Shin-Etsu silicone

Greases
Oil Compounds

 Facts about Silicone P.2

Safety data P.22

Information on Silicone Greases Oil Compounds P.3

Precautions concerning handling, safety and hygiene P.22

Product selection guides P.4

Packaging P.23

Product introductions
1. Greases P.6
2. Oil compounds P.14

Facts about Silicone

Chemical properties of silicones
The main chain of a silicone is made up of inorganic siloxane linkages (Si-O-Si), to which are attached side chains which
contain organic groups. Silicones are a sort of hybrid polymer with both inorganic and organic components.

Features attributable to siloxane linkages

Features attributable to molecular structure

Silicones have a backbone of siloxane linkages, with attached side

chains which contain organic groups.

The molecules of dimethyl silicone exhibit a twisted, helical structure.

R
Si

R
O

Si

R
O

Si

Si

Organic
groups

O
Si

Si

Si

C H

Si

Si

O
O

Heat resistance Weatherability

Chemical stability Dielectric properties

C H

O
O

Organic
groups

Si

Si

Inorganic
material

Si

Si

Si

C
H

Water repellency Release properties Cold resistance

Low temperature-dependence

Compared to organic polymers, which have a carbon skeleton (C-C bond energy: 85 kcal/mol), silicones have superior heat resistance and
weatherability (UV light, ozone resistance). This is due to the greater stability of siloxane bonds, which have a bond energy of 106 kcal/mol.
Siloxane bonds have a bond length of 1.64 and bond angle of 134. Compared to carbon bonds (bond distance: 1.54 , bond angle: 110), they
have a long bond distance and high bond angle, and a low rotational energy barrier. As a result, siloxane bonds move more freely and intermolecular
forces are weak. These characteristics manifest themselves in the features of silicone materials, which include softness, gas permeability, cold resistance,
and little change in viscosity due to temperature changes.
The backbone of dimethyl silicone exhibits a helical structure.
Hydrophobic methyl groups cover almost the entire surface of the silicone polymer molecules, and surface energy is low. This gives rise to unique
properties including water repellency and easy release.
Moreover, silicones are low-polarity polymers, so they exhibit minimal moisture absorption.

Silicone Greases Oil Compounds

Silicone greases are products which consist of a base oil of silicone fluid
compounded with thickening agents (such as metallic soaps) and other additives.
They can be used in a wide range of temperatures and are used primarily on
moving parts to provide lubrication and adhesion.
Silicone oil compounds are products which consist of a base oil of silicone fluid
compounded with fillers such as silica powder or metallic oxides. The intended
application will dictate the type of filler used.
They can be used in a wide range of temperatures and are used primarily on nonmoving parts for thermal conduction, electrical insulation and sealing.

Features of silicone greases oil compounds

Because they use silicone fluid as the base oil, Shin-Etsu silicone greases and oil compounds offer the
following advantages.

Outstanding heat and cold resistance, so they perform well in

1 extreme conditions and will continue to do so over prolonged use.

2 Electrically insulating, so they can be used with confidence.
3 Outstanding moisture resistance and water repellency.
4 Non-corrosive.
5 Effective in small amounts.

Heat resistance comparison (Left: mineral oil Right: silicone fluid)

Before using any of these products, be sure to test beforehand to determine the product's suitability to the intended application.
3

Greases

Selection Guide

Intended Use

Application/Feature

G-30F

P.6

G-30L

P.6

G-30M

P.6

G-30H

P.6

G-40L

P.6

G-40M

P.6

G-40H

P.6

Extreme High Temperature

Applications

G-420

P.6

High Load Applications

G-302

P.8

FG-720

P.7

FG-721

P.7

FG-722

P.7

Regular

G-501

P.7

High Load Applications

G-503

P.8

G-411

P.8

Med. Torque

G-330

P.12

High Torque

G-331

P.12

G-332

P.12

G-333

P.12

G-334

P.12

G-340

P.12

G-341

P.12

G-342

P.12

G-631

P.12

G-632

P.12

G-633

P.12

Low Temperature
Applications

General Purpose

Lubrication

Product Name

High Temperature
Applications

Solvent & Chemical

Resistant

For Plastics

For Rubbers

For Torque Damping

Low Torque

Adhesion
Low Temperature
Applications

For Bearings

Improves Feeling

Oil compound
Intended Use

Selection Guide

Application/Feature

General Purpose

High Reliability

Thermal
Interface

High Thermal Conductivity

General Purpose

Heat Resistant
High Vacuum Seals
Compatible With Silicone

Sealing
General

Valve Seals
Anti-rust Sealant
Electrically Conductive
Insulator

Optical Applications

Product Name

KS-609

P.14

KS-613

P.14

G-747

P.14

G-775

P.14

G-776

P.14

G-777

P.14

G-765

P.15

G-750

P.15

G-751

P.15

X-23-7762

P.15

X-23-7783D

P.15

X-23-7868-2D

P.15

X-23-7921-5

P.15

KS-63W

P.19

KS-64

P.19

KS-64F

P.19

KS-62F

P.19

KS-62M

P.19

HIVAC-G

P.19

KS-650N

P.20

KS-651

P.20

KS-65A

P.20

KS-623

P.20

KS-622

P.20

KS-660

P.20

KS-660B

P.20

KS-63G

P.20

Optseal

P.21

Optseal-L

P.21

Properties of grease products

Silicone greases are made using a silicone fluid as the base oil. This is compounded with other materials such as
thickeners, oiliness improvers and antioxidants. Compared to common mineral oil greases, silicone greases have
greater thermo-oxidative stability and moisture resistance, and have a wider range of use temperatures. Silicone
greases are also chemically inert, and so are compatible with almost all types of equipment.

Low-temperature lubrication applications

G-30F G-30L G-30M G-30H
The greases in the G-30 series were specially designed to provide excellent lubrication at low temperatures. There are four
grades of thickness: F, L, M and H.
Typical properties
G-30F

Parameter

G-30M

G-30L

Grayish white paste

Appearance
25C

Specific gravity
Penetration

0.99

1.00

0.99

340 400

280 320

240 280

200 240

200+

200+

200+

5.7

2.3

0.5

kPa

30

30

30

400 (max.)

400 (max.)

400 (max.)

25C/worked
150C100h
1

150C50h
JIS K2220 Oxidative stability
Test method Moisture resistance
Worked stability

Grayish white grease

0.99

Drop point
Oil separation

G-30H

100,000 strokes

Low-temperature torque
-60C
(Starting/Running)

mN m

107/31

266/93

329/122

MIL-L15719A Low-temperature torque -60C

2000 g-cm

Less than 1 sec

1 sec

1 sec

0.41

0.35

BTB

Neutral

Free acid or free alkali

C

Use temperature range

Volatile content

150C100h

60 to +180

0.35

ppm

Low-molecular-weight silicone content D3-D10

100

1 The oxidative stability test conditions prescribed in JIS K 2220 indicate 99C/100 hours, but in this case measurement was done at 150C50 h.
G-30 greases are suitable for speed factors (bearing bore in mm _ bearing shaft speed in rpm) up to 200,000.

(Not specified values)

High-temperature lubrication applications

G-40L G-40M G-40H G-420
The greases in the G-40 series were specially designed to provide excellent lubrication at high
temperatures, and are ideal for lubrication of sealed bearings.
There are three grades of thickness: L, M and H. G-420 provides outstanding lubrication at very
high temperatures.

Bearing lubrication

Typical properties
Appearance
Penetration

White grease

1.06

1.10

280 320

240 280

200 240

281

200+

200+

200+

200+

8.9

5.9

3.0

5.72

kPa

10

10

10

400 (max.)

360 (max.)

320 (max.)

310 (max.)

66/29

83/46

117/57

41/25

Less than 5 sec.

Less than 5 sec.

Less than 5 sec.

Less than 5 sec.

Drop point
Oxidative stability

150C50h

JIS K2220
Test method Moisture resistance

Worked stability

100,000 strokes

Low-temperature torque
(Starting/Running)

-20C

mN m

MIL-L15719A Low-temperature torque

-20C

2000 g-cm

Free acid or free alkali

Neutral
30 to +200

Use temperature range

Volatile content

150C100h

Low-molecular-weight silicone content D3-D10

%
ppm

0.4

30 to +250
0.3

0.3

0.32

100

1 For information on safety, see page 22 (Safety & hygiene).

2 200C24h
3 The oxidative stability test conditions prescribed in JIS K 2220 indicate 99C100 h, but in this case measurement was done at 150C50 h.
G-40 greases are suitable for speed factors (bearing bore in mm _ bearing shaft speed in rpm) up to 200,000.

Brown grease

25C/worked
150C100h

G-420

1.05

25C

Oil separation

G-40H

1.06

Beige grease

Specific gravity

BTB

G-40M

G-40L

Parameter

(Not specified values)

 For lubrication of plastics

G-501
G-501 is compounded with a special silicone fluid as the base oil. This grease is ideal for blower bearings and plastic parts,
where it provides both lubrication and noise reducing properties.
With its special formula, G-501 is much less likely to cause stress cracking of polycarbonate (PC), polyacetal (POM), ABS
and other plastics.
It is also an excellent lubricant for steel/steel contacts.
Typical properties
G-501

Parameter
Appearance

White to pale yellow grease

Specific gravity
Penetration

25C

0.92

25C/worked

306

150C24h
JIS K2220 Oil separation
Test method Low-temperature torque
-50C
(Starting/Running)

%
mN m

Use temperature range

150C24h

Volatile content

Low-molecular-weight silicone content D3-D10

2.5
211103

50 to +150

0.1

ppm

100
Lubrication of plastic gears

(Not specified values)

Solvent resistant greases

Fluorosilicone greases
FG-720 FG-721 FG-722
The greases in the FG-720 series feature a fluorosilicone fluid as the base oil, compounded with fluoropolymer powder. These
hybrid greases exhibit certain properties of both silicones and fluorine compounds, and offer outstanding heat resistance,
solvent resistance and chemical resistance.
These greases provide excellent lubrication even in high speed, high load conditions.
Typical properties
FG-720

Parameter

Appearance

FG-721 1

FG-722

White grease

Specific gravity
Penetration

25C

1.40

1.44

1.43

25C/worked

303

303

281

231

246

295

3.9

2.6

0.2

150C50h2 kPa

10

10

10

100,000 strokes

346

319

322

63/44

214/127

199/185

Drop point
Oil separation
JIS K2220 Oxidative stability
Test method Worked stability
Low-temperature torque
(Starting/Running)

200C24h

-30C

mN m

Pass

Copper strip corrosion Room temp.24h

Use temperature range
Volatile content

30 to +200

C
200C24h

Low-molecular-weight silicone content D3-D10

0.3

0.5

0.4

100

ppm

1 For information on safety, see page 22 (Safety & hygiene).

2 The oxidative stability test conditions prescribed in JIS K 2220 indicate 99C100 h,
but in this case measurement was done at 150C50 h.

(Not specified values)

Solvent resistance of FG-720, FG-721 & FG-722 (normal temp.)

Solvent
Methyl alcohol
Ethyl alcohol
Isopropyl alcohol
Ethylene glycol
Acetone
Methyl ethyl ketone
Methyl isobutyl ketone
Tetrahydrofran
Benzene
Toluene

Solvent resistance

Solvent
Xylene
Styrene
n-hexane
Kerosene
Perchloroethylene
Dichloromethane
Butane
Ethyl ether
Dimethyl silicone fluid KF96 (20 mm2/s) *
Water
Mfd. by Shin-Etsu

Solvent resistance

Insoluble Soluble

 High load applications

G-302 G-503
G-302 and G-503 are compounded with chlorine- and sulfur-based extreme-pressure additives. These greases provide
outstanding lubrication under high loads. G-302 offers the highest load resistance of any grade we offer. G-503 provides
superior lubrication even under low loads.
Typical properties
G-302

G-503

White

Yellow

25C

1.13

0.97

Penetration

25C/worked

280

294

Oil separation

150C24h

1.2

2.2

kPa

400

10

Starting torque

107

122

Parameter
Appearance
Specific gravity

JIS K2220 Oxidative stability

Test method

99C100h

Low-temperature torque -30C mN m

Volatile content

Running torque

28

52

0.3

0.5

60 to +180

50 to +150

150C24h

Use temperature range

Low-molecular-weight silicone content

D3-D10

ppm

100
(Not specified values)

Non-mineral-oil grease for lubrication of rubbers

G-411
G-411 is a non-mineral-oil grease for rubbers. It has excellent heat resistance and cold resistance and was designed for
automotive applications. G-411 provides consistent lubricating properties and will not damage synthetic rubber cups.
Typical properties
Parameter
Appearance
Specific gravity
Penetration
Drop point
Oil separation
Oxidative stability
JIS K2220 Evaporation loss
Test method

25C
25C/worked

C
%
kPa
%
10 m
Over25 m
Impurities
Impurities/cm3
Over75 m
Over125 m
Humidity cabinet test
50C500h
SBR
Base diameter
mm
NR
Rubber swelling
SBR
Change in hardness
Hs
702/1202h
NR
Appearance
SBR
Base diameter
mm
NR
Rubber swelling
SBR
Change in hardness
Hs
1202/702h
NR
Appearance
Tinplate
Copper
Aluminum
Condition of
Change in mass
Metal corrosion
Cast iron
1002/1202h metal test strip mg/cm3
Brass
Steel
Zinc
Use temperature range
C
Volatile content
150C100h
%
Low-molecular-weight silicone content
D3-D10
ppm
150C100h
100C100h
100C22h

G-411
Brown
1.1
303
229
5.1
7
0.18
2930
220
0
0
Class A
+0.06
+0.28
2
4
No change
+0.07
+0.42
3
11
No change
+0.004
+0.007
+0.010
+0.058
+0.008
+0.012
+ 0.015
30 to +200
1.4
100
(Not specified values)

 Reference data
Boundary lubrication properties
Rotation

Properties of extreme-pressure greases

G-30M
G-40M
G-501
G-503
G-302
KS-660B
FG-721
Mineral oil type

4-ball weld load (kgf)

102
126
158
316
501
148
348
183

4-ball test

Test conditions
Speed: 1500 rpm
Time: 1 min
Temp.: room temperature
Test balls: 1/2 inch DIA
Pressure

kgf values: 1500 rpm/1 min.

Steel ball bearings

Torque (sliding resistance)

Measured in accordance with JIS K 2220. 6204 bearings, 1 rpm.
Grease is kept at a prescribed temperature for two hours, then starting torque is measured. Rotation is continued, and the
torque value after 10 minutes is taken to be the running torque.

Starting torque

Torque(mNm)

500

G-40M

100

G-30M

50

G-501

-60

-50

-40

-30

-20

-10

10

20

30

Temp. (C)

Running torque
1000

G-40M

Torque(mNm)

500

100

G-30M

50

G-501
20
-60

-50

-40

-30

-20

-10

10

20

30

Temp. (C)

Penetration (hardness)

Penetration tester

Effect of change in temperature on penetration

Dial gauge

350
G-420

Mineral oil type

G-501

Cone

Penetration (unworked)

G-40M
300
FG-721

Grease cup
G-30M
250

200

Penetration test
A penetration tester of the type prescribed in the penetration test
method in JIS K 2220 (grease) was used. For the test, a sample is
put into the prescribed grease cup and the surface is leveled, then
the sample is kept at 250.5 C. The cone is then lowered and
allowed to press vertically into the grease for 5 seconds. The
penetration depth is measured to a precision of 0.1 mm, and this
value is multiplied by 10 to get the penetration of the sample.
Worked penetration is the penetration measured after the grease
has been worked for 60 strokes over 1 minute using a mechanical
grease worker of the prescribed type.

150
-100

-50

50

100

150

200

Temp. (C)

Reliability comparison: Silicone grease vs. Non-silicone grease

Penetration

Volatile content
10

400

- G-40L
- Non-silicone grease A
- Non-silicone grease B

350

- G-40L
- Non-silicone grease A
- Non-silicone grease B

9
8

300

Volatile content (%)

Penetration (unworked)

7
250

200

150

6
5
4
3

100
2
50

1
0
0

100

200

300

Time (h)

Test conditions: 150 C 500 h

10

400

500

100

200

300

Time (h)

Test conditions: 150 C 500 h

400

500

Compatibility with plastics

Plastic name
Product name

ABS POM PBT PVC

PS

PP

PC

HIPS PMMA

AS

ASGF Nylon 6

Nylon
Nory Duranex
6-6

G-330

G-332

G-334

G-340

G-342

G-631

G-632

G-30M

G-40M

G-501

FG-720

KS-63W

KS-64

KS-65A

KS-660

KS-62M

HIVAC-G

KF-96H-200000 mm2/s

Potential of silicone greases & oil compounds to cause stress cracking of plastics
When a stressed plastic is subjected to prolonged contact with certain chemicals, it may be more likely to crack at a much
lower load than it would were it not in contact with the chemical. This phenomenon is commonly called stress cracking,
and is characterized by glass-like cracking, usually with no whitening of the plastic.
Stress cracking of plastics can be a function of several factors which include stress, temperature, time and chemicals. Of
these, exposure to chemicals is the most important factor. Silicone greases have also been known to cause stress
cracking in plastics.
The particulars of the stress cracking will vary depending on the type of silicone grease and plastic involved. And even for
molded pieces made using the same type of plastic, the effects of a grease may differ depending on the molding strain,
orientation and other conditions.
Thus, before using a silicone grease where it will be in contact with a plastic, it is important to first determine how the
grease will affect the plastic.
Shin-Etsu tests its products using the experimental method described below. The user should perform their own tests
which simulate the conditions of actual use to make sure that the product will not cause problems when it is used.
Test method
1. A plastic test strip (140 mm long, 25 mm wide, 3 mm thick) is clamped in a jig set to a length of 130 mm.
2. Grease is applied evenly to the convex surface of the strip.
3. In this state, the strip is heated at 80C for 16 hours.
4. After heating, the grease is wiped off and a visual inspection is made for cracking.
5. A visual check is done to look for cracking or surface deterioration.

The results are compared to those for a strip to which grease has not been applied.

11

 Tacky greases (torque, damper applications)

G-330 G-331 G-332 G-333 G-334
G-340 G-341 G-342
G-631 G-632 G-633
The products in the G-330 and G-340 series are highly tacky greases that exhibit little change in torque values due to
changing temperatures.
These greases can be applied to sliding and rotating parts in a variety of equipment, where their high tackiness provides a
superior damping effect.
G-330 has medium shear resistance (torque), while G-331 has high shear resistance. G-332, G-333 and G-334 are lowtorque greases.
The greases in the G-340 series are specially formulated to ensure stable physical properties at low temperatures.
The greases in the G-631 series were developed as bearing greases for variable resistors, and can also be used as damping
greases.
Note that the greases in the G-631 series are made using non-silicone base oils, and so the use temperature range will not be
as wide as those of the other products.

G-330

Parameter
Appearance

White grease

Specific gravity
JIS K2220 Penetration
Test method Oil separation
Torque

G-331

G-333

G-334

Blue grease

White grease

Blue grease

25C

1.15

1.15

1.12

1.11

1.08

25C/unworked

285

305

307

304

250

0.01

0.01

0.12

0.38

0.36

23

34

0.06

0.06

105C24h

Nm10-4*

After 50 turns

Use temperature range

C
105C24h

Volatile content

G-332

Low-molecular-weight silicone content D3-D10

30 to +150
0.05

0.05

ppm

0.06
100

(Not specified values)

Torque meter: Torque Tester MDT2-AMP made by Shinmei Electric.

The sample is applied evenly to the shaft (4 mm DIA_8 mm) and in the bearing clearance (35 m). The shaft is then turned 50 times (1 turn=360) by hand at a rate of 1 turn per
second. After 50 turns, the sample is loaded into the torque meter and the torque value is measured after rotation at 10 rpm for 1 minute. This value is taken as the test value.

G-340

Parameter
Specific gravity
Penetration

JIS K2220
Test method Oil separation
Torque

G-341

G-342

Grayish yellow grease

Appearance
25C

1.01

1.02

25C/unworked

158

182

168

0.03

0.06

0.02

16

105C24h

After 50 turns

Nm10-4*

Use temperature range

Volatile content

11

40 to +100

C
105C24h

Low-molecular-weight silicone content D3-D10

1.04

0.06

ppm

0.08

0.07

100

Torque meter: Torque Tester MDT2-AMP made by Shinmei Electric.

The sample is applied evenly to the shaft (4 mm DIA_8 mm) and in the bearing clearance (35 m). The shaft is then turned 50 times (1 turn=360) by hand at a rate of 1 turn per
second. After 50 turns, the sample is loaded into the torque meter and the torque value is measured after rotation at 10 rpm for 1 minute. This value is taken as the test value.

(Not specified values)

G-631

G-632

G-633

Creamy white translucent

grease

Colorless to pale
yellow transparent grease

Pale yellow to creamy

white translucent grease

25C

0.89

0.98

0.87

25C/unworked

213

228

235

0.78

0.02

0.04

30

64

Parameter
Appearance
Specific gravity
JIS K2220 Penetration
Test method Oil separation
Torque

105C24h

Nm10-4*

After 50 turns

13

0 to +80

Use temperature range

Volatile content

105C24h

Low-molecular-weight silicone content

D3-D10

%
ppm

0.07

0.06

Torque meter: Torque Tester MDT2-AMP made by Shinmei Electric.

The sample is applied evenly to the shaft (4 mm DIA_8 mm) and in the bearing clearance (35 m). The shaft is then turned 50 times (1 turn=360) by hand at a rate of 1 turn per
second. After 50 turns, the sample is loaded into the torque meter and the torque value is measured after rotation at 10 rpm for 1 minute. This value is taken as the test value.

12

0.07

100
(Not specified values)

 Reference data
Temperature vs. Torque

Torque(Nm10-4)

150

Non-silicone grease

Measurement conditions
Shaft size: 4 mm DIA 8 mm
Clearance: 35 m
Rotational speed at time
of measurement: 10 rpm

100
G-331

50

G-340

0
-60

-40

-20

20
40
Temperature (C)

20

40
60
Temperature (C)

60

80

100

Temperature vs. Penetration

Penetration(unworked)

400

300

G-333

G-332
200
G-330
G-331
100

-40

-20

80

100

120

140

Rotational speed vs. Torque

Torque(Nm10-4)

150

100

50
G-330

G-332
G-334

10

20

30
40
50
Rotational speed (rpm)

60

70

80

13

Properties of silicone oil compounds

A silicone oil compound features a base oil of silicone fluid, compounded with silica or metal powders. Silicone oil
compounds have superior electrical properties and water repellency and are exceptionally stable against heat and
oxidation across a wide temperature range. These products are thus used extensively as a dielectric material, as a
thermal interface material, for sealing, and to improve water repellency.

Thermal interface compounds (General purpose)

KS-609 KS-613 G-747
All three feature silicone fluid as the base oil, plus thermally conductive fillers. These oil compounds offer excellent thermal
conductivity and electrical properties.
They are ideal for use as a thermal interface and insulator for semiconductor elements (transistors, thermistors) and various
types of heatsinks.
KS-609 is a general purpose product, KS-613 has enhanced heat resistance for potting of thermistors, and G-747 can be
used as a thermal interface material for resin-encapsulated power transistors.
Typical properties
KS-609

Parameter

KS-613

G-747

White grease

Appearance
Specific gravity

25C

Viscosity

25C

Penetration2

25C/worked
2

Pas

Thermal conductivity
Volume resistivity
Dielectric breakdown strength

Low-molecular-weight silicone content

D3-D10

50

328

346

328

2.65

0.3

2.3

0.01 1

W/mK

0.76

0.90

Tm

2.3

0.5

2.5

kV

3.5

9.9

3.7

55 to +200

50 to +250

50 to +150

0.3

0.3

0.06

Use temperature range

200C24h

60

0.73

0.25mm

Volatile content

2.36

70

200C24h

Oil separation

2.50

100

ppm

(Not specified values)

1 Measured at 120 C24 h. 2 Tested in accordance with JIS K 2220. Hardness controlled as a measure of penetration.

Thermal interface compounds (High reliability)

G-775 G-776 G-777
All three feature a base oil of silicone fluid, compounded with thermally conductive fillers. These oil compounds offer excellent
thermal conductivity and electrical properties.
Compared to general purpose products, these oil compounds offer better resistance against pump-out, creep and oil
separation, meaning they can be used in spots where long-lasting reliability is required.
G-775 is high viscosity and offers the ultimate in creep resistance.
G-776 has been diluted with an isoparaffin solvent, to achieve properties which are normally at odds, namely low viscosity
(ease of use) and low oil bleed.
G-777 is an all-purpose product that offers a balance of good working properties, heat resistance, thermal conductivity, and
resistance against pump-out.
Typical properties
G-775

Parameter
Appearance
25C

Viscosity

25C

Penetration2

25C/unworked

Pas
W/mK

Thermal conductivity
0.25mm

Use temperature range

Volatile content

150C24h

Low-molecular-weight silicone content

D3-D10

3.4

2.9

3.2

500

58

140

250

354

190

3.6

1.3 1

3.3

kV

2.5

2.9

3.2

40 to +150

40 to +200

40 to +200

0.26

3.10

ppm

300

1 Value after evaporation of solvent. 2 Tested in accordance with JIS K 2220. Hardness controlled as a measure of viscosity.

14

G-777

White grease

Specific gravity

Dielectric breakdown strength

G-776

0.1
100
(Not specified values)

 Thermal interface compounds

(High thermal conductivity)
G-765 G-750 G-751 X-23-7921-5
These oil compounds have excellent thermal conductivity. All feature a base oil of silicone fluid
compounded with high thermal conductivity fillers.
G-765 and G-750 have high dielectric strength, while in G-751 and X-23-7921-5 the
emphasis is on thermal conductivity, and their dielectric strength is lower than that of other
silicone products. Thus, G-751 and X-23-7921-5 are not recommended for applications that
require a material with insulating properties.
G-765 and G-750 can be used as a thermal interface for IGBTs, while G-751 and X-23-79215 are ideal for CPUs and MPUs.

Thermal interface for CPUs

Typical properties
G-765

Parameter

G-750

G-751

X-23-7921-5

2.51

2.8
363

Gray grease

Appearance
Specific gravity

25C

Viscosity

25C

150C24h

Oil separation

Thermal conductivity
Volume resistivity
Dielectric breakdown strength

0.25mm

Use temperature range

2.77

2.77

Pas

250

300

420

0.01

0.01

0.01

W/mK

2.9

3.5

4.5

6.0

Tm

0.1

0.1

0.008

kV

4.5

4.5

0.06

0.28

Volatile content

150C24h

Low-molecular-weight silicone content

D3-D10

Below measurable limit

50 to +120

ppm

0.10

0.44

100
(Not specified values)

Tested in accordance with JIS K 2220. Hardness controlled as a measure of viscosity.

Thermal interface
(High thermal conductivity, solvent diluted types)
X-23-7762 X-23-7783D X-23-7868-2D
These oil compounds have excellent thermal conductivity. All feature a base oil of silicone fluid compounded with high
thermal conductivity fillers.
They are compounded with around 2-3% isoparaffin based solvent so they not only have high thermal conductivity, but are
also easier to work with. These products are ideal as a thermal interface for CPUs and MPUs.
X-23-7783D is essentially X-23-7762 compounded with a fine filler to give it a lower thermal resistance.
X-23-7868-2D has a lower viscosity than X-23-7783D, making it easier to work with and giving it an even higher thermal
conductivity.
Typical properties
X-23-7762

Parameter
Appearance

X-23-7868-2D

Gray grease

Specific gravity

25C

Viscosity

25C
0.25mm

Use temperature range

2.55

2.55

2.5

180

200

100

4.06.0

3.55.5

3.66.2

Pas
W/mK

Thermal conductivity
Dielectric breakdown strength

X-23-7783D

kV

Below measurable limit

Volatile content

150C24h

Low-molecular-weight silicone content

D3-D10

%
ppm

Value after evaporation of solvent. Hardness controlled as a measure of viscosity.

50 to +120
2.58

2.43

2.70

100
(Not specified values)

15

 Reference data
Correlation between thermal conductivity and viscosity

High

X-23-7868-2D
6.2W/mK
100Pas

X-23-7762

X-23-7921-5

6.0W/mK
180Pas

6.0W/mK
363Pas

Thermal conductivity

X-23-7783D
5.5W/mK
200Pas

G-751
4.5W/mK
420Pas

3.6W/mK
500Pas

3.5W/mK
300Pas

3.3W/mK
140Pas

G-765
2.9W/mK
250Pas

G-776
G-747

G-775

G-750

G-777

1.3W/mK
58Pas

0.9W/mK
50Pas

Low

KS-613

KS-609

0.76W/mK
60Pas

0.73W/mK
70Pas

Viscosity

High
Solvent diluted type

Solventless type

Correlation between thermal resistance and thickness of oil compound

140

G-765
G-750
G-751
X-23-7762
X-23-7783D
X-23-7868-2D
X-23-7921-5

KS-609

120

G-747
Thermal resistance (mm2-K/W)

Thermal resistance (mm2-K/W)

40

KS-613

G-776

100

G-777
G-775

80
60
40

30

20

10

20
0

0
0

50

100

150

Compound thickness (m)

16

200

250

50

Compound thickness (m)

100

Reliability
Reliability comparison: Silicone compound vs. Non-silicone compound
Silicone thermal interface compound, mfd. by Shin-Etsu

Non-silicone compound (competitor's product)

70

50
40

Initial
After 250 h (cycles)
After 500 h (cycles)

30
20
10
0

85C/85%RH
High humidity test

Silicone compound
from a competitor

50
40
30
20
10
0

-40C/125C
150C
Cycling test Heat resistance test

Creep resistance of G-775

Initial
After 250 h
(cycles)
After 500 h
(cycles)

60

Thermal resistance (mm2-K/W)

Thermal resistance (mm2-K/W)

60

70

85C/85%RH
High humidity test

-40C/125C
150C
Cycling test Heat resistance test

Resistance to oil-bleed of G-776

Conditions

G-775

Sample
After
100
cycles

23C64h
Conventional
product

125C64h
G-776

Conventional
product

G-776

20.6

1.6

Photo
After
500
cycles
Bleed distance
mm
[Test method ]
1 A 0.1cc sample is sandwiched between a microscope slide
(glass) and an aluminum plate, which are separated by a
0.3mm spacer.
2 This test piece is stood vertically, and a heat cycle test is
conducted (cycling between -40 C and +125 C).

10.0

1.5

[ Test method ]
1 A 0.1 g sample is placed on a piece of frosted glass.
2 The oil bleed distance (radius of circle) is measured and oil separation is evaluated.
3 Bleed is measured after keeping samples at 23 C and 125 C.

Solvent evaporation time

Solvent evaporation conditions (guide)
Evaporation data for X-23-7783D

2.5
2
1.5

25C/50%RH

1
0.5
0

200

400
Time (min)

600

800

Volatile content (%)

Volatile content (%)

Evaporation data for X-23-7783D

2.5
2
1.5

105C

80C

0.5

60C

20

Time (min)

40

60

Solvent diluted products: G-776, X-23-7762, X-23-7783D, X-23-7868-2D

[Test method ]
Using a metal screen, X-23-7783D was applied (application size: 25 mm long 25 mm wide _ 120 m thick) to aluminum plates.
The samples were kept at various temperatures, and the change in weight was measured.

17

 Heat resistance: Evaluation & Measurement methods

Thermal conductivity
At a given temperature, thermal conductivity is a value intrinsic to a particular substance. According to Fourier's
Law, in a steady state, the proportionality constant is the thermal conductivity.
Thermal
conductivity

Q =

(T1T2) A

Q
A

(T1T2)

From this we get

Q: heat flow rate A: cross-sectional surface area
T1: temperature at high side T2: temperature at low side

Thermal resistance
Thermal resistance is the sum of contact resistance plus the resistance as heat flows (Q) from T1 to T2.

Thermal
resistance

R0 =

T1T2
Q

R = R0 RS

A
In reality

R0: Intrinsic thermal resistance of substance RS: Thermal contact resistance

Tave()=
Po
r

t
D()

Po
3

2 r

Fig. 1: Setup of samples

Fig. 2: Applied current and change in sensor signal over time

Temperature rise

Two pouches were prepared by wrapping grease samples in

kitchen wrap. A sensor was sandwiched between the pouches
as shown in Figure 1, and a constant current was applied to the
sensor so as to generate a specific amount of heat. Thermal
conductivity was calculated from the rise in temperature of the
sensor.
The sensor is constructed with a double spiral of nickel metal,
and can detect temperature changes as the change in electrical
resistance of the sensor. Figure 2 shows the signals obtained
from the sensor when the constant current is applied.
If we take the graph showing temperature rise (Fig. 2) and scale
the X-axis (function of time and thermal diffusivity () of the
sample) to D(), we get the graph in Figure 3.
From Equation (1), we know that the slope of this straight line is
inversely proportional to the thermal conductivity () of the
sample. The temperature rise (Tave) of the sensor may be
theoretically expressed by the following equation.

Applied current

Thermal conductivity measurement method

Time

Time

Fig. 3: Temperature rise curve vs. D()

D()(1)

: Total power (W) applied to the sensor

: Radius (m) of sensor
: Thermal conductivity (W/m_K) of sample
: Dimensionless parameter, defined by t/r2
: Thermal diffusivity (m2/s) of sample
: Test time (sec)
: Dimensionless function of

Tave

D()

Method used to measure thermal resistance (laser flash)

Thermal resistance was measured by the laser flash method, which is one method used to measure thermal
constants. In this method, one face of a sample is irradiated with a pulse laser to heat it. The temperature rise at the
opposite face is measured using an infrared sensor, which does not touch the sample.

18

 For dielectric & sealing applications (General purpose)

KS-62F KS-62M KS-63W KS-64F KS-64
These oil compounds have superior electrical properties and water repellency, and are chemically inert. They are ideal for use
as insulating and sealing materials for electric and electronic equipment.
KS-63W, KS-64 and KS-64F are general purpose products, while KS-62F and KS-62M are heat resistant products.

KS-62F

KS-62M

KS-63W

KS-64F

KS-64

Off-white paste

White translucent grease

White grease

White paste

White grease

Parameter
Appearance
25C

Specific gravity
JIS K2220
Test method

1.13

1.18

1.02

1.01

1.05

Penetration

25C/worked

229

225

385

246

Oil separation

200C24h %

1.3

2.91

181

5.8

kV

3.4

3.5

3.8

3.6

4.0

Tm

0.15

56

130

230

620

Dielectric breakdown strength

0.1mm

Volume resistivity
Permittivity

60Hz

2.96

2.88

2.84

2.80

2.80

Dissipation factor

60Hz

2.5104

3.2104

2.4104

1104

2.3104

0.20

0.19

0.17

0.19

W/mK

Thermal conductivity
Use temperature range

0.17

30 to +250

200C24h %

Volatile content

Low-molecular-weight silicone content D3-D10

50 to +200
0.11

0.3

1.0

ppm

0.11

0.1

100
(Not specified values)

1 Measured at 150 C24 h.

For dielectric & sealing applications (High vacuum seals)

HIVAC-G
HIVAC-G features a base oil of specially refined silicone fluid, compounded with silica powder. This oil compound has
excellent heat resistance, oxidative stability and chemical stability. Through an intensive refining process, volatile content has
been reduced to very low levels, thereby making it possible to attain high vacuums of 10-6 Torr. HIVAC-G forms exceptionally
tight seals on gaskets and sliding mechanisms, and is widely used as a sealing compound for high vacuum devices.

Vapor pressure curve of HIVAC-G

HIVAC-G

Parameter
Appearance

White grease
Penetration

JIS K2220
Oil separation
Test method
Copper strip corrosion
Dielectric breakdown strength

25C

1.03

25C/worked

209
%

200C24h
Room temp./24h
0.1mm

0.1
Pass

kV
Tm

Volume resistivity

60Hz

2.82

Dissipation factor

60Hz

2.210-4
C

Volatile content

200C24h

Low-molecular-weight silicone content

D3-D10

%
ppm

10-4

900

Permittivity
Use temperature range

10-3

50 to +200

Vapor pressure

(mmHg)

Specific gravity

0.1
100

10-5

(Not specified values)

10-6

220

210

200

190
180
170
Temperature (C)

160

150

Sealing of high vacuum devices

19

 For dielectric & sealing applications (Special purpose)

KS-650N KS-651 KS-65A KS-623 KS-622 KS-63G
These oil compounds have superior electrical properties and water repellency, and are
chemically inert. They are ideal for use as insulating and sealing materials for electric and
electronic equipment.
KS-650N and KS-651 will not cause swelling of silicone rubber.
KS-65A and KS-623 are ideal for sealing valves, cocks and packing in common chemistry
equipment.
KS-622 is specially formulated to prevent corrosion of copper, and is ideal for terminal
protection for copper wiring.
KS-63G can be applied to insulators to help prevent flashover which can be caused by salt
damage.

Protecting insulators from salt damage

(application example for KS-63G)

Typical properties

Penetration

JIS K2220
Test method Oil separation

KS-622

KS-63G

White grease

White grease

Creamy white
grease

Green grease

1.02

1.04

1.03

1.03

1.06

258

221

211

268

209

KS-651
Pale yellow to
yellow grease

25C

0.98

25C/worked

263

Appearance
Specific gravity

KS-623

KS-650N
Creamy white
translucent grease

Parameter

Silicone rubber swelling

(Weight change/volume change)

105C500h %

Dielectric breakdown strength

0.1mm

Volume resistivity

KS-65A

0.7(105C24h) 2.0(150C24h) 1.1(200C24h) 1.9(200C24h) 2.74(150C24h) 0.8(150C24h)

+0.5/+1.1

kV
Tm

+0.6/+1.3

3.7

1.5<

111

208

1.3

2,600

1<

2,300
2.82

Permittivity

60Hz

2.48

2.6

Dissipation factor

60Hz

3.310-4

4.710-4

50 to +160

50 to +200

Use temperature range

10 to +100

Volatile content

Low-molecular-weight silicone content D3-D10

50 to +200
50 to +170

0.5(105C24h) 0.1(150C24h) 0.1(200C24h) 0.2(200C24h) 0.44(150C24h) 0.1(150C24h)

ppm

100
(Not specified values)

1: 0.25mm

Electrically conductive
KS-660 KS-660B
These oil compounds feature a base oil of silicone fluid compounded with carbon. They have excellent conductivity, heat
resistance, and thermo-oxidative stability. KS-660 is for conductive sealing applications, while KS-660B is ideal for use as a
conductive lubricant.
Typical properties
KS-660

Parameter
Appearance

KS-660B
Black grease

Specific gravity
Penetration

25C

1.04

1.00

25C/worked

247

301

Drop point

JIS K2220
Test method Oil separation

200+

200+

8.0(200C24h)

3.9(150C24h)

Copper strip corrosion Room temp.24h

Volume resistivity
Thermal conductivity
Aluminum strip corrosion

0.83

11

W/mK

0.38

0.38

Room temp.24h

Use temperature range

Volatile content
Low-molecular-weight silicone content

Pass

D3-D10

Pass
C

50 to +200

0.2(200C24h)

ppm

50 to +150
0.1(150C24h)
100
(Not specified values)

20

 For optical applications

Optseal Optseal-L
These oil compounds have high transparency, close to that of quartz glass. A 10 mm layer of Optseal allows over 90% of
visible light (400-700 nm) to pass through. These compounds are thus ideal for use as a filler to protect the junction points of
optical fiber and optoelectronics devices. Optseal is a non-flow compound, while Optseal-L is somewhat soft and slightly
flowable.
Typical properties
Optseal

Optseal-L

High transparency grease

High transparency grease

Parameter
Appearance
Specific gravity
Penetration

JIS K2220
Test method

25C

1.1

1.1

25C/worked

300

400

Oil separation 200C24h

0.01

1.4690

1.4690

40 to +200

40 to +200

1.1

1.1

Refractive index (n25D )

Use temperature range
200C24h

Volatile content

Low-molecular-weight silicone content D3-D10

ppm100
(Not specified values)

Optseal: Temperature vs. Refractive index

Visible light transmittance

(Grease thickness: 10 mm)

100
1,500

90
Transmittance (%)

Refractive index

1,490
1,480
1,470
1,460
1,450
1,440
-40

-20

20

40

60

80

80
70
60
50
400

500

Temperature, C

600

700

Wavelength (nm)

Filling junction points of optical equipment

Reference data
Various silicone fluids and their swelling of synthetic rubbers
Test of swelling tendencies of base oils on synthetic rubbers
Rubber
type
IIR
CR
NR
NBR
EPDM
Silicone

Test item

KS-64 (base oil)

(70C, 120C240h)

650N (base oil)

G-40 (base oil)

G-30 (base oil)

FG-720 (base oil)

70C

120C

70C

120C

70C

120C

70C

120C

70C

120C

Weight change (%)

1.8

3.7

1.5

2.1

1.8

2.8

2.0

3.6

0.2

0.9

Volume change (%)

3.1

6.3

2.4

3.5

3.0

4.9

3.3

6.2

0.4

1.6

Weight change (%)

11.8

12.1

13.1

14.1

11.0

11.6

12.1

12.4

10.3

11.1

Volume change (%)

18.5

19.7

20.1

22.1

17.4

18.9

19.0

1.4

16.1

18.1

Weight change (%)

3.0

4.2

2.3

5.0

0.6

3.0

3.0

4.6

1.4

2.0

Volume change (%)

5.1

9.4

3.5

9.4

1.4

7.3

5.1

10.1

2.2

5.3

Weight change (%)

5.4

9.6

6.3

10.8

6.1

10.0

5.8

9.8

4.9

8.6

Volume change (%)

6.5

12.9

7.7

13.9

7.3

13.0

7.1

13.2

6.1

11.6

Weight change (%)

17.6

17.9

14.7

15.8

17.7

17.9

18.1

18.4

11.3

14.3

Volume change (%)

19.5

20.5

15.8

17.4

19.5

20.4

20.2

21.1

12.1

16.3

Weight change (%)

+32.0

+31.2

0.2

0.4

+7.2

+7.7

+33.2

+33.4

0.6

1.5

Volume change (%)

+38.9

+38.5

+0.3

+0.2

+8.3

+9.4

+39.2

+39.8

0.5

1.2

Note: The data in the table above are the values observed in severe tests in which strips of rubber were immersed in the base oils, and do not represent results obtained with greases. The table
should be taken as a guide with respect to compatibility with the materials shown. The same tests conducted with the actual greases tend to yield absolute values which are lower.

21

 Safety data
Toxicity test results for silicone greases & oil compounds
Item
Product name

Skin irritation (human)1

HIVAC-G
KS-64
G-30M
G-40M

LD50: Oral (rat)

(unit: g/kg)

Negative

5<

Negative

5<

Negative

5<

Negative

5<

As the table at left shows, most silicone greases and oil

compounds are highly safe. (See below for information on
oral toxicity standards.) However, Shin-Etsu's special grades
may differ in terms of safety, so please contact us for
inquiries about products other than those shown at left.

1 Tested by the Japanese Society for Cutaneous Health.

Oral toxicity standards

Acute toxicity test
Generally, an animal subject is exposed to a large quantity of a substance to determine the lethal dose.
This is normally expressed as LD50 (Lethal Dose, 50%). See the table below for information on degrees of toxicity.
Categories of strength of toxicity
Degree of toxicity

LD50: Oral (rat) (unit: g/kg)

Extremely toxic

<0.001

Strongly toxic

0.0010.05

Moderately toxic

0.050.5

Mildly toxic

0.55

Minimally toxic

515

Nearly non-toxic

15<

Source: Hodge, H.G. and Sterner, J.H.

: American Industrial Hygiene Association Quarterly, 10:4, 93, 1943

Precautions Related to Handling, Safety and Hygiene

Handling & storage
1. After prolonged storage, oil may have separated, but it does not mean there is a problem with product. Stir the product well
before using.
2. Before applying the product to the intended area, clean and dry the area thoroughly.
3. Do not mix these products with other oils or greases.
4. After opening product containers, take care to keep dirt and other contaminants out of containers.
5. If product is left over after use, close containers tightly and be sure to store in a cool, dark place.

Safety & hygiene

1. Wear gloves and other protective gear when using these products.
2. If product gets on the hands or other exposed skin, wipe off with a dry cloth and then wash thoroughly with soap and water. In
case of eye contact, immediately flush eyes with plenty of running water, and consult a physician if necessary. Contact lens
wearers must be careful to avoid contact between product and their contact lenses. If it comes into contact with the lens, the
contact lens may become stuck to the eye.
3. Be sure there is adequate ventilation when handling these products at the time of heating in particular. Avoid handling in a
poorly ventilated area causing inhalation of [Link] you feel ill after breathing the vapors, move immediately to an area with
fresh air.
4. Keep out of the reach of children.
5. If product gets on the floor, it will become slippery. After wiping product up with a cloth, spread sand or other absorbent
material, then wipe again to remove product completely.
6. Fluorosilicone greases (FG-720 series), G-420 are essentially harmless when used normally. However, if heated to
temperatures above 150 C, trace amounts of toxic gas will be released. When using these products in high temperature
conditions, be sure there is adequate ventilation.
7. Be sure to read the Material Safety Data Sheets (MSDS) for these products before use. MSDS are available from the Shin-Etsu
Sales Department.
22

 Packaging
Metal can

Pail can

G-30F

100g

1kg

18kg

G-30L

100g

1kg

18kg

G-30M

100g

1kg

18kg

G-30H

100g

1kg

18kg

G-40L

100g

1kg

20kg

G-40M

100g

1kg

20kg

G-40H

100g

1kg

20kg

1kg

20kg

1kg

16kg

Tube

Polyethylene bottle

Syringe

Plastic container

G-420

Greases

G-501

80g

FG-720

100g

1kg

20kg

FG-721

100g

1kg

20kg

FG-722

100g

1kg

20kg

G-302

1kg

18kg

G-503

1kg

16kg

G-411

100g

1kg

20kg

G-330

100g

1kg

15kg

G-331

100g

1kg

20kg

G-332

100g

1kg

20kg

G-333

1kg

20kg

G-334

1kg

20kg

G-340

100g

1kg

18kg

G-341

100g

1kg

18kg

G-342

1kg

18kg

G-631

1kg

18kg

G-632

1kg

18kg

G-633

1kg

18kg

KS-609

200g

1kg

KS-613
G-747

200g
100g

G-776

100g

G-777

200g
200g

G-750

Oil compound

90g, 1kg
1kg
90g

1kg

90g

1kg

90g

1kg

150g

1kg

G-751

100g

X-23-7762

100g

1kg

X-23-7783D

100g

1kg

X-23-7868-2D

100g

1kg
60g

X-23-7921-5

20kg
20kg

1kg

G-775

G-765

20kg

1kg

1kg
1kg

20kg

KS-64

100g

1kg

20kg

KS-64F

100g

1kg

20kg

KS-62F

1kg

20kg

KS-62M

1kg

20kg

1kg

20kg

1kg

16kg

1kg

18kg

KS-65A

1kg

20kg

KS-623

1kg

20kg

KS-622

1kg

15kg

KS-660

1kg

15kg

KS-660B

1kg

18kg

KS-63G

1kg

20kg

KS-63W

HIVAC-G

100g

KS-650N

100g

KS-651

50g
100g

Optseal

50g

Optseal-L

50g

1 DC(S): Designated Combustible (Synthetic resin)

23


< RTV Rubber & Grease and Oil compounds >
6-1, Ohtemachi 2-chome, Chiyoda-ku, Tokyo, Japan
Phone : +81-(0)3-3246-5152 Fax : +81-(0)3-3246-5362
1150 Damar Drive, Akron, OH 44305, U.S.A.
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CEP 01311-902 Sao Paulo/SP Brazil
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GT Tower 15F, 1317-23, Seocho-Dong,
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Bangkok 10500, Thailand
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Zhao Jia Bang Road, Shanghai 200032, China
Phone : +86-(0)21-6443-5550 Fax : +86-(0)21-6443-5868
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Tianhe, Guangzhou, Guangdong 510610, China
Phone : +86-(0)20-3831-0212 Fax : +86-(0)20-3831-0207

[Link]
C Shin-Etsu 2005.4 /2014.5
4 . K.N. Web in Japan.