28-06-2026

1001CJA106213260007 JA

PART-1 : MATHEMATICS

SECTION-I (i)

1) If x1,x2 are the roots of x2 – x + K = 0 and x3,x4 are the roots of x2 – 4x + L = 0 such that x1,x2,x3,x4
are in G.P. Then the product of the integral values of K and L is -

(A) 64
(B) 67
(C) 70
(D) 60

2) If α, β, γ be the roots of x3 + (a4 + 4a2 + 1)x = x2 + a2 (where a ∈ R), then minimum value of

is

(A) 6
(B) 8
(C) 4
(D) 3

3) If 2 sec2A – sec4A – 2cosec2A + cosec4A = , then tan2A is equal to

(A)

(B)

(C) 1

(D)

4) Let x3 – 12x2 + 22x – 100 = 0 has three roots : α, β, γ. Find the value of .

(A)

(B)

(C)

(D)
 SECTION-I (ii)

1) If S is sum of solutions & P is product of solutions of the equation

, then -

(A) S + P = 11
(B) S2 = 16
(C) P2 = 25
(D) S2 = 25

2) Consider the equation |x – 6| + |x – 2| – |x – 4| = k

Identify the correct statement(s) -

(A) Equation has exactly two positive solutions for k = 4 whose sum is 12
(B) Equation has exactly three positive solutions for k = 4 whose sum is 12
(C) Equation has exactly four solutions for k = 3 whose sum is 17
(D) Equation has exactly four solutions for k = 3 whose sum is 16

3) If a, b, c are positive numbers where a + 2b = 4 and b + 2c = 5, then

(A)
maximum value of ab3 is

(B)
maximum value of b2c3 is

(C)
minimum value of is 4

(D)
minimum value of is 6

4) If A,B,C are three angles such that cot 2A cot 2B + cot 2B cot 2C + cot 2C cot 2A = 1, then which
of the following option(s) can be true ?

(A) sin(A + B + C) = –1
(B) tan(A + B + C) = 0
(C) cos(A + B + C) = 1
(D) cot(A + B + C) = 0

5) Consider a polynomial equation :

x4 – 3x3 – 2x2 – 3x + 1 = 0
Tick the correct option(s) :-

(A) The equation has 0 rational roots.

(B) The equation has 2 real roots.
(C) The equation has 2 imaginary roots.
(D) The sum of all real roots is 4.
 SECTION-II (i)

Common Content for Question No. 1 to 2

Consider the series ...........

1) Let S denotes the sum of the first 1023 terms of the series when x = 1. Suppose 7S + 1 = pn,
(where p is a prime number and n ∈ ), then the value of p + n is

2) If x = –1, then sum of first 1023 terms is equal to

Common Content for Question No. 3 to 4

Consider the equation .

3) Number of solutions of the equation is -

4) If α is a root of the given equation, then difference between greatest and least value of log10α is -

SECTION-II (ii)

1) Let Tn = 3n – 2 and T'm = 7m + 2 be nth & mth term of two sequences each having 2004 terms (m, n
∈ N). The number of common terms between the two sequences is

2) A set of consecutive natural number from 1 to n are written and one number is removed. The

arithemetic mean of the remaining number is found to be , then sum of all possible value(s) of the
number removed from the set is k, then is

3) If and λ2 is the minimum value of the

expression (3sinx – 4cosx – 10)(3sinx + 4cosx – 10) then equals

4) is equal to

5) Let P(x) = 4x2 + 6x + 7 and Q(y) = 4y2 – 12y + 29. If P(x). Q(y) = 95, then the value of 8(x + y) is

PART-2 : PHYSICS

SECTION-I (i)
1) In the figure shown, there is a smooth tube of radius 'R', fixed in the vertical plane. A ball 'B' of
mass 'm' is released from the top of the tube. B slides down due to gravity and compresses the
spring. The end 'C' of the spring is fixed and the end A is free. Initially the line OA makes an angle of
60° with OC and finally it makes an angle of 30° after compression. Find the spring constant of the

spring.

(A)

(B)

(C)

(D) None of these

2) Two small balls A and B are launched in the same vertical plane simultaneously, with same speed
of 20m/s at t = 0. Ball A has an initial horizontal velocity and ball B has initial velocity at an angle θ
above the line joining A and B as shown. If the projectiles collide in mid-air at time t :–

(A)
θ = 30°, t = s

(B)
θ = 60°, t = s

(C)
θ = 30°, t = s

(D)
θ = 60°, t = s

3) In a water park there is a circular river in which the flow is at a speed u along a circular path. A
small toy boat is steered radially with speed v relative to water. It starts from point A and reaches a
diametrically opposite point B to the other bank in half round (180°). The time to cross the river and

reach B is. (r0 is radius of central circle.)

(A)

(B)

(C)

(D) None of these

4) Consider a setup consisting of a four-way small pipe connected toa tube from below. The
structure rotates at an angular velocity ω anti-clockwise and water flows upwards into the pipe at a
constant rate. What would the pattern of water that flow out of the pipes look like from a ground

observer watching from top ?

(A)
(B)

(C)

(D)

SECTION-I (ii)

1) The two particles of mass m and 2m, respectively are connected by a light rod of negligible mass
and slide with negligible friction on a circular path of radius r on the inside of a fixed vertical
circular ring. If the system is released from rest at θ = 0° and θ is taken from positive x-axis in

clockwise direction.

The speed of the particles when the rod passes the horizontal position is
(A)
(B)
The maximum speed of the particles is

(C)
The maximum speed of the particles is at
(D) The maximum value of θ is 2tan–1(2)

2) Figure shows a block of mass m3 placed on a smooth wedge of mass m2. (Assume all conditions as
ideal). Find the minimum value of m1 and the corresponding tension (T) in the string, so that block
m3 will move vertically downward with an acceleration of 10 ms–2 . (Take g = 10 ms–2)

(A)
m1 =

(B)
m1 =

(C)
T=

(D)
T=

3) A particle moves along straight line acted by a force which delivers power P = Ct7. Initially it's
velocity is zero. Where C is constant and t is time. Then mark the correct option :-

(A) Displacement of the particle is proportional to t5

(B) Force acting on the particle increases with time.
(C) Acceleration of the particle is proportional to t3.
(D) Rate of change of kinetic energy is proportional to t6.

4) A warrior, who can throw his spear at maximum speed V, is riding on a horse running at speed V.
He observes that his enemy warrior is coming directly towards him with velocity (3V/2). He throws
his spear at an angle of 60° to the horizontal, with maximum speed towards his enemy.

(A) The spear can never hit the enemy.

(B)
If the spear should hit the enemy, he must throw it when enemy is at distance of .

(C)
The spear will hit the enemy at a distance from the place it was launched.
 If the spear hits the enemy at a distance l from the point of launching than time of flight for
(D)
spear is .

5) The roller-coaster track shown in contained in a vertical plane. The portion of track between A
and B is straight and horizontal, while the portions of the left of A and to the right of B have radii of
curvature as indicated. A car is travelling at a speed of 72 km/h when the brakes are suddenly
applied, causing the wheels of the car to slide on the track (µk = 0.20). Choose INCORRECT

options.

The initial rate at which speed of the car decreases if the brakes are applied as the car has
(A)
almost reached A is approximately 0.8 m/s2
The initial rate at which speed of the car decreases if the brakes are applied as the car has
(B)
almost reached A is approximately 4.67 m/s2
The initial rate at which speed of the car decreases if the brakes are applied as the car has just
(C)
passed B is approximately 0.47 m/s2.
The initial rate at which speed of the car decreases if the brakes are applied as the car has just
(D)
passed B is approximately 0.67 m/s2.

SECTION-II (i)

Common Content for Question No. 1 to 2

Configuration of L shaped block and two other blocks are shown. System is set free to move. At any
moment, match the following parameters,

(g = 10 m/s2) Then find:

1) Friction force between block A and B

2) Tension in string
Common Content for Question No. 3 to 4
The spring of constant k = 50 N/m is unstretched when the slider of mass m = 2 kg passes through
position B. The slider is released from rest in position A. There is friction between slider and guide
whose work done from A to B is –11 J and from B to C is –4 J. (Radius of circular portion of guide is R

= 3m & acceleration due to gravity g = 10 m/s2)

3) If speed of slider at position B and C are vB and vC respectively then (in m/s) will be :

4) If the normal force at position B and C are NB and NC respectively then |NC| – |NB| will be in (N) :

SECTION-II (ii)

1) In the figure shown, given that all blocks remain in contact. If velocity of A with respect to ground
is 3 m/s downward, find velocity of B with respect to ground :

2) A pan of negligible mass is supported by an ideal spring which is vertical. Length of the spring is
L0. A mass M of sand is lying nearby on the floor. A boy lifts a small quantity of sand and gently puts
it into the pan. This way he slowly transfers the entire sand into the pan. The spring compresses by

Assume that height of the sand heap on the floor as well as in the pan is negligible. If they work

0
done by the boy against gravity in transferring the entire sand into the pan is mg L . Find the value
of .

3) The small marble is projected with a velocity of 10 m/s in a direction 45° from the y-direction on
the smooth inclined x-y plane. Calculate the magnitude v of its velocity (in m/s) after 2 seconds. Take

g = 10 m/s2.

4) A small cubical block of mass 1 kg is placed inside a rough rectangular groove made in a
circular smooth table as shown in the figure. The table starts rotating clockwise with angular
acceleration 1 rad/sec2 in a horizontal plane about its axis. The time after which the block will start

motion with respect to table is T second. Fill . Assume the size of block slightly smaller then the

width of groove.

5) With two hands, you hold a cone motionless upside down, as shown in figure. The mass of the
cone is m = 1kg, and the coefficient of static friction between your fingers and the cone is μ = 0.5.
What is the minimum normal force (in N) you must apply with each hand in order to hold up the

cone? Consider only translational equilibrium.

PART-3 : CHEMISTRY

SECTION-I (i)

1) H4P2O6 exists in two forms : X and Y. 'X' has basicity = 3 whereas 'Y' has basicity = 4. Select the
incorrect statement.

(A) Average oxidation state of P in both X and Y is same

(B) Number of pπ–dπ linkage is same in both X and Y.
(C) Hybridisation of P in both X and Y is same
(D) 'X' has P-P linkage but 'Y' has P-O-P linkage

2) Consider skeleton of following two species :

where θ1,θ2 and θ3 and θ3 are O–Cl–O

bond angles and x,y and z are 'Cl–O' bond lengths then which of the following order is INCORRECT.

(A) θ2 > θ1
(B) x > y
(C) θ2 < θ3
(D) z > y

3) A sample of protein was analysed for metal content and analysis revealed that it contained
magnesium and titanium. If these are the only metallic species present in the protein and it contains
0.004% Mg by mass and 0.006%. Ti by mass, then the minimum possible molar mass (in gm/mol) of
the protein is : [Mg = 24, Ti = 48]
(A) 6 × 105
(B) 1.5 × 105
(C) 3 × 105
(D) 24 × 105

4) 10 ml of gaseous hydrcarbon is exploded with 100 ml O2. The residual gas on cooling is found to
measure 95 ml of which 20 ml is absorbed by KOH and the reminder, by alkaline pyrogallol. The
formula of the hydrocarbon is :

(A) CH4
(B) C2H6
(C) C2H4
(D) C2H2

SECTION-I (ii)

nd rd
1) An unknown element A is in the 2 period and B is in the 3 period. They show a diagonal
relationship. Which of the following statements is/are correct regarding their ions?

The hydration enthalpy of An+(aq) is expected to be more exothermic than that of the Group 1
(A)
element in the same period as B.
(B) The ionic radius of B(n+1)+ is slightly smaller than An+ if they are Li+ and Mg2+.
(C) Both A and B ions produce oxides that are amphoteric if A is Beryllium.
(D) Conductivity of B(n+1)+ is always less than An+

2) In compound PXnY5–n ; X & Y are monovalent surrounding atoms and order of electronegativity is
X > Y then according to given information correct statement is / are :

If n = 3 then bond angle between central atom and less electronegativity atoms is greater than
(A)
120° .
(B) If n = 0, then all five bond lengths are not equal.
If n = 1, then axial plane can have two same substituent and equatorial plane can have three
(C)
same substituent.
If n = 4 then axial plane can have three same substituent and equatorial plane can have two
(D)
same substituent.

3) A compound contains 48.96% carbon and 2.72% hydrogen. On Carius estimation, 2.56 mg of the
compound gave 5 mg of AgCl. Select the correct statement. (Ag = 108, Cl = 35.5)

(A) Empirical formula of compound is C2H2OCl

(B) Empirical formula of compound is C3H2Cl
(C) Molar mass of compound may be 294
(D) Molar mass of compound may be 155

4) 1.0 g mixture of CaCO3(s) and glass beads liberate 0.22 g of CO2 upon treatment with excess of
HCl. Glass does not react with HCl. Which of the following statement(s) is/are CORRECT ?
(A) The mass of CaCO3 in the original mixture is 0.5 g
(B) The mass of calcium in the original mixture is 0.2 g
(C) The mass percent of calcium in the original mixture is 40% Ca.
(D) The mass percent of Ca in the original mixture is 20% Ca.

5) Consider the following species :

(P) (Q) (R) (S)
Which of the following statements are correct?

(A) At least one atom in each species is sp2 hybridized.

(B) All the species possess resonance stabilization.
(C) The maximum oxidation statement attained by the central atom is the same in P and Q.
(D) Exactly two of the given species are linear in their most stable form.

SECTION-II (i)

Common Content for Question No. 1 to 2

Two solutions are shown in the following figure

Container (I) contains aqueous solution of 50 ml 40% w/v NaOH and container (II) contains aqueous
solution of 50 ml 2M NaOH.
Answer the following questions. [Atomic mass : Na = 23]

1) If solution of these containers are mixed together, then the molarity of final solution is

2) If final solution have density 1.2 g/ml, then the molality of final solution is:

Common Content for Question No. 3 to 4

The more ionic character (i.e. poorer covalency ) in a bond (due to the more electronegative
substituent to the central atom) leads to the utilisation of hybrid orbitals containing more p-
character (i.e. less s-character) of the central atom. In other words, the multiple bond encourages
the central atom to utilize its hybrid orbitals which contain more s-character.
The percentage of s or p character between two adjacent and equivalent hybrid orbitals can
determined from the knowledge of the corresponding bond angle (θ) as follows :

3) If x1 , x2 and x3 are S-S bond lengths in , and respectively, then correct order
for S-S bond length is :
(for example, if your answer is x2 > x3 > x1 then write 23.10 as your answer)
4) The percentage of p-character (approx) in hybrid orbital having the lone pair at central atom in
SF4 molecule will be (given equatorial bond angle is 102° and cos 102° = –0.21)

SECTION-II (ii)

1) A diatomic molecule has a dipole moment of 1.2 D. If bond length is 1.0 Å, what percentage of an
electronic charge exists on each atom.
[Add the digits untill you are getting single digit. e.g. If the answer is 537, then 5 + 3 + 7 = 15]
again 1 + 5 = 6 and 6 is to be written as answer.

2) Find the group number of element 'X' which belongs to s-or-p-block, having successive ionisation

energies as per the graph gives below : Give your answer

according to long form of periodic table.

3) 100 ml, 1M H2SO4 solution of density 1.5 gm/ml is mixed with 400 ml of water , resulting in a
diluted solution of density 1.25 gm/ml. If the molarity of final diluted solution is ‘Z’, then report your
answer as ‘100Z’. (Given : Density of water = 1 gm/ml).

4) 5 g sample of CuSO4.5H2O was dissolved in water. BaCI2 solution was mixed in excess to this
solution. The precipitate (BaSO4) obtained was washed and dried, it weighed 4.66 g. If the % of SO42–
by weight in the sample is x% then the value of x is : (Cu = 63.5, Ba = 137, Cl = 35.5, S = 32, O =
16)

5) Acid number is commonly used in paint industry. It is defined as milligrams of potassium

hydroxide required to completely neutralise acid in 1 gm paint. If 0.75 gm paint sample requires
2.25 m mol KOH for complete neutralisation. Acid number of this paint sample is x. What is the value

of ? (K = 39)
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I (i)

Q. 1 2 3 4
A. A D A A

SECTION-I (ii)

Q. 5 6 7 8 9
A. A,D A,D A,C A,B,C,D A,B,C,D

SECTION-II (i)

Q. 10 11 12 13
A. 32.00 -1.00 5.00 6.00

SECTION-II (ii)

Q. 14 15 16 17 18
A. 286.00 8.48 to 8.49 3.06 to 3.07 2.00 6.00

PART-2 : PHYSICS

SECTION-I (i)

Q. 19 20 21 22
A. B A A D

SECTION-I (ii)

Q. 23 24 25 26 27
A. A,B,D A,C A,B,C C,D A,C,D

SECTION-II (i)

Q. 28 29 30 31
A. 10.00 50.00 1.15 57.33

SECTION-II (ii)

Q. 32 33 34 35 36
A. 3.14 to 3.16 3.00 10.00 2.00 65.00

PART-3 : CHEMISTRY
 SECTION-I (i)

Q. 37 38 39 40
A. D C D D

SECTION-I (ii)

Q. 41 42 43 44 45
A. A,B,C A,B,C,D B,C A,B,D A,B,C,D

SECTION-II (i)

Q. 46 47 48 49
A. 6.00 6.25 12.30 34.71

SECTION-II (ii)

Q. 50 51 52 53 54
A. 7.00 13.00 22.60 to 22.80 38.40 16.80
 SOLUTIONS

PART-1 : MATHEMATICS

1) Let the common ratio of G.P. be 'r' then x2 = x1r. x3 = x1r2, x4 = x1r3
And x1 + x2 = 1, x1x2 = K. x3 + x4 = 4, x3,x4 = L
∴ r = –2 and x1 = 1
⇒ K = –2, L = –32

2) Given equation can be written as

∵ α, β, γ are roots ∴
Now,

3) (2 sec2A – sec4A) – (2 cosec2A – cosec4A) =

sec2A(2 – sec2A) – cosec2A(2 – cosec2A) =

Put tan4A = t,

4t2 + 16t – t – 4 = 0

4) (α + β + γ) = (α2 + β2 + γ2) + 2(αβ + βγ + γα)

α2 + β2 + γ2 = (α + β + γ)2 – 2(αβ + βγ + γα)
= 144 – 2(22)
= 100

5)
⇒ x2 – x – 4x +
⇒ x2 – 5x + 6 = 0 has sol. x = 2 & 3
∴S=5&P=6
6)
ƒ(x) = |x – 6| + |x – 2| – |x – 4|

for k = 4 ⇒ three solutions 0, 4, 8

⇒ two positive solutions whose sum is 12
for k = 3 ⇒ four solutions
1, 3, 5, 7
whose sum is 16

7) a + 2b = 4, b + 2c = 5

(A)

(B)

(C)

(D)

8) 2A + 2B + 2C = nπ, n ∈ I

⇒A+B+C=

9) The poly equation is symmetric about the middle term. Hence,

(÷ x2)

Let

⇒ t2 – 3t – 4 = 0
(t – 4)(t + 1) = 0

(x2 – x + 1)(x2 – 4x + 1) = 0

10) 12x1 + 22x2 + 22x3 + 42x4 + 42x5 + 42x6 + 42x7+.....

number of terms containing 12 ⇒ 1
number of terms containing 22 ⇒ 2
number of terms containing 42 ⇒ 4
1 + 2+ 4 + 8 +.......upto n terms = 1023

so the complete series is

put x = 1
13 + 23 + 43+..........upto 10 terms

11) 12x1 + 22x2 + 22x3 + 42x4 + 42x5 + 42x6 + 42x7+.....

number of terms containing 12 ⇒ 1
number of terms containing 22 ⇒ 2
number of terms containing 42 ⇒ 4
1 + 2+ 4 + 8 +.......upto n terms = 1023

so the complete series is

put x = –1 ⇒ all the terms vanishes except for the first term

12)

⇒ or

or or
⇒ log10x = 1, 2, 3, –3, 0
⇒ x = 10, 102, 103, 10–3, 1 (all satisfy)
Number of solutions = 5

13)

⇒ or

or or
⇒ log10x = 1, 2, 3, –3, 0
⇒ x = 10, 102, 103, 10–3, 1 (all satisfy)
Difference = 6

14) 3n – 2 = 7m + 2

n = 7λ + 6 and m = 3λ + 2
3λ + 2 ≤ 2004 and 7λ + 6 ≤ 2004
λ ≤ 667 and λ ≤ 285
⇒ 286 common terms

15)

; hence n can be 69, 70 or 71

for n = 69 ; ⇒x=1

for n = 70 ; ⇒x∉N
for n = 71 ⇒ x = 71
⇒ k = 1 + 71 = 72

16)

y = (3sinx – 4cosx – 10)(3sinx + 4cosx – 10)

 y = (3sinx – 10)2 – 16cos2x
y = 9sin2x – 60sinx + 100 – 16 + 16sin2x
y = 25sin2x – 60sinx + 84
y = (5sinx – 6)2 + 48
ymin = λ2 = 49

17) As we know that cotθ – tanθ = 2cot2θ

18) P(x) = 4x2 + 6x + 7 =

Q(y) = 4y2 – 12y + 29 =

⇒ P(x).Q(y)

and Q(y) = 20 ⇒
8(x + y) = 6

PART-2 : PHYSICS

19)

By energy conservation

mgR(1 + cos 30°) =

20) Condition for collision in mid air.

αAB = 0 and should be directed from A to B.
∴
Relative velocity perpendicular to line joining A and B should be zero
20sin 30° = 20sinθ
θ = 30°

time to collide =

time to collide = = .

21)

22)

Correct Answer is (D)

23)
Δu = uf – ui
= mgr – (2mgrsinθ + mgrcosθ)
tanθ = 2
for θ = θmax, v = 0

24) h = ½ gt2 ; x = ½ at2 ;

tan θ = ; a = g cot θ
m1g - T = m1g cot θ
T = m1g(1 - cot θ) ; T = m2g cot θ

T= ; m1g (1 - cot θ) = m2g cot θ

m1 =

25)

gives v ∝ t4 ...(i)

given S ∝ t5 ....(ii)
v ∝ t gives a ∝ t3 ......(iii)
4

....(iv)

26)

Correct Answer is (C,D)

27)

Question Explanation: A roller-coaster car moves on a track lying in a vertical plane. The
track is straight and horizontal between A and B, and curved on both sides. Brakes are applied
suddenly, and we must find how fast the speed starts decreasing at A and just after B.
Concept: This question is based on friction force with normal reaction in circular motion.
Solution:

(A) N – mg = ; = 4.67
mg – N = ;
Final Answer: Option (2)

28)
100 - T = 10 a
T - N = 6a
N = 4a________
100 = 2a
a=5
N = 20
FL = µN
= 0.5 (20)
= 10 N
Force due to gravity 40N > F 10 N so F = 10 N

29)
10g = 20a

30)

Correct answer is 1.15

31) Correct answer is 57.33

32)
vy = 3

12 + 3vx = 9
vx = –1

33)

Correct Answer is 3

34)
T = 2 sec
or particle will strike plane at 2 sec
Hence speed will be 10 m/s

35)

Correct Answer is 2

36) For equilibrium in vertical direction,

..... (1)
PART-3 : CHEMISTRY

37) The correct answer is option (D)

38)

The correct answer is option (C)

39) Explain Question:

Asked minimum possible molar mass.
Concept:
Based on % composition.
Solution:
We have to find, minimum possible molar mass of protein :

Mass ratio of 'Mg' and 'Ti' =

Mole ratio of 'Mg' and 'Ti' =

It means, 1 mole of protein contains,
4 mole of Mg and 3 mole of Ti
4 mole of Mg = 24 × 4 = 96 g
3 mole of Ti = 3 × 48 = 144 g
Total mass of metal = (96 + 144)g = 240 g

∴ % Mass of metal =

⇒ 0.01 =
∴ Molar mass of protein = 2400000 g/mol
Molar mass of protein = 24 × 105 g/mole
Final answer: Option (D)

40) Volume of CO2 = 20 ml (absorbed gas by KOH)

Volume of air unreacted = 95 – 20 = 75 (gas absorbed by pyrogallol)
∴ O2 reacted = 100 – 75 = 25 ml
∵ 10 ml hydrocarbon libarates 20 ml CO2.
∴ 2 atoms of ‘C’ are present in the compound.
∴ C2Hx + yO2 —→ 2CO2 + H2O
 initial 10 ml 25 ml
final 0 0 20 ml 10 ml
volume of water vapours = (25 – 20) × 2 = 10 ml
∵ 10 ml hydrocarbon gives 10 ml water vapours.
∴ No. of Hydrogen atoms in compounds are 2.
∴ Compound will be C2H2.

41)

Concepts :
Hydration enthalpy, Amphoterism, Fajan’s Rule.

Solution:

A. (A) Li+ vs Na+. Li+ is smaller, so ΔHhyd​ is more exothermic. Correct.

B. (B) Mg2+ (0.72 Å) is smaller than Li+ (0.76 Å). Correct.
C. (C) BeO and Al2​O3​ are both amphoteric. Correct.

42)

The correct answer is option (A), (B), (C), (D)

43) % of Cl =

Element % Atomic ratio Simplest ratio

C 48.96 4.08 3

H 2.72 2.72 2

Cl 48.32 1.36 1
Empirical formula of compound is C3H2Cl

44)
CaCO3 ⇒ x g
Glass bead ⇒ (1 – x)g
CaCO3 + 2HCl ⟶ CO2 + H2O + CaCl2
Xg

Moles of CO2 produced = = 5 × 10–3

Moles of CaCO3 reacted = 5 × 10–3
Weight of CaCO3 reacted = (5 × 10–3) × 100 g = 0.5 g
Weight of CaCO3 in original sample = 0.5 g
Weight of Ca in original sample = 5 × 10–3 × 40 = 0.2 g
% of Ca =

45) The correct answer is option (A), (B), (C) (D)

46)

The correct answer is 6.00

47) The correct answer is 6.25

48) The correct answer is 12.30

49) The correct answer is 34.71

50) Explain Question: To find what percentage of an electronic charge exists on each atom

Concept:
Solution:
μobs = 1.2 D , % of electronic charge present means % ionic character

So answer ⇒ 2 + 5 = 7
Final Answer: (7)

51) The correct answer is 13.00

52)

Moles of H2SO4 in initial sol = 0.1 mole

Mass of initial sol = 150 gm
Mass of water = 400 gm
Total mass of sol = 550 gm

Final volume

53) CuSO4.5H2O(aq) + BaCl2(aq) —→ BaSO4(s) + CaCl2 (aq)

4.66 g
Mass of BaSO4 = 4.66 g

Mole of BaSO4 = =
∴ Mole of SO42– =

Mass of SO42– = (ionic mass of SO42–) = 1.92 g

% SO42– = × 100 = 38.4%.

54) 0.75 gm paint requires ⇒ 2.25 millimole KOH

1 gm point

millimoles KOH
⇒ 3 millimoles KOH
⇒ 3×56 mg KOH
⇒ 168