Easy to Learn….

SOLUTIONS

EXERCISE LEVEL-01
(Topic Wise Questions)
CONCENTRATION TERMS Q.9 1000 g aqueous solution of CaCO3 contains 5 g
Q.1 What is the mole fraction of glucose in 10% w/w of calcium carbonate concentration of the
aqueous solution of glucose solution? solution is:
(1) 0.01 (2) 0.02 (3) 0.03 (4) 0.04 (1) 5 ppm (2) 50 ppm
(3) 500 ppm (4) 5,000 ppm
Q.2 What is the normality of 2M H3PO2 solution?
(1) 0.5 N (2) 1.0 N Q.10 Normality of 10% (w/V) H2SO4 solution is nearly
(3) 2.0 N (4) 3.0 N (1) 0.1 (2) 2 (3) 0.5 (4) 0.2

Q.3 6.02 × 1020 molecules of urea are present in Q.11 Molarity of 400 g of pure water is:
100 mL of its solution. The concentration of (1) 40M (2) 4M
solution is: (3) 55.5M (4) Can't be determined
(1) 0.01 M (2) 0.02 M
(3) 0.1 M (4) 0.001 M Q.12 8 g NaOH is dissolved in one litre of solution. Its
molarity is:
Q.4 The molarity of 98% (w/w) H2SO4 (d = 1.8 g mL–1)
(1) 0.8 M (2) 0.4 M
is:
(3) 0.2 M (4) 0.1 M
(1) 6 M (2) 10 M
(3) 18 M (4) 4 M Q.13 Mole fraction of ethanol in water is 0.25.
Hence percentage by weight of ethanol in
Q.5 4 g NaOH is dissolved in 500 mL solution what
solution is:
is the molarity of resulting solution?
(1) 25% (2) 75% (3) 46% (4) 54%
(1) 0.6 M (2) 0.2 M
(3) 1 M (4) 0.4 M
Q.14 H2O2 solution used for hair bleaching is sold as a
solution of approximately 5.0 g H2O2 per 100 mL
Q.6 Density of 2.03 M aqueous solution of acetic acid
of the solution. The molarity of this solution is
is 1.017 g mL–1. Calculate the molality of
approximately:
solution?
(1) 0.15 M (2) 1.5 M
(1) 2.27 m (2) 1.27 m
(3) 3.0 M (4) 3.4 M
(3) 3.27 m (4) 4.27 m
Q.15 15 gram of methyl alcohol is dissolved in 35 gram
Q.7 A molar solution is one that contains one mole of
of water. What is the mass percentage of methyl
solute in:
alcohol in solution?
(1) 1000 g of the solvent
(1) 70% (2) 50%
(2) one litre of the solution
(3) 30% (4) 75%
(3) 1000 g of the solution
(4) 22.4 litre of the solution
Q.16 An X molal solution of a compound in benzene
has mole fraction of solute equal to 0.2. The value
Q.8 A 500 g tooth paste sample has 0.02 g fluoride
of X is:
concentration. What is the concentration of
(1) 14 (2) 2
fluorine in terms of ppm level?
(3) 1.4 (4) 3.2
(1) 250 (2) 400 (3) 40 (4) 1000
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CHEMISTRY Easy to Learn….
Q.17 Two bottles of A and B contains 1M and 1m Q.23 Increasing the temperature of an aqueous solution
aqueous solution of sulphuric acid respectively: will change:
(d  1 g mol–1) (1) molality (2) molarity
(1) Concentration of A = conc. of B (3) mole fraction (4) % w/w
(2) B is more concentrated than A
HENRY'S LAW
(3) A is more concentrated than B
Q.24 Which of the following relation represents the
(4) It is not possible to compare the concentration
Henry’s law?
Q.18 Molar concentration of a solution in water is: (1) P = KHX (2) P = KH
(d  1 g mol–1) (3) (1) and (2) (4) None of these
(1) Always equal to normality
Q.25 Henry's law constant for dissolution of CH 4 in
(2) More than molality of the solution
benzene at 298 K is 2 × 105 mm of Hg. Then
(3) Equal to molality of the solution
solubility in mole fraction of CH 4 in benzene
(4) Less than the molality of the solution
at 298 K under 760 mm of Hg is:
Q.19 The mole fraction of the solute in one molal (1) 1.2 ×10–5 (2) 3.8×10–3
aqueous solution is : (3) 4×10–7 (4) 1×10–2
(1) 0.027 (2) 0.036
Q.26 Which of the gas will not follow Henry's law?
(3) 0.018 (4) 0.009
(1) HCl (2) He (3) O2 (4) H2
Q.20 Strength of H2O2 is 15.18 gL–1, then it is equal to:
Q.27 In solubility of gas 'X' is 0.5 gL–1 at 1 bar then its
(1) 5 volume (2) 10 volume
solubility at 3 bar pressure will be:
(3) 1 volume (4) 7 volume
(1) 0.5 gL–1 (2) 1.5 gL–1
Q.21 The concentration of a solution of H2O2 is (3) 3.0 gL–1 (4) 2 gL–1
6.8%(w/v) then the volume strength of the
VAPOUR PRESSURE AND RAOULT'S LAW
solution is:
(LIQUID-LIQUID MIXTURE)
(1) 22.4 (2) 11.2
Q.28 Two liquids X and Y form an ideal solution. At
(3) 20 (4) 5
300 K, vapour pressure of the solution containing
Q.22 Which of the following statement is true: – 1 mol of X and 3 mol of Y is 550 mm Hg. At the
(a) Molarity is the no. of moles of solute same temperature if 1 mol of Y is further added
dissolved per litre of solvent. to this solution, vapour pressure of the solution
(b) The molarity and normality of a solution of increases by 10 mm Hg. Vapour pressure (in mm
sodium carbonate are same. Hg) of X and Y in their pure states will be
(c) Molality (m) of a solution is defined as the respectively
number of moles of solute dissolved in 1000 (1) 200 and 300 (2) 300 and 400
g of solution (3) 400 and 600 (4) 500 and 600
(d) The ratio of mole fraction of solute and Q.29 The boiling point of C6H6, CH3OH, C6H5NH2 and
solvent is in the ratio of their respective C6H5NO2 are 80°C, 65°C, 184°C and 212°C
moles. respectively. Which will show highest vapour
(1) a & c (2) a & d pressure at room temperature:
(3) b & c (4) Only d (1) C6H6 (2) CH3OH
(3) C6H5NH2 (4) C6H5NO2

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 Easy to Learn…. SOLUTIONS
Q.30 At 88 °C benzene has a vapour pressure of IDEAL AND NON-IDEAL SOLUTION
900torr and toluene has a vapour pressure of Q.36 Among the following that forms an ideal solution:
360torr. What is the mole fraction of benzene in (1) water and methanol
the mixture with toluene that will boil at 88 °C at (2) acetone and ethanol
1 atm. pressure, benzene - toluene form an ideal- (3) benzene and toluene
solution: (4) water and HCl
(1) 0.416 (2) 0.588
(3) 0.688 (4) 0.740 Q.37 On mixing 10 mL of acetone with 40 ml of
chloroform the total volume of the solution is:
Q.31 1 mole of heptane (V. P. = 92 mm of Hg) was (1) <50 ml (2) > 50 ml
mixed with 4 moles of octane (V. P. = 31mm of (3) = 50 ml (4) cannot be predicted
Hg). The vapour pressure of resulting ideal
solution is: Q.38 Among the following, that does not form an ideal
(1) 46.2 mm of Hg (2) 40.0 mm of Hg solution is:
(3) 43.2 mm of Hg (4) 38.4 mm of Hg (1) C6H6 and C6H5CH3
(2) C2H5Cl and C6H5OH
0 0
Q.32 If PA and PB are 108 and 36 torr respectively. (3) C6H5Cl and C6H5Br
What will be the mole fraction of A in vapour (4) C2H5Br and C2H5I
phase if in solution equal moles of A and B
Q.39 Which condition is not satisfied by an ideal
present?
solution?
(1) 0.25 (2) 0.75 (3) 0.60 (4) 0.35
(1) H mixing = 0
Q.33 The vapour pressure of two pure liquids (A) and (2) V mixing = 0
(B) are 100 and 80 torr respectively. The total (3) S mixing = 0
pressure of the solution obtained by mixing 2 mol (4) Obeyance of Raoult's law
of (A) and 3 mol of (B) would be:
(1) 20 torr (2) 36 torr Q.40 A mixture of liquid showing positive deviation in
(3) 88 torr (4) 180 torr Raoult's law is:
(1) (CH3)2 CO + C2H5OH
Q.34 The vapour pressure of ethanol and methanol are
(2) (CH3)2CO + CHCl3
42.0 mm and 88.5 mm Hg respectively. An ideal
(3) (C2H5)2O + CHCl3
solution is formed at the same temperature by
(4) (CH3)2CO + C6H5NH2
mixing 46.0 g of ethanol with 16.0 g of methanol.
The mole fraction of methanol in the vapour is: Q.41 Which of the following plots does not represent
(1) 0.467 (2) 0.502 the behaviour of an ideal binary liquid solution:
(3) 0.513 (4) 0.556 (1) Plot of PA versus XA (mole fraction of A in
liquid phase) is linear
Q.35 What is correct relation between mole fraction in
(2) Plot of PB versus XB is linear
vapour phase (YA) of A in terms of XA. If mole
(3) Plot of ptotal versus XA (or XB) is linear
fraction in solution of A is: (XA) (If PA° is vapour
(4) Plot of ptotal versus XA is non-linear
pressure of A is pure state)
XA Q.42 For a solution of two liquids A and B, it was proved
(1) (1 − X A ) PA
0
(2) PA0
1 − XA that P = XA (PA0 – PB0) + PB0. The solution is:
1 − XA 0 PA0 X A (1) Ideal (2) Non-ideal
(3) PA (4)
XA PS (3) Semi ideal (4) None of the above

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CHEMISTRY Easy to Learn….
Q.43 Study the figures given below and mark the COLLIGATIVE PROPERTIES
correct statement: Q.47 Which is a colligative property?
P3
(1) Osmosis

Vapour pressure
(2) vapour pressure
P1 P2 (3) freezing point
(4) Relative lowing in vapour pressure
x1 = 0 x1 x1 = 1
x2 = 1 x2 = 0
x2 Q.48 The lowering of vapour pressure of a solvent by
(i)
addition of a non-volatile solute to it is directly
proportional to:
Vapour pressure

P3 (1) Mole fraction of solute

P1
P2 (2) The nature of the solute in the solution
x1 = 0 x1 = 1 (3) The atmospheric pressure
x1
x2 = 1 x2 = 0 (4) All
x2
(ii)
(1) (i) Nitric acid + water (ii) Acetone + ethyl Q.49 The vapour pressure of a solution having solid as
alcohol solute and liquid as solvent is:
(2) (i) Water + ethyl alcohol (ii) Acetone + (1) Directly proportional to mole fraction of the
Benzene solvent
(3) (i) Acetone +ethyl alcohol (ii) Acetone (2) Inversely proportional to mole fraction of the
+chloroform solvent
(4) (i) Benzene +chloroform (ii) Acetone + (3) Directly proportional to mole fraction of the
chloroform solute
(4) Inversely proportional to mole fraction of the
AZEOTROPIC MIXTURE solute
Q.44 Azeotropic mixture are:
(1) Mixture of two solids Q.50 The vapour pressure of pure benzene, C6H6 at
(2) Those which boil at different temperatures 50°C is 268 Torr. How many moles of non-
(3) Those which can be fractionally distilled volatile solute per mol of benzene is required to
(4) Constant boiling mixtures prepare a solution of benzene having a vapour
pressure of 167 Torr at 50°C?
Q.45 The azeotropic mixture of water (B.P 100°C) and
(1) 0.605 (2) 0.377 (3) 0.623 (4) 0.395
HCl (B.P. 85°C) boils at 108.5°C. When this
mixture is distilled, it is possible to obtain: Q.51 The vapour pressure of a dilute aqueous solution
(1) Pure HCl of Glucose is 750 mm of mercury at 373 K. The
(2) Pure water mole fraction of solute is:
(3) Pure water as well as HCl 1 1 1 1
(1) (2) (3) (4)
(4) Neither HCl nor H2O in their pure states 10 7.6 35 76

Q.46 An azeotropic mixture of two liquids has b.p. Q.52 The vapour pressure of water at room
lower than either of them when it: temperature is 23.8 mm of Hg. The vapour
(1) shows a +ve deviation from Raoult's law pressure of an aqueous solution of sucrose with
(2) shows no deviation from Raoult's law mole fraction 0.1 is equal to:
(3) shows +ve deviation from Henry's law (1) 23.9 mm Hg (2) 24.2 mm Hg
(4) shows -ve deviation from Henry's law (3) 21.42 mm Hg (4) 31.44 mm Hg

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 Easy to Learn…. SOLUTIONS
Q.53 The vapour pressure of pure A is 10 torr and at Q.59 Elevation in boiling point was 0.52 °C when 6 g
the same temperature when 1 g of B is dissolved of a compound x was dissolved in 100 g of water.
in 20 g of A, its vapour pressure is reduced to 9.0 Molecular weight of x is:(Kb = 0.52 K kg mol–1)
torr. If the molecular mass of A is 200 amu, then (1) 120 (2) 60 (3) 100 (4) 342
the molecular mass of B is:
(1) 100 amu (2) 90 amu Q.60 Pure benzene freezes at 5.45 °C at a certain place
(3) 75 amu (4) 120 amu but a 0.374 m solution of tetrachloroethane in
benzene freezes at 3.55 °C. The Kf for benzene is:
Q.54 The vapour pressure of a solvent decreases by (1) 5.08 K Kg mol–1
10mm. of Hg when a non-volatile solute was (2) 508 K Kg mol–1
added to the solvent. The mole fraction of the (3) 0.508 K Kg mol–1
solute in the solution is 0.2. What should be the (4) 50.8 °C Kg mol–1
mole fraction of the solvent if the decrease in
vapour pressure is to be 20 mm. of Hg: Q.61 An aqueous solution containing 1g of urea boils
(1) 0.2 (2) 0.4 (3) 0.6 (4) 0.8 at 100.25 °C. The aqueous solution containing 3g
of glucose in the same volume will boil at:
Q.55 The molal elevation constant is the ratio of the (1) 100.75 °C (2) 100.5 °C
elevation in B.P. to: (3) 100 °C (4) 100.25 °C
(1) Molarity
(2) Molality Q.62 An aqueous solution freezes at –
(3) Mole fraction of solute 0.186 °C (Kf = 1.86°; Kb = 0.512°). What is the
(4) Mole fraction of solvent elevation in boiling point?
0.512
(1) 0.186 (2) 0.512 (3) (4) 0.0512
Q.56 Camphor is used as solvent to determine the 1.86
molecular weight of non-volatile solute by Rast
method because for camphor: Q.63 Which inorganic precipitate acts as
(1) Molal depression constant is high semipermeable membrane?
(2) Melting point is high (1) Calcium sulphate
(3) Being cheap (2) Barium oxalate
(4) All (3) Nickel phosphate
(4) Copper ferrocyanide
Q.57 The freezing point of a 0.05 molal solution of a
non-electrolyte in water is: Q.64 The osmotic pressure of solution increases if:
(Kf = 1.86 K molality–1) (1) Temperature is decreased
(1) –1.86 °C (2) –0.93 °C (2) Concentration is decreased
(3) –0.093 °C (4) 0.093 °C (3) Number of solute particles is increased
(4) Volume is increased
Q.58 Molal depression constant of water is 1.86 K Kg
mol–1. 0.02 mol of urea dissolved in 100 g of Q.65 The best colligative property used for the
water will produce a depression in freezing point determination of molecular masses of polymers is:
of: (1) Relative lowering in vapour pressure
(1) 0.186 °C (2) 0.372 °C (2) Osmotic pressure
(3) 1.86 °C (4) 3.72 °C (3) Elevation in boiling point
(4) Depression in freezing point

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CHEMISTRY Easy to Learn….
Q.66 If mole fraction of the solvent in solution Q.72 If 0.1 M solution of glucose and 0.1 M urea
decreases then: solution are placed on two sides of a
(1) Vapour pressure of solution increases semipermeable membrane to equal heights, then
(2) B. P. decreases it will be correct to say that:
(3) Osmotic pressure increases (1) There will be not net movement across the
(4) All are correct membrane
(2) Glucose will flow towards urea solution
Q.67 In osmosis phenomenon net flow of: (3) Urea will flow towards glucose solution
(1) Solute molecules move from higher (4) Water will flow from urea solution towards
concentration to lower concentration glucose solution.
(2) Solvent molecules move from lower
ABNORMAL COLLIGATIVE PROPERTY AND
concentration to higher concentration
VAN’T HOFF FACTOR
(3) Solvent molecules move from higher
Q.73 Equimolal solutions of A and B show depression
concentration to lower concentration
in freezing point in the ratio of 2: 1. A remains in
(4) Solute molecules move from lower
normal state in solution. B will be in ......... state
concentration to higher concentration
in solution:
(1) Normal (2) Associated
Q.68 If a thin slice of sugar beet is placed in
(3) Hydrolysed (4) Dissociated
concentrated solution of NaCl then:
(1) Sugar beet will lose water from its cells Q.74 Van't Hoff factor is:
(2) Sugar beet will absorb water from solution (1) Less than one in case of dissociation
(3) Sugar beet will neither absorb nor lose water (2) More than one in case of association
(4) Sugar beet will dissolve in solution (3) Always less than one
(4) Less than one in case of association
Q.69 Osmotic pressure of a solution (density is 1g/ml)
contain 3 g of glucose (molecular weight = 180) Q.75 The Vant Hoff factor (i) for a dilute solution of
in 60 g of water at 15°C is: K3[Fe(CN)6] is:
(1) 0.34 atm (2) 0.65 atm (1) 10 (2) 4
(3) 6.25 atm (4) 5.57 atm (3) 5 (4) 0.25

Q.70 Osmotic pressure of a sugar solution at 24°C is Q.76 The experimental molecular weight of an
2.5 atmosphere. The concentration of the solution electrolyte will always be less than its calculated
is: value because the value of Van’t Hoff factor, 'i' is:
(1) 10.25 M (2) 1.025 M (1) Less than 1
(3) 1025 M (4) 0.1025 M (2) Greater than 1
(3) One
Q.71 If density of 2 molal sucrose solution is 1.4 gm/ml (4) Zero
at 25°C, find osmotic pressure?
Q.77 The substance A when dissolved in solvent B
(1) 4.06 atm shows the molecular mass corresponding to A3.
(2) 2 atm The Vant Hoff's factor will be:
(3) 40.6 atm (1) 1 (2) 2
(4) 3.4 atm 1
(3) 3 (4)
3

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 Easy to Learn…. SOLUTIONS
Q.78 The value of observed and calculated molecular Q.84 The molal elevation constant of water is 0.51. The
weight of silver nitrate are 92.64 and 170 boiling point of 0.1 molal aqueous NaCl solution
respectively. The degree of dissociation of silver is nearly:
nitrate is: (1) 100.05°C (2) 100.1°C
(1) 60% (2) 83.5 % (3) 100.2°C (4) 101.0°C
(3) 46.7% (4) 60.23%
Q.85 The osmotic pressure of equimolar solutions of
Q.79 Which of the following solutions at the same BaCl2, NaCl, and glucose will be in the order:
temperature will be isotonic? (1) Glucose > NaCl > BaCl2
(2) BaCl2> NaCl > Glucose
(1) 3.42 g of cane sugar in one litre water and
(3) NaCl > BaCl2> Glucose
0.18 g of glucose in one litre water.
(4) NaCl > Glucose > BaCl2
(2) 3.42 g of cane sugar in one litre water and
0.18 g of glucose in 0.1 litre water. Q.86 Which one of the following pairs of solutions will
(3) 3.42 g of cane sugar in one litre water and be expected to be isotonic under the same
0.585 g of NaCl in one litre water. temperature?
(4) 3.42 g of cane sugar in one litre water and (1) 0.1M urea and 0.1 M NaCl
1.17 g of NaCl in one litre water. (2) 0.1M urea and 0.2 M MgCl2
(3) 0.1M NaCl and 0.1M Na2SO4
Q.80 The freezing point order of the solution of (4) 0.1M Ca(NO3)2 and 0.1M Na2SO4
glucose is:
(1) 10% > 3% > 2% > 1% Q.87 When mercuric Iodide is added to the aqueous
(2) 1% > 2% > 3% > 10% solution of potassium iodide?
(3) 1% > 3% > 10% > 2% (1) The boiling point does not change
(4) 10% > 1% > 3% > 2% (2) Freezing point is raised
(3) The freezing point is lowered
Q.81 In cold countries, ethylene glycol is added to (4) Freezing point does not change
water in the radiators of cars during winters. It
results in reducing: Q.88 The correct relationship between the boiling
points of very dilute solutions of AlCl3(T1) and
(1) viscosity (2) specific heat
CaCl2(T2), having the same molar concentration
(3) freezing point (4) boiling point
is:
Q.82 Calculate the molal depression constant of a (1) T1 = T2 (2) T1> T2
(3) T2 = T1 (4) T2> T1
solvent, which has freezing point 16.6 oC and
latent heat of fusion 180.75 Jg-1: Q.89 Which of the following solutions will have
(1) 2.68 (2) 3.86 (3) 4.68 (4) 2.86 highest boiling point?
(1) 1% w/W Glucose (aq)
Q.83 The lowering of vapour pressure of 0.1 M (2) 1% w/W Sucrose (aq)
aqueous solutions of NaCl, CuSO4 and K2SO4 (3) 1% w/W NaCl (aq)
are: (4) 1% w/W Urea (aq)
(1) All equal
Q.90 The freezing point of equimolal aqueous solution
(2) In the ratio of 1: 1: 1.5
will be highest for:
(3) In the ratio of 3: 2: 1
(1) C6H5NH3Cl (2) Ca(NO3)2
(4) In the ratio of 1.5: 1: 2.5 (3) La(NO3)3 (4) C6H12O6(Glucose)

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CHEMISTRY Easy to Learn….
Q.91 Arrange the following aqueous solutions in the Q.94 Van't Hoff Factor of Hg2Cl2 in its aqueous
order of their increasing boiling points: solution will be: (Hg2Cl2 is 80% ionized in the
(i) 10–4 M NaCl (ii) 10–4 M Urea solution)
–3
(iii) 10 M MgCl2 (iv) 10–2 M NaCl (1) 1.6 (2) 2.6
(1) (i) < (ii) < (iv) < (iii) (3) 3.6 (4) 4.6
(2) (ii)<(i)=(iii)<(iv)
(3) (ii)<(i)<(iii)<(iv) Q.95 The osmotic pressure of a solution at 0°C is 4 atm.
(4) (iv)<(iii)<(i)=(ii) What will be its osmotic pressure at 546 K under
similar condition?
Q.92 The Van't Hoff Factor for 0.1 M Ba(NO3)2 (1) 4 atm (2) 2 atm
solution is 2.74 . The degree of dissociation is: (3) 8 atm (4) 1 atm
(1) 91.3% (2) 87%
(3) 100% (4) 74%
Q.93 What is the freezing point of a solution containing
8.1 g of HBr in 100 g. water assuming the acid to
be 90% ionised:
(Kf for water = 1.86 K molality–1): –
(1) 0.85°C (2) –3.53°C
(3) 0°C (4) –0.35°C

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 Easy to Learn…. SOLUTIONS

EXERCISE LEVEL-02
(MULTICONCEPT QUESTIONS)
Q.1 At a given temperature, total vapour pressure in Q.6 For an aqueous solution, freezing point is
Torr of mixture of volatile components A and B –0.186°C. Elevation of boiling point of the
is given by
P = 120 – 75 XB same solution is (K f = 1.86°K mol – 1 kg)
hence, vapour pressure of pure A and B respectively and (K b = 0.512°K mol –1 kg)
(in Torr) are - (1) 0.186° (2) 0.0512°
(1) 120, 75 (2) 12, 195 (3) 1.86° (4) 5.12°
(3) 120, 45 (4) 75, 45 Q.7 Aqueous solutions of 0.004 M Na2SO4 and 0.01M
Glucose are isotonic. The degree of dissociation
Q.2 Decimolar solution of potassium ferricyanide,
of Na2SO4 is -
K3[(Fe(CN)6] has osmotic pressure of 3.94 atm at
(1) 25% (2) 60% (3) 75% (4) 85%
27°C. Hence percent ionization of the solute is
(1) 10% (2) 20% Q.8 PtCl4.6H2O can exist as a hydrated complex 1
(3) 30% (4) 40% molal aq. solution has depression in freezing
point of 3.72°. Assume 100% ionisation and
Q.3 100 ml of liquid A and 25 ml of liquid B is mixed
Kf(H2O) = 1.86° mol–1 kg, then number of ions
to give a solution which does not obey Raoult’s
given by complex are –
law, The volume of the solution -
(1) 2 (2) 3 (3) 4 (4) 5
(1) will be 125 ml
(2) can > or < than 125 ml Q.9 At higher altitudes, water boils at temperature
lower then 100°C because
(3) can be greater than, equal to or less than 125 ml
(1) temperature of higher altitudes is low
(4) will be less than 125 ml
(2) atmospheric pressure is low
Q.4 When mango is placed in dilute aqueous solution (3) the proportion of heavy water increases
of hydrochloride acid, it - (4) atmospheric pressure becomes more.
(1) Shrinks (2) Swells
Q.10 At 323 K, the vapour pressure in millimeters of
(3) Bursts (4) Nothing happens
mercury of a methanol-ethanol solution is
Q.5 The V.P. curve of same solution in the same represented by the equation p = 120 XA + 140,
solvent are shown. The curves are parallel to each where XA is the mole fraction of methanol. Then
other & do not intersect. The concentration of the value of lim p A is
x A →1 XA
solution are in order of –
(1) 250 mm (2) 140 mm
(3) 260 mm (4) 20 mm
Q.11 Two liquids A and B form an ideal solution at
temperature T. When the total vapour pressure
above the solution is 400 torr, the mol fraction of
A in the vapour phase is 0.4 and in the liquid phase
0.75. What are the vapour pressure of pure A?
(1) I < II < III (2) I = II = III (1) PA = 213.33 torr (2) PA = 216.32 torr
(3) I > II > III (4) I > III > II (3) PA = 219.35 torr (4) PA = 209.33 torr
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CHEMISTRY Easy to Learn….
Q.12 Total vapour pressure of mixture of 1 mol Q.17 Y g of non-volatile organic substance of
A ( PA0 =150 torr) and 2 mol B ( PB0 =240 torr) is molecular mass M is dissolved in 250 g benzene.
200 torr. In this case: Molal elevation constant of benzene is Kb.
(1) there is positive deviation from Raoult's law Elevation in its boiling point is given by:
(2) there is negative deviation from Raoult's law M 4K b Y
(1) (2)
(3) there is no deviation from Raoult's law KbY M
(4) molecular masses of A and B are also KbY KbY
(3) (4)
required for calculating the deviation 4M M

Q.13 For the given electrolyte AxBy, the degree of Q.18 pH of 0.1 M monobasic acid is measured to be 2. Its
dissociation '' can be given as osmotic pressure at a given temperature T K is
i −1 (1) 0.1 RT (2) 1.1 RT
(1)  =
x + y −1 (3) 0.11 RT (4) 0.01 RT
(2) i = (1– ) + x + y
Q.19 The vapour pressure of acetone at 20°C is
(3)  = 1− i
185torr. When 1.2 g of a non-volatile substance
1− x − y
was dissolved in 100 g of acetone at 20°C, its
(4) All of these
vapour pressure was 183 torr. The molar mass
Q.14 1.0 molal aqueous solution of an electrolyte X3Y2 (g mol–1) of the substance is:
is 25% ionized. The boiling point of the solution (1) 32 (2) 64
is (Kb for H2O = 0.52 K kg/mol) (3) 128 (4) 488
(1) 375.5 K (2) 374.04 K
Q.20 A 0.004 M solution of Na2SO4 is isotonic with
(3) 377.12 K (4) 373.25 K
0.010 M solution of glucose at same temperature.
The apparent percentage dissociation of Na2SO4
Q.15 Which of the following has been arranged in
is:
order of decreasing freezing point?
(1) 0.05 M KNO3> 0.04 M CaCl2> 0.140 M (1) 25% (2) 50% (3) 75% (4) 85%
sugar > 0.075 M CuSO4
Q.21 The vapour pressure of pure benzene and toluene
(2) 0.04 M BaCl2> 0.140 M sucrose > 0.075 M
are 160 and 60 torr respectively. The mole
CuSO4> 0.05 M KNO3
fraction of toluene in vapour phase in contact
(3) 0.075 M CuSO4> 0.140 M sucrose > 0.04 M
with equimolar solution of benzene and toluene
BaCl2> 0.05 M KNO3
is:
(4) 0.075 M CuSO4> 0.05 M NaNO3> 0.140 M
(1) 0.50 (2) 0.6 (3) 0.27 (4) 0.73
sucrose > 0.04 M BaCl2
Q.22 The boiling point of an aqueous solution of a non-
Q.16 A solution containing 4g of polyvinyl chloride in volatile solute is 100.15 °C. What is the freezing
1 litre of dioxane was found to have an osmotic point of an aqueous solution obtained by diluting
pressure of 6×10–4 atm at 300K. The molecular the above solution with an equal volume of
mass of polymer is: water? The values of Kb and Kf for water are
(1) 3 ×103 (2) 1.6×105 0.512 and 1.86 K molality–1:
(3) 5×104 (4) 6.4×102 (1) –0.544 °C (2) –0.512 °C
(3) –0.272 °C (4) –1.86 °C

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 Easy to Learn…. SOLUTIONS
Q.23 How many grams of a non volatile solute having Q.30 Which of the following statement is/are correct?
a molecular weight of 90 are to be dissolved in (i) For ideal solution (Van't Hoff factor), i = 1
97.5 g water in order to decrease the vapour (ii) For non-electrolyte, i = 1
(iii) For electrolyte undergoing dissociation, i > 1
pressure of water by 2.5 percent:
(iv) For electrolyte undergoing association, i < 1
(1) 25 (2) 18 (3) 12.5 (4) 9
Correct option is :-
Q.24 A 0.2 molal aqueous solution of a weak acid (HX) (1) ii (2) iii, iv
(3) i, ii, iii (4) All of these
is 20% ionised. The freezing point of this solution
is : (Given : Kf = 1.86°C/m for water) Q.31 Which of the following is correct for an ideal
(1) – 0.31°C (2) – 0.45°C solution?
(i) Gmix = 0 and Hmix>0
(3) – 0.53°C (4) – 0.90°C
(ii) Hmix = 0 and Vmix = 0
Q.25 The osmotic pressure of human blood is 7.8 bar (iii) Vmix = 0 and Smix> 0
at 37°C. What is the concentration of an aqueous (iv) Hmix> 0 and Smix> 0
NaCl solution that could be used in the blood Correct option is :
(1) i, ii, iii (2) ii, iii
stream:
(3) i, ii, iv (4) i, ii, iii, iv
(1) 0.16 mol/L (2) 0.32 mol/L
(3) 0.60 mol/L (4) 0.45 mol/L Q.32
Column-I Column-II
–1
Q.26 A solution of urea (mol. mass 56 g mol ) boils at (A) 1: 0.1 M (P) 1 and 2 are
100.18°C at the atomospheric pressure. If Kf and glucose; 2 : 0.1 isotonic
Kb for water are 1.86 and 0.512K kg mol–1 M urea
(B) 1: 0.1 M NaCl; (Q) No net migration
respectively, the above solution will freeze at:
2 : 0.1 M of solvent across
(1) –6.54°C (2) –0.654°C the membrane
Na2SO4
(3) 6.54°C (4) 0.654°C
(C) 1: 0.1 M NaCl; (R) 1 is hypertonic to
2: 0.1 M KCl 2
Q.27 A solution has a 1 : 4 mole ratio of pentane to
(D) 1: 0.1 M CuSO4: (S) 1 is hypotonic to
hexane. The vapour pressures of the pure
2: 0.1 M sucrose 2
hydrocarbons at 20°C are 440 mmHg for pentane
(1) A → Q, P; B → S; C → P, R, Q; D → Q;
and 120 mmHg for hexane. The mole fraction of
(2) A → S, Q; B → P; C → P, R; D → S;
pentane in the vapour phase would be :
(3) A → P, Q; B → S; C → P, Q; D → R;
(1) 0.200 (2) 0.478 (4) A → Q, P; B → R; C → S, Q; D → R;
(3) 0.549 (4) 0.786 Q.33
Column-I Column-II
Q.28 Kf for water is 1.86 K kg mol–1. If your (A) 0.1 M Al2(SO4)3 (P) Solution with highest
automobile radiator holds 1.0 kg of water, how boiling point.
many grams of ethylene glycol (C2H6O2) must (B) 0.1 M APO4 (Q) Van’t Hoff factor is
you add to get the freezing point of the solution greater than 1
(C) 0.1 M urea (R) Solution with lowest
lowered to –2.8°C?
osmotic pressure
(1) 27 g (2) 72 g (3) 93 g (4) 39 g (D) 0.1 M MgCl2 (S) Solution with lowest
freezing point
Q.29 Which of the following solution will have highest (1) A → P, Q; B → Q; C → R, S; D → P;
freezing point? (2) A → S, Q; B → P; C → P, Q; D → S;
(1) 2 M NaCl (2) 1.5 M AlCl3 (3) A → P, Q, S; B → Q; C → R; D → Q;
(3) 1M AI2(SO4)3 (4) 3M urea (4) A → Q, Q; B → S; C → P, Q; D → P;

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CHEMISTRY Easy to Learn….

ASSERTION & REASON TYPE QUESTIONS Q.37 Assertion : ∆𝐻mix and ∆𝑉mix in an ideal solution
are zero.
Each question contains Assertion and Reason. Each
Reason : 𝐴 − 𝐵 interactions in ideal solutions are
question has the 4 choices (A), (B), (C) and (D) out of
same as between A - A and B - B
which ONLY ONE is correct.
(1) A (2) B (3) C (4) D
(A) Assertion is True, Reason is True; Reason is
correct explanation for Assertion Q.38 Assertion : On adding NaCl to water its vapour
(B) Assertion is True, Reason is True; Reason is not pressure increases.
correct explanation for Assertion Reason : Addition of non-volatile solute
(C) Assertion is True, Reason is False decreases the vapour pressure
(D) Assertion is False, Reason is True (1) A (2) B (3) C (4) D

Q.34 Assertion : The boiling point of 0.1 M urea Q.39 Assertion : The elevation in boiling point of a
solution is less than that of 0.1 M KCl solution. solution of non-electrolyte is proportional to its
Reason : Elevation of boiling point is directly molality
proportional to the number of species present in Reason : The molal elevation constant is the ratio
the solution. of the elevation in boiling point to its molality
(1) A (2) B (3) C (4) D (1) A (2) B (3) C (4) D

Q.35 Assertion : The Molar mass of acetic acid

molecule in benzene is more than the actual.
Reason : Molecules of acetic acid dimerise in
benzene due to hydrogen bonding.
(1) A (2) B (3) C (4) D

Q.36 Assertion : Azeotropic mixture are formed only

by nonideal solution and they may have boiling
points either greater than both the components or
less than both the components.
Reason : The composition of the vapour phase is
same as that of the liquid phase of an azeotropic
mixture.
(1) A (2) B (3) C (4) D

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 Easy to Learn…. SOLUTIONS

EXERCISE-03 : NEET PYQ

Q.1 200 mL of an aqueous solution of a protein Q.5 Boiling point of benzene is 353.23 K. When
contain its 1.26 g. The Osmotic pressure of this 1.8 g of non-volatile solute is dissolved in 90 g of
solution at 300 K is found to be 2.57 × 10–3 bar. benzene. Then boiling point raised to 354.11 K.
The molar mass of protein will be: Given Kb (benzene)=2.53 K kg mol-1. Then
–1 –1
(R = 0.083 L bar mol K ) molecular mass of non-volatile substance is:
[AIPMT Mains 2011] [AIIMS 2013]
(1) 61038 g mol–1 (2) 51022 g mol–1 (1) 58 g mol –1

(3) 122044 g mol–1 (4) 31011 g mol–1 (2) 120 g mol–1

(3) 116 g mol–1
Q.2 pA and pB are the vapour pressure of pure liquid (4) 60 g mole–1
components, A and B, respectively of an ideal
binary solution. If xA represents the mole fraction Q.6 Of the following 0.10 m aqueous solutions, which
of component A, the total pressure of the solution one will exhibit the largest freezing point
will be: [AIPMT Mains 2012] depression? [AIPMT 2014]
(1) pB + xA (pB – pA) (1) KCl
(2) pB + xA (pA – pB) (2) C6H12O6
(3) pA + xA (pB – pA) (3) Al2(SO4)3
(4) pA + xA (pA – pB) (4) K2SO4

Q.7 The boiling point of 0.2 mol kg–1 solution of X in

Q.3 Which of the following compounds can be used
water is greater than equimolal solution of Y in
as antifreeze in automobile radiators?
water. Which one of the following statements is
[AIPMT Mains 2012]
true in this case? [AIPMT 2015]
(1) Nitrophenol (2) Ethyl alcohol
(1) Molecular mass of X is greater than the
(3) Methyl alcohol (4) Glycol
molecular mass of Y.
(2) Molecular mass of X is less than the
Q.4 Vapour pressure of chloroform (CHCl3) and
molecular mass of Y.
dichloromethane (CH2Cl2) at 25°C are 200 mmHg
(3) Y is undergoing dissociation in water while
and 41.5 mmHg respectively. Vapour pressure of
X undergoes no change.
the solution obtained by mixing 25.5 g of CHCl3
(4) X is undergoing dissociation in water while
and 40g of CH2Cl2 at the same temperature will
Y undergoes no change.
be: (Molecular mass of CHCl3 = 119.5 u and
molecular mass of CH2Cl2 = 85 u) Q.8 Which one is not equal to zero for an ideal
[AIPMT Mains 2012] solution? [AIPMT 2015]
(1) 90.93 mmHg
(1) Smix
(2) 285.5 mmHg
(2) Vmix
(3) 173.9 mmHg
(3) P = Pobserved- PRaoult
(4) 615 mmHg
(4) Hmix

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CHEMISTRY Easy to Learn….
Q.9 Which one of the following electrolytes has the Q.15 Consider the following liquid-vapour equilibrium
same value of van't Hoff's factor (i) as that of the 
Liquid  vapour
Al2(SO4)3 (if all are 100% ionised [AIPMT 2015]
(1) K3[Fe(CN)6] (2) Al(NO3)3 Which of the flowing relation is correct?
(3) K4[Fe(CN)6] (4) K2SO4 [NEET 2016]
dnG H v dnP −H v
Q.10 Osmotic pressure of a solution containing 1 g (1) = (2) =
dT 2 RT 2 dT RT
protein in 100 mL solution at 300 K is 1.66 bar.
What is the molecular weight of protein: dnP −H v dnP H v
(3) = (4) =
(R = 0.083 L bar mol–1 K–1) [AIIMS 2015] dT 2 T2 dT RT 2
(1) 150 (2) 120 (3) 130 (4) 300
Q.16 0.5 mole NaCl has dissolved in 500 g H2O then
Q.11 The van't Hoff factor (i) for a dilute aqueous find out its freezing point and boiling point.
solution of the strong electrolyte barium
Given- ( K f )H O = 1.8 K kg/mol
hydroxide is [NEET (II) 2016] 2

(1) 2 (2) 3 (3) 0 (4) 1

( K b )H O = 0.5K kg/mol
2
[AIIMS 2016]
Q.12 Which one of the following is incorrect for ideal (1) –1.8°C, 100.5°C (2) –3.6°C, 101°C
solution? [NEET (II) 2016] (3) –3.6°C, 99°C (4) 0°C, 100°C
(1) P = Pobs – Pcalculated by Roult's law = 0
(2) Gmix = 0 Q.17 If molality of the dilute is doubled, the value of
(3) Hmix = 0 molal depression constant (Kf) will be:
(4) Umix = 0 [NEET 2017]
(1) doubled (2) halved
Q.13 Which of the following statement about the
composition of the vapour over an ideal 1: 1 (3) tripled (4) unchanged
molar mixture of benzene and toluene is correct?
Assume that the temperature is constant at 25°C. Q.18 Which of the following is dependent on
(Given: Vapour Pressure Data at 25°C, benzene temperature? [NEET 2017]
= 12.8 kPa, Toluene = 3.85 kPa) (1) Molality (2) Molarity
[NEET (I) 2016] (3) Mole fraction (4) Weight percentage
(1) The vapour will contain a higher percentage
of benzene Q.19 When 45 g solute is dissolved in 600 g water
(2) The vapour will contain a higher percentage freezing point lower by 2.2 K, calculate molar
of toluene
mass of solute (Kf = 1.86 K kg mol–1).
(3) The vapour will contain equal amounts of
benzene and toluene [AIIMS 2018]
(4) Not enough information is given to make a (1) 63.4 (2) 80 gm (3) 90 gm (4) 21 gm
predication.
Q.20 For an ideal solution, the correct option is:
Q.14 At 100°C the vapour pressure of a solution of [NEET 2019]
6.5g of a solute in 100g water is 732 mm Hg. If
(1) Vmix  0 at constant T and P
Kb =0.52, the boiling point of this solution will
(2) Gmix = 0 at constant T and P
be: [NEET (I) 2016]
(1) 101°C (2) 100°C (3) Smix = 0 at constant T and P
(3) 102°C (4) 103°C (4) Hmix = 0 at constant T and P

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 Easy to Learn…. SOLUTIONS
Q.21 The mixture which shows positive deviation from Q.27 One mole of sugar is dissolved in three moles of
Raoult’s law is: [NEET 2020] water at 298 K. The relative lowering of vapour
(1) Benzene + Toluene pressure is [NEET 2022]
(2) Acetone + Chloroform (1) 0.20 (2) 0.50
(3) Chloroethane + Bromoethane (3) 0.33 (4) 0.25
(4) Ethanol + Acetone
Q.28 KH value for some gases at the same temperature
Q.22 If 8 g of a non-electrolyte solute is dissolved in
'T' are given:
114 g of n-octane to reduce its vapour pressure to
Gas KH/k bar
80%, the molar mass (in g mol–1) of the solute is
[Given that molar mass of n-octane is 114 g mol–1] Ar 40.3
[Covid NEET 2020] CO2 1.67
(1) 60 (2) 80 (3) 20 (4) 40 HCHO 1.83 × 10–5
CH4 0.413
Q.23 Isotonic solutions have same Where KH is Henry's Law constant in water. The
[Covid Re-NEET 2020] order of their solubility in water is; [NEET 2022]
(1) Freezing temperature
(1) Ar < CO2 < CH4 < HCHO
(2) Osmotic pressure
(2) Ar < CH4 < CO2 < HCHO
(3) Boiling temperature
(3) HCHO < CO2 < CH4 < Ar
(4) Vapour pressure
(4) HCHO < CH4 < CO2 < Ar
Q.24 The following solutions were prepared by
dissolving 10 g of glucose (C6H12O6) in 250 ml of Q.29 The density of 1 M solution of a compound 'X'
in water (P1) 10 g of urea (CH4N2O) in 250 ml is 1.25 g mL–1. The correct option for the
water (P2) and 10 g of sucrose (C12H22O11) in 250 molality of solution is (Molar mass of compound
ml of water (P3). The right option for the X = 85g): [NEET 2023]
decreasing order of osmotic pressure of these (1) 0.705 m (2) 1.208 m
solutions is: [NEET 2021] (3) 1.165 m (4) 0.858 m
(1) P2 > P1 > P3 (2) P1 > P2 > P3
(3) P2 > P3 > P1 (4) P3 > P1 > P2 Q.30 The Henry’s law constant (KH) values of three
gases (A, B, C) in water are 145, 2 × 10–5 and
Q.25 The correct option for the value of vapour
35kbar, respectively. The solubility of these gases
pressure of a solution at 45°C with benzene to
in water follow the order: [NEET 2024]
octane in molar ratio 3 : 2 is:
(1) B > A > C
[At 45°C vapour pressure of benzene is
280mmHg and that of octane is 420 mm Hg.] (2) B > C > A
[NEET 2021] (3) A > C > B
(1) 160 mm of Hg (2) 168mm of Hg (4) A > B > C
(3) 336 mm of Hg (4) 350mm of Hg
Q.31 The plot of osmotic pressure () vs concentration
Q.26 In one molal solution that contains 0.5 mole of a (mol L–1) for a solution gives a straight line with
solute there is [NEET 2022] slope 25.73 L bar mol–1. The temperature at
(1) 50 mL of solvent which the osmotic pressure measurement is done
(2) 500 g of solvent is (Use R = 0.083 L bar mol–1 K–1) [NEET 2024]
(3) 100 mL of solvent
(1) 37°C (2) 310°C
(4) 1000 g of solvent.
(3) 25.73°C (4) 12.05°C
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CHEMISTRY Easy to Learn….
Q.32 Match List - I with List - II Q.35 Identify the correct statements- [NEET 2026]
List-I List-II A. The molality of 2.5 g of ethanoic acid (Molar
(Example) (Type of Solution) mass : 60 g mol−1 ) in 75 g of benzene
A. Humidity I. Solid in solid solution is 0.556 m .
B. Alloys II. Liquid in gas B. The molarity of a solution containing
C. Amalgams III. Solid in gas 5 g of NaOH (molar mass : 40 g mol−1) in
D. Smoke IV. Liquid in solid 450 mL of solution is 0.278 M at 298 K.
Choose the correct answer from the options given C. Aquatic species are more comfortable in cold
below: [NEET 2025] water.
(1) A-II, B-IV, C-I, D-III D. The solubility of gas increases with decrease
(2) A-II, B-I, C-IV, D-III in pressure.
(3) A-III, B-I, C-IV, D-II E. For a binary-mixture of A and B , the number
(4) A-III, B-II, C-I, D-IV of moles of A and B are nA and nB
respectively. The mole fraction of B will be
𝑛𝐴
Q.33 Which of the following aqueous solution will xB = 𝑛𝐴 +𝑛𝐵
.
exhibit highest boiling point? [NEET 2025] Choose the correct answer from the options given
(1) 0.01 M Urea below:
(2) 0.01MKNO3 (1) A and C only (2) A, B and C only
(3) 0.01MNa2 SO4 (3) A, D and E only (4) A and B only
(4) 0.015MC6 H12 O6

Q.36 Mixture of chloroform and acetone forms a

Q.34 5 moles of liquid X and 10 moles of liquid Y solution with negative deviation from Raoult's
make a solution having a vapour pressure of law due to : [NEET 2026]
70torr. The vapour pressures of pure X and Y are (1) formation of hydrogen bonding between
63torr and 78 torr respectively. Which of the acetone and chloroform.
following is true regarding the described (2) increase in escaping tendency of molecules
solution? [NEET 2025] of each component.
(1) The solution shows positive deviation. (3) stronger intermolecular forces between
(2) The solution shows negative deviation. chloroform molecules than those between
(3) The solution is ideal. chloroform and acetone molecules.
(4) The solution has volume greater than the sum (4) repulsive forces.
of individual volumes.

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 Easy to Learn…. SOLUTIONS

ANSWER KEY

PRACTICE SECTION-01
Que. 1 2 3 4 5 6
Ans. 2 3 1 3 4 1

PRACTICE SECTION-02
Que. 1 2 3 4 5 6 7 8 9
Ans. 2 2 1 1 1 3 1 2 3

PRACTICE SECTION-03
Que. 1 2 3 4 5 6
Ans. 4 3 2 2 2 4

PRACTICE SECTION-04
Que. 1 2 3 4 5 6
Ans. 3 2 4 1 1 2

EXERCISE LEVEL-01
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 1 3 1 3 2 1 2 3 4 2 3 3 3 2 3
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 4 3 4 3 1 1 4 2 1 2 1 2 3 2 4
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 3 2 3 3 4 3 1 2 3 1 4 1 3 4 4
Que. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 1 4 1 1 1 4 3 2 3 2 1 3 2 2 1
Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. 4 4 4 3 2 3 2 1 3 4 3 1 2 4 2
Que. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans. 2 4 2 2 2 3 2 2 2 2 4 2 2 3 4
Que. 91 92 93 94 95
Ans. 3 2 2 2 3

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CHEMISTRY Easy to Learn….

EXERCISE LEVEL-02
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 2 2 2 1 2 3 1 2 3 1 2 4 2 1
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 2 2 3 2 3 3 3 3 2 1 2 2 3 4 4
Que. 31 32 33 34 35 36 37 38 39
Ans. 2 3 3 1 1 2 1 4 2

EXERCISE-03 : NEET PYQ

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 1 2 4 1 1 3 4 1 3 1 2 2 1 1 4
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 2 4 2 1 4 4 4 2 1 3 2 4 1 4 2
Que. 31 32 33 34 35 36
Ans. 1 2 3 2 2 1

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