03-05-2026

1103CJA101021260003 JA

PHYSICS

SECTION-I

1) Seven capacitors, each of capacitance 2μF are to be connected to obtain a capacitance

of 10/11μF. Which of the following combinations is possible ?

(A) 5 in parallel 2 in series

(B) 4 in parallel 3 in series
(C) 3 in parallel 4 in series
(D) 2 in parallel 5 in series

2) Find the potential difference across AB. If voltage of ideal battery 5 Volt is :

(A) 4 V
(B) 2 V
(C) 1 V
(D) None of these

3) Two air filled capacitors are connected as shown. The left capacitor is suddenly filled with a
dielectric of constant K. The work done by battery after that is 24µJ. Dielectric constant K is :-

(A) 2
(B) 3
(C) 4
(D) 6

4) In figure an arrangement of three identical capacitors is shown along with a switch S and a
battery B. If the switch S is closed, then the ratio of the energy of the capacitors system in the final
steady state to the initial state is :

(A) 2 : 1
(B) 4 : 3
(C) 3 : 2
(D) 3 : 4

5) In the circuit diagram shown all the capacitors are in μF. The equivalent capacitance between

points A & B is (in μF)

(A) 14/5
(B) 7.5
(C) 3/7
(D) None of these

6) In the circuit shown in figure, the equivalent capacitance between the points X and Y is :

(A)
(B)
(C)
(D)

7) Initially the circuit is in steady state. Now one of the capacitor is filled with dielectric of dielectric
constant 2. Find the heat loss in the circuit due to insertion of dielectric:
(A)

(B)

(C)

(D)

8) A parallel plate capacitor of capacitance 1 μF is charged to a potential difference of 20 V. The

distance between plates is 1 μm. The energy density between plates of capacitor is :

(A) 1.8 × 103 J/m3

(B) 2 × 10–4 J/m3
(C) 2 × 102 J/m3
(D) 1.8 × 105 J/m3

9) In the figure shown, C1 = 10 mF, C2 = 20 mF and C3 = 15 mF. The charge on C2 is:

(A) 400 mC
(B) 800 mC
(C) 1200 mC
(D) 200 mC

10)

Three capacitors are connected as shown in figure. Then the charge on C1 is

(A) 6 μC
(B) 12 μC
(C) 18 μC
(D) 24 μC

11) Figure shows the capacitors in steady state, with S open. When S is closed :-

(A) Both batteries supply energy & heat is lost.

(B) Both batteries supply energy to increase the energy of both the capacitors separately
(C) One battery supplies & other absorbs energy and no heat loss takes place
(D) One battery supplies energy, other absorbs and heat is lost in the process.

12) A simple pendulum of mass 'm', length 'ℓ' and charge '+q' suspended in the electric field
produced by two conducting parallel plates as shown. The value of deflection of pendulum in

equilibrium position will be

(A)

(B)

(C)

(D)

13) Two conducting large plates P1 and P2 are placed parallel to each other at very small separation
‘d’. The plate area of either face of plate is A. A charge + 2Q is given to plate P1 and –Q to the plate
P2 (neglect ends effects). If plate P1 and P2 are now connected by conducting wire, then total amount
of heat produced is:

(A)

(B)

(C)

(D) None of these

14) Three dielectrics of relative permittivities , and are introduced in a parallel

plate capacitor of plate area A and separation d. Find the effective capacitance between A and B.

(A)

(B)

(C)

(D) None of these

15) Five identical parallel conducting plates each of area A have separation ‘d’ between successive
surfaces. The plates are connected to the terminal of a battery as shown in the fig. The effective

capacitance of the circuit is

(A)
(B)

(C)

(D)

16) In an isolated parallel-plate capacitor of capacitance C, the four surfaces have charges Q1, Q2, Q3

and Q4, as shown. The potential difference between the plates is-

(A)

(B)

(C)

(D)

17) A capacitor of capacitance 100 µF is charged to potential difference of 24 V. The charging

battery is disconnected and the capacitor is connected to another battery of emf 12 V with positive
plate of capacitor joined with positive terminal of battery.

List–I List–II

(P) Work done by battery of emf 24 V (1) 7.2 mJ

(Q) The decrease in electrostatic field energy (2) 14.4 mJ

(R) Work done on battery of emf 12 V (3) 21.6 mJ

The heat developed during flow of charge after

(S) (4) 57.6 mJ
reconnection.
(A) (P) - (4) ; (Q) - (3) ; (R) - (2) ; (S) - (1)
(B) (P) - (4) ; (Q) - (2) ; (R) - (1) ; (S) - (3)
(C) (P) - (2) ; (Q) - (3) ; (R) - (1) ; (S) - (4)
(D) (P) - (2) ; (Q) - (3) ; (R) - (4) ; (S) - (1)

18) Figure given below shows two identical parallel plate capacitors connected to a battery with
switch S closed. The switch is now opened and the free space between the plate of capacitors is
filled with a dielectric of dielectric constant 3. What will be the ratio of total electrostatic energy
stored in both capacitors before and after the introduction of the dielectric :-
(A) 3 : 1
(B) 5 : 1
(C) 3 : 5
(D) 5 : 3

19) The energy stored in the capacitor is :-

(A) 56 µJ
(B) 60 µJ
(C) 64 µJ
(D) 68 µJ

20) In the figure shown, after the switch 'S' is turned from position 'A' to position 'B', the energy
dissipated in the circuit in terms of capacitance 'C' and total charge 'Q' is:

(A)

(B)

(C)

(D)

SECTION-II

1) The value of equivalent capacitance of the combination shown in figure between the points P
and Q is nC, find n.

2) Initially S is open and capacitor A is charged up to potential difference and capacitor B is

uncharged. After closing the switch S the heat loss in the circuit is . Find n?

3) In the given figure charge on capacitor C2 is α2 μC. Then α is :

4) 3 plates A, B & C each of area 1 m2 are separated by 0.885 mm. Energy stored in system (in µJ) is

5) A parallel plate capacitor having plates of area S and plate separation d, has capacitance C1 in air.
When two dielectrics of different relative permittivities (ε1 = 2 and ε2 = 4) are introduced between

the two plates as shown in the figure, the capacitance becomes C2. Then ratio is
 CHEMISTRY

SECTION-I

1) An aromatic compound 'A' C7H6Cl2, gives AgCl on bonding with alcoholic AgNO3 solution, and
yields C7H7OCl on treatment with sodium hydroxide. 'A' on oxidation gives a mono chlorobenzoic
acid which affords only one mononitro derivative. The compound A is:

(A)

(B)

(C)

(D)

2) In the given reaction 3-Bromo-2, 2-dimethyl butane Product A is:

(A) 2-Ethoxy-3, 3-dimethyl butane
(B) 1-Ethoxy-3, 3-dimethyl butane
(C) 2-Ethoxy-2, 3-dimethyl butane
(D) 2-Hydroxy-3, 3-dimethyl butane

3)

(A)

(B)

(C)

(D) None of these

4) Consider the solvolysis of 5-hexenyl-p-nitrobenzenesulfonate. The rate is slightly enhanced and a

cyclic product is formed. This is an example of:

(A) π-participation (double bond NGP).

(B) σ-participation.
(C) SN​2′.
(D) SN​1 with rearrangement.

5) Identify A in the given reaction.

(A)
(B)

(C)

(D)

6) The ascending order of relative rate of solvolysis of following compounds is

(A) (D) < (A) < (B) < (C)

(B) (C) < (B) < (A) < (D)
(C) (D) < (B) < (A) < (C)
(D) (C) < (D) < (B) < (A)

7) pH of a 1 M monobasic weak acid is found to be 2. Hence its osmotic pressure at a given

temperature T K is -

(A) 0.1 RT
(B) 0.11 RT
(C) 1.1 RT
(D) 1.01 RT

8) If a ground water contains H2S at concentration of 2 mg/l, determine the pressure of H2S in head
space of a closed tank containing the ground water at 20°C. Given that for H2S, Henry's constant is
equal to 6.8 × 103 bar at 20°C.

(A) 720 Pa
(B) 77 × 102 Pa
(C) 553 Pa
(D) 55 × 102 Pa

9) For the solution of the gases w, x, y and z in water at 298K, the Henrys law constants (KH) are 0.5,
2, 35 and 40 kbar, respectively. The correct plot for the given data is :-

(A)

(B)

(C)

(D)

10) V. P. of pure A p°A = 100 mmHg V. P. of pure B p°B = 150 mmHg

Distillate of vapours of a solution containing 2 moles A and 3 moles B will have total vapour
pressure, approximately, on condensation

(A) 135 mm
(B) 130 mm
(C) 140 mm
(D) 145 mm

11) Which of the following has been arranged in order of decreasing freezing point ?

(A) 0.05 M KNO3 > 0.04 M CaCl2 > 0.140 M sugar > 0.075 M CuSO4
(B) 0.04 M BaCl2 > 0.140 M sucrose > 0.075 M CuSO4 > 0.05 M KNO3
(C) 0.075 M CuSO4 > 0.140 M sucrose > 0.40 M BaCl2 > 0.05 M KNO3
(D) 0.075 M CuSO4 > 0.05 M NaNO3 > 0.140 M sucrose > 0.04 M BaCl2
12) Which of the following aqueous solution will show maximum vapour pressure at 300 K?

(A) 1 M NaCl
(B) 1 M CaCl2
(C) 1 M AlCl3
(D) 1 M C12H22O11

13)
0 0
Two liquids A and B have, PA and PB = 1 : 3 at a certain temperature. Assume A and B form an ideal
solution, and the ratio of mole of A to B in the liquid phase are 1 : 3, then mole fraction of A in
vapour phase in equilibrium with the solution -

(A) 0.1
(B) 0.2
(C) 0.5
(D) 1.0

14)

On mixing 10 mL of acetone with 40 mL of chloroform , the total volume of the solution is :

(A) < 50 mL
(B) > 50 mL
(C) = 50 mL
(D) Cannot be predicted

15) 1.0 molal aqueous solution of an electrolyte A2B3 is 60% ionised. The boiling point of the solution
at 1 atm is ( )

(A) 274.76 K
(B) 377 K
(C) 376.4 K
(D) 374.76 K

16) The relative lowering of the vapour pressure of an aqueous solution containing a urea solute is
0.2. The molality of solution is :

(A)
mole/kg

(B)
mole/kg

(C)
mole/kg

(D)
mole/kg
17) Statement-1 : 5% w/V aqueous solution of glucose is isotonic with 5% w/V aqueous solution of
urea at same temperature.
Statement-2 : Glucose and urea has same Van't Hoff factor in their aqueous solution.

(A) Statement-1 is true, Statement-2 is true and Statement-2 is correct explanation for Statement-1
Statement-1 is true, Statement-2 is true and Statement-2 is NOT the correct explanation for
(B)
Statement-1
(C) Statement-1 is true, Statement-2 is false
(D) Statement-1 is false, Statement-2 is true

18) When a concentrated solution is separated from a dilute solution by SPM, which is the best
description of what is occurring ?

(A) Solute molecules flow from the solution of higher concentration.

(B) Solute molecules flow from the solution of lower concentration.
Solvent molecules move in each direction with an overall movement from concentrated to the
(C)
dilute solution.
Solvent molecules move in each direction with an overall movement from dilute to concentrated
(D)
side of the solution.

19) Two solutions S1 and S2 containing 0.1 M NaCl (aq) and 0.05 M BaCl2 (aq) are separated by

semipermeable membrane. Which among the following statement(s) is/are

correct ? (Assume complete dissociation of both the electrolytes)

(A) S1 and S2 are isotonic

(B) S1 is hypertonic while S2 is hypotonic
(C) S1 is hypotonic while S2 is hypertonic
(D) All the above

20) Predict the product of the following reaction: (S)−2-iodooctane + CH3​COO− (in the presence of a
catalytic amount of Ag+ and a neighboring o−COO− group on an attached benzene ring).

(A) (R)-2-octyl acetate

(B) (S)-2-octyl acetate
(C) Racemic 2-octyl acetate
(D) 1-octene

SECTION-II

1)
Among the 6, how many cyclic isomers of molecular formula C7H13Br can form 1-
methylcyclohexane-1-ol on reaction with H2O/acetone/Ag+.

(I) (II)

(III) (IV)

(V) (VI)

2)

Identify total number of SN1 reactions

3)

Calculate percnetage of SN1 product if (R)–2–chloro butane on reaction with NaOH/H2O and acetone
gives 98 per cent inverted product.

4)
Give total number of ether products (including stereoisomers) in above reaction.

5)

Liquids A and B form ideal solution over the entire range of composition. At temperature T,
equimolar binary solution of liquids A and B has vapour pressure 45 Torr. At the same temperature,
a new solution of A and B having mole fractions xA and xB respectively, has vapour pressure of 22.5

Torr. If the value of in the new solution is Y. Then the value Y – 10 is :

(Given that the vapour pressure of pure liquid A is 20 Torr at temperature T)

MATHEMATICS

SECTION-I

1) Let f(x) be a continuous function in [–1, 1] such that , then (p

+ q + r) is equal to

(A) 3
(B) 2
(C) 1/3
(D) 5

2) Consider two functions ƒ(x), g(x) as follows

g(x) = ƒ(x + 2) + ƒ(x – 2). The number of points of discontinuity of g(x) is -

(A) 0
(B) 1
(C) 2
(D) 3
3) If , then f(x) is :

(A) Differentiable at x = 0
(B) Not differentiable at x = 0
(C) Differentiable & Continuous ∀ x ∈ R
(D) None of these

4) If f(x) = cosx.cos2x.cos4x.cos8x.cos16x then ........

(A)

(B)

(C) 1
(D) None of these

5) If is continuous at x = 0, then k equals

(A) log102 log103

(B)
(C) ℓn2 ℓn3
(D) none of these

6) The function f(x) = [x]2 – [x2] is discontinuous at

(A) all integers

(B) all integers except 1
(C) all integers except 0
(D) None of these

7) Let f : (–1,1) → R be a function defined by f(x) = max If K be the set of all points
at which f is not differentiable, then K has exactly :

(A) Three elements

(B) One element
(C) Five elements
(D) Two elements

8) Let
Let S be the set of points in the interval (–4,4) at which f is not differentiable. Then S:

(A) is an empty set

(B) equals {–2, –1, 1, 2}
(C) equals {–2, –1, 0, 1, 2}
(D) equals {–2, 2}

9) Let the functions ƒ : → and g : → be defined as :

and
Then, the number of points in where (fog)(x) is NOT differentiable is equal to :

(A) 3
(B) 1
(C) 0
(D) 2

10) Let α ∈ R be such that the function

is continuous at x = 0, where {x} = x – [x], [x] is the greatest integer less than or equal to x. Then :

(A)

(B) α = 0
(C) no such α exists

(D)

11)

The value of is
(where [.] is greatest integer function)

(A) 199
(B) 198
(C) 0
(D) does not exist

12) equals :

(A)
(B)

(C) 3

(D)

13) is equal to

(A)

(B)

(C)

(D) None of these

14) exists and is non-zero, then the value of n is -

(A) 1
(B) 3
(C) 2
(D) 0

15) is equal to

(A)

(B)

(C) 1
(D) D.N.E.

16) If , then λ is equal to -

(A) –π
(B) π

(C)

(D)

17) For each t ∈ R, let [t] be the greatest integer less than or equal to t. Then
(A) is equal to 15.
(B) is equal to 120.
(C) does not exist (in R).
(D) is equal to 0.

18)

If y = , =

(A)

(B)

(C)

(D) None of these

19) If xpyq = (x + y)p + q then the value of is where p, q ϵ N :

(A) 0
(B) -1
(C) 1
(D) None of these

20) If then at x = 0 is :

(A) 1
(B) 0
(C) –1
(D) None of these

SECTION-II

1)

The slope of the tangent to the curve y = xx lnx + xlnx at x = 1 is

2) If y = , then the value of is equal to -

3) If the value of is e–A then ‘A’ is :

4) Value of is

5) If x ∈ [–1,3], then number of points of discontinuity of the function ƒ(x) = [x2 – 2x + 5] is equal to
(where [.] represents greatest integer function)
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C A B A D A A B A D C B C B C A C C A

SECTION-II

Q. 21 22 23 24 25
A. 3.00 8.00 6.00 1.00 7.00

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A C B A B A D A C A A D A A D A D D B B

SECTION-II

Q. 46 47 48 49 50
A. 5.00 3.00 4.00 4.00 9.00

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A B A C B A C B C B B A B B C B B A A

SECTION-II

Q. 71 72 73 74 75
A. 1.00 4.00 0.36 1.33 8.00
 SOLUTIONS

PHYSICS

1)

5(2μF) in series with , 10μF in series with 1μF, Ceq=

2)

∴ 1V

3) Explain Question: We have to find the dielectric constant(K) of the dielectric filled
between the plate of a parallel plate capacitor, when the work done by the battery is given.
Concept: This question is based on dielectric analysis of capacitors.
Solution: Work done by battery: WD = ΔQV
WD = ΔQV
24µJ = ΔQ(6) ⇒ ΔQ = = 4µC

Initial Charge: Qi = = 8µC

Final charge: Qf = Qi + ΔQ = 8µC + 4µC = 12µC
Qf = Ceq × 6 ⇒ Ceq = 2µF ⇒ C1 = C2 = 4µF
Now, the dielectric constant K can be obtained as: K × 2μF = 4μF
Thus the value of dielectric constant K is 2.
Final Answer: Option (1)

4)
5)

6)

Circuit is redrawn as shown in Figure

In the Circuit, capacitors and are connceted in series. Combination of this is in

parallel with and capacitors.

7)

charge given by battery =

⇒ work done by battery =
Initial energy stored

Final energy stored

Wb = ΔU + Heat loss

⇒ Heat loss =

8)

C = 1 μF

V = 20 V

d = 1 μm

Energy density =

U = 1.77 × 103 J/m3

9)
QTot = CeqV
QTot = (Ceq)20

10) Asking About:

The question asks to determine the charge stored on capacitor C1 in a circuit containing
multiple capacitors and voltage sources.
Concept:
• Conservation of Charge: The total charge at a node remains conserved.
• Capacitance Relation: Capacitance C is the ratio of charge Q stored to the voltage V across
the capacitor:
• Potential Difference: The voltage difference between two points determines the charge
stored in a capacitor.
Formula : Q = C × V Calculation / Explanation:
1. Determine Potential at Point A:
• Let the potential at point A be z.
• Using charge conservation at node A: (x – 6)2 + (x – 6)2 + (x + 0)4 = 0 Simplifies to: 4x –
24 + 4x = 0 8x=24 ⇒ x = 3V 2. Calculate Charge on C1:
• Capacitance of C1 = 2 µF.
• Potential difference across C1 is: |x – 6| = |3 – 6| = 3V • Using Q = C × V: Q1 = 2 × 3 = 6 μC
Final Answer:
The charge across capacitor C1 is 6 μC

11)

One battery supplies energy, other absorbs and heat is lost in the process.

12)
Let E be electric field in air
T sinθ = qE
T cosθ = mg

tanθ =

Now,

13) ,
After connecting
Uf = 0

Heat =

14) C= assume

C1 = = 2C

C2 = = 3C

C3 =

CAB =
15)
C = 4C
eq

16) Plane conducting surfaces facing each other must have equal and opposite charge
densities.
Here, as the plate areas are equal, Q2 = –Q3.
The charge on a capacitor means the charge on the inner surface of the positive plate, in this
case, Q2.
Potential difference between the plates = charge on the capacitor ÷ a capacitance.

∴ potential difference =

17) (P) W24 = 2400 × 10–6 × 24

= 576 × 10–4
W24 = 57.6 mJ

(Q) ΔU = (100 × 10–6)[(24)2 – (12)2]

= 21.6 mJ
(R) ΔQ = 1200 – 2400 = –1200 µC
W12 = –1200 × 10–6 × 12 = – 14.4 mJ
(S) W12 = ΔU + H
∴ H = –14.4 + 21.6
H = 7.2 mJ

18) Explain Question: We have to find the ratio of initial and the final energy of the given
capacitor circuit after the introduction of dielectric and opening the switch.

Concept: This question is based on energy analysis of capacitors and dielectric analysis.

Solution: Initially, with switch S closed, both identical capacitors (let's say capacitance C) are

in parallel across the battery V. The total initial energy:

When the switch S is opened, capacitor A remains connected to the battery V, while capacitor
B becomes isolated

B will get disconnected from the battery, and since it is isolated, charge on it remains the
same. Hence, p.d. across B decreases and capacitance increase due to insertion of dielectric.
Ratio of energies :

Final Answer: Option(3)

19) Potential at B = +6 + (–4 + 2) = + 4V

Energy stored in the capacitor

20)

21) Explanation:
The question gives a network of capacitors connected between two points P and Q. We need to
find the total or equivalent capacitance of this combination and express it as nC, where n is
the required numerical value.

Concept:
This question is based on the concept of series and parallel combinations of capacitors.
Solution :

Cequ = C + 2C = 3C
Final Answer : 3

22)

Let charge supplied by battery is q.

Apply KVL

Energy supplied by battery ; Energy consumed by capacitors = Uf – Ui

Heat loss =

23)

24) here,

= 2 × 10–8 F

= 1 µJ

25)
 and

CHEMISTRY

26) Question Explanation:

Identify aromatic compound 'A' C7H6Cl2. It precipitates AgCl with alcoholic AgNO3, reacts with
NaOH to form C7H7OCl, and oxidizes to a monochlorobenzoic acid yielding only one mononitro
derivative.

Concept:

This question is based on

A. Chemical Tests for Halides,

B. Reactions of Benzylic Halides,

C. Oxidation of Alkylbenzenes,

D. Directing Effects in Electrophilic Aromatic Substitution.

Solution:
Reactions are as follows:

Final Answer: Option (1)

27)

28)

29) Concepts:
π-assisted solvolysis (π-route).

Solution:
The π-bond at the 5-6 position can attack the C1 center to form a cyclohexyl cation (5-exo-
trig/6-endo-trig logic).

Final Answer: Option (1)

30)

31)

Solvolysis or SN1 ∝ stability of carboccation

Stability order

32) 1M
HA H+ + A –
(C – C∝) C∝ C∝
+ –2
[H ] = 10 ∵ PH = 2
C∝ = 10–2
1 × ∝ = 10–2
∝ = 10–2
π = i CRT
=(1 + ∝) CRT
=(1 + 10–2) × 1RT
1.01 RT

33) Henry's law,

Pi = [Link]; where;
Pi = partial pressure of gas above the liquid
Xi = mole fraction of gas in the liquid
KH = Henry's constant
substituting values in the expression; we get

⇒
= 7.2 × 10–3 bar = 720 Pa

34) Question Explanation : Find correct plot for the given data.
Concept : Henrys law
Solution:
According to Henry's law;
Pi = KH. Xi ; where
Pi = partial pressure of gas above the solution
Xi = mole fraction of gas in the solution
KH = Henry's constant
⇒ Pi = KH
⇒ Pi = (– KH) ; comparing with
Y = (m)X + C ;
slope = – kH ; y-interecpt = kH
Final Answer : Option (3)

35)

In the distillate, above solution will be liquid.

Hence, , .

Hence, new

36)

Correct Answer is Option (1).

37)

Correct Answer is Option (D).

38)

Pt = =

=
PT . YA =

⇒ yA =

39)

Acetone and chloroform forms hydrogen bonding so volume decreases.

40) ΔTb = i. kb. m
= [1 + 0.6 (5 – 1)] × 0.52 × 1
= 1.768
Tb = 1.768 + 373 = 374.76 K

41)

42) Explain the question: Assess if two solutions are isotonic and the validity of the given
reason.
Concept: Osmotic Pressure and Van't Hoff Factor.
Solution:
Statement-2. Glucose and urea are both non-electrolytes; they do
not dissociate in an aqueous solution. Therefore, the Van't Hoff factor for both is 1. So,
Statement-2 is true.
Statement-1. For the solutions to be isotonic, must equal . Since ' i ', ' R ', and ' T
' are the same for both, this condition requires their molar concentrations (C) to be equal.
For 5\% w/V glucose: C = ( )/ .
For
Since the molar concentrations are not equal , the solutions are not isotonic.
Therefore, Statement- 1 is false.

Final Answer: Option (4)

43) Question Explanation:

Describe the process of osmosis.

Concept:
Osmosis / Solvent Potential.

Solution:
Osmosis is the spontaneous net movement of solvent molecules through a semi-permeable
membrane (SPM) into a region of higher solute concentration. The SPM blocks the passage of
larger solute molecules. While individual solvent molecules move randomly across the
membrane in both directions, there is a greater probability of movement from the dilute side
(which has a higher concentration of solvent molecules) to the concentrated side (which has a
lower concentration of solvent molecules). This results in a net flow that aims to equalize the
solute concentrations on both sides.

Final Answer:
Correct option is (4)

44) For S1; i1 × C1 = 2 × 0.1 = 0.2 → Hypertonic

 For S2; i2 × C2 = 2 × 0.05 = 0.15 → Hypotonic

45) Concepts:
Ortho-carboxylate participation in benzylic/alkyl systems.

Solution:
This is a classic "double inversion" setup. The o−COO− attacks first to form a cyclic
intermediate (inversion 1), then the external acetate attacks the intermediate (inversion 2).
Result: Retention.

Final Answer: Option (2)

46)

Explanation Question: Question is asking about how many cyclic isomer of molecular
formula C7H13Br cam form 1-methyl cyclohexane -1-o . on reaction with H2O/ Acetone/Ag+.
Concept: This question is based on SN1 reaction of alkyl halide.
Solution:

(i)

(ii)

(iii)

(iv)
No rearrangement required

(v)
1, 2 Hydride Shift
(vi)
Only 5 will give desired products

Final answer (5)

47)

Reaction occurs only in presence of solvent follows SN1 mechanism

48)

49)

Concept : This question is based on

(a) free radical allylic substitution
(b) SN2 reaction of alkyl bromide.

Solution :-
NBS is used for allylic or benzylic bromination.
This reaction follows free radical substitution.
 Final answer: 4

50) Explain Question: The question is asking to find the value of Y – 10

Concept: Raoult's law
Solution:
Given : →
1. → A and B are in equimolar solution.
= 0.5
= 45 Torr, = 20 Torr

45 = 0.5 × 20 + 0.5
45 – 10 = 0.5
= 70 Torr
2. PT = 22.5 Torr
PT = XA + XB , XA + XB = 1 XA = 1– XB
PT = (1–XB)
22.5 = 20 – 20XB + 70 XB
2.5 = 50 XB
XB = 0.05
XA= 1–0.05 = 0.95

y – 10 = 19 – 10 =
Final Answer: (9)

MATHEMATICS
51)

Correct Answer is Option (B).

52)

Correct Answer is Option (A).

53) LHD =

RHD =

54)

Correct Answer is Option (A).

55) Explain Question:

Find unknown parameter k.

Concept:
Use standard limit

Solution:

= 2(ℓn9.ℓn4. )
=

Final Answer: option (3)

56)

Correct Answer is Option (B).

57) f : (–1, 1) → R
 f(x) = max

Non-derivable at 3 points in (–1, 1)

58)

Explain Question: Check differentiability of the given function.

Concept: Draw the graph of the function and observe corner points.

Solution:

ƒ(x) is not differentiable at x = {–2,–1,0,1,2}

⇒ S = {–2, –1, 0, 1, 2}

Final Answer: Option (3)

59)

Explain Question: Check differentiability of fog(x)

Concept: First find fog and check differentiability at the point where function breaks.

Solution:
at x = 0
L.H.L. ≠ R.H.L. (Discontinuous) ⇒ Not differentiable
At x = 1
L.H.D. = 6 = R.H.D. ⇒ differentiable
∴ fog(x) is differentiable for x ∈ –{0}

Final Answer: Option (2)

60)

Explain Question:
Check L.H.L. & R.H.L. at x=0

Concept:
Use F.P.F, standard limit

Solution:

Let 1 – x2 = cos θ

Now,

⇒ RHL ≠ LHL
Function can't be continuous
⇒ No value of α exist

Final answer: option (3)

61)

Correct Answer is Option (B).

62)

Correct Answer is Option (B).

63)

Correct Answer is Option (A).

64)

Cleally limit is finite and non-zero if n = 3

and limit

65)

66)

put

67)

∵ 0≤ <1
0≤x <x

= = 120

68)

Question Explanation: Differentiating an infinite functional power series.

Concept: Logarithmic Differentiation of Infinite Series.

Solution:

Given:

A. Simplified form:

B. Taking Log:

C. Differentiating:

D. Isolating

E. Simplifying:

F. Result:

Final Answer: Option (3)

69)

Correct Answer is Option (A).

70)
Multiplying numerator and denominator by (1 – x)

⇒
⇒

So,
Hence option (1) is correct answer.

71)

Explain Question:
Calculate the slope of the tangent to the curve y=xx ln x+xlnx at the point x=1.

Concept:
Product Rule, Logarithmic Differentiation. Solution:
Let y=u+v, where u=xx ln x and v = xlnx.

Slope m =

1. Derivative of first part (u) :

Using product Rule

2. Derivative of second part (v):

Let v = xln x ⇒ ln v = (ln x)2.

At x = 1:

Total Slope :

⇒ =1+0=1
Final answer : 1.00

72)

Correct Answer is 4.00

73)

74) Let

75) Rough sketch of the curve y = x2 – 2x + 5 the greatest integer

function is discontinuous at y = 5,6,7,8 (integral values except y = 4)
i.e. the points A,B,C,D,E,F,G,H (in figure)