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BEST HIGHER SECONDARY SCHOOL BHAIRAVNATH ROAD Std 11 Sem 1 Marks 30 Date 23/8/13 Time 60min Roll No Div All questions carries 1 mark {0.25% negative marking for incorrect answer} Which of the following has the highest mass? (A) 20g of sulphur (B) 4 mol of carbon dioxide (C) 12 1024 atoms of hydrogen (D) 11.2L of helium at S.T.P. If NA is Avogadro's number, then the number of oxygen atom in one g equivalent of oxygen is (A)NA (B) NA/2 (C) NA/4 (D) 2NA. The number of oxygen atoms present in 14.6 g of magnesium bicarbonate is{Mg =24, C=12,O=16,H=1} (A) 6No (B) 0.6 No (C) No (D) N0/2. NO reacts with O2 to form NO2. When 10 g of NO2 is formed during the reaction, the mass of O2 consumed is (A) 1.90 g (B) 5.0 g (C)3.48g (D)13.9g. One of the following combinations which illustrates the law of reciprocal proportions? (A) N2O3, N2O4, N2O5 (B) NaCI, NaBr, NaI (C)CS2, CO2, SO2 (D)PH3, P2O3 ,P2O5 On analysis a certain compound was found to contain iodine and oxygen in the ratio of 254 g of iodine (at. mass 127) and 80 g oxygen (at. Mass 16). What is the formula of the compound? (A) IO (B) I2O (C) I5O3 (D) I2O5 Insulin contains 3. 4% sulphur. What will be the minimum molecular weight of insulin? (A) 94.117 (B) 1884 (C) 941.76 (D) 976. B1 g of an element gives B2 g of its chloride, the equivalent mass of the element is (A) 35.5 (B) 35.5 (C) 35.5 (D) 35.5. The haemoglobin from red blood corpuscles of most mammals contain approximately 0.33% of iron by mass. The molecular mass of haemoglobin is 67200. The number of iron atoms in each molecule of haemoglobin is (A) 3 (B) 4 (C) 2 (D) 6. Two oxides of a metal contain 50% and 40% metal (M) respectively. If the formula of first oxide is MO2 the formula of second oxide will be (A) MO2 (B) MO3 (C) M2O (D) M2O5 Which one of the following properties of an element is not variable? (A) Valency (B) Equivalent mass (C) Atomic mass (D) All the three. Chlorophyll, the green colouring matter of plants responsible for photosynthesis contains 2.68 % of magnesium by mass. The number of magnesium atoms in 2.00 g of chlorophyll are (A) 1.33 x 1023 (B) 6.02 x 1023 (C)3.01 1021 (D) 1.34 x 1021 Following is the graphical presentation of volumes occupied by different gases at S.T.P. Which is/are not placed at correct position?
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(A) H2 He (B) He,NH3 (C) NH3, CH4 (D) CH4, H2 14. An organic compound contains 49.3% carbon,6.84% hydrogen and its vapour density is 73. Molecular formula of compound is (A) C3H5O2 (B) C6HI0O4 (C) C3H10O2 (D) C4HIOO2. 15. Molarity of liquid HCI with density equal to 1.17 g/cc is (A) 36.5 (B) 18.25 (C) 32.05 (D) 4.65 16. In uni electron system, the wave number of any spectral line is directly proportional to
(A) the number particles present in the system (B)the velocity of electron undergoing transition (C) (D)the charge on the nucleus and the of light used
17. The total number of electrons in a subshell designated by azimuthal quantum number, l is given as (A) 2 l + 1 (B) l2 (C) 4 l + 2 (D) 2l + 2. 18. According to Bohr's model of the atom, an electron can revolve around the atomic nucleus in a suitable orbit without emitting energy if its orbit (A) is a perfect circle (B) is a circle with a large radius (C) houses a whole number of de-Broglie waves (D) houses odd number of de-Broglie waves. 19. The transition of electrons inH atom that will emit maximum energy is (A) n3 n2 (B) n4 n3 (C) ns n4 (D) n6 ns 20. If the energy of electron in H atom is given by expression, 21. kJ mol-1, then the energy required to excite the electron from ground state to 1st excited state is (A) 328 kJ (B) 656 kJ (C) 984 kJ (D) 1312 kJ. In an atom which has 2K, 8L, 8M and 2N electrons in the ground state, the total number of electrons having =1are (A) 20 (B) 8 (C) 12 (D) 10. The penultimate shell of Francuim (Z =87) has the configuration (A) 2s22p6 (B)6s26p6 (C) 4s2 4p6 4d1o 4f14 (D) 5s2 5p65d10. Which shape is associated with the orbital designated by n =2; =1 ? (A) spherical (B) tetrahedral (C) dumb-bell (D) pyramidal. The two electrons have the following sets of quantum numbers . X: 3, 2, -2, + , Y : 3, 0, 0, + . What is true of the following? (A) X and Y have same energy (B) X and Y have unequal energy (C)X and Y represent same electron (D) None of the statements is correct. The total number of orbitals in fifth energy level should theoretically be (A) 10 (B) 25 (C) 15 (D) 18. The electronic configuration of a dipositive ion M+2 is 2, 8, 14 and its mass number is 56. The number of neutrons present is (A) 32 (B) 42 (C) 30 (D) 34. An atom has 2 K, 8 L, 11 M, 2 N electrons, the total number of s-electrons will be (A) 6 (B) 8 (C) 10 (D) 4. Sodium chloride imparts a yellow colour to the Bunsen flame. This can be interpreted due to the (A) low ionization energy of sodium (B) sublimation of metallic sodium to give yellow vapour (C) emission of excess energy absorbed as a radiation in the visible region (D) photosensitivity of sodium. The number of d-electrons in Fe2+ (atomic number = 26) is equal to that of (A) p electrons in 10Ne (B) s electrons in 12Mg (C) d electrons in Fe (D) p electrons in Cl. Two electrons in the same atomic orbital can be distinguished by their (A) principal quantum number (B) azimuthal quantum number (C) magnetic quantum number (D) spin quantum number Q No. 1 2 3 4 5 6 7 8 9 10 A B C D Q No. 11 12 13 14 15 16 17 18 19 20 A B C D Q No. 21 22 23 24 25 26 27 28 29 30 A B C D
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