DRYING
D
RYING
(conventionalvs enhanced)
Solid LiquidSeparation
Solid
Liquid Separation
Drying
Drying
Dryingisremovalofliquidfrommaterialsbymeansofitsits
transportandevaporation.
Dryingisahighlyenergyintensiveprocess
Aneffectiveandefficientdryingprocesscansignificantly
p
decreasetotalproductioncosts
Drying Mechanism
DryingMechanism
Mechanism of drying:
Mechanismofdrying:
Transportofenergyintothewettedmaterial
Transportofliquidthroughporestothe
Transport of liquid through pores to the
meniscus
Evaporationatthemeniscus
Evaporation at the meniscus
Transportofvaporthroughpores
Transportofvaportosurroundings
Transport of vapor to surroundings
Drying Mechanism (2)
DryingMechanism(2)
TP
T,P
Po
Po :saturatedvaporpressure
T : absolute temperature
T:absolutetemperature
Vmol:molarvolume
r:meniscusradius
Rate of Evaporation
RateofEvaporation
Mass transport from wetted surface
Masstransportfromwettedsurface
kg :masstransportcoefficient
Po :saturatedvaporpressureattemperatureT
Pi:vaporpressureinbulk
p p
Heattransport
h:heattransportcoefficient
p
T:bulktemperature
Ts:temperatureatwettedsurface
:heatofevaporationattemperatureT
Dry and Wet Bulb Temperature
DryandWetBulbTemperature
Incaseofwaterevaporationandtheprocessis
In
case of water evaporation and the process is
adiabatic
flowingair
wet
dry
H:absolutehumidity
H
b l
h idi
Hs:absolutehumidityatsaturation
RelativeHumidityand
Ab l
AbsoluteHumidity
H idi
Absolute humidity H
Absolutehumidity,H
massofwater/massofdryair
Relativehumidity,RH
p:partialwaterpressure
ps :saturateswaterpressure=Po
P:totalpressure
p
Mw:molecularweightofwater
Ma:molecularweightofair
Psychrometric Chart
PsychrometricChart
Drying Process
DryingProcess
Drying Process (2)
DryingProcess(2)
A:evaporationfromwetexternalsurface,heatingrate>
p
,
g
evaporationrate
B:similartoA,butheatingrate=evaporationrate,liquidatthe
externalsurfacemaybereplenishedbyinterparticleliquid
t
l f
b
l i h db i t
ti l li id
tocauseshringkage
C:[Link]
p
q
p
g
oftransport<evaporationrate
D:evaporationfromsmallerporesandinterparticledistances.
Th
Theremainingliquidcanberemovedaboveboilingpointof
i i li id
b
d b
b ili
i
f
theliquidorlongexposureofheating
Drying Process (3)
DryingProcess(3)
Drying Process (4)
DryingProcess(4)
Moistureco
ontent
Low Temperature Drying
LowTemperatureDrying
wettedair
compressor
dryingchamber
valve
warmdryair
condensate
Freeze Drying
FreezeDrying
Also
Alsocalledlyophilization
called lyophilization orcryodesiccation
or cryodesiccation
Freezedryingworksbyfreezing thematerial
and then reducing the surrounding pressure
andthenreducingthesurroundingpressure
andaddingenoughheattoallowthefrozen
water in the material to sublime directlyfrom
waterinthematerialtosublime
directly from
thesolidphasetothegasphase.
Operatingconditionisbelowthetriplepoint
O
i
di i i b l
h i l
i
Freeze Drying (2)
FreezeDrying(2)
Waterphasediagram
1atm =760torr
Freeze Drying (3)
FreezeDrying(3)