12-07-2026

1803CJA101016260012 JM

PART-1 : PHYSICS

SECTION-I

1) A gas bubble forms from an explosion under water, oscillates with a time period proportional to
PadbEc, where P is the static pressure, d is the density of water and E is the energy of explosion. Then
a, b and c are respectively

(A) 1,1,1

(B)

(C)

(D)

2) A force of 10N is applied horizontally on block 2kg, (i) on right hand side and in case (ii) on the
left hand side, then the difference of the magnitude of acceleration (initially) of 1kg block in both the

cases will be (all surface are smooth)

(A) zero

(B)

(C)

(D)

3)

‘y-x’ graph of the particle moving in plane is given below. If the graph shows the motion of a particle
for 2 sec. The ratio of average velocity and average speed is :-

(A) 1

(B)
(C)

(D)

4) A block is projected with some velocity on a rough inclined plane, inclined at an angle θ from
horizontal. Time of ascent is half of time of descent to reach at same position on inclined plane, then
coefficient of friction between block and inclined plane is :

(A) µ = tan θ
µ=
(B)

µ=
(C)

(D)
µ=

5) Two blocks of masses 4 kg and 6 kg are attached to the two ends of a spring and they are placed
on a smooth horizontal surface and a force of 30 N is applied on 6 kg block and 5 N is applied on 4
kg block as shown in figure. If acceleration of 4 kg mass is 1.5 m/s2 then acceleration of 6 kg block

will be :-

(A) 2.5 m/s2

(B) 1.5 m/s2
(C) 3.17 m/s2
(D) 3.31 m/s2

6) If , then the value of is:-

(A) (A2 + B2 + AB)1/2

(B)

(C) (A + B)
(D) (A2 + B2 + )1/2

7) For the given situation select the INCORRECT statement :-

(A)
= 80 m/s
(B) Rate of change of angular position of (A) w.r.t (B) is 1rad/sec
(C) Magnitude of rate of change in position vector of (A) w.r.t (B) is m/s

(D)
m/s

8) A projectile is given an initial velocity of , where is along the horizontal ground and
2
is along the vertical. If g = 10 m/s , the equation of its trajectory is :

(A) y = 2x – 5x2
(B) 4y = 2x – 5x2
(C) 4y = 2x – 25x2
(D) y = x – 5x2

9) If the velocity V of a particle moving along a straight line decreases linearly with its displacement
S from 20 m/s to a value zero at S = 30 m, then acceleration of the particle at S = 15 m is :-

(A)
m/s2

(B)

(C)

(D)

10) In the arrangement shown in the figure below, at a particular instant the roller is coming down
with a speed of 12 m/s and C is moving up with 4 m/s. At the same instant it is known that w.r.t.
pulley P, block A is moving down with speed 3 m/s. Determine the velocity of block B w.r.t. ground
(A) 7 m/s in upward direction
(B) 7 m/s in downward direction
(C) 3 m/s in upward direction
(D) 4 m/s in downward direction

11) O is origin and Q is fixed point on y-axis. A point P is moving with constant velocity of 10 m/s as
shown. At some moment it is on x-axis. Rate of change of separation between O and P is R1 and rate

of change of separation between Q and P is R2 .What is at the moment shown in diagram.

(A)

(B) 1

(C)

(D) None of these

12) The block shown in the figure is equilibrium. Find acceleration of the block just after the string

burns.

(A)

(B)
(C)

(D) None of these

13) Initially both A & B are at origin (x = 0) and can move along straight line (y = 0). Velocity-time

graph for both particles is shown. Choose the INCORRECT option :-

(A) Acceleration of A & B are not equal.

(B) Both A & B meet in between t = 1s to t = 5s
(C) At t = 5 s distance between A & B is 1m.
(D) A travels more distance than B.

14) A man is crossing a river flowing with velocity of 5 m/s. He reaches a point directly across the

river at a distance of 60 m in 5 sec. His velocity in still water should be :-

(A) 12 m/s
(B) 13 m/s
(C) 5 m/s
(D) 10 m/s

15) All surfaces shown in figure are assumed to be frictionless and the pulleys and the string are

light. The acceleration of the block of mass 2 kg is :

(A) g

(B)

(C)

(D)

16)
Find acceleration of the lower block w.r.t. upper block if both blocks were at rest initially and then a
force F acts on upper block as shown in figure. Friction coefficients between different surfaces are
as shown in figure.

(A) 1 m/s2
(B) 0
(C) 2 m/s2
(D) 5 m/s2

17) A person climbs up a stalled escalator in 60 s. If standing on the same but escalator running with
constant velocity he takes 40 s. How much time is taken by the person to walk up the moving
escalator?

(A) 27 s
(B) 45 s
(C) 37 s
(D) 24 s

18) If and , if the magnitude of component of along is .

Then x will be.

(A) 5
(B) 6
(C) 9
(D) 3

19) An object, moving with a speed of 6.25 m/s, is decelerated at a rate given by

where v is the instantaneous speed. The time taken by the object, to come to rest, would be :-

(A) 4s
(B) 8s
(C) 1s
(D) 2s

20) Two blocks of mass M1 = 20 kg and M2 = 12 kg are connected by a metal rod of mass 8 kg. The
system is pulled vertically up by applying a force of 480 N as shown. The tension at the mid-point of
the rod is

(A) 96 N
(B) 144 N
(C) 240 N
(D) 192 N

SECTION-II

1)

A car is moving on circular path of radius 100 m such that its speed is increasing at the rate of
5m/s2. At t = 0 it starts from rest. The radial acceleration of car at the instant it makes one complete

round trip, will be equal to m/s2 then find x:

2) In the arrangement shown in the figure, the rod and the sleeve have friction coefficient of 1/3. The
mass of the hanging block is 5 kg. The sleeve is just on the verge of sliding down. What is the mass

(in kg) of the sleeve.

3) A particle starts from rest with an acceleration of 2 m/s2. The acceleration of particle decreases
down to zero linearly in 4 s. Find the velocity (in m/s) of the particle after 2 s.

4) Two monkeys each of mass m move with acceleration relative to the light inextensible
sting as shown in the figure. The ratio of tensions in the portions AB and BC of the string is :-
5) m1 = 4 kg, m2 = 2 kg, friction coefficient between the blocks m1 & m2 is µ = 0.4 & g = 10 m/s2.
Find minimum value of M (kg) for which m2 will start sliding over m1. (Ground is frictionless)

PART-2 : CHEMISTRY

SECTION-I

1)

The electrons, identified by quantum number n and ℓ :

(i) n = 3 ; ℓ = 0
(ii) n = 5 ; ℓ = 2
(iii) n = 2 ; ℓ = 1
(iv) n = 4 ; ℓ = 3
can be placed in order of increasing energy from the lowest to highest as :

(A) (iii) < (i) < (iv) < (ii)

(B) (i) < (iii) < (iv) < (ii)
(C) (ii) < (iii) < (iv) < (i)
(D) (ii) < (iv) < (i) < (iii)

2) If magnetic moment (µ) = 2 for X+2 then X is:

(A) Nb (Z = 41)
(B) Pd (Z = 46)
(C) Ba (Z = 56)
(D) Cr (Z = 24)

3) The degeneracy of H-atom in a shell is 9. The value of 'n' for the shell is

(A) 3
(B) 9
(C) 1
(D) None of these

4) Correct order of EA is :-

(A) Be > N > Li > B > C > O

(B) O > C > Li > B > N > Be
(C) O > C > B > N > Be > Li
(D) Be > N > B > Li > O > C

5) Match list-I with list-II:

List-I List-II
(Periodic properties) (Order)

(P) Ionisation energy (1) Sn < Pb

(Q) Radii (2) N < C < O

(R) Electronegativity (3) Li < Be < B

(S) Electron affinity (4) O– < S–

Select the correct code:
(A) P-4, Q-1, R-3, S-2
(B) P-1, Q-2, R-3, S-4
(C) P-4, Q-3, R-2, S-1
(D) P-1, Q-4, R-2, S-3

6) Which have maximum number of lone pair on central atom :-

(A) SO2
(B) SCl2
(C) XeF2
(D) XeO2F2

7) The pair in which both species have same hybridisation and same molecular shape both :

(A) CH4 , H2O

(B) PCl5 , SF4
(C) XeF4 , ICl2¯
+
(D) PCl4 , SiF4
8) What is the shape of the cationic part of solid Cl2O6 :

(A) V-shape
(B) Square pyramidal
(C) Square planar
(D) None of these

9) Which of the following having least bond angle

(A) PF3
(B) NF3
(C) PH3
(D) PCl3

10) Consider the ions/molecule

For increasing bond order the correct option is:

(A)

(B)

(C)

(D)

11) For H2O2, H2S, H2O and HF, the correct order of decreasing strength of hydrogen bonding is :

(A) H2O > HF > H2O2 > H2S

(B) HF > H2O2 > H2O > H2S
(C) HF > H2O > H2O2 > H2S
(D) H2O2 > H2O > HF > H2S

12) If , types species are planar and non-polar, then which of the following match is correct
(where X is number of F atoms and n is charge on species)

(A) x = 2 and n = +1
(B) x = 3 and n = 0
(C) x = 2 and n = –1
(D) x = 5 and n = 0

13) Consider the given reaction

H4P2O7 + 2NaOH → Na2H2P2O7 + 2H2O If 534 gm of H4P2O7 is reacted with 30 × 1023 molecules of
NaOH then total number of molecules produced in the product is
Given that : Atomic masses : P = 31, O = 16, H = 1

(A) 2.5 × NA
(B) 5 × NA
(C) 7.5 × NA
(D) 75 × NA

14) Which of the following species has 2π and bond character?

(A)
(B) O2
(C)
(D)

15) Calculate number of nodal planes in delta anti bonding molecular orbital .

(A) 1
(B) 2
(C) 0
(D) 3

16) Which compound having cyclic structure?

(A) H5P3O10
(B) H4B4O8
(C) H6P4O13
(D) H6B4O9

17) Find maximum number of atoms lying in one plane in the following molecule.

(A) 4
(B) 10
(C) 6
(D) 7

18) Find the number of P – O – P linkages in P2O5.

(A) 2
(B) 3
(C) 8
(D) 6
19) In BrF5 molecule, if maximum number of planes having maximum atoms = x and maximum
atoms lying in one plane = y. Then calculate value of x × y.

(A) 5
(B) 8
(C) 12
(D) 10

20) Find out the total number of oxide(s), which is/are amphoteric?
CrO3, N2O, Fe2O3, Al2O3, SnO, SnO2, ZnO, PbO, V2O5, Mn2O7, As2O3, Cr2O3

(A) 6
(B) 7
(C) 8
(D) 9

SECTION-II

1) Formula of borax is If
No. of B – O – B bond = x
No. of – OH directly attached with boron = y
Maximum no. of Boron can be in one plane = z
The calculate the value of x × y + z

2) How many gram–ions of are present in 1.25 mole of K2SO4. Al2(SO4)3.24 H2O

3)

Consider the three different samples I. 24 g of ozone II. 22.7 L of CO2 at STP III. 6.3 g of HNO3 The
sum of the total atoms in the three sample is 3011 × 10y. Value of y is ________.

4) If 5 moles of BaCl2 is mixed with 2 moles of Na3PO4, the maximum number of moles of Ba3(PO4)2
formed is ___. (Nearest Integer)

5) Consider the following table

Than calculate value of

expression

PART-3 : MATHEMATICS

SECTION-I

1) If = cosy – 5, where y∈[0, 2π], then the number of possible values of ordered
pair (x, y) is/are :

(A) 0
(B) 1
(C) 2
(D) 3

2) If log8x + log8y = log8x.log8y and logxy = 3, then the value of x is -

(A) 8
(B) 16
(C) 32
(D) 64

3) The solution set of the inequality

is

(A)

(B)

(C)

(D) None

4) The number of solution(s) of log4(x –1) = log2(x – 3) is-

(A) 0
(B) 1
(C) 2
(D) 3

5)

If a2b3c4, a3b4c5, a4b5c6 are in A.P. (a,b,c > 0), then minimum value of (a + b + c) is equal to-
(A) 1
(B) 3
(C) 4
(D) 8

6) is -

(A)

(B)

(C)

(D)

7) is equal to -

(A)

(B)

(C)

(D)

8) If a, b, c are in G.P. then loga 10, logb 10, logc 10 are in –

(A) A.P.
(B) G.P.
(C) H.P.
(D) None

9)

The arithmetic mean of the numbers

(1 + 2).(12 + 22), (2 + 3).(22 + 32), (3 + 4).(32 + 42),..., (99 + 100).(992 + 1002) is 101(n4 + 1) where n ∈
N then value of n is
(A) 10
(B) 20
(C) 5
(D) 15
10) Let α, β are roots of x2 – 4x + A = 0, and γ, δ are roots of x2 – 36x + B = 0. If α, β, γ, δ form an
increasing G.P. such that At = B then value of t is equal to

(A) 4
(B) 5
(C) 6
(D) 8

11) If (10)9 + 2(11)1 (10)8 + 3(11)2 (10)7 + ......+ 10 (11)9 = k (10)9 , then k is equal to :

(A)

(B)

(C) 100
(D) 110

12) Let a1, a2, a3,.... a100 be an arithmetic progression with a1 = 5 and . If is
independent of n where m = 5n then sum of possible values of a2 is

(A) 3
(B) 20
(C) 5
(D) 15

13) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(A) (I) 1

(B) (II) –1

(C) (III) 0

(D) (IV) 2

(A) (A)→(I); (B)→(IV); (C)→(III); (D)→(II)

(B) (A)→(IV); (B)→(III); (C)→(II); (D)→(I)
(C) (A)→(II); (B)→(IV); (C)→(III); (D)→(I)
(D) (A)→(II); (B)→(I); (C)→(IV); (D)→(III)

14) If then
(A)

(B)

(C)

(D)

15) If two circular arcs of the same length subtend angles of 60o and 80o at their respective centres,
then the ratio of their radii is

(A)

(B)

(C)

(D)

16) The interior angles of a convex polygon are in A.P. The smallest angle is 120° & the common
difference is 5°. Find the number of sides of the polygon

(A) 9
(B) 16
(C) 12
(D) None of these

17) If sinx + 3sin2x + sin3x = 3, then find the value of cos6x + 4cos4x + 8cos2x.

(A) 1
(B) 2
(C) 3
(D) 4

18) If α, β be the roots of equation

, then is equal to :

(A) –10
(B) 0
(C) 10
(D) None of these

19) If then
(A)
(B)
(C)
(D)

20) If x > 0, y > 0, z > 0, t > 0, if x, y, z, t are positive real numbers, then maximum value of

is

(A) 16
(B) 32
(C) 64
(D) 128

SECTION-II

1)

If , then

2) If Harmonic Mean of two numbers is 4, Arithmetic Mean of these two number is 'A' and their
Geometric Mean is 'G' such that 2A + G2 = 27, then modulus of difference of these two numbers is

3) If a, b, c are non zero real numbers, then minimum value of the expression

is k then sum of digits of k is

4) The value of

is

5) If sec θ – tan θ = 5 then (m, n are coprime). The value of n – 2m is :

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C D B C C A D A B A A C B B B B D B D D

SECTION-II

Q. 21 22 23 24 25
A. 80 5 3 4 6

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A B A B A C D A C A C C C C D B D D C C

SECTION-II

Q. 46 47 48 49 50
A. 23 5 21 1 16

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C B C B B C B C A B C B C C B A D C D C

SECTION-II

Q. 71 72 73 74 75
A. 2 3 9 2 3
 SOLUTIONS

PART-1 : PHYSICS

1)

Question Explanation:
Time period T of an underwater explosion bubble scales as Pᵃ dᵇ Eᶜ; find exponents a, b, c by
dimensional analysis.

Concept:
This question is based on dimensional analysis (equating M, L, T exponents).

Solution:
Dimensions: [P] = M L⁻¹ T⁻², [d] = M L⁻³, [E] = M L² T⁻², [T] = T.

Require: T = Pᵃ dᵇ Eᶜ → M{a+b+c} L{–a-3b+2c} T{–2a – 2c} = T1.

Equate exponents:

M: a + b + c = 0

L: −a − 3b + 2c = 0

T: −2a − 2c = 1 ⇒ a + c = −1/2

From a + c = −1/2 and a + b + c = 0 ⇒ b = 1/2.

Use b = 1/2 in L-equation:

−a − 3(1/2) + 2c = 0 ⇒ −a − 3/2 + 2c = 0.

With c = −1/2 − a, substitute:

−a − 3/2 + 2(−1/2 − a) = 0 ⇒ −a − 3/2 −1 −2a = 0

⇒ −3a − 5/2 = 0 ⇒ a = −5/6.

Then c = −1/2 − a = −1/2 + 5/6 = 1/3.

So (a, b, c) = (−5/6, 1/2, 1/3).

Final Answer: The correct option is (3).

2) Ans. (4)

In case (i) ; a =

or
All three move together
In case (ii) 2kg, rod & 3kg block move together, but no normal between 2kg and 1kg
∴ a of 1kg block will be zero

∴ Diffrence in two cases = m/s2

3) Explain Question: we need to find the ratio of average velocity and average speed
Concept : Average velocity, Average speed , kinematics
Solution :
Displacement: initial position (0,0) final position (8,0)

Total Distance : The particle morse from (0,0) to (4,3)

distance covered =
The particle maves from (4,3) to (8,0)

distance covered =
Total distance travelled = 5+ 5 = 10 m

Average velocity = = 4 m/s

Average speed =
Ratio of Average velocity to average speed

The ratio of average velocity and overage speed is 4/5

Final answer ; correct option (2)

4)

Question Explanation: A block is projected up a rough inclined plane. The problem says the
time to go up (ascent) is half the time to come back down (descent). We need to find the
friction coefficient µ.
Concept: This question is based on motion on an inclined plane with friction and how
acceleration and time relate to distance.
Solution:
- Upward motion (ascent):
aa = g (sinθ + µ cosθ)
- Downward motion (descent): ad = g (sinθ − µ cosθ)
Distance covered: S = ½ a t² → aa ta² = ad td²
ta = ½ td → ta / td = 1/2
Then: ad / aa = (ta / td)² = (1/2)² = 1/4
ad / aa = (sinθ − µ cosθ) / (sinθ + µ cosθ) = 1/4
4 (sinθ − µ cosθ) = sinθ + µ cosθ
4 sinθ − 4 µ cosθ = sinθ + µ cosθ
3 sinθ = 5 µ cosθ
µ = (3/5) tanθ
Final Answer: Option (3)

5)
kx – 5 = 4 × 1.5
kx = 11

= 3.17 m/s2

6)
∴ AB sin θ =
or tan θ = or θ = 60°

= (A2 + B2 + AB)1/2

7) m/s

8) Vx = 1; Vy = 2
Now x = Vxt ⇒ x = t

y = Vyt – gt2 ⇒ y = 2t – 5t2 ⇒ y = 2x – 5x2

9)

Question Explanation: The question asks to find acceleration at S = 15 m.

Concept: Acceleration as a function of displacement.
Solution:

In a velocity-displacement (v – s) graph, acceleration is calculated using the relation

We first determine the linear equation for velocity, find its constant slope and then
 multiply it by the velocity at the required position.

Calculation:

A. Slope : From the graph,

B. Velocity Equation:

C. Velocity at

D. Acceleration

Final Answer: Option (2)

10) Velocity of pulley p is 4 m/s upwards

Also

11)

R1 = 10 cos 37
R1 = 10 cos 2 × 37

13) Slope of graphy is greater for be so the acceleration.

SA = × 5 × 10 = 25m; SB = × 4 × 12 = 24m
Then never meet

14) Solution :

t = 5 sec
D = 60 m

v cos θ = 12 ...(1)
Velocity of boat in x is zero
vr – v sin θ = 0
v sin θ = 5 ....(2)
from (1) & (2)
v= = 13 m/s

Final Answer : The correct option is (2)

15)
40 – 2T = 4a
T – 10 = 4a ⇒ 20 = 12 a

⇒ a = 5/3 ⇒ 2a = ⇒

16) T – 4mg = 4ma

⇒ T = 4 × 0.1 × (9.8 + 2.5) = 4.92 N

17)

t = 24 sec

18)

x=6

19)

–2 × 2.5 = –2.5 t
t = 2s

20) Conceptual
22) Question Explanation: We need to analyze the forces acting on the system and find out
mass of the sleeve when the sleeve is on the verge of sliding down.
Concept: Equilibrium, NLM
Solution: T = 5g

N = 5g sin 37°
mg = 5gcos37° + μN

mg = (5gsin37°)

mg = 4g +
mg = 4g + g
m=5
Final Answer: The mass of the sleeve is 5 kg.

23)

At, t = 2 sec

= –1 + 4 = 3 m/s

24)

Question Explanation : The question to find the ratio of tensions in the portions AB and BC

of the string when two monkeys each of mass m m moves with acceleration a1 = a2 = relative
to the light inextensible string.

Concept: “This question is based on Newton's second law, Pseudo force ”

Solution:
 For monkey 'B' ⇒ T1 – mg – T2 =

For monkey 'A' ⇒ ;

∴ T1 =

Final Answer: The ratio of tensions in the portions AB and BC of the string is 4.

25)

T = 6a1 ....(1)
Mg – 2T = Ma2 ........(2)
–2Ta2 + Ta1 = 0 ⇒ a1 = 2a2 .......(3)

Now 0.4 × 10 × 2 = 8N
fr = 8N = 2a1
a1 = 4m/s2

T = 24 N & a2 =
Now Mg – 48 = M × 2
M(g – 2) = 48
M = 6kg

PART-2 : CHEMISTRY

26)
Energy is given by (n + ℓ) value. When (n + ℓ) value is equal, the orbital with greater n-value
has greater energy.

Energy Thus, energy

(i) 3+0=3

(ii) 5+2=7
(iii) < (i) < (iv) < (ii)
(iii) 2 + 1 = 3

(iv) 4 + 3 = 7

27) Question Explanation:

We need to determine which element (from the options) can give this magnetic moment when
it forms X+2 ion.

Concept:
Magnetic Moment formula = . (n = no. of unpaired e¯) and Electronic
Configuration.

Solution:

1.
2.
3.
4.

Final answer : Option (2)

28) Question Explanation :

The frequency of shell (objects) for H or like atoms (uni-electron system).

Concept :
This question is based on total orbitals in M shell have equal energy.

Solution :
3rd shell (M-shell) consists of

∴n=3

Final answer : Option (1)

30) (P) Ionisation energy ⇒ O– < S–

because we know
|I.E. O–| = |ΔHeg O|
&
–
|I.E. S | = |ΔHeg S|
&
 Electron gain enthalpy of
So I.E. order
(Q) Radii → Sn < Pb
(due to lanthanide contraction)
(R) Electronegativity → Li < Be < B (E.N. α Zeff)
(S) Electron affinity → N < C < O
Because C N O
2p 2p 2p4
2 3
outer subshell
configuration
Half filled subshell is more stable
&
E.A. ∝ Zeff
So E.A. order is N < C < O
Ans. (A) P→4; Q→1; R→3, S→2

31)

Sol. XeF2

32) PCl4⊕ → sp3 hybridisation , tetrahedral shape

SiF4 → sp3 hybridisation , tetrahedral shape

33) ClO4–

(Bent/v-shape / angular shape)

34) Question Explanation:

The question asks which molecule has the least bond angle and to explain it using Drago's
rule.

Concept:
Drago's Rule, Hybridization Exception, VSEPR Theory

Solution:
Drago's rule states:

For central atoms of group 15 and 16 having high atomic size and low electronegativity,
hybridization is not preferred if:

The central atom is large

The substituents are not highly electronegative
No strong π-bonding is involved In such cases, bonding occurs using almost pure p orbitals
instead of sp3 hybrid orbitals.

Now applying to given molecules:

NF3
Nitrogen is small and highly electronegative.
It follows normal sp3 hybridization.
Bond angle

PF3 and PCl3

Phosphorus is larger, but F and Cl are quite electronegative.
Some hybridization occurs.
Bond angles % 97 – 100

PH3
Phosphorus is large and hydrogen is weakly electronegative.
According to Drago's rule, hybridization is minimal.
Bonding occurs mainly through pure p orbitals.

Pure p-orbital angle = 90°

Actual bond angle of , which is very close to 90°.

Thus, PH3 has the least bond angle due to non-hybridized (Drago rule) bonding.

Final Answer: Option(3)

35)

36)

The strength of hydrogen bonding depends on the polarity of H-A which further depends upon
the difference in the electronegativity of H and A atoms.

The accumulated negative charge on oxygen atom in H2O is more as compared to that in H2O2.
So strength of hydrogen bonding in H2O is more than H2O2.
No hydrogen bonding in H2S.
So correct order is (C) HF > H2O > H2O2 > H2S

37) (A) x = 2 and n = –1

sp3 hybridization, polar
bent shape, planar
(B) x = 3 and n = 0

IF3

sp3d hybridization, polar

T shape, planar
(C) x = 2 and n = –1

sp3d hybridization, non-polar

Linear shape, planar
(D) x = 5 and n = 0

sp3d2 hybridization, polar

Sq. pyramidal, non-planar

38) Explain Question:

Find number of molecule.

Concept:
Based on calculation mole.

Solution:
 H4P2O7 + 2NaOH → Na2H2P2O7 + 2H2O

2.5 5
∴ NaOH is L.R
total mole of products = 2.5 + 5
= 7.5
total number of molecule present = 7.5NA

Final answer: Option (3)

39) Sol.

40) Theory based.

41) Meta acid

42) Plane passing through carbon of CH2 group not including hydrogen of CH2 group.

43) Based on P4O10.

44) x = 3, y = 4

45) Except CrO3, N2O, Fe2O3, Mn2O7.

46) x = 5, y = 4 and z = 3

47) = 1.25 × 4 = 5
 48)

49)
Ba3(PO4)2 + 6NaCl
Hence, Na3PO4 acts as limiting reagent.
Therefore, maximum number of moles of

50)

Question Explanation : Find the value of using molecular data.

Concept: VSEPR Theory for molecular geometry.
Solution :

A. (i) AXn1 (Group 16): Planar and polar geometry corresponds to a Bent shape sp3 like H2O. Thus,
n1 = 2 (bonds) and m1 = 2 (lone pairs).
B. (ii) BXn2 (Group 15): A Trigonal Pyramidal shape sp3 like NH3 has n2 = 3 and m2 = 1.
C. (iii) CXn3 (Group 14): A zero dipole moment in this group indicates a symmetric Tetrahedral
shape sp3 like CH4. Thus, n3 = 4 and m3 = 0.
D. (iv) (Group 13): Bond angles of 120º indicate a Trigonal Planar shape sp2 like BF3. Thus,
n4 = 3 and m4= 0.

Summing values:

A.
B.

C. Expression:
 Final Answer: 16

PART-3 : MATHEMATICS

51) Explanation of Question:

We have to solve given equation and find number of ordered pairs (x, y).

Concept:
x2 + y2 = 0 ⇒ x = 0, y = 0 if x, y ∈ R.

Solution:

⇒
⇒ only possible when
, cos y = 1
x = 25, y = 0, 2π
Hence 2 ordered pairs (x, y) : (25, 0) or (25, 2π)

Final Answer:
The correct option is (3)

52) y = x3 [∵ logxy = 3]
∴ 4log8x = 3(log8x)2

⇒ log8x = 0; log8x =
⇒

53) Solution:

................(i)
And domain :
x2 – 3x + 2 > 0
(x – 1)(x – 2) > 0 ................(ii)
(i) ∩ (ii)

x∈

Final Answer: Option (3)

54) log2(x – 1) = log2(x – 3)2
⇒ x – 1 = (x – 3)2
⇒ x – 1 = x2 + 9 – 6x
⇒ x2 – 7x + 10 = 0 ⇒ x = 2,5
x = 2 rejected because x > 3

55)

2a3b4c5 = a2b3c4 + a4b5c6

div. by a2b3c4, we get
2abc = 1 + a2b2c2 ⇒ (abc–1)2 = 0 ⇒ abc = 1

56) Question Explanation: To find value of .

Concept: This question is based on write each term as difference of two terms.

Solution:

Final answer: The correct option is (3).

57)
58) If a, b, c, → G.P.
log10 a, log10 b, log10 c → A.P.
⇒ loga 10, logb 10, logc 10 → H.P.

59)

Question Explanation: Finding the mean of a sequence using summation.

Concept: Arithmetic Mean and Summation of Series.
Solution: The sequence consists of terms where the rth term is
. We find the sum of these terms from r = 1 to 99 and divide
by the total number of terms (99) to find the mean. This mean is then compared to the given
expression to find n.
Calculation:
The rth term is:

This is a telescoping-like expansion: .

Sum of 99 terms:

Arithmetic Mean (AM):

Comparing with , we get .

Final Answer: Option (1)

60)

x2 – 4x + A = 0 α+β=4 ; αβ = A

x2 – 36 + B = 0 γ + δ = 36 ; γδ = B
∵ α, β, γ, δ are in increasing G.P. then
α = a, β = ar, γ = ar2, δ = ar3
Now, α + β = a (1+r) = 4 ...(i)
2
γ + δ = ar (1+r) = 36 ...(ii)
eq. (i) ÷ (ii)
r2 = 9 ⇒ r = 3 (increasing GP ∴ r > 0)
substituting the value of r = 3 in eq. (i)
a(1 + 3) = 4 ⇒ a = 1
∴ α = 1, β = 3, γ = 9, δ = 27
Given At = B ⇒ (αβ)t = (γδ)
⇒ (3)t = 9 × 27 = 35
t=5

61) S=109 + 2(11)1(10)8 + 3(11)2 (10)7 ... 10(11)9...(1)

 S = 11(10)8 + 2(11)2 (10)7 + ... 1110 ...(2)
Sub (1) – (2)

– = 109 + 11 . 108 + 112 . 107 + ... 119 – 1110

⇒ S = 1011 = K109
⇒ K = 100

62) d = common difference

is independent of n
⇒ d = 0, 10
a2 = 5, 15

63) (A) –1 + 1 – 1 + 1 – 1 = –1

(B)
(C) log1 = 0
(D) |cos5° + cos10° +....cos180°| = |0 – 1| = 1

64)

65) Given that, S1 = S2

If the radii are r1 and r2, then

66) 120°, 125°, 130°, ............ , nth angle (term)

360n – 720 = 235 n + 5n2

n = 16, n = 9
but at n = 16 , polygen will be can cave
i.e n = 9

67) sinx + sin3x = 3cos2x

[sinx(1 + sin2x)]2 = 9cos4x
sin2x (1 + 1 – cos2x)2 = 9cos4x
(1 – cos2x)(2 – cos2x)2 = 9cos4x
(1 – cos2x)(4 + cos4x – 4cos2x) = 9cos4x
4 – 4cos2x + cos4x – cos6x – 4cos2x + 4cos4x = 9cos4x
cos6x + 4cos4x + 8cos2x = 4

68)

Explain Question :- In this question we have to given a quadratic equation including

logarithms having roots α and β then ask value of α2 + β2.
Concept :-This question is based on logarithmic properties.
Solution :- given equation is

+ =0
has roots α and β

sum of roots = α + β =

Product of roots = αβ =
= 3(0 + 1) = 3

equation becomes x2 – 4x + 3 = 0
⇒(x – 3)(x – 1) = 0
⇒ x = 1, 3
α = 1, β = 3, so α2 + β2 = 1 + 9 = 10

Final answer : Option (3)

69)
 70)
by using
Ans. 64

71)

72) Let that numbers be a, b

Then

⇒ a + b + ab = 27
a + b + 2(a + b) = 27
a + b = 9, ab = 18
(a – b)2 = (a + b)2 – 4ab = 81 – 72

73)

Question Explanation: Find the minimum value of a product of three independent terms.

Concept: Arithmetic Mean - Geometric Mean (AM-GM) Inequality.

Solution:

clearly minimum value occurs when

a2 = b2 = c2 = 1 and minimum value
= 3 × 9 × 13 = 351
Sum of digits of k = 3 + 5 + 1 = 9

Final Answer: 9

74) Use
75)