19-07-2026

2302CJA101033260001 JM

PART-1 : PHYSICS

SECTION-I

1) A bead can slide on a smooth straight wire and a particle of mass m attached to the bead by a
light string of length ℓ. The particle is held in contact with the wire and with the string taut and is
then let fall. If the bead has mass m then when the string makes an angle θ with the wire, the bead

will have slipped a distance :

(A) ℓ(1 – cos θ)

(B) (ℓ/2) (1 – cos θ)
(C) (ℓ/3) (1 – cos θ)
(D) (ℓ/6) (1 – cos θ)

2) Six rods of the same mass m and length ℓ are arrange as shown in figure. Calculate the

coordinate of the centre of mass of the system:-

(A)

(B)

(C)

(D)

3) A 640-N hunter gets a rope around a 3200 N polar bear. They are stationary, 30m apart, on
frictionless level ice. When the hunter pulls the polar bear to meet him, the polar bear will move:

(A) 25 m
(B) 15 m
(C) 20 m
(D) 5 m

4) Lower surface of a plank is rough and lying at rest on a rough horizontal surface. Upper surface of
the plank is smooth and has a smooth hemisphere placed over it through a light string as shown in
the figure. After the string is burnt, trajectory of centre of mass of the sphere is :

(A) a circle
(B) an ellipse
(C) a straight line
(D) a parabola

5)

A particle of mass m, initially at rest is acted upon by a variable force F for a brief interval of time T.
It begins to move with a velocity u after the force stops acting.

F is shown in the graph as a function of time. The curve is a ellipse. Select correct option.

(A)

(B)

(C)

(D)

6) A bullet of mass 10 gm moving with a horizontal velocity 100m/s passes through a wooden block
of mass 100 gm. The block is resting on a smooth horizontal floor. After passing through the block
the velocity of the bullet is 10m/s. The velocity of the emerging bullet with respect to the block is :-

(A) 10 m/s
(B) 9 m/s
(C) 1 m/s
(D) 5 m/s

7)

Three particles each of 1kg mass are placed at corners of a right angled triangle AOB, ‘O’ being the
origin of coordinate system (OA and OB along the x-direction and +ve y-direction). If OA = OB =1m,
the position vector of centre of mass (in metres) is:
(A)

(B)

(C)

(D)

8) A fan and a sail are mounted vertically on a cart that is initially at rest on a horizontal table as
shown in the diagram. When the fan is turned on, an air stream is blown towards the right and is
incident on the sail. The cart is free to move with negligible resistance forces. After the fan has been

turned on the cart will

(A) move to the right and then to the left

(B) remain at rest
(C) move towards the right
(D) move towards the left

9) A man of mass ‘m’ is standing in a lift of the same mass ‘m’ which is balanced on a pulley by a
block of mass 2m. If the man jumps suddenly with a velocity V0 upwards with respect to ground, then

the speed of the man relative to lift just after he jumps would be :

(A)

(B) V0

(C)

(D) Zero

10) A uniform rectangular thin sheet ABCD of mass M has length a and breadth b, as shown in the
figure. If the shaded portion HBGO is cut-off, the coordinates of the centre of mass of the remaining
portion will be :-

(A)

(B)

(C)

(D)

11) Two blocks of mass 3 kg and 6 kg respectively are placed on a smooth horizontal surface. They
are connected by a light spring of force constant k = 200 N/m. Initially the spring is unstretched.
The indicated velocities are imparted to the blocks. Find the maximum extension of the spring.

(A) 30 cm
(B) 10 cm
(C)
(D) 15 cm

12) For shown situation find the maximum elongation in the spring. Neglect friction everywhere.
Initially, the blocks are at rest and spring is unstretched.

(A)

(B)

(C)

(D)

13) A uniform rod of length and mass m is allowed to rotate in a horizontal plane about a vertical
axis passing through one of its ends with an angular velocity . Then the tension in the rod in
terms of distance x measured from the axis of rotation is :

(A)

(B)

(C)

(D)

14) A particle moves in x – y plane under the influence of a force such that its linear momentum
is . If k is constant, the angle between and will be.

(A)

(B)

(C)

(D)

15) For shown situation the acceleration of block is represented by. (Here t is time in second) (g =
10ms–2)

(A)

(B)
(C)

(D) None of these

16) A block is placed on a rough plank moving with velocity and velocity of block relative to plank

is , find unit vector in direction of kinetic friction force acting on the block :-

(A)

(B)

(C)

(D)

17) Two forces 50 N and F are acting on a block of mass 3 kg as shown in the figure. The block is
having acceleration of 10m/s2. Find friction force acting on the block :-

(A) 5 N
(B) 10 N
(C) 0 N
(D) None of these

18) A block of mass m is placed on rough horizontal floor. Coefficient of friction between block and
floor is µ & force F making an angle θ with horizontal is applied as shown in diagram & block is
accelerating towards right. Then its acceleration will be (F < mg cosec θ and acceleration due to

gravity is g):-
(A)

(B)

(C)

(D)

19) An agent applies force of constant magnitude F0 always in the tangential direction as shown in
the figure. Find the speed of the bob when string becomes horizontal, assuming that it is at rest at

its lowest point :-

(A)

(B)

(C)

(D)

20) A simple pendulum is released from rest with the string in the horizontal position. The vertical
component of the velocity of the bob becomes maximum when the string makes an angle θ with the
vertical. The angle θ is equal to:-

(A)

cos–1
(B)

(C)
sin–1

(D)

SECTION-II

1)

A uniform thin metal plate of mass 10 kg with dimensions is shown. The ratio of x and y coordinates

of center of mass of plate in . The value of n is ___________.

2) An inclined plane is bent in such a way that the vertical cross-section is given by where y is
in vertical and x in horizontal direction they are in meters. If the upper surface of this curved plane
is rough with coefficient of friction µ = 0.5, the maximum height in cm at which a stationary block
will not slip downward is ________ cm.

3) A small frictionless block slides with velocity on the horizontal surface as shown in the

figure. The block leaves the surface at point C. The angle then find x :

4) Two points of a rod move with velocities 3 v & v perpendicular to the rod and in the same

direction, separated by a distance 'r'. Then the angular velocity of the rod is x × . Find x.

5) A block of mass m = 20 kg is kept at a distance R = 1m from central axis of rotation of a round

turn table (A table whose surface can rotate about central axis). Table starts from rest and rotates
with constant angular acceleration, α = 3 rad/sec2. The friction coefficient between block and table

is μ = 0.5. At time t = sec from starting of motion (i.e. t = 0 sec) the block is just about to slip.

Find the value of x.

PART-2 : CHEMISTRY

SECTION-I

1) Which of the following would result in the formation of strongest π-bond if the molecular axis is x-
axis ?

(A) 2px + 2px

(B) 2py + 2py
(C) 2py + 3dxy
(D) 2pz + 4pz

2) Bonds present in N2O5(Nitrogen pentaoxide) are :-

(A) Only ionic

(B) Only covalent
(C) Covalent and co-ordinate
(D) Covalent and ionic

3) Which of the following order is incorrect ?

(A) Ionic character : MCl<MCl2<MCl3

(B) Polarisibility : F–<Cl–<Br–<I–
(C) Polarising power : Na+< Mg+2<Al+3
(D) Covalent character : LiF<LiCl<LiBr<LiI

4) Give the correct order of initials T or F for following statements. Use T if statement is true and F
if it is false :
(a) The order of repulsion between different pair of electrons is :
lp – lp > lp – bp > bp – bp
(b) In general, as the number of lone pair of electrons on central atom increases, value of bond angle
from normal bond angle also increases
(c) The number of lone pair of O in H2O is 2 while on N in NH3 is 1
(d) The structures of xenon fluorides and xenon oxofluorides could not be explained on the basis of
VSEPR theory

(A) TTTF
(B) TFTF
(C) TFTT
(D) TFFF

5) The correct order of increasing s-character (in percentage) in the hybrid orbitals of following
molecule/ion is :-
(I) (II) XeF4 (III)
(IV) NCl3 (V) BeCl2(g)

(A) II < III < IV < I < V

(B) II < IV < III < V < I
(C) III < II < I < V < IV
(D) II < IV < III < I < V

6)

The correct codes for stability of oxidation states for given cations are :-
(A) Pb2+ > Pb4+, Tℓ+ < Tℓ3+
(B) Bi3+ < Sb3+, Sn2+ < Sn4+
(C) Pb2+ > Pb4+ , Bi3+ > Bi5+
(D) Tl3+ < Ιn3+, Sn2+ > Sn4+

(E) Sn2+ < Pb2+, Sn4+ > Pb4+ (F) Sn2+ < Pb2+, Sn4+ < Pb4+
(A) E and F
(B) A, C and F
(C) C and E
(D) B and D

7) 0.1 M solution of KMnO4 (in acidic medium) may oxidise (having same volume)

(A)
(B)
(C)
(D)

8) Hydrazine reacts with KIO3 in presence of HCl as;

N2H4 + + 2H+ + Cl–
→ ICl + N2 + 3H2O
The equivalent masses of N2H4 and KIO3 respectively are : (K = 39, I = 127) :-

(A) 8,87
(B) 8,35.6
(C) 16,53.5
(D) 8,53.5

9) In the redox reaction

xMnO + yPbO2 + zHNO3 → HMnO4 + Pb(NO3)2 + H2O

(A) x = 2, y = 5, z = 10
(B) x = 2, y = 7, z = 8
(C) x = 2, y = 5, z = 8
(D) x = 2, y = 5, z = 5

10) In an acidic solution, I– changes to I2. How many grams of I2 is produced if in the same
process, 1.5 × 1022 electrons are used upto reduce H3AsO4 to H3AsO3 ? (I = 127)

(A) 1.6 g
(B) 6.4 g
(C) 4.8 g
(D) 3.2 g

11) in basic medium values of P, S in balanced equation :-

(A) 1,4
(B) 4,1
(C) 7,4
(D) 4,7

12) If x mole of FeSO4 require y mole of KMnO4 for complete oxidation in acidic medium then how
many mole of KMnO4 will completely oxidise x mole of FeC2O4 in acidic medium :-

(A) y

(B)

(C) 3y

(D)

13) The equilibrium constant for the reaction

N2(g) + O2(g) 2NO(g) is 4 × 10–4 at 200 K. In presence of a catalyst, equilibrium is attained ten
times faster. Therefore, the equilibrium constant in presence of the catalyst at 200 K is :-

(A) 40 × 10–4
(B) 4 × 10–4
(C) 4 × 10–3
(D) difficult to compute without more data

14) For which of the following reaction is product formation favoured by low pressure and low
temperature?

(A) CO2(g)+C(s) 2CO(g); ΔH° = 172.5 kJ

(B) CO(g)+2H2(g) CH3OH(l) ; ΔH° = –21.7 kJ
(C) 2O3(g) 3O2(g); ΔH° = –285 kJ
(D) H2(g) + F2(g) 2HF(g); ΔH° = 541 kJ

15) N2(g) + 3H2(g) 2NH3(g)

Initially the molar ratio of N2 and H2 was 1 : 3. At equilibrium 50% of each reactant has reacted. If
the equilibrium pressure is P then the partial pressure of NH3 at equilibrium is :-

(A)

(B)

(C)

(D)

16) In a reversible reaction , the initial concentration of A and B are a and b and the
equilibrium concentration are (a – x) and (b + x) respectively. Express "x" in terms of k1, k2, a and b :
(A)

(B)

(C)

(D)

17) Find the value of KP for reaction

2SO2(g) + O2 (g) ⇌ 2SO3(g)
if the degree of dissociation of SO3 is a and equilibrium pressure is PT.

(A)

(B)

(C)

(D)

18) For the following reaction :

A+2B C+3D; if the partial pressure of all the four substances A,B,C and D at equilibrium are 0.20,
0.10, 0.30 and 0.50 respectively, then calculate the equilibrium constant :-

(A) 18.75
(B) 5.3
(C) 11.25
(D) None of these

19) For the reaction NH4HS(s) in a closed flask, the equilibrium pressure is P atm
.
The standard free energy change ( ) of the reaction would be :-

(A) –RT lnp

(B) –2.303 RT(logP – log2)
(C) –2RT (lnP – ln2)
(D) –2RT lnP

20) 1 mole of CO2 dissociate in 1 Liter container as follows :-

⇌ CO(g) +
The equilibrium constant KP is given by :-
(when α <<1) (P ⇒ Total pressure at equilibrium)
(A)

(B)

(C)

(D)

SECTION-II

1) If s and p-orbital mixing is operative for all species given, then how many following species is/are
paramagnetic in nature?

2) Consider y-axis as internuclear axis, how many of the following will lead to π-bond formation ?
(a) py + py (b) px + px
(c) pz + pz (d) dxy + dxy
(e) dyz + dyz (f) px + dxy

3) In an experiment, 50 mL of 0.1 M solution of a metal salt reacted with 25 mL of 0.1 M solution of

sodium sulphite.
The half equation for the oxidation of sulphite ion is

If the oxidation number of metal in the salt was 3, what would be the new oxidation number of metal
?

4) 100 mL of NaHC2O4 requires 50 mL of 0.1 M KMnO4 solution in acidic medium for its complete
oxidation. Volume of 0.1 M NaOH required by 100 mL of same NaHC2O4 for its complete
neutralization is (in ml)

5) Total number of paramagnetic species in which unpaired electron(s) is/are present in π* M.O.
O2+; O2– ; O2; N2– ; N2+ ; N22–; B2

PART-3 : MATHEMATICS

SECTION-I

1) The value of :-

sin sin sin sin sin sin sin is equal to

(A)

(B)

(C)

(D)

2) If cos θ = , then tan2 is equal to :-

(A) tan2

(B) cos2

(C) sin2

(D)
cosec2

3) If sec θ = and θ ∈ . Then value of Expression is –

(A) 1
(B) –1
(C) 0

(D)

4) If 2 tan2x – 5 sec x is equal to 1 for exactly 7 distinct values of , n ∈ N, then the

greatest value of n is :-

(A) 6
(B) 12
(C) 13
(D) 15

5) If 0 x 3π, 0 y 3π and cos x ⋅ sin y = 1, then the possible number of values of the ordered
pair (x, y) is :-
(A) 6
(B) 12
(C) 8
(D) 15

6) If one root of the equation is square of the other, then the value of b3 + ac2 + a2c
is :

(A) –3abc
(B) 2abc
(C) 3abc
(D) –2abc

7) Let α and β be the roots of the equation . If , , then which one of

the following statements is not true?

(A)
(B)
(C) p3 = p5 – p4
(D)

8) ax2 + bx + c = 0 has real and distinct roots

α and β(β > α). Further a > 0, b < 0 and c < 0, then

(A) 0 < β < |α|

(B) 0 < |α| < β
(C) α + β < 0

(D)
|α|+|β|=

9) The equation whose roots are the squares of the roots of the equation is -

(A)

(B)

(C)

(D)

10) If and have a common factor then 'a' is equal to

(A) 24
(B) 1
(C) 2
(D) 12
11) The expression lies in the interval ; (x ∈ R)

(A) [0, –1]

(B)
(C) [0, 1)
(D) none of these

12) Find the relation R an the set N × N defined by (a, b) R(c, d) ⇒ a + d = b + c ∀ (a, b), (c, d) ∈ N
×N

(A) Only reflexive

(B) Only symmetry
(C) Both A and B
(D) Equivalence

13) If , then fofof(x) is equal to

(A)

(B)

(C)

(D) None of these

14) In the set A = {1, 2, 3, 4, 5}, a relation R is defined by R = {(x, y) : x, y ∈ A and x < y}. Then R
is-

(A) Reflexive
(B) Symmetric
(C) Transitive
(D) None of these

15)

Let ƒ : R → R, be a function defined by , then ƒ(x) is -

(A) injective but not surjective

(B) injective and surjective
(C) neither injective nor surjective
(D) surjective but not injective

16) Let ƒ be a functional equation satisfy ƒ(x + ƒ(y)) = ƒ(x) + y ∀ x, y ∈ R. If ƒ(1) = 2, then value of ƒ(4)
is equal to -

(A) 4
(B) 5
(C) 8
(D) 9

17) Let f(x) =

then fundamental period of the function f(x) is- (where [.] & {.}
denotes greatest integer function & fractional part function respectively)

(A) 1

(B)

(C)

(D) aperiodic

18) If f(x) be a polynomial function satisfying f(x).f = f(x) + f and f(4) = 65 then value of f(6)
is:

(A) 217
(B) 215
(C) 216
(D) 65

19) If g : [–2, 2] → R, where g(x) = x3 + tanx + is an odd function, then the value of
parameter P is where [.] is G.I.F.

(A) P ∈ [0, 1)
(B) P ∈ [1, 5]
(C) P ∈ (5, ∞)
(D) P ∈ (0, 5]

20) If equation sin4x + cos4x = k has a solution then sum of maximum and minimum possible value of
k is

(A) 1

(B)

(C)
(D)

SECTION-II

1) The minimum value of the function f (x) = (3sin x – 4 cos x – 10)(3 sin x + 4 cos x – 10), is:

2) If equation = 1 has two roots equal in magnitude and opposite in sign, then the value
of a + b is -

3) The number of integral values of m for which the quadratic expression.

(1 + 2m)x2 – 2(1 + 3m)x + 4(1 + m), x ∈ R, is always positive, is :

4) The maximum value of 27cos3x 81sin3x is

5) If sin x + sin2x = 1; then

cos8x + 2 cos6x + cos4x =
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B A D C C C A B C D A A A A B B C C A B

SECTION-II

Q. 21 22 23 24 25
A. 15 25 6 8 2

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B C A B A C A D A D B C B C A A B A C A

SECTION-II

Q. 46 47 48 49 50
A. 2 5 2 125 5

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D A B D A C D B C A C D C C B B C A C D

SECTION-II

Q. 71 72 73 74 75
A. 49 0 7 243 1
 SOLUTIONS

PART-1 : PHYSICS

1)
mx – my = 0
x=y
also x + y = ℓ (1 – cos θ)

2)

By symmetry xCM =

3)

m1s1 – m2s2 = 0
640 × s1 – 3200 s2 = 0 ... (i)
s2 + s1 = 30 ... (ii)
on solving
s2 = 5m

4)

On sphere there is no external force in horizontal direction

&
COM will fall vertically downward
Path of COM Straight line & vertical downwards

5) Area = ΔP
6) Use momentum conservztion for block + bullet system

7)

8) Impulse given by fan to sail through air = Impulse given by air to fan.
Net impulse on system = zero
system remains at rest.

9) Velocity of lift =

10)

x=

= =

y=

11)
12)

At the instant of maximum extension, the relative velocity of one block w.r.t another block
must be zero.

13)
Let cut the rod at distance x
mass of (L – x) part

Com of (L – x) part

14)
15) Block moves of
;
Just after start its acceleration

a=

After that a =

⇒ Slope of a–t curve

16) friction will act opposite to the relative velocity.

17)

Since normal force is zero, thus friction force will also be zero.

18)

N = mg – F sinθ

a= (cos θ + μ sinθ) – μg

19) Force is always tangential implies

{r → length of path}

0
W=F

Wnet =
20)

for maximum vy

⇒ tan θ = 2

21)

22) Explain the question: Find the maximum vertical height in cm where a block remains
stationary on a curved surface .

Concept: Static equilibrium ( )

Solution:
 Final Answer: The maximum height is .

23)
–ΔU = ΔK

mg r (1 – cos θ) = ....(1)

mg cos θ = ....(2)

24) vrel. being the velocity of one point w.r.t. other.

and ‘r’ being the distance between them.

25)
at = 3
ac = 4
= ω2R
ω = 2 = 0 + 3t
t = 2/3

PART-2 : CHEMISTRY

26) Explain Question : We have to find strongest π - bond formation if molecular axis is x -
axis
 Concept : Based on strangth of covalent bond
Solution :
2px + 2px will form σ-bond
2py + 2py and 2px + 3dxy will form
π-bond but 2pπ - 2pπ bond is stronger
than 2pπ - 3dπ.
Final answer :2

27)
It has covalent and co-ordinate bonds.

28) Question Explanation: Identify the incorrect order regarding covalent character.

Concept: Fajan's Rule and Cation Charge.

Solution: Higher charge on the cation increases its polarizing power and thus increases the
covalent character of the compound. Therefore, covalent character should increase
from NaCl to AlCl3.

A. Trend 1: Covalent character NaCl > MgCl2​ > AlCl3​ is incorrect.

B. Correct Trend: AlCl3​ > MgCl2​ > NaCl.

Final Answer: Option (1)

29) The structure of xenon fluorides and xenon oxofluorides could be explained on the basis of
VSEPR theory.

30) Question Explanation:

Find the increasing order of s-character in hybrid orbitals by determining the hybridization of
each given molecule or ion.

Concept: Hybridization determines percentage s-character.

Solution:
The percentage s-character is calculated using the formula:

1. (II) XeF4 : Steric number = 4 bonds +2 lone pairs . % s-character

2. (III) : Steric number = 2 bonds +3 lone pairs . % s-character

3. (IV) NCl3 : Steric number = 3 bonds +1 lone pair . % s-character

4. (I) : Steric number = 3 sigma bonds +0 lone pairs . % s-character

5. (V) BeCl2(g) : Steric number = 2 bonds +0 lone pairs = 2(sp). % s-character

Increasing order: II < III < IV < I < V

Final Answer: Option(A)

31) Chance of inert pair effect increases down the group.

32) Question Explanation:

Choose correct option.

Concept:
This question is based on Equivalent concept.

Solution:

→ Mn+2
eq. of KMnO4 = M × V × n.f = 0.1 × v × 5
= 0.5 V
(1) → CO2
eq. of = 0.25 × 2 × V = 0.5 V
+2 +3
(2) Fe → Fe
eq. of Fe+2 = 0.8 × 1 × V = 0.8 V
(3) FeC2O4 → Fe+3 + CO2
n.f.: 3
eq. of FeC2O4 = 3 × 0.1 × V = 0.3 V
(4) → Cr+3
n.f. = 6
eq. of = 0.6 × 6 × V = 3.6 V

Final Answer:
The correct option is (A).

33)

34) Question Explanation: Balancing a redox reaction using the oxidation number method.

Concept: Oxidation Number Method (Redox Reactions)

Solution: The reaction involves the oxidation of Mn and the reduction of Pb. We calculate the
 change in oxidation states, equalize the electrons gained and lost by cross-multiplying, and
then balance the remaining atoms (H and O) by inspection.
1. Identify Oxidation State changes:

A. Mn in MnO is +2 ; in HMnO4 it is +7. (Change = +5)

B. Pb in PbO2 is +4 ; in Pb(NO3)2 it is +2 . (Change = –2)

2. Equalize Electrons:

A. Multiply Mn species by 2 and Pb species by 5.

B.

3. Balance Nitrate (NO3–) and Hydrogens:

A. There are 10 NO3 groups on the right, so we need 10 HNO3 on the left (z = 10).
B. Check H: 10 on left → 2 (in HMnO4) + 8 (in 4 H2O) on right.

Final Answer: Option (A)

35) 2e– + H3AsO4 —→ H3AsO3

+5 —→ +3
–
2I —→ I2 + 2e–
________________________

Mass of I2 =

⇒ × 254 = 3.2 gm

36)
(2) 8
1 4
4 Zn + (1) P=4 S=1

37) n-factor for FeSO4 ⇒ Fe (+2 to + 3) × 1 = 1

n -factor for FeC2O4 ⇒
Fe(+2 to + 3) × 1 = 1e– loss
C(+3 to + 4) × 2 = 2e– loss = 3
Equivalent of FeSO4 = Equivalent of KMnO4
⇒ x mol × 1 = y mol × 5 .... (i)
Similarly,
Equivalent of FeC2O4 = Equivalent of KMnO4
⇒ x mol × 3 = (mol of KMnO4 = ?) × 5 ...(ii)
∴ Mol of KMnO4 required = 3y

38)

Question Explanation : Determining the effect of a catalyst on the value of the equilibrium
constant.

Concept : Chemical Equilibrium and Catalysis

Solution : A catalyst increases the rate of both the forward and reverse reactions equally by
lowering the activation energy. However, it does not alter the position of equilibrium or the
value of the equilibrium constant (Keq).
The equilibrium constant changes only with temperature. Since the temperature remains
constant at 200 K, Keq remains unchanged.
Final Answer : Option (B)

39) Explanation:
Product formation favoured b low pressure and low temperature.
Concept:
Le-Chaelier Prrincila
Solution:
1. For product formation high temp favour
2. , lowtemp, high press
3. , low temp, low press
4. , high temp.
Final Answer: Option: (C)

40) N2(g) + 3H2(g) 2NH3(g)

initially 1 3 0
at eqn (1–0.5) (3–1.5) 2×0.5 = 1 mole
∴ Total moles at equilibrium = 0.5 + 1.5 + 1 = 3

Partial pressure of NH3 =

41) Keq = = =
K1a – K1x = K2b + K2x
K1a – K2b = (K1 + K2)x

x=

42) 2SO3(g) ⇌ 2SO2(g) + O2 (g)

1–α α α

then KP for reaction

2SO2(g) + O2 (g) ⇌ 2SO3(g)
43) KP =

44) Question Explanation: Calculating standard free energy change using equilibrium
pressure.
Concept: Gibbs Free Energy and Equilibrium Constant (Kp)
Solution: In the decomposition of solid NH4HS, the total equilibrium pressure P is the sum of
the partial pressures of the gaseous products. Since the stoichiometry is 1:1, the partial
pressure of each gas is P/2. We find Kp by multiplying these partial pressures and then
substitute it into the standard free energy equation
∵ = –2.303 RT log KP
or, = – RT lnKP
NH4HS(s) NH3(g) + H2S(g)
P/2 P/2
KP =

= –2RT
Final Answer: Option (3) –2RT (lnP – ln2)

45) ⇌ +
t=0 1 mole 0 0

t = teq (1– α) α

∵ 1 >> α ⇒ (1–α)

KC =

46) Formula based.

47) py + py σ-bond
All remaining overlapping are -bond.

48) M+3 → M+n (Reduction)

n-factor = (3 – n) e– gain
(oxidation)
 n-factor = (+ 4 to + 6)
= 2e– loss
Total loss = Total gain
0.1 M × (3 – n) × 50 ml = 0.1 M × (2) × 25 ml
3–n=1
n=2

49)

50) : (σ1s)2 (σ*1s)2 (σ2s)2(σ*2s)2 σ22pz (π22px = π22py) π*12px

: (σ1s)2 (σ*1s)2 (σ2s)2(σ*2s)2 σ22pz (π22px = π22py) (π*22px = π*12py)O2 : (σ1s)2 (σ*1s)2 (σ2s)2(σ*2s)2 σ22pz
(π22px = π22py) (π*12px = π*12py)
: (σ1s)2 (σ*1s)2 (σ2s)2(σ*2s)2 (π22px = π22py) σ22pz π*12px : (σ1s)2 (σ*1s)2 (σ2s)2(σ*2s)2 (π22px =
π22py) σ12pz

B2 : (σ1s)2 (σ*1s)2 (σ2s)2(σ*2s)2 (π12px = π12py)

PART-3 : MATHEMATICS

51) sin

= sin ×1

= =

52)

tan2 = =

= = tan2
53) ∵ sec θ =

∴ cos θ =
so tan θ = – 1
cosec θ = –
cot θ = – 1

54) 2tan2x – 5sec x = 1

2 (sec2x – 1) – 5secx = 1
2sec2x – 5secx – 3 = 1

∴ cosx =

55) max cosθ = 1. So, cosx ⋅ siny = 1

⇒ cos x = 1, sin y = 1 or cos x = –1, sin y = –1
cos x = 1, sin y = 1 ⇒ x = 0, 2π

and y = (from the equation)

cos x = 1, sin y = –1

⇒ x = π, 3π and y = (from the equation)

∴ the required number of ordered pair
=2×2+2×1=6

56) ax2 + bx + c = 0
α, α2
α + α2 = – b/a

α3 =

(α + α2)3 = –

a→α=–
a2c+ac2 – 3abc = – b3
b3 + ac2 + a2c = 3abc

57) Explain Question : α and β are roots of given equation. We have to solve given options.
Concept : Newton's formula
Solution :
α + β = 1, αβ = –1

⇒
&
⇒
⇒
⇒
⇒
⇒
⇒
Final Answer : (D)

58) Solution:
Let α and β are zeros of ax2 + bx + c = 0
since β > α, a > 0, b < 0 and c < 0

then α + β = is positive; α β = is negative

so one root is negative and other is positive
α is negative, β is positive and |α| < β
so 0 < |α| < β

Final Answer: option (2)

59) Solution :
Let α, β are roots of given equation ax2 + bx + c = 0

So, the equation whose are α2 and β2 is

⇒ x2 – (α2 + β2)x + α2β2 = 0
⇒ x2 – [(α + β)2 – 2αβ]x + α2β2 = 0

⇒ =0
2 2 2 2
⇒ a x – (b – 2ac)x + c = 0
Final Answer : Option (3)

60)

Solution:
x2 – 11x + a and x2 – 14x + 2a
Let x – α be a common factor so
α2 – 11α + a = 0
α2 – 14α + 2a = 0

α=

putting the value of α in any of the equation =0

a2 – 24a = 0
a = 24

Final Answer: Option (1)

61) Solution:

Let
y(x2 + 2x + 7) = x2 + 2x + 1
(y – 1)x2 + 2(y – 1)x + (7y – 1) = 0 (y ≠ 1)
For x ∈ R, D ≥ 0
[2(y – 1)]2 – 4(y – 1)(7y – 1) ≥ 0
4(y2 + 1 – 2y) – 4(7y2 – 8y + 1) ≥ 0
–6y2 + 6y ≥ 0
6y(–y + 1) ≥ 0
⇒ y ∈ [0, 1)

Final Answer: option (3)

62) Reflexive : (a, b) ∈ N × N

a+b=b+a
(a, b) R (a, b)
Symmetry : (a, b) R (c, d)
a+d=b+c
c+b=d+a
(c, d) R (a, b)
Transitive : (a, b), (c, d), (e, f) ∈ N × N
(a, b) R (c, d) ⇒ a + d = b + c
(c, d) R (e, f) ⇒ c + f = d + e
a+f= b+e

63)

64) Since x ≮ x, therefore R is not reflexive. Also

x < y does not imply that y < x, So R is not symmetric. Let xRy and yRz. Then, x < y and
y < z ⇒ x < z i.e., xRz. Hence R is transitive.

65)

Given
∵ ƒ(x) is odd degree polynomial
∴ Range = (–∞,∞) hence surjective
also,ƒ'(x) = 1 – x + x2 – x3 + x4 – x5 + x6 > 0 ∀ x ∈ R
hence ƒ(x) is one-one.

66) Put x = y = 1, ƒ(1 + ƒ(1)) = ƒ(1) + 1

ƒ(3) = 3
Put x = 1, y = 3 ƒ(4) = ƒ(1) + 3 = 5

67) Question Explanation : We have to find fundamental period of the function f(x).
Concept : Periodic function
Solution :

Given f(x) =
We know that {x + m} = {x} ; m ∈ I
And [x] ∈ I

f(x) =

f(x) =

So,

fundamental period of the function f(x) =

Final Answer : Option (3)

68) f(x) = (1 ± xn)

69) g(x) is odd function

∴ g(–x) + g(x) = 0

–2 < x < 2
∴ 0 < x2 < 4
 1 < x2 + 1 < 5
∴P>5

70) For solution k lies in range of sin4x + cos4x

71) f(x) = 9 sin2x – 16 cos2x – 10(3 sin x – 4 cos x) – 10(3 sin x + 4 cos x) + 100
= 25 sin2x – 60 sin x + 84
= (5 sinx – 6)2 + 48
∴ f (x)min occurs when sin x = 1
Minimum value = 49

72) Given equation is x2 – 2(a + b)x + 3ab = 0

for given condition, co-efficient of x must be zero
⇒ a+b=0

73) Expression is always positive it

2m + 1 > 0 ⇒ m > –
& D < 0 ⇒ m2 – 6m – 3 < 0
...(iii)
∴ Common interval is

∴ Integral value of m {0,1,2,3,4,5,6}

74)

27cos3x 81sin3x

(As )

75) sinx = 1 – sin2x ⇒ sin2x = cos4x

⇒ 1 – cos2x = cos4x ⇒ cos4x + cos2x = 1
squaring both sides; cos8x + cos4x + 2cos6x = 1