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0% found this document useful (0 votes)
3 views37 pages

Solution (4)

The document contains a series of physics, chemistry, and mathematics problems, each with multiple-choice answers. It covers various topics including mechanics, thermodynamics, chemical bonding, and algebra. The problems are designed for students preparing for exams, providing a range of scenarios and calculations.

Uploaded by

rajveerrajme
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

02-08-2026

2401CJA101001260012 JM

PHYSICS

SECTION - I

1) All surfaces shown in figure are smooth. For what ratio m1 : m2 : m3, system is in equilibrium. All

pulleys and strings are massless :-

(A) 1 : 2 : 1
(B) 2 : 2 : 1
(C) 2 : 1 : 2
(D) 1 : 2 : 2

2) Find acceleration of the lower block w.r.t. upper block if both blocks were at rest initially and
then a force F acts on upper block as shown in figure. Friction coefficients between different

surfaces are as shown in figure.

(A) 1 m/s2
(B) Zero
(C) 2 m/s2
(D) 5 m/s2

3) The ratio of the reading of weighing machine when a man standing on the weighing machine in a
stationary lift & when lift is moving downward with uniform acceleration 'a' is 3 : 2. The value of 'a'
is :- (g = acceleration due to earth)

(A)
g
(B) g

(C)
g

(D)
4) In the following figure, two blocks of masses m1 = 10 kg and m2 = 5 kg are in contact on a
frictionless table. A horizontal force of F = 15N is exerted on mass m2, the force of contact between

m1 and m2 will be :-

(A) 5 N
(B) 10 N
(C) 15 N
(D) 20 N

5) In the system shown in figure acceleration of 1 kg mass :-

(A) g/4 downward


(B) g/4 upward
(C) g/2 downward
(D) g/2 upward

6) A disc starts from rest and it gains an angular acceleration given by α = 3t – t2. Calculate the
angular velocity after 2 sec in rad/s :-

(A)

(B)

(C) 20
(D) 10

7) A boy can throw a stone up to a maximum height of 10 m. The maximum horizontal distance that
the boy can throw the same stone up to will be :

(A)
(B) 10 m
(C)
(D) 20 m

8) Two blocks A and B one on top of other, are released on a fixed incline. All surfaces are
frictionless then acceleration of A & B are represented by two vectors respectively :-
(A)

(B)

(C)

(D)

9)

A force acts on block shown. The force of friction acting on the block is :

(A)
(B)
(C)
(D)

10) A uniform rod of mass M and length L lies flat on a frictionless horizontal surface. Two forces F
and 2F are applied along the length of the rod as shown. The tension in the rod at point P is

(A) F
(B) 3F

(C)

(D)

11) In the figure shows blocks are initially at rest on the floor. Mark the correct statement(s) :
(A) When applied force on pulley is 200 N the normal reaction on block A is zero.
(B) When applied force is 400 N acceleration of B is 10 m/s2
(C) When applied force is 240 N acceleration of pulley is 2 m/s2
(D) For a force F = 100 N, normal reaction on B is zero.

12) Shown system is in equilibrium. String is cut at t = 0. The acceleration of blocks at t = 0 (i.e. just

after cutting the string joining B and C).

(A) aA =0, aB = aC = g↓
(B) aA =0; aB = g ; aC = g ↓
(C) aA =2g ↓, aB =2g↓, aC = 0
(D) aA = g , aB = aC = g↓

13) The breaking tension of a string is 10N. A particle of mass 0.1 kg tied to it is rotated along a
horizontal circle of radius 0.5 meter on a smooth horizontal surface. The maximum speed with which
particle can be rotated is :-

(A)
(B)
(C)
(D)

14) A particle of mass m is tied to a light string of length L and moving in a horizontal circle of
radius r with speed v as shown. The forces acting on the particle are :-

(A) mg and T

(B)
mg, T, directed inwards

(C)
mg, T, directed outwards

(D)
only

15) A rigid body is rotating such that angular displacement at any instant t is given by θ = 2t2 + 3t +
4.

List-I List-II

(A) Angular velocity at t = 2 units (I) 4 units

(B) Angular acceleration at t = 3 units (II) 0 units

(C) Average angular velocity between t = 0 and t = 2 units (III) 7 units

(D) Average angular acceleration between t = 0 and t = 2 units (IV) 11 units


(A) A → IV; B → I; C → III; D → I
(B) A → III; B → I; C → IV; D → I
(C) A → I; B → II; C → III; D → IV
(D) A → IV; B → III; C → II; D → I

16) When the road is dry and the coefficient of friction is μ, the maximum speed of a car in a circular
path is 10 m/s, if the road becomes wet and μ’ = μ/2. What is the maximum speed permitted ?

(A) 5 m/s
(B) 10 m/s
(C) 10 m/s
(D) 5 m/s

17) A block is rotating in contact with vertical wall as shown. Find the minimum value of ω so that
the block does not slide down.

(A)

(B)

(C)

(D)

18) Force acting on an object is given by . Dimensional formula of a is (v is speed) :-

(A) M–1L
(B) MLT–1
(C) M–1LT–2
(D) ML–1

19) A particle is in a unidirectional potential field where the potential energy (U) of a particle
depends on the x-coordinate given by Ux = a (1 – cos bx) & a and 'b' are constants. The physical
dimensions of 'b'

0 0
(A) M LT
0 0
(B) M L–1T
(C) MLT–1
(D) ML2T–2

20) A bird moves from point (1, –2) to (4, 2). If the speed of the bird is 20 m/s, then the velocity
vector of the bird is

(A)

(B)
(C)
(D)
SECTION - II

1)

Two identical bead of mass m are connected by a light string, can slide on a smooth ring. Both are
released from rest from the position shown in figure. Find initial acceleration (in m/s2) of bead A.

2) If acceleration (in m/s2) of wedge (leftwards) so that block just leaves contact with the wedge is .

Find value of n.

3) A uniform heavy rope is being pulled by a force 100 N, find tension (in N) at its' mid point :-

4) In the figure shown, a lift goes downward with a constant retardation. An observer in the lift
observes a conical pendulum, revolving in a horizontal circle, with time period 2s. The distance
between the centre of circle and the point of suspension is 2.0m. Find the retardation of the lift (in
m/s2).

[use : π2 = 10 and g = 10 m/s2]


5) A particle is thrown horizontally with speed 15 m/s. Find the time (in sec) at which it strikes the

inclined plane as shown in figure. (g = 10 m/s2)

CHEMISTRY

SECTION - I

1) In Silica (SiO2), each silicon atom is bonded to -

(A) Two oxygen atoms


(B) Four oxygen atoms
(C) One silicon and two oxyen atoms
(D) One silicon and four oxyen atoms

2) The number of P–OH bonds and the oxidation state of phosphorus atom in pyrophosphoric acid
(H4P2O7) respectively are :-

(A) five and four


(B) five and five
(C) four and five
(D) four and four

3) Which of the following species does not exist?

(A) SH2

(B) PI6
(C) SeF6

(D) XeF5

4) A cyclic silicate anion is represented as [Si3O9]n-

(A) 3
(B) 4
(C) 6
(D) 8

5) Which of the following would result in the formation of strongest π-bond if the molecular axis is x-
axis ?
(A) 2px + 2px
(B) 2py + 2py
(C) 2py + 3dxy
(D) 2pz + 4pz

6) Which of the following compound is formed in the second excitation state of sulphur atom :

(A) SF4
(B) SF6
(C) SF2
(D) None

7) Nitrogen does not form NF5 because

(A) Nitrogen is a member of V group


(B) It contains no empty d-orbital
(C) The bond energy of N ≡ N is very high
(D) Inert pair effect exists in the molecule

8) Which orbital is not involved in the formation of PCl5 molecule :-

(A) s
(B) dz2
(C) dx2–y2
(D) pz

9) In which of the following pairs, the hybridisation of central atoms is same, but shape is not the
same?

2–
(A) SO3, CO3
2–
(B) SO3 , NH3
(C) PCl5, POCl3
(D) XeF2, ICl3

10)

5.6 L of oxygen gas at S.T.P. contains how many number of atoms at 1 atm and 273 K ?

(A) 6.02 × 1023


(B) 3.01 × 1023
(C) 1.505 × 1023
(D) 12.04 × 1023

11) The number of oxygen atoms in 4.4gm of CO2 is approx.


(A) 1.2 × 1023
(B) 6 × 1022
(C) 6 × 1023
(D) 12 × 1023

12)

Calculate the number of atoms in 11.2 L of SO2 gas at STP.

(A)

(B)

(C) 3NA
(D) NA

13) Number of Ca+2 and Cl– ion in 111 g of anhydrous CaCl2 are -

(A) NA, 2NA


(B) 2NA, NA
(C) NA, NA
(D) None

14) 90 gm mixture of H2 and O2 is taken in stoichiometric ratio and gives H2O with 50% yield. The
produced mass of H2O (in gm) is :

(A) 45 gm
(B) 36 gm
(C) 20 gm
(D) 90 gm

15) The weight of water present in 1.61g of Na2SO4.10H2O is :-

(A) 0.09 g
(B) 0.9 g
(C) 0.8 g
(D) 0.7 g

16) If law of conservation of mass was to hold true, then 20.8 g of BaCl2 on reaction with 9.8 g of
H2SO4 will produce 7.3 g of HCl and BaSO4 equal to :–

(A) 11.65 g
(B) 23.3 g
(C) 25.5 g
(D) 30.6 g
17) Three elements X, Y and Z are in the 3rd period of the periodic table. The oxides of X, Y and Z,
respectively, are basic, amphoteric and acidic. The correct order of the atomic numbers of X, Y and Z
is :

(A) Z < Y < X


(B) X < Z < Y
(C) X < Y < Z
(D) Y < X < Z

18)

How much P4O10 will be produced from 31 g P4 and 32 g O2?

(A) 56.8 g
(B) 60 g
(C) 284 g
(D) 100 g

19) 5.6 gm CaO react with 4.48 litre of CO2 & form CaCO3. Calculate mass of CaCO3.

(A) 10 gm
(B) 20 gm
(C) 30 gm
(D) 40 gm

20) For the reaction : 2 A + 3B → 4C + D, 5 moles of A and 9 moles of B will produce

(A) 4 moles of C, 1 mole of D


(B) 20 moles of C, 5 moles of D
(C) 10 moles of C, 2.5 moles of D
(D) 32/3 moles of C, 8/3 moles of D

SECTION - II

1) From 0.2 kg calcium, 1.2 × 1024 atoms are removed. The number of g-atoms of calcium left is :
[Take : NA = 6 × 1023, Ca = 40]

2) An element X has three isotopes . The percentage abundance of is 90% and


average atomic mass of the element is 20.18. The percentage abundance of should be

3) Number of orbitals taking part in hybridisation in ion is ……

4) The number of water molecule(s) directly bonded to the metal centre in CuSO4.5H2O is :
5) Which of the given set of orbitals form 'σ' bond between two atoms along y-axis?
s + px, s + py, py + py, px + py, py + pz, px + pz.

MATHEMATICS

SECTION - I

1) The sum of 'n' terms of series

1·4·7 + 4·7·10 + 7·10·13 + ....... ,


then a + b + c + d equals

(A) 100
(B) 212
(C) 112
(D) –112

2) The sum 1 + 3 + 7 + 15 + 31 + .....to n terms is

(A) 2n – 2 – n
(B) 2n–1 – 1 – n
(C) 2n+1 – 2 – n
(D) None of these

3) If Sn = then =

(A) 1
(B) 6
(C) 2
(D) 1/6

4) The largest common term to the arithmetic progressions 3, 7, 11, .... 407 and 2, 9, 16, ....709 is :

(A) 14
(B) 387
(C) 397
(D) 487

5) If a, b, c are in A.P and (a + 2b – c)(2b + c – a)(c + a – b) = k abc, then k =

(A) 4
(B) 2
(C) 1
(D) None of these

6)

(A) 1
(B) –1
(C) 0
(D) 2

7)

If then

(A)
(B)
(C)
(D) None of these

8) If , then a =

(A) –5
(B) –6
(C) –4
(D) –2

9) If 2x.3x+4 = 7x, then x = :-

(A)

(B)

(C)

(D)

10) If all the values of x satisfying log2 log4 log5x < 0 is given by x ∈ (a, b), then a + b is

(A) Not defined


(B) 630
(C) 625
(D) 626
11) The expression simplifies to (a, b, c > 1)

(A) log(abc)
(B) 3log(abc)
(C) 3
(D) 1

12) Let p and q be two positive numbers such that p + q = 2 and . Then p and q are
roots of the equation :

(A)
(B)
(C)
(D)

13) The number of integral values of k, for which one root of the equation lies in the
interval (1, 2) and its other root lies in the interval (2, 3), is :

(A) 2
(B) 0
(C) 1
(D) 3

14) If the A.M. of the roots of a quadratic equation is and A.M. of their reciprocals is , then the
quadratic equation is -

(A) 5x2 – 8x + 7 = 0
(B) 5x2 – 16x + 7 = 0
(C) 7x2 – 16x + 5 = 0
(D) 7x2 + 16x + 5 = 0

15) If sin α & cos α are the roots of the equation ax2 + bx + c = 0 then :

(A) a2 – b2 + 2ac = 0
(B) a2 + b2 + 2ac = 0
(C) a2 – b2 – 2ac = 0
(D) a2 + b2 – 2ac = 0

16) f(x) when divided by x2- 3x + 2 leaves the remainder ax + b. If f(l) = 4 and f(2) = 7, determine a
and b.

(A) a=2, b = 1
(B) a=3, b = 1
(C) a=2, b =3
(D) None

17) If cosecθ + cotθ = 5, then sinθ is equal to :-

(A)

(B)

(C)

(D)

18) If 5tanθ = 4 then is equal to :-

(A) 0
(B) 1

(C)

(D) 6

19) If in two circles, arcs of same length subtends angles of 60º and 75º at the centre, then the ratio
of their radii is :-

(A) 4 : 5
(B) 5 : 4
(C) Not deribable
(D) None

20) If the ratio of the roots of ax2 + 2bx + c = 0 is same as the ratio of the roots of px2 + 2qx + r = 0,
then:-

(A) b/ac = q/pr


(B) b2/ac = q2/pr
(C) 2b/ac = q2/pr
(D) None of these

SECTION - II

1) If n(A) = 25, n(B) = 15 & n(A ∩ B) = 10 then the value of :

2) Let U = {x ∈ N; x ≤ 10}, A = {x ∈ N; 1 ≤ x3 < 150} and B = {x ∈ N x is prime number greater


than 2} and C = {x ∈ N ; 5x} then number of elements in (Ac ∩ Bc ∩ Cc) is
3) _________

4) Find the number of digit in 523(given log102 = .3010)

5) If p, q, r are distinct real numbers, then


ANSWER KEYS

PHYSICS

SECTION - I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B D B D B D C D D B B B A A D C A B D

SECTION - II

Q. 21 22 23 24 25
A. 5.00 15.00 50.00 10.00 2.00

CHEMISTRY

SECTION - I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B C B C B B B C D B A B A A B B C A A C

SECTION - II

Q. 46 47 48 49 50
A. 3.00 2.00 4.00 4.00 2.00

MATHEMATICS

SECTION - I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C C C B A C A C A B D D C B A B B C B B

SECTION - II

Q. 71 72 73 74 75
A. 3.00 3.00 2.00 17.00 3.00
SOLUTIONS

PHYSICS

1)
T = m3g ......(i)
2T = m2g ......(ii)
T = m1g sin 30° ......(iii)

2) Question Explanation:
The problem asks to calculate the relative acceleration of two blocks as shown in figure, when
a horizontal force is applied to the upper block.

Concept:
This question is based Friction, block over block system.

Solution:
(1) Limiting friction between for blocks = 0.3 × 20 = 6N

(2) Let the acceleration of system (common acceleration)

= 1 m/s2

(3) Check for ac


FBD of 3 kg block
∴ fs = 3 × 1 = 3N (< 6N)

So, both the blocks have same acceleration i.e., their relative acceleration will be zero.

Final answer: The correct option is (2).

3) Question Explanation: We are given that ratio of the reading of weighing machine when a
man standing in a stationary lift and lift is moving downward with uniform acceleration a is
3:2. We need to find the value of a.
Concept: This question is based on Newton's 2nd law of motion or pseudo force.
Solution:
(i) Case-I stationary lift
N1 = mg

(ii) When lift is moving downwards with uniform acceleration 'a'.

mg – N2 = ma
N2 = mg – ma


3g – 3a = 2g

Final answer: The correct option is (4).

4) Question Explanation:
We need to find the force of contact between m1 and m2.

Concept:
This question is based on Newton's law of motion.

Solution:
Total mass of the system = m1 + m2 = 10 + 5 = 15 kg
Since, the table is frictionless, the net force acting on the system is the applied force F = 15 N
using Newton's second law

N = m1⋅a
= 10 × 1
= 10 N
Therefore, the force of contact between m1 and m2 will be 10 N.
Final Answer:
The correct option is (2)

5)

Explain Question: Two blocks are connected with string through pulley, it is asked to
calculate acceleration of 1kg block.
Concept: NLM, Constrained motion
Solution:

Using constrained edition


– 2T.a1 + T.a2 = 0
a2 = 2a1
T – m2g = m2a2 ........(i)
m1g – 2T = m1a1........(ii)
2T – 2m2g = 2m2a2 ........(iii)
g(m1 – 2m2) = m1a1 + 2m2a2
g(4 – 2) = 4a1 + 2 × 1 × 2a1

Acceleration of 1kg block = = = upward

Final Answer

The correct option is (4)

6) Question Explanation:
A disc starts from rest with angular acceleration α = 3t – t2. Find the angular velocity after 2
seconds using integration.
Concept:
Variable angular acceleration requires integration to calculate angular velocity over a time
interval from rest.
Formula:

Calculation:
At t = 2

Final Answer: rad/s

7) Explanation
To determine the maximum horizontal distance the boy can throw the stone, we must
consider projectile motion. The horizontal range of a projectile is maximum when the angle of
projection is 45°.
Concepts Involved:
1. Projectile Motion:
• The motion of the stone can be divided into two components:

A. Vertical motion (determines the maximum height).


B. Horizontal motion (determines the range or distance traveled).

2. Formulas Used:
• The maximum height (H ) is given by:

where:

A. u = initial velocity of the stone,


B. θ = angle of projection,
C. y = 9.8 m / s2 (acceleration due to gravity).

• The horizontal range (R) of the projectile is given by:

For maximum range, θ = , so:

Step 1: Find the Initial Velocity u:


From the maximum height formula:

Here, H = 10m, θ = (since the stone is thrown vertically upward):

m/s
Step 2: Calculate the. Maximum Horizontal Range R:
For the maximum horizontal range (R):

Substitute u = 14 m/s and g = 9.8 m/s2:


m
Final Answer:
The maximum horizontal distance the boy can throw the stone is:
20 m

8) B will fall along the plane, while A will vertically downward, since force on A is only weight.

9)

Explanation of Question: A block is placed on a rough horizontal surface as shown in figure


and it is asked to find friction acting on block.

Concept: “This question is based on friction ”

Solution:

N = mg – 6
fs,max = μN
= .8 (1 × 10 – 6)
= 3.2 N
force applied in horizontal direction
Fx = 2N
Fx < fs,max
So f = Fx
f = 2N
Considering direction f = N

Final Answer: The correct option is (4)

10)

2F – F = Ma

2F – T = ⇒ 2F – T = ∴ T=
11)

F = 400 ⇒

Fnet = 200 – 100 = 10 × 9


a = 10 m/sec

12) Question Explanation:


The problem asks for the acceleration of the blocks A, B and C immediately after the string
joining B and C is cut, given that the system was initially in equilibrium.

Concept:
This question is based on spring, newton's laws.

Solution:
Just before cutting the string tension & spring forces are shown in figure.

Just after cutting the string FBD of C

mg = mac
ac = g (↓)
FBD of B

2mg – mg = maB
aB = g (↑)
FBD of A

3mg – mg – 2mg = maA

Final Answer:
The correct option is (2)

13)

Explain question : A particle tied to a string and being rotated in horizontal circle we have to
find maximum speed of rotation such that string doesh't break
Concept : This question is based on dinamics of circular motion.
Solution :-

v2 = 50

Final answer :- (2)

14)

Explanation Question: It is asking about the forces acting on mass m in an inertial frame i.e
in ground frame.
Concept: Newton's law of motion and dynamics of circular motion
Solution:

Forces acting on 'm' are mg due to gravitation pull and the tension exerted by the string.
The forces on 'm' are as shown in FBD of mass m
is not the real force acting on m, it is just the net effect of components of all forces acting
towards the center.
Final answer: Option (1)

15) Angular velocity ω = = 4t + 3


⇒ (ω)t = 2 = 4(2) + 3 = 11 units

Angular acceleration
⇒ (α)t = 3 = 4 unit
At t = 0, θ = 2(0) + 3(0) + 4 = 4
At t = 2, θ = 2(2)2 + 3(2) + 4
= 8 + 6 + 4 = 14

<ω>= units
At t = 0, ω = 4(0) + 3 = 3 units
At t = 2, ω = 4(2) + 3 = 11 units

<α> units

16) Question Explanation: We are given that a car performs circular path at maximum
speed. We have to calculate the maximum speed when coefficient of friction becomes half of
previous.

Concept: This question is based on dynamics of circular motion.

Solution: When car is moving with maximum speed on circular road.

flimiting =
μN =

.....(i)
Initial Case-
Coefficient of friction = μ
Max. speed of car = 10m/s
From equation...(i)

μmg = ....(ii)
when, coefficient of friction = μ/2
Max. speed of car = v'
Again from equation ....(i)

...(iii)
(ii) ÷ (iii)

Final answer: The correct option is (4).

17) Here mg = fs to it do not slip


2
N = mw R (centripetal force) ...(1)
mg = µN ...(2) ∵ f = µN
Plut value of N from (1) in (2)

mg = µmω2R ⇒ ω2 =

18) Question Explanation: We are given a formula of force in terms of velocity and two
variables 'a' and 'b'. We have to find the dimensional formula of 'a'.

Concept: This question is based on application of dimensional analysis to find the dimensions.
Solution:

So,

[a] = M–1L

Final answer: The correct option is (1).

19) Explain question : We have to find the dimension of 'b' when potential energy of particle
is Ux = a(1 – cos bx)
Concept : This question is based on finding the dimensions of constants by dimension
analysis.
Solution : The dimension of angle is 1 i.e. angle is a dimensionless quantity.
∴ [bx] = 1

⇒ [b] =

=
0 0
∴ [b] = M L–1T

Final Answer The correct option is (2)

20) Explanation :- A bird moves from one position to another then vel. vector has to be find
Concept :- position and displacement vector.

Solution :- vector =

unit vector =

=
Final answer :-
21)
for A T cos 45 = ma
for B mg – T cos 45 = ma

22)

a = g cot 53°

23)

100 = Ma

&T=

24)

Explain question : A lift is fulling down word with constant retardation observer inside lift
observers the time period which is given and retardation of lift has to be calculated.
Concept : This question is based on Dynamics of circular motion.
Solution :-

From FBD : Tcosθ = mg + ma

Tsinθ = mω2R =

tanθ =

⇒ 10h = 10 + a
a = 10h – 10 = 20 –10
a =10m/s2

Final answer :- a = 10m/s2

25) m/s
t = 2 sec

CHEMISTRY

26)

Ans. (B)
B is the correct answer

27)

Ans. (C)
C is the correct answer

28) Question Explanation:


Question is asking to choose molecule which does not exist.

Concept:
This question is based on Steric Hindrance.

Solution:
The anion PI6−​ does not exist because the large size of the iodine atoms causes too much steric
repulsion around the relatively small central phosphorus atom, making the octahedral
arrangement unstable.

Final Answer:
The correct option is (2)

29) Question Explanation:


Determining the charge (n) on a cyclic silicate anion.

Concept: Structure of Silicates.

Solution:
In cyclic silicates, each SiO4​ tetrahedron shares two oxygen atoms with its neighbors. The
general formula is . For the given anion [Si3O9]n– , we have m = 3 . The charge 'n' is
therefore 2m = 2 × 3 = 6.
Final Answer: The correct option is (3).

30) Question Explanation:


About the strongest π-bond is given options.

Concept:
This question is based on bond strength ∝ bond length

Solution:
(1) 2px + 2px form σ-bond about x-axis.
(2) 2py + 2py form π-bond (2pπ – 2pπ)
(3) 2py + 3dxy form π-bond (2pπ – 3dπ)
(4) 2pz + 4pz form π-bond (2pπ – 4pπ)
unstable
Length is minimum for 2pπ – 2pπ therefore strength will be maximum.

Final Answer:
The correct option is (2).

31)

Ans. (B)
B is the correct answer

32)

Ans. (B)
B is the correct answer

33) PCl5 → sp3d → s + px + py + pz + dz 2

34)

Ans. (D)
D is the correct answer

35)

5.6 Ltr O2 at STP

moles

no. of atoms

36) mole = mol of CO2


1 mole CO2 → 2 mole 0-atom
.1 mole CO2 → 2 × .1
= .2 mol
= .2 × 6 × 1023
= 1.2 × 1023

37)

Ans. (B)
B is the correct answer

38)

Ans. (A)
A is the correct answer

39)

H2 + ½O2 → H2O
2g 16g → 18g
For 18 gm mixture → 18 gm H2O is produced
For 90g mixture → 90g H2O is produced (100%) yield
If yield is 50% then 45 gm H2O is produced

40)

Ans. (B)
B is the correct answer

41)

Ans. (B)
B is the correct answer

42) X Y and Z → 3rd period


Oxides basic amphoteric acidic
Along the period, basicity of oxides decreases and acidity increases (atomic number of atom
also increases)
∴ X<Y<Z (acidic character)
X<Y<Z (atomic number)

43)

Ans. (A)
A is the correct answer
44) CaO + CO2 → CaCO3

CaO is L.R.
1 mole CaO → 1 mole CaCO3
0.1 → 0.1 mole CaCO3
Mass = Mole × M. wt.
= 0.1 × 100 = 10 gm

45)

2A + 3B → 4C + D
5 mole 8 mole
LR

⇒ 2.5 (Limiting reagent)

⇒ 2.66

× 4 = nC = 10 mole


⇒ 2.5 mole

46)

0.2 Kg = 200g = =5
5-2=3

47)

48) Hybridisatoin is sp3 so total orbital taking part is 4.

49) CuSO4.5H2O exist as [Cu(H2O)4]SO4.H2O


∴ Four water molecule directly coordinated to Cu2⊕.

50) s + px, px + py, py + pz, px + pz can not form any type of bond along y-axis.

MATHEMATICS
51) Solution:
Tn = (3n – 2)·(3n + 1)·(3n + 4)
using vn method sum.

= [(3n – 2) (3n + 1) (3n + 4) (3n + 7) + 56]

= [(9n2 – 3n – 2) (9n2 + 33n + 28) + 56]

= [81n4 + 270n3 + 135n2 – 150n] = [27n4 + 90n3 + 45n2 – 50n]

Final Answer: Option (3) 112

52)

Ans. (C)
C is the correct answer

53) tn = Sn – Sn–1

tn =

tn = =2 =2

54)

First common term = 23


LCM (4, 7) = 28
So, required A.P :
23, 51, .......
and last term can not be greater than 407.
So, 23 + (n – 1)28 ≤ 407
(n – 1)28 ≤ 384

n = 14
Hence, largest common term
⇒ 23 + (14 – 1)28 ⇒ 387

55) ∵ a, b, c are in A.P.


∴ 2b = a + c
(a + 2b – c) (2b + c – a) (c + a – b)
∴ (2a)(2c)(b) = 4abc
k=4

56)

57)

Ans. (A)
A is the correct answer

58) squaring both sides,


=8+5+2 ⇒ a=–4

59) 2x.3x+4 = 7x
Taking log on both sides, we get
loge2x + loge3x+4 = loge7x
⇒ xloge2 + (x + 4)loge3 = xloge7
⇒ xloge2 + xloge3 – xloge7 = –4loge3
⇒ xloge6 – xloge7 = –4loge3

⇒x=

60) log2 log4 log5x < 0


⇒ 0 < log4 log5x < 1
1 < log5x < 4 ⇒ 5 < x < 625

61)

logabca + logabcb + logabcc = logabc(abc) = 1

62) Solution :
Given : p + q = 2 and .

Consider






∴ as p and q be two positive numbers
∴ Required equation : whose p and q are roots

Final Answer : Option (4)

63) Solution :
2x2 – 8x + k = 0

f (1) . f (2) < 0 & f (2) . f (3) < 0


(k – 6)(k – 8) < 0 & (k – 8)(k – 6) < 0
k ∈ (6, 8) k ∈ (6, 8)
integral value of k is 7
number of integral values of k is 1
Final Answer : Option (3)

64) and

and

or

or

So quadratic equation is
5x2 – 16x + 7 = 0

65)

sin α + cos α = and sin α cos α


(sin α + cos α) = sin2α + cos2α + 2sin α cos α
2

or b2 = a2 + 2ca
or a2 – b2 + 2ac = 0

66)

f(x) can be written as


f(x) = (x2–3x + 2) g(x) + ax + b
for x = 1, f(1) = (12 – 3 + 2) g(1) = a + b
⇒a+b=4 ....(1)
2
for x = 2, f(2) = (2 – 3 × 2 + 2) g(2) + 2a + b
⇒ 2a + b = 7 ....(2)
from (1) and (2)
a = 3 and b = 1

67)

cosec θ =

∴ sin θ =

68) Dividing cosq gives , put tan θ =

69)

Since arc length is same


∴ ratio of radius is

70) Let ratio of roots be m : n, so that roots are


αm, αn

∴ (m + n)α = – , mnα2 =

Similarly, roots of px2 + 2qx + r = 0 are in ratio m : n, then ∴

71)
& n(A ∪ B) = n(A) + n(B) – n(A ∩ B)
= 25 + 15 – 10 = 30
72)

A = {1, 2, 3, 4, 5}
B = {3, 5, 7} U ={1, 2, 3, 4, 5, 6, 7, 8, 9, 10}
C = {5, 10} A ∪ B ∪ C = {1, 2, 3, 4, 5, 7,10}
n(Ac ∩ Bc ∩ Cc) = n(U) – n(A ∪ B ∪ C)
= 10 – 7 = 3

73) G.E = [sec A + (tan A – 1)][sec A – (tan A – 1)] = sec2A – (tan2 A – 2tan A + 1)
= (sec2 A – tan2 A) + 2tan A – 1 = 2 tan A

74)

Ans. (17.00)
(17.00) is the correct answer

75)

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