Solution (2)
Solution (2)
1001CJA101002260006 JA
PART-1 : MATHEMATICS
SECTION-I
(A) 2
(B) 4
(C) 8
(D) none of these
(A) P = 2Q
(B) P = 3Q
(C) 2P = Q
(D) 3P = Q
3) Assertion-A : In a ΔABC, given that tanA : tanB : tanC = 3 : 4 : 5, then the value of sinAsinBsinC
is .
and
Reason-R : In any non right angle ΔABC, tanA + tanB + tanC = tanA tanB tanC.
(A) 1
(B) 2
(C) 3
(D) 4
(B)
(C)
(D)
(A) 0
(B) 1
(C)
(D) 2
(A) S + P < 0
(B) S.P > 0
(C)
(D) logP(1+S) > 0
8) The value of is
(A)
(B)
(C)
(D) 1
List-I List-II
10) Let a, b, c be the three numbers such that (a – b)2, (b – c)2, (c – a)2 are in A.P. Then a – b, b – c, c –
a are always in (a ≠ b ≠ c)
(A) A.P.
(B) G.P.
(C) H.P.
(D) A.G.P.
11) The sum of the product of the 2n numbers ±1,±2,±3,........,±n taken two at a time is -
(A)
(B)
(C)
(D)
12) The sum of infinite number of terms of a G.P. is 2 and the sum of their cubes is 24, then second
term of G.P. is -
(A)
(B)
(C)
(D)
13)
15) Statement-1 : If cotθ + tanθ + cot2θ + tan2θ + cot4θ + tan4θ = acotθ + bcot(cθ) ; a, b, c ∈ I,
then a + b + c = 6. (Functions are defined)
and
Statement-2 : cotθ – tanθ = 2cot2θ.
16) Two sides 'a' and 'b' of triangle ABC are given by the roots of the equation x2 – 4x + 1 = 0
and the included angle between them is , then the value is (where c is third side of the
triangle ABC) -
(A)
(B)
(C)
(D) 4
(A)
(B)
(C)
(D)
(A) a + c = 2b
(B)
(C)
(D) None of these
19) If , then x is -
(In all the choices k ∈ I)
(A)
(B)
(C) ϕ
(D)
20) In a triangle ABC, given b = 2, , ∠A = 30° (Where symbols used have usual meaning),
then in radius of ΔABC is
(A)
(B)
(C)
(D)
SECTION-II
2) The units digit of the least positive integer which when divided by 6, 7, 8, 9 and 12 leaves the
remainder 1 is
3) Let f(x) = x7 + x5 + ax3 + bx. The remainder when f(x) is divided by (x + 1) is –6 and the remainder
when it is divided by (x2 – 1) is g(x) then determine |g(1)|
4) The value of is :
of , is
PART-2 : PHYSICS
SECTION-I
1) A force is applied on the body of mass 2 kg which varies with displacement of body according to
the given graph. If initial speed is 2 m/s, find the final speed of the body :-
(A) 8 m/s
(B) 6 m/s
(C) 4 m/s
(D) 10 m/s
2) A block is hanging in equilibrium as shown. Now an external force is applied so that spring is
stretched slowly by an additional 1m. Find work done by the external force.
(A) 50 J
(B) 100 J
(C) 10 J
(D) 200 J
3) A body is projected directly up a plane which is inclined at an angle θ to the horizontal. It was
found that when it returns to starting point its speed is half of its initial speed. The coefficient of
friction between body and inclined will be :-
(A)
(B)
(C)
(D) tan θ
4) A car is moving on a circular level road of radius of curvature 300m. If the coefficient of friction is
0.3 and acceleration due to gravity is 10m/s2, the maximum speed the car can have is :-
(A) 30 km/h
(B) 81 km/h
(C) 108 km/h
(D) 162 km/h
5) ABCD is a smooth horizontal fixed plane on which mass m1 = 0.1 kg is moving in a circular path of
radius r = 1m. It is connected by an ideal string which is passing through a smooth hole and
connects to mass m2 = at the other end as shown. m2 also moves in a horizontal circle of same
radius of 1m with a speed of m/s. If g = 10 m/s2 then the speed of m1 is :-
(A) m/s
(B) 10 m/s
(C)
m/s
(D) None of these
6) A disc of radius R has a light pole fixed perpendicular to the disc at the circumference which in
turn has a pendulum of length R attached to its other end as shown in figure. The disc is rotated
with a constant angular velocity ω. The string is making an angle 30° with the rod. Then the angular
(A)
(B)
(C)
(D)
7) A particle of mass m is fixed to one end of a light spring having force constant k and unstretched
length . The other end is fixed. The system is given an angular speed ω about the fixed end of the
spring such that it rotates in a circle in gravity free space. Then the stretch in the spring is :-
(A)
(B)
(C)
(D)
8) Two identical discs of same radius R are rotating about their axes in opposite directions with the
same constant angular speed ω. The discs are in the same horizontal plane. At time t = 0, the points
P and Q are facing each other as shown in the figure. The relative speed between the two points P
and Q is vr. In one time period (T) of rotation of the discs vr, as a function of time is best represented
by :-
(A)
(B)
(C)
(D)
9) A block of mass 10 kg is at rest on rough inclined of inclination 37°, with help of a constant force
F1. Force F1 have magnitude 20 N. At t = 0 another force F2 start acting on block. Magnitude of force
F2 changes with time as F2 = 10t N. Both forces F1 and F2 are parallel to inclined and are acting up
the inclined. Friction force acting on block is f. Match the list-I and List-II.
List-I List-II
10) A uniform chain is placed over a table such that part of it overhangs as shown. If chain
remains in equilibrium, then coefficient of static friction between chain and table will satisfy
following condition :-
(A) µ ≥ 1
(B) µ ≥ 0.75
(C) µ ≥ 0.5
(D) µ ≥ 0.3
11) Two block (A) 2 kg and (B) 5 kg rest one over the other on a smooth horizontal plane. The
coefficient of static and dynamic friction between (A) and (B) is the same and equal to 0.60. The
maximum horizontal force that can be applied to (B) in order that both (A) and (B) do not have any
(A) 42 N
(B) 42 kgf
(C) 5.4 kgf
(D) 1.2 N
(A) 4 m/s2
(B) 5 m/s2
(C) 0 m/s2
(D)
m /s2
13) The horizontal surface below the bigger block is smooth. The coefficient of friction between the
block's is μ. The maximum force which can be applied to keep the smaller block at rest with respect
(A)
(B)
(C)
(D) (1 + μ) (M + 2m)g
14)
Assuming all surfaces to be smooth. Minimum value of horizontal acceleration 'a' so that sphere
looses contact at P is :-
(A) g sin α
(B) g tan α
(C) g cot α
(D) g cosec α
15) Figure shows a 5 kg ladder hanging from a string that is connected with a ceiling and is having a
spring balance connected in between. A man of mass 25 kg is climbing up the ladder at acceleration
1 m/s2. Assuming the spring balance and the string to be massless, the reading of the spring balance
is :-
(A) 30 kg
(B) 32.5 kg
(C) 35 kg
(D) 37.5 kg
16) Two blocks of masses m1 and m2 being connected with a light spring of stiffness k are driven
with forces F1 and F2 on a smooth horizontal plane. If the blocks move with same acceleration a0, the
value of a is :-
(A)
(B)
(C)
17) Two balls are projected from an inclined plane from point Q & P respectively as shown. Select
the incorrect statement:- (During the time both remain in air)
18) A ball is thrown from the tower of height 25 m as shown in figure. If the ball rises to a maximum
height of 20m above the point of projection and strikes at a distance 75 m from the foot of the tower,
the angle of projection α (with horizontal x-axis) is :- (Take : g = 10 m/s2)
(A)
tan–1
(B)
tan–1
(C)
tan–1
(D)
tan–1
19) A ball is thrown at angle α(90° > α > θ) on inclined plane as shown in figure then the minimum
(A) u cos α
(B) u cos θ
(C) u cos (α – θ)
(D) Zero
20) The trajectory of two projectiles 1 and 2 as shown in the figure :-
T1 = T2 &
(A)
(B) &
T1 > T2 &
(C)
T1 = T 2 &
(D)
SECTION-II
1) The acceleration a versus time t graph of a body in straight line motion is as shown in the figure.
The body has a velocity of 14 m/s at t = 2 s. Its velocity (in m/s) at t = 0 is :-
2) An ant travels around a cuboid as shown in figure from point A to B. The distance travelled by ant
3) In a new system of unit, unit of mass is 4kg, unit of length is 2m and unit of time is sec. How
much Newton is equal to 1 unit of force in this new system?
4) In a new system of units, mass, acceleration & frequency are taken as fundamental units. If unit of
mass is 100 g, unit of acceleration is 2 m/s2 and unit of frequency is 4 sec–1, in this new system of
units, then the value of 10 J in this new system is K × 100. Fill K :
5) In the given figure if the angle between and is 5α°, find the value of α.
PART-3 : CHEMISTRY
SECTION-I
3
(A) sp d hybridisation involves dxy orbital
(B) Hybridised orbital form σ-bond when overlaps with other orbitals.
(C) SF2 molecule is more polar than CS2
(D) o-nitrophenol is more volatile than p-nitrophenol.
3) The correct values of ionization energies (in kJ mole–1) of Si, P, Cl and S are respectively :-
4) Which of the following diagrams shows correct change in the polarity of bond ?
(A)
(B)
(C)
(D)
(A) H2S2O5
(B) H4P2O5
(C) H2S2O3
(D) H2N2O2
(A) Statement-1 is true, Statement-2 is True, Statement-2 is a correct explanation for statement-1
Statement-1 is true, Statement-2 is True, Statement-2 is not a correct explanation for
(B)
statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
8) 30 mL of a mixture of CO and H2 were mixed with excess of O2 and exploded & cooled. There was
a volume contraction of 33 mL. All volume measurements corresponds to room temperature (27°C)
and one atmospheric pressure. Determine the volume ratio V1 : V2 of CO and H2 in the original
mixture
(A) 6 : 13
(B) 1 : 3
(C) 2 : 3
(D) 7 : 13
9) The atomic weights of two elements A and B are 40 and 80 respectively. If x g of A2 contains y
atoms of 'A', how many atoms of 'B' are present in 2x g of B3 ?
(A)
(B)
(C) y
(D) 2y
11) What weight of CaCO3 must be decomposed to produce the sufficient quantity of carbon dioxide
to convert 21.2 kg of Na2CO3 completely in to NaHCO3. [Atomic mass Na = 23, Ca = 40]
CaCO3 → CaO + CO2
Na2 CO3 + CO2 + H2O → 2NaHCO3
(A) 100 kg
(B) 20 kg
(C) 120 kg
(D) 30 kg
12)
13) 92 g mixture of CaCO3 and MgCO3 heated strongly in an open vessel. After complete
decomposition of the carbonates it was found that the weight of residue left behind is 48 g. Find the
mass of MgCO3 in grams present in the original mixture.
(A) 45
(B) 42
(C) 50
(D) 48
14) Match the list (Relative atomic mass : Na = 23, K = 39, Ca = 40) :
List-I List-II
(P) 20% (w/w) solution of KOH (density of solution = 1.02 gm/mL) (1) 4.00 M
Molarity of pure liquid (A) having density = 2 g/ml and molecular mass = 180
(R) (3) 0.2 M
g/mol
(A)
(B)
(C)
(D)
List-I List-II
(Compound) (DOU)
(P) (1) 2
(Q) (2) 4
(R) (3) 5
(S) (4) 7
(A) P → 1; Q → 2; R → 3; S →4
(B) P → 2; Q → 4; R → 1; S →3
(C) P → 2; Q → 3; R → 4; S →1
(D) P → 3; Q → 2; R → 4; S →1
(A) 2-carbonyl-5-formylhex-3-ene
(B) 2-formyl-5-carbonylhex-3-ene
(C) 2, 5-dimethyl-6-oxohex-3-enamide
(D) 1-amino-2,5-dimethyhex-3-enedial
(B)
(C)
(D)
(A) Both assertion and reason are true and the reason is a correct explanation of assertion.
(B) Both assertion and reason are true but reason is not a correct explanation of assertion.
(C) Assertion is true but the reason is false.
(D) Assertion is false but the reason is true.
SECTION-II
1) The difference between the bond angle of the cationic and anionic part of solid N2O5 is xo. Predict
the value of .
2) In sulphur estimation, 0.20 g of an organic compound gave 0.466 g of barium sulphate (BaSO4).
The mass percentage of sulphur in compound is (Given : Gram atomic mass of Ba = 137 g/mol)
3) A sample of 25 ml H2O2 (aq) solution required 100 ml 0.1M KMnO4 for the complete reaction.
Calculate the molarity of H2O2(aq) solution.
2KMnO4 + 3H2SO4 + 5H2O2 K2SO4 + 2MnSO4 + 3H2O + 5O2
4) How many carbon atoms are present in the parent chain of succinic acid?
5) Find total number of functional groups in the following organic compound [X].
ANSWER KEYS
PART-1 : MATHEMATICS
SECTION-I
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D A A B C A C D A C C A B A D B B C A A
SECTION-II
Q. 21 22 23 24 25
A. 5 1 6 425 5
PART-2 : PHYSICS
SECTION-I
Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A A C C B D B A C C A C C B B A C A C D
SECTION-II
Q. 46 47 48 49 50
A. 10 5 4 4 3
PART-3 : CHEMISTRY
SECTION-I
Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A A C D D B A C C D B B B D C A C C B D
SECTION-II
Q. 71 72 73 74 75
A. 5 32 1 4 6
SOLUTIONS
PART-1 : MATHEMATICS
1)
⇒ tanx = 1 ⇒
but at this value tan2x is underfined, hence there is no solution.
2)
3)
∴ tanA = 3λ, tanB = 4λ, tanC = 5λ
In any ΔABC tanA + tanB + tanC = tanA tanB tanC
3λ + 4λ + 5λ = 60λ3
∴ 12λ = 60λ3 ∴
sinAsinBsinC =
Hence A and R both are true and R is a correct explanation for A.
4) Question Explanation:
Solve trigonometric equation in given interval
Concept:
Types of trigonometry equation.
Solution:
Express cos2 x in terms of sin x.
–3 is invalid
sin x = 1/3 gives two solutions in [0, π]
5)
6)
Question Explanation: Finding the sum of a sine series with angles in arithmetic
progression.
Solution:
The given expression is:
We know that .
Therefore:
Final Answer: 0
7)
Question Explanation: Evaluate the product of sine terms and sum of cosine terms.
Solution:
For S:
Since , we get
For P:
Checking Option 3:
8)
Question Explanation: Evaluate the ratio of the sum and product of three tangent values.
Solution:
Final Answer: 1
9) (A)
f(0) < 0
k∈ϕ⇒Q
(B)
⇒ f(0).f(1) < 0
9.(1 + 2k – 6 + 9) < 0
k < –2 ⇒ S
(C)
D≥0
(D)
x2 + 2(k – 3)x + 9 = 0
a.f(0) > 0 D ≥ 0
10)
12)
Question Explanation: Finding the second term of an infinite G.P. using sums of terms and
their cubes.
Solution:
Given — (i)
Second term
Final Answer: Option (1)
13) Question Explanation: We have to check nature of roots of given quadratic equation.
14)
cotθ – tanθ =
Statement-1 :
cotθ + tanθ + cot2θ + tan2θ + cot4θ + tan4θ
= cotθ + (cotθ – cot2θ) + (cot2θ – cot4θ) + tan4θ
= 2cotθ + tan4θ – cot4θ
= 2cotθ – 2cot8θ
a = 2, b = –2, c = 8
a+b+c=8
Statement-1 is false
16)
17) a + b = 13 k
b + c = 11 k
c + a = 12 k
add
a + b + c = 18k
a = 7k b = 6k c = 5k
18)
19)
1– sin2x + 2sin2x = 1 – (sin2x – 2sin2x)
= 3 – (sin2x + 2cos2x)
∴
Put
t2 – 28t + 27 = 0
t = 1, 27
∴ sin2x + 2cos2x = 0, 3
⇒ 2sinx cosx + 2cos2x = 0, 3
Case-I : 2cosx(sinx + cosx) = 0
⇒ cosx = 0, tanx = –1
Case-II : 2cosx(sinx + cosx) = 3
⇒ cos2x + sin2x = 2 which is not possible from case-I general solution is
x = (2K + 1)
20)
a=1
Now use
Where
a = 1, b = 2,
⇒ y = (t – 1)(t + 1)
= t2 – 1 = [–1, 24]
but y ∈ [a, b]
then
22) Through L.C.M. of 6, 7, 8, 9, 12 is 504 and if it leaves remainder 1 than number is 505 but
least positive integer is still 1
= – 16
= 452 – 16
= 452 – 1600
= 452 – 402
= 5 × 85
= 425
25)
=
=
=
= 24 – 33 + 42 = 16 – 27 + 16 = 32 – 27 = 5
PART-2 : PHYSICS
26) Explain Question : A force is applied on a body of mass 2 kg which varies with
displacement of body according to given F-s graph. If initial speed is 2 m/s and we need to find
the final speed of the body.
Concept : This question is based on work-energy theorem, force-displacement graph.
Solution : Let apply W.E.T
W = KEf – KEi
× 10 (10 + 2) = ×2×
60 = –4
= 64
Vf = 8
object is finally move at 8 m/s
Final Answer: Option (1)
27) Explanation Question: Force is applied on block. Determine the work done by the force.
Concept: Work Energy Theorem.
Solution:
Wgravity + Wfriction =
O – µmgcosθ × 2x = =
O = v2 – 2(gsinθ + µgcosθ)x
∴ µ=
29) Question Explanation: Find the maximum speed a car can have on a circular level road
with friction.
Concept: Maximum safe speed on a level curved road.
Solution: This is similar to
1. Calculate vmax :
2. Convert to km/h :
Thus, .
For m1 on the smooth plane, this same tension provides the centripetal force:
31)
T sin 30 = m . ....(1)
T cos 30 = mg ....(2)
From (1)/(2)
32) kx = m ω2 + mxω2
33) Question Explanation: We are given, two discs rotates in opposite direction with same
constant angular speed. We have to choose the correct graph between relative velocity (Vr)
and time. At t = 0, the points P and Q are facing each other as shown
Concept: This question is based on Kinematics of circular motion.
Solution:
At t = 0, Vr is zero
at t= Vr is 2ωR
at t= Vr is 0
at t = Vr = 2ωr
at t = T Vr = 0
So in one time period (T), relative velocity (Vr) becomes zero three times
Final Answer: The correct option is (1)
34) mgsinθ = 60 N
fs max = µmgcosθ = 80 N
35) Explanation Question: The problem ask for the condition that the coefficient of friction
must for a uniform chain to remains in equilibrium when one-third of its length over hang a
table
Concept: Friction & Equilibrium
Solution:
μ ≥ 0.5
Final answer : Correct option (3)
36) Question Explanation : Two blocks, A of mass 2 kg and B of mass 5 kg, are placed one
over the other on a smooth horizontal plane. The coefficient of both static and kinetic friction
between A and B is 0.60. A horizontal force is applied to block B. We are asked to find the
maximum value of this force so that both move together without any relative motion between
them.
Concept : This question is based on block over block system.
Solution :
Maximum acceleration of block A,
(aAmax) = μg = 0.60 × 10 = 6 m/s2
Therefore required force, Fmax = (2+5) (6) = 42 N
Final Answer : Option (1)
38) For maximum force block A has tendency to move left while B has tendency to move up.
...(1)
...(2)
∴
39)
In wedge's frame :
⇒
a = gtanα
T = R + WL
T = 275 + 50 = 325 N
reading 32.5 kg
41)
42) Explain Question : Choose the incorrect statement if the two projectiles in vertical plane
if they are projected from the inclined plane as shown.
Concept : projectile motion on Inclined plane.
Solution : Since acceleration of both is g downward hence relative acceleration will be zero
and relative velocity will remains constant & path will be straight line as seen by other.
Final answer: option (3).
u sin α = 20
t2 – 4t – 5 = 0
t2 – 5t + t – 5 = 0
t(t – 5) + 1(t – 5) = 0
t = 5, –1
75 = u cos α × 5
u cos α = 15
α = tan–1
Final Answer:
Option (1)
45) Explanation:
The trajectories of two projectiles are given. We have to compare their time of flight and
velocities of projection.
Concept:
This question is based on two-dimensional projectile motion.
Solution:
Since the maximum heights of both projectiles are same,
their vertical components of velocity are equal.
So, v₁ sinθ₁ = v₂ sinθ₂
Hence, Time of flight depends only on vertical component,
therefore T₁ = T₂.
Given θ₁ > θ₂.
For the same vertical component, the projectile with larger angle must have smaller speed.
Thus, v₁ < v₂.
Final Answer: Option (4)
46) Δv = area
v = 10 m/s
47)
48) Explanation: We have to find the 1 unit of force in new system if the units of new system
are related by the units of SI system.
Concept: Conversion of unit by using dimensional formula.
Solution:
[F] = MLT–2 = nM1L1T1–2 = 1M2L2T2–2
n=1
Final Answer: 4
49)
Question Explanation: In a new system mass, acceleration and frequency are taken on
fundamental units. then it is asked to calculate value of 10 joules.
Concept : This question is based on this question is based on Unit and dimension.
Solution :
Joule = N. M.
=
Energy × (mass . acceleration2 / frequency2)
n1 u1 = n2 u2
n2 = 400
K=4
Final Answer : 4
50) Explanation :- finding angle b/w given vectors.
Concept :- angle b/w vectors
5α = 15
α=3
final answer: α = 3
PART-3 : CHEMISTRY
O=C=O
(2) (2) (4)
53) Si P S Cl
2 3 4 5
3p 3p 3p 3p
I.E. = Cl > P > S > Si
Solution: Pyrophosphorous acid (H4P2O5) contains a P–O–P bridge. Sulfurous acids often have
direct S–S bonds or different linkages.
57) All have same number of electrons, so they are isoelectronic species.
58)
x x/2 x
Vol cont. = + = 33
y = 18
x = 12
59) 2 × × NA = y
3× × NA = a
a=y
60) In option D :
M=
61)
62)
A + 2B → E
mole = 5 6 (L.R.)
Left = 2 mole 0 3 mole
E + C → B + 2D
3 excess 3 6 mole
63)
mole
0 mole mole
MgCO3(s) —→ MgO(s) + CO2(g)
mole
0 mole mole
Weight of residue =
g
x = 50 g
Concept:
Concentration and volume calculations rely on converting between mass and moles using
molar mass and between mass and volume using density.
Solution:
(P) 20 gm of KOH present in 100 gm solution
V= = 98.04 ml
M= = 3.64 M
(Q) 444 gm CaCl2 in 1 lit. solution
Molarity = =4M
(R) [A] =
(S) Volume of 0.2 M NaOH solution
0.2 × V = 1 × 10–3 mole
V= × 1000
V = 5 ml
The correct matching sequence: (I→Q), (II→P), (III→S), (IV→R).
Final Answer: Option (D)
65)
(C)
66)
DOU = 3
68)
69)
71)
NO2+ NO3–
O=N=O
180° 120°
= 180° - 120°
= 60°= x°
72)
Mass% of S = = 32
73) Initially
0.1 × 100 × 10–3 mole
2KMnO4 + 3H2SO4 + 5H2O2 K2SO4 + 2MnSO4 + 3H2O + SO2
no. of moles of H2O2 reacted with KMnO4
= = 0.025
74)