.1672

0.0112

0.1059

0.0176

1.007

79.0249
6

0.1934

0.0055

0.0740

0.0256

1.013

82.1842
3

0.2407

0.1182

0.3438

0.0287

1.030

86.8841
4

0.3103

0.0149

0.1221

0.0530

1.050

90.1233
3

0.3580

0.0012

0.0353

0.0604

1.085

93.4701
9

0.4125

0.0698

0.2642

0.0654

1.111

95.0913
4

0.4417

0.0055

0.0743

0.0718

1.137

96.3647
9

0.4680

0.0000

0.0002

0.0832

1.179

97.7850
5

0.5032

0.0193

0.1390

0.0812

1.210

98.5693
3

0.5267

0.0115

0.1073

0.0907

1.299

99.9498
2

0.5857

0.0193

0.1388

0.0915

1.330

100.236
9

0.0823

0.2869

0.0872

0.6306

0.0519

0.2278

0.0818

0.6611

0.0474

0.0772

1 cal

2 cal

1.905

1.000

68.728

1.839

1.001

71.9035
2

0.0679

1.778

1.002

74.7621
7

1.720

1.005

1.684
1.611
1.495
1.409
1.315
1.266
1.226
1.179
1.151
1.096
1.082
1.066
1.050

1.371
1.423

100.505
8
100.684
8

0.6054

83
100.9
99

0.775
2

101.0
59

0.792
2

99.87
7

0.908
0

99.79
9

0.944
8

96.88
5

1.000
0

0.77
29
0.78
76
0.89
59
0.93
36
1.00
00

0.2178

1.035

1.486

100.718
3

1.030

1.513

100.678
8

0.7133

0.1446

0.3802

0.0743

1.006

1.732

99.4441
1

0.8475

0.1874

0.4329

0.0484

1.002

1.816

98.6218
1

0.9017

1.3858

1.1772

0.0319

1.000

1.957

96.885

1.0000

0.0000

0.0000

0.0000

0.6974

0.0788

0.2807

0.0755

2.66203

Grafik Perbandingan P-x-y Data Eksperimen dan Perhitungan


105
100
P vs 95
x1 (Calculation)

P vs y1 (Calculation)

P vs x1 (Experimen)

90
P/KPa

85
80

75
P vs y1 (Experimen)
70
65
0.00

0.10

0.20

0.30

0.40

0.50

x1,y1

0.60

0.70

0.80

0.90

1.00

Residual P dan y1
0.80
0.60
0.40
Residual P
Residual y1

0.20
0.00
-0.20
-0.40
0.00

0.20

0.40

0.60
x1

0.80

1.00

1.20

Dengan Menghitung selisih GE/RT


Pexp/Kpa

x1

y1

68.728

0.000
0
0.028
7
0.057
0
0.085
8
0.104
6
0.145
2
0.217
3
0.278
7
0.357
9
0.405
0
0.448
0
0.505
2
0.543
2
0.633
2
0.660
5
0.694
5
0.732
7
0.775
2
0.792
2
0.908
0
0.944
8
1.000
0

0.000
0
0.064
7
0.129
5
0.184
8
0.219
0
0.269
4
0.363
3
0.418
4
0.477
9
0.513
5
0.551
2
0.584
4
0.617
4
0.677
2
0.692
6
0.712
4
0.738
3
0.772
9
0.787
6
0.895
9
0.933
6
1.000
0

72.278
75.279
77.524
78.951
82.528
86.762
90.088
93.206
95.017
96.365
97.646
98.462
99.811
99.95
100.278
100.467
100.999
101.059
99.877
99.799
96.885

ln 1
exp

ln 2
exp

GE/RT
exp

ln1
cal

0.000
0.520

0.013

0.027

0.568

0.011

0.043

0.544

0.006

0.052

0.534

0.002

0.058

0.458

0.026

0.089

0.404

0.027

0.108

0.334

0.055

0.133

0.250

0.098

0.152

0.218

0.123

0.161

0.202

0.131

0.163

0.153

0.177

0.165

0.144

0.182

0.162

0.097

0.245

0.151

0.079

0.275

0.145

0.060

0.317

0.139

0.044

0.358

0.128

0.039

0.395

0.119

0.036

0.407

0.113

0.017

0.497

0.061

0.018

0.558

0.048

0.000

0.52
22
0.49
14
0.46
11
0.44
18
0.40
17
0.33
53
0.28
37
0.22
38
0.19
16
0.16
45
0.13
17
0.11
20
0.07
18
0.06
14
0.04
96
0.03
79
0.02
67
0.02
28
0.00
44
0.00
16
0.00
00

ln2
cal

GE/RT
cal

( GE/RT)2

Pcal/KP
a

y1 c

0.000
0
0.000
9
0.003
5
0.007
8
0.011
5
0.021
6
0.046
5
0.073
8
0.115
9
0.144
0
0.171
2
0.209
4
0.235
7
0.299
7
0.319
3
0.343
7
0.370
8
0.400
5
0.412
2
0.487
0
0.508
5

0.000
0
0.015
9
0.031
3
0.046
7
0.056
5
0.076
8
0.109
3
0.132
3
0.154
5
0.163
3
0.168
2
0.170
2
0.168
5
0.155
4
0.149
0
0.139
5
0.126
9
0.110
8
0.103
7
0.048
8
0.029
6
0.000
0

0.000000
00
0.000127
50
0.000132
29
0.000028
36
0.000001
34
0.000140
41
0.000000
61
0.000000
36
0.000004
37
0.000004
38
0.000029
59
0.000026
85
0.000048
17
0.000016
33
0.000013
21
0.000000
84
0.000001
24
0.000063
95
0.000094
79
0.000152
65
0.000321
87
0.000000
00

68.728

0.0
0
0.0
6
0.1
9
0.1
3
0.2
1
0.2
4
0.3
2
0.4
9
0.4
7
0.5
6
0.5
9
0.5
1
0.5
0
0.6
6
0.6
4
0.7
9
0.7
7
0.7
9
0.7
5
0.8
7
0.9
6
1.0
0

71.503
74.065
76.505
78.013
81.055
85.795
89.230
92.924
94.752
96.189
97.766
98.606
99.935
100.15
7
100.31
8
100.34
8
100.20
1
100.09
1
98.653
97.991
96.885

Dari Trial didapat :


A12 = 0.554
0.0012091

A21=0.538

105
100
95
P90
vs x1 (experimen)

P/KPa

P vs y1 (Eks perimen)

P vs x1 (Calculation)

85
80
75
P vs y1 (Calculation)
70
65
0.00

0.10

0.20

0.30

0.40

0.50
x1,y1

0.60

0.70

0.80

0.90

1.00

Residual Ge/RT dan ln1/2


0.20
0.15
0.10
0.05
Residual GE/RT

0.00

Residual ln1/2
-0.05
-0.10
-0.15
-0.20
0.00

0.20

0.40

0.60

x1

0.80

1.00

1.20

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