WHY IS THE SKY BLUE ?
A clear cloudless day-time sky is blue because molecules in te air scatter
blue li!t "rom te sun more tan tey scatter red li!t# Wen $e look
to$ards te sun at sunset% $e see red and oran!e colours because te blue
li!t as been scattered out and a$ay "rom te line o" si!t#
Te $ite li!t "rom te sun is a mi&ture o" all colours o" te rainbo$# Tis
$as demonstrated by Isaac 'e$ton% $o used a (rism to se(arate te
di""erent colours and so "orm a s(ectrum# Te colours o" li!t are
distin!uised by teir di""erent $a)elen!ts# Te )isible (art o" te s(ectrum
ran!es "rom red li!t $it a $a)elen!t o" about *+, nm% to )iolet $it a
$a)elen!t o" about -., nm% $it oran!e% yello$% !reen% blue and indi!o
bet$een# Te tree di""erent ty(es o" colour rece(tors in te retina o" te
uman eye res(ond most stron!ly to red% !reen and blue $a)elen!ts% !i)in!
us our colour )ision#
Tyndall Effect
Te "irst ste(s to$ards correctly e&(lainin! te colour o" te sky $ere taken
by /on Tyndall in 0.12# He disco)ered tat $en li!t (asses trou! a
clear "luid oldin! small (articles in sus(ension% te sorter blue $a)elen!ts
are scattered more stron!ly tan te red# Tis can be demonstrated by
sinin! a beam o" $ite li!t trou! a tank o" $ater $it a little milk or
soa( mi&ed in# 3rom te side% te beam can be seen by te blue li!t it
scatters4 but te li!t seen directly "rom te end is reddened a"ter it as
(assed trou! te tank# Te scattered li!t can also be so$n to be
(olarised usin! a "ilter o" (olarised li!t% 5ust as te sky a((ears a dee(er blue
trou! (olaroid sun !lasses#
Tis is most correctly called te Tyndall e""ect% but it is more commonly
kno$n to (ysicists as 6aylei! scatterin!--a"ter Lord 6aylei!% $o studied
it in more detail a "e$ years later# He so$ed tat te amount o" li!t
scattered is in)ersely (ro(ortional to te "ourt (o$er o" $a)elen!t "or
su""iciently small (articles# It "ollo$s tat blue li!t is scattered more tan
red li!t by a "actor o" 7*,,89,,:
9
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Dust or Molecules?
Tyndall and 6aylei! tou!t tat te blue colour o" te sky must be due to
small (articles o" dust and dro(lets o" $ater )a(our in te atmos(ere# E)en
today% (eo(le sometimes incorrectly say tat tis is te case# Later scientists
realised tat i" tis $ere true% tere $ould be more )ariation o" sky colour
$it umidity or a=e conditions tan $as actually obser)ed% so tey
su((osed correctly tat te molecules o" o&y!en and nitro!en in te air are
su""icient to account "or te scatterin!# Te case $as "inally settled by
Einstein in 0200% $o calculated te detailed "ormula "or te scatterin! o"
li!t "rom molecules4 and tis $as "ound to be in a!reement $it
e&(eriment# He $as e)en able to use te calculation as a "urter )eri"ication
o" A)o!adro>s number $en com(ared $it obser)ation# Te molecules are
able to scatter li!t because te electroma!netic "ield o" te li!t $a)es
induces electric di(ole moments in te molecules#
Sunsets
Wen te air is clear te sunset $ill a((ear yello$% because te li!t "rom te
sun as (assed a lon! distance trou! air and some o" te blue li!t as
been scattered a$ay# I" te air is (olluted $it small (articles% natural or
oter$ise% te sunset $ill be more red# Sunsets o)er te sea may also be
oran!e% due to salt (articles in te air% $ic are e""ecti)e Tyndall scatterers#
Te sky around te sun is seen reddened% as $ell as te li!t comin! directly
"rom te sun# Tis is because all li!t is scattered relati)ely $ell trou!
small an!les--but blue li!t is ten more likely to be scattered t$ice or more
o)er te !reater distances% lea)in! te yello$% red and oran!e colours#
MUHAMMAD ZIA-UL-HAQUE
RATHORE
Lecturer in ?emistry
SZABIST Intermediate ?olle!e
@ir(urkas
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