21-06-2026

2302CJA101003260001 JM

PART-1 : PHYSICS

SECTION-I

1)

A particle moves m in South–West direction, 12m in upward direction and then 1m in East
direction. Find the net displacement.

(A) 13 m
(B) 17 m
(C) 14 m
(D) 18 m

2)

The position of a particle is given by y = a + bt + ct3. The initial velocity and acceleration are
respectively :

(A) b,0
(B) –b, 2c
(C) b, 2c
(D) 2c, –4d

3)

Particle is projected with a velocity of m/s. If it have a constant acceleration of

. Then select the correct statement :

(A) Initially speed of particle increases

(B) Initially speed of particle decreases
(C) Speed remain constant throughout the motion but its direction changes.
(D) Speed and direction both remain constant.

4) Position vector of a particle is given by , t is time and r0 and a are constants. The
velocity of particle when it returns to starting point :-

(A)
(B)
(C)
(D)
5) X coordinate of a particle moving along X-axis is given by X = + t cos t2 here t is time
and C is a positive constant. Then its instantaneous velocity will be :-

(A)

(B)

(C)

(D) C – t2 – t sin t2

6) A particle moving along x-axis, its v2 and position graph given in the figure. Initial acceleration of

the object is:-

(A) zero
(B) 6 m/s2
(C) 4 m/s2
(D) 3 m/s2

7)

A car moving with constant acceleration covers two successive kilometers in 30 sec and 20 sec
respectively. The acceleration of car is :-

(A) 5/3 m/s2

(B) 3/5 m/s2
(C) 2/3 m/s2
(D) 5/2 m/s2

8)

A body starts from rest and is uniformly accelerated for 15 s. The distance travelled in the first 5 s is
x1, next 5 s is x2 and the last 5 s is x3. Then x1 : x2 : x3 is the same as

(A) 1 : 2 : 4
(B) 1 : 2 : 5
(C) 1 : 3 : 5
(D) 1 : 3 : 9

9) The velocity–time graph of a linear motion is shown in figure. The displacement from the origin till
8 sec., is (initially particle was at origin) :-

(A) 5 m
(B) 16 m
(C) 8 m
(D) 6 m

10) The x coordinate of an object is given as a function of time by x = 4t2 – 3t3, where x is in meters
and t is in seconds. Its average acceleration over the time interval from t = 0 to t = 2s is

(A) – 4 m/s2
(B) 10 m/s2
(C) – 10 m/s2
(D) – 13 m/s2

11) The acceleration of a particle moving along x-axis is given by a = Be–Ct. Its velocity is zero at t =
0, then terminal velocity (velocity after a long time) is :

(A)

(B)

(C) CB

(D)

12) A particle moves along the positive branch of the curve where , x and y are
measured in meters and t in seconds. At t = 2 s, the velocity of the particle is :

(A)
(B) m/s
(C) m/s
(D) m/s

13) A particle is thrown from a point on an incline plane, with a velocity of 20 m/s at an angle of 60°
with the horizontal, angle of incline plane is 30°. At what time the velocity of the projectile becomes

parallel to the incline plane ?

(A)

(B)

(C)

(D)

14) If R is the horizontal range for θ inclination and h is the maximum height reached by the
projectile, Then maximum range is :

(A)

(B)

(C)

(D)

15) The velocity-time relation of an electron starting from rest and moving along a straight line is
given by v = 3t2 – 27, where v is velocity in m/s and t is time in seconds. Then the distance traversed
by the particle from t = 0 to t = 4 second is:

(A) 42 m
(B) 44 m
(C) 68 m
(D) 64 m

16) A particle starts from rest at t = 0 and moves along a straight line. The acceleration-time graph
of this particle is as shown. Then the corresponding velocity-time graph is best represented by:

(A)
(B)

(C)

(D) None of these

17) Particle is projected upward with velocity 100m/s at an angle of 30° with horizontal. Find the
time when its velocity is perpendicular to the acceleration :-

(A) 10 sec
(B) 5 sec
(C) 20 sec
(D) 10 sec

18) Acceleration–time graph of a particle is as shown in figure. Initially particle was at rest and
moves on straight line with variable acceleration. Find the time at which particle will have maximum

magnitude of velocity.

(A) 4 sec
(B) 8 sec
(C) 16 sec
(D) 35 sec

19) The equation of path of a projectile is y = 12x – x2 then find horizontal range :-

(A) 12.4 m
(B) 21 m
(C) 16 m
(D) 36 m

20) A ball is thrown at an angle of 45° with the horizontal with kinetic energy E. The kinetic energy
at the highest point during the flight is :-

(A) Zero
(B) E/2
(C) E
(D) (2)1/2E

SECTION-II

1) A piece of marble is projected from earth's surface with velocity of 25 m/s. 2 seconds later, it just
clears a wall 5 m high. What is the angle (in degree) of projection with horizontal? (g = 10 m/s2)

2) A bullet looses its 1/8th velocity in crossing a wooden sheet. How many such wooden sheets are
required to bring the bullet at rest? Assume constant retardation.

3) An object is projected up the incline at the angle 37° with incline as shown in figure with an initial
velocity of 20 ms–1. The angle of inclination of inclined with horizontal is also 37°. Find the range (in

m) of particle along inclined surface (g = 10 m/s2)

4) A particles starts from point A with constant speed m/s on a circle of radius R. Find
magnitude of average velocity (in m/s) during its journey from A to D :- (particle moves along abcd)

5) A particle starts from the origin at t = 0 and moves in the X–Y plane with constant acceleration a
in the Y-direction. Its equation of motion is y = bx2. If the x component of its velocity is given by

, then n will be :

PART-2 : CHEMISTRY

SECTION-I
1) If a0 be the radius of first Bohr's orbit of H-atom, then de-Broglie's wavelength of an electron
revolving in 3rd Bohr's orbit will be -

(A) 3πa0
(B) 6πa0
(C) 9πa0
(D) 12πa0

2) The ground state of a hydrogen atom has an energy of -13.6 eV. So the energy of second excited
state of He+ ion ________ is eV.

(A) –3.4
(B) –54.4
(C) –27.2
(D) –6.04

3) Which of the following combination of quantum numbers about last entered electron of Ti is
correct?

(A) n = 4, ℓ = 0, m = 0, ms = +1/2
(B) n = 3, ℓ = 2, m = –2, ms = +1/2
(C) n = 3, ℓ = 0, m = 0, ms = –1/2
(D) n = 3, ℓ = 3, m = –1, ms = +1/2

4) If velocity of an electron in I orbital of H atom is V. What will be the velocity of electron in 3rd orbit
of Li2+ ?

(A) V
(B) V/3
(C) 3V
(D) 9V

5) In a sample of atomic hydrogen, electrons are present in 4th excited state. Then total number of
possible spectral lines when electrons are de-excited to ground state.

(A) 6
(B) 15
(C) 10
(D) 3

6) Only certain transitions are allowed from one energy level to another, in one electron species, the
change in 'ℓ' of an allowed transition is ±1 for example a '3p' electron can move to a 2s orbital but
not to 2p. Thus in a UV series where 'n'final = 1 allowed transition can start from a 'p' orbital (ℓ = 1)
of n = 2 or higher , but not from a s(ℓ = 0) or d (ℓ = 2) of n = 2 or higher. From what orbital do
each of the allowed transition start for the four emission lines in the visible spectrum (nfinal = 2)
(i) 2 p to 2s (iv) 4s → 2p
(ii) 3s to 2p (v) 3p → 2s
(iii) 3d to 2p (vi) 5s → 2s

(A) only (ii), (iii) ,(iv) & (v)

(B) only (i), (ii) ,(iii) & (v)
(C) only (i), (vi) ,(iii) & (iv)
(D) only (i), (iii) ,(iv) & (v)

7)

The uncertainty in the momentum of an electron is 1.0 × 10–5 kg m s–1. The uncertainty of its
position will be
(h = 6.626 × 10–34 kg m2 s–1) -

(A) 1.05 × 10–28 m

(B) 1.05 × 10–26 m
(C) 5.27 × 10–30 m
(D) 5.25 × 10–28 m

8) A particle 'x' moving with a certain velocity has de-Broglie wavelength of 1Å. If particle 'y' has
mass 25% that of 'x' and velocity 75% that of 'x', de-Broglie wavelength of y will be :

(A) 3 Å
(B) 5.33 Å
(C) 6.88 Å
(D) 4.8 Å

9) If proton, electron and α-particle are moving with same kinetic energy then the order of their de-
Broglie's wavelength is

(A) λp > λe > λα

(B) λα > λp > λe
(C) λα < λp < λe
(D) λe = λp < λα

10) At temperature T, the average kinetic energy of any particle is kT- The de Broglie wavelength
follows the order :

(A) Visible photon > Thermal electron > Thermal neutron

(B) Thermal proton > Thermal electron > Visible photon
(C) Visible photon > Thermal neutron > Thermal electron
(D) Thermal proton > Visible photon > Thermal electron

11)

The electrons, identified by quantum number n and ℓ :

 (i) n = 3 ; ℓ = 0
(ii) n = 5 ; ℓ = 2
(iii) n = 2 ; ℓ = 1
(iv) n = 4 ; ℓ = 3
can be placed in order of increasing energy from the lowest to highest as :

(A) (iii) < (i) < (iv) < (ii)

(B) (i) < (iii) < (iv) < (ii)
(C) (ii) < (iii) < (iv) < (i)
(D) (ii) < (iv) < (i) < (iii)

12) For electron in '2s' and '2p' orbitals, the orbital angular momentum values, respectively are :

(A)
and 0

(B)
and
0 and
(C)

0 and
(D)

13) Give the correct order of initials T (true) or F (false) for following statements :-
(I) If an ion has 2 electrons in K shell, 8 electrons in L shell and 6 electrons in M shell, then number
of electrons present in s subshell of that element is 6.
(II) The maximum number of electrons in a subshell is given by 2n2
(III) If electron has magnetic quantum number –1, then it cannot be present in s-orbital.
(IV) Only one radial node is present in 3p orbital.

(A) TTFF
(B) FFTF
(C) TFTT
(D) FFTF

14) Among halogens, the correct order of amount of energy released in electron gain (electron gain
enthalpy) is :

(A) F > Cl < Br < I

(B) F < Cl < Br < I
(C) F < Cl > Br > I
(D) F < Cl < Br > I

15) Which of the following statement is incorrect

(A) Te and I form a anamolous pair in Mendeleev classification

(B) Three quantum numbers are required to specify the orbital of electron in an atom
 Electronegativity in Pauling scale is greater than electronegativity in Allred-Roschow Scale for
(C)
same atom
(D) O–(g) > S–(g) (IE order)

16) If I.E. of Na, Mg and Si are respectively 496, 737 and 786 kJ mol–1. The I. E. of Aℓ in kJ mol–1 is :-

(A) 575
(B) 760
(C) 390
(D) 1120

17) The ionic radii decrease in the order :

(A) Cr6+ > Sc3+ > V5+ > S2– > K+

(B) S2– > K+ > Sc3+ > V5+ > Cr6+
(C) Cr6+ > V5+ > Sc3+ > S2– > K+
(D) K+ > S2– > Sc3+ > V5+ > Cr6+

18) Which of the following represents the correct trend for the mentioned property ?
(A) F > P > S > B – Frist Ionization Energy
(B) Cl > F > S > P – Electron Affinity
(C) K > Al > Mg > B – Metallic character
(D) K2O > Na2O > MgO > Al2O3 – Basic character
Choose the correct answer from the option given below.

(A) A, B and D only

(B) A, B, C and D
(C) A and B only
(D) B and C only

19) The correct order of electronegativity for O, O+ and O– is-

(A) O– > O > O+

(B) O > O+ > O–
(C) O+ > O– > O
(D) O+ > O > O–

20) The number of d-electrons in Fe2+ (Z = 26) is not equal to the number of electrons in which one
of the following?

(A) p-electrons in Cl (Z = 17)

(B) d-electrons in Fe (Z = 26)
(C) p-electrons in Ne (Z = 10)
(D) s-electrons in Mg (Z = 12)

SECTION-II
1) The work function (ϕ) of some metals is listed below. The number of metals which will show
photoelectric effect when light of 500 nm wavelength falls on the metal is :

Metal Li Na K Mg Cu Ag Fe Pt W
ϕ (eV) 2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75

2) The ratio of (E2 – E1) to (E4 – E3) for the hydrogen atom is approximately equal to (Answer neglect
decimal value)

3) The successive ionisation energies of an element are given (in eV) :

IE1 IE2 IE3 IE4 IE5 IE6 IE7 IE8

10.36 22.51 33.61 45.64 70.13 84.95 271.06 316.7

The number of electrons present in outermost p-subshell of this representative element is expected
to be-

4) Find the number of electrons having (n × l + m) = 3 for Kr–atom. ([Link].: Z = 36)

5) I.E and E.A values of an element are 13.0 eV and 3.8 eV respectively. Its electro-negativity on
Pauling scale is____.

PART-3 : MATHEMATICS

SECTION-I

1) Let α and β be the roots of the equation . If , , then which one of

the following statements is not true?

(A)
(B)
(C) p3 = p5 – p4
(D)

2) If and ; then which of the following is correct ?

(A)
(B)
(C) B – A = R – (–2, 5)
(D) A – B = [–1, 2)

3) ax2 + bx + c = 0 has real and distinct roots

α and β(β > α). Further a > 0, b < 0 and c < 0, then

(A) 0 < β < |α|

(B) 0 < |α| < β
(C) α + β < 0

(D)
|α|+|β|=

4) If α, β are the roots of the equation x2 – 2x + 3 = 0, then the equation whose roots are α3 – 3α2 +
5α – 2, β3 – β2 + β + 5 is

(A) x2 – 3x + 2 = 0
(B) x2 – 2x + 5 = 0
(C) x2 + 3x – 10 = 0
(D) x2 – 2x + 3 = 0

5) If α, β & γ are the roots of the equation x3 – x – 1 = 0, then has the value
equal to :

(A) zero
(B) –1
(C) – 7
(D) 1

6) Graph of y = ax2 + bx + c is as shown in the figure then

(A) b and c have the same sign and different than a.

(B) a > 0
(C) D < 0
(D) C < 0

7) Let α and β be the roots of x2 – 6x – 2 = 0, with α > β. If an = αn – βn for n ≥ 1, then the value of

is

(A) 1
(B) 2
(C) 3
(D) 4

8) Let p, q ∈ R. If is a root of the quadratic equation, x2 + px + q = 0, then :

(A) q2 + 4p + 14 = 0
(B) p2 – 4q – 12 = 0
(C) q2 – 4p – 16 = 0
(D) p2 – 4q + 12 = 0

9) If equation ax2 + bx + c = 0, (a, b, c ∈ R, a ≠ 0) and 2x2 + 3x + 4 = 0 have a common root, then a

: b : c equals :

(A) 2 : 3 : 4
(B) 3 : 2 : 1
(C) 1 : 2 : 3
(D) 4 : 3 : 2

10) The expression lies in the interval ; (x ∈ R)-

(A) [0, –1]

(B)
(C) [0, 1)
(D) None of these

11) Roots of the equation a(b–c) x2 + b (c–a) x + c (a – b) = 0 are :

(A)

(B)

(C)
1,

(D)
1,

12) The product of all the rational roots of the equation is equal
to

(A) 14
(B) 21
(C) 28
(D) 7

13) The number of integral values of k, for which one root of the equation lies in the
interval (1, 2) and its other root lies in the interval (2, 3), is :

(A) 0
(B) 1
(C) 3
(D) 2

14) If the equation x3 + 5x2 + p1x + q1 = 0 and x3 + 7x2 + p1x + r1 = 0 have two roots in common,
then product of uncommon roots is

(A) –35
(B) 35
(C) –12
(D) 12

15) If x ∈ R then maximum and minimum value of are :-

(A)
5, –

(B)
1, –

(C)
7,
(D) 4, 1

16)

Let α, β be the roots of the equation (x – m)(x – n) + c = 0, then the roots of the equation (x – α)(x –
β) = c are

(A) α + m, β + n
(B) m, n
(C) m + c, n + c
(D) α, β

17) The integral value of k for which the inequality is valid for all
real x is

(A) –1
(B) 2
(C) 3
(D) 5

18) If α, β, γ, δ are the roots of x4 – 100x3 + 2x2 + 4x + 10 = 0 then is equal to –

(A)

(B)

(C) 4
(D)

19) The values of m for which both the roots of

x2 – 2mx + m2 – 1 = 0 are greater than –2 but less than 4, are lies in the interval :-

(A) (3, ∞)
(B) (–1, 3)
(C) (1, 4)
(D) (–2, 0)

20) For the equations x2 – kx – 21 = 0 and x2 – 3kx + 35 = 0 the value of k so that one root is
common, is :-

(A) 0
(B) ± 1
(C) ± 3
(D) ± 4

SECTION-II

1) Find the number of distinct real roots of equation e4x + e3x – 4e2x + ex + 1 = 0 is ___.

2) If α2 = 5α – 3, and β2 = 5β – 3 also then p + q equals :

3) The sum of the values of m for which the quadratic polynomial P(x) = x2 + (m + 5)x + (5m + 1) is
a perfect square (m ∈ R) is

4) If then x is = .......

5) Range of is then a + b = ?
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A B B B D C C A C B C B C D C B D C B

SECTION-II

Q. 21 22 23 24 25
A. 30 5 21 4 2

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B D B A C A C B C A A D C C D A B A D A

SECTION-II

Q. 46 47 48 49 50
A. 3 15 4 6 3

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D C B A C A C B A C B A B B A B C D B D

SECTION-II

Q. 71 72 73 74 75
A. 1 22 10 3 14
 SOLUTIONS

PART-1 : PHYSICS

1)

Explain Question : This problem involves the movement of a particle in three segments , each
in a different direction . we need to find net displacement
Concept : Vector addition . displacement , resolving vectors into components
Solution :
South-West
= ;
= 12 m upward
= 12 ,
= 1 m East = 1

Net is placement

, = 13m
Final answer : The correct option is (1)

2) Question explanation:
We are given the position y(t) = a + bt + ct3
We must find initial velocity and initial acceleration (i.e., at t = 0).

Concept
Use differentiation:

A. Velocity

B. Acceleration

Then put t = 0.

Solution
Given:

y = a + bt + ct3

Velocity:

At t = 0 :

v0 = b

Acceleration:
 At t = 0 :
a0 = 0

Final Answer:
Initial velocity = b
Initial acceleration = 0

3)

Explanation Question: Particle is projected and we have to select the following

Concept: This question is based on kinematics of particle
Solution:
Since is –ve thats why speed decreases initially.

Final Answer
The correct option is (2)

4)

Question Explanation : Given position vector as a function of time, find the velocity when the
particle returns to its starting point.

Concept: Velocity = time derivative of position vector

Solution:
Position vector:
r = r₀ (1 − a t) t

Starting point corresponds to r = 0.

This occurs at:
t = 0 and t = 1/a

Velocity vector:
v = dr/dt
v = r₀ [ (1 − a t) + t(−a) ]
v = r₀ (1 − 2 a t)

At return time t = 1/a:

v = r₀ (1 − 2)
v = − r₀
Final Answer: Option (2)

5) + t cos t2

= + cos t2 – 2t2 sin t2

6) Question Explanation: A graph between V2 and x is given and acceleration of particle is
asked.
Concept : This question is based on Graph in 1D Motion.

Solution: Slope of curve

Final answer : The correct option is (4)

7) Explain Question: We need to find acceleration of a car if is moving constant acceleration

covers two successive kilometres in 30 sec and 20 see
Concept : kinematics
Solution :

⇒ 6u + 90 a = 200 ....(i)

⇒ u + 40a = 50 ....(ii)
Solving (i) & (ii) we get a = 2/3 m/s2

Final answer : correct option (3)

8) Explain Question : A body is accelerated with uniform acceleration it is asked to find out
ratio distance in 5 sec interval
Concept : Constant Acceleration motion

Solution : x = 5 a (5)2

x10= a(10)2

x15 = a (15)2

x1 = a (25)

x2 = x10 – x5 = a( 100 – 25) = a (75)

x3 = x15 - x10 = a (225-100) = a (125)

x1: x2: x3 = 25 : 75 : 125
=1:3:5
Final answer: Option (3)
 9) Question Explanation: Calculate total displacement from t = 0 to t = 8s using the given v-
t graph.
Concept: Displacement = Area above time axis – Area below time axis.
Solution :
Step 1: Calculate Positive Area (0 to 4 s ) This is a trapezium with height 4 and parallel sides 4
and 2.

× (4+2) × 4 = 12 m
Step 2: Calculate Negative Area ( 4 to 8 s) This is a trapezium with height 2 and parallel sides
8 – 4 = 4 and 7.5 – 4.5 = 3.

× (4 + 3) × 2 = 7m
Step 3: Calculate Net Displacement
Displacement = 12 – 7 = 5m
Final Answer: Option (1)

10)

Explanation Question: We are given coordinate of object and we have to find average
acceleration.
Concept: This question is based on motion with variable acceleration
Solution:

v= = 8t – 9t2
∴ Δv = (16 – 36) – (0) = – 20

∴ aavg =
Final Answer
The correct option is (3)

11)

Question Explanation: Acceleration varies exponentially with time as . Initial

velocity is zero, and terminal velocity after a long time is required.
Concept: Integration and motion under variable acceleration .
Solution:

Velocity is obtained by integrating acceleration with respect to time. Given , we

write

using the condition . As time becomes very large , the exponential term
tends to zero, so velocity approaches a constant maximum value.
Final Answer: Option (2)

12) Velocity at t = 2

therefore velocity is v = m/sec.

13) vy = v sin 30° – g cos 30° t = 0

14)

15) Velocity time graph is

Distance

= 54 + 10 = 64 m Ans.

16) From t = 0 to t = 3 sec. and from t = 3 to t = 9 sec., the magnitude of acceleration is same.
Hence in velocity time graph, the magnitude of slope from t = 0 to t = 3 sec. and from t = 3 to
t = 9 sec. will be same.

17)

Velocity will be perpendicular to acceleration at heighest point

 = 5 sec

18) Area under (a – t) curve gives change in velocity.

19)
R = 16

20) KεP = =E

KεH = =

21)

Question Explanation : We have to find the projection angle for the given projectile

Concept: “This question is based on projectile motion.”

Solution:

in t = 2 sec
Sy = 5m
vy = 25 sinθ
ay = –g

5 = 25sinθ × 2 – × 10 × (2)2
5 = 50sinθ – 5 × 4
25 = 50 sinθ

sinθ = θ = 30°

Final Answer: (30)

22) and
 23)

= 48 – 27
= 21 m

24) vavg. =

t=

= × 2 × 3π = 4 m/sec.

25) y = bx2

Vy = 2bxVx

ay = 2b(Vx)2 + 2bx × 0
a = 2bVx2

∴ n=2

PART-2 : CHEMISTRY

27)

eV

28)

Explain the question: Ti's last entered electron QNs.

Concept: Aufbau principle & quantum set.

Solution:
Titanium (Z = 22) has a ground-state electronic configuration of 1s22s22p63s23p64s23d2.
According to the Aufbau principle, orbitals fill in order of increasing (n + ℓ) value. For the
4s orbital, n + ℓ = 4 + 0 = 4, while for the 3d orbital, n + ℓ = 3 + 2 = 5.
Since 3d has higher energy, it is filled after 4s, making the last entering electron a 3d electron.
For a 3d electron, the principal quantum number n is 3 and the azimuthal quantum number
ℓ is 2 .
The magnetic quantum number m can be any integer from –2 to +2 , and the spin quantum
number ms can be ±1/2.
Option 2 is the only choice that correctly identifies n = 3 and ℓ = 2.

Final Answer: Option (2)

29)

30) Question Explanation:

Find total number of spectral lines.

Concept:
This question is based on line spectrum of hydrogen.

Solution : n1 = 1 (ground state) ; n2 = 1 + 4 = 5 Upper energy level from G.S. are excited
state.

Spectral lines = = 10
Final Answer:
The correct option is (3)

32) Question Explanation: Calculating uncertainty in position given uncertainty in

momentum.

Concept: Heisenberg Uncertainty Principle.

Solution: Use the minimum uncertainty relation Δx⋅Δp = ​ to calculate the minimum
uncertainty in position (Δx).
Given: Uncertainty in momentum (Δp) =1.0×10−5 kg ms−1, Planck's constant (h) = 6.626
×10−34 kg m2s−1.
The minimum uncertainty in position,

Δx = ​

Δx = ​

Δx ≈
Δx ≈ 0.527 × 10−29 m
Δx≈ 5.27 × 10–30 m
 Final Answer: Option (3)

34)

If K.E. is same

35) λ =

K.E. = mv2 ×
2mKE = (mv)2

mV = 2m × KT
mV = 3mKT

λ=
since mn > me
[λe > λn]
Similarly [λe > λp]

36)
Energy is given by (n + ℓ) value. When (n + ℓ) value is equal, the orbital with greater n-value
has greater energy.

Energy Thus, energy

(i) 3+0=3

(ii) 5+2=7
(iii) < (i) < (iv) < (ii)
(iii) 2 + 1 = 3

(iv) 4 + 3 = 7

37) Orbital angular momentum =

∴ For 2s orbital : ℓ = 0
Orbital angular momentum = 0
∴ For 2p orbital : ℓ = 1

Orbital angular momentum =

 38) (I) in K shell ⇒ n = 1 ⇒ 1s2
in L shell ⇒ n = 2 ⇒2s2 2p6
in M shell ⇒ n = 3 ⇒ 3s2 3p4
⇓
are present in s-subshell
(II) maximum number of in a subshell is 2(2 l + 1)
(III) for s-orbital, l = 0, so m will have only one value i.e. zero.
(IV) for 3p orbital
radial node = n – l – 1
⇒3–1–1⇒1

39) Cl has highest EA is periodic table.

40)

O–(g) > S–(g) (IE order)

41)

Order of IE :-
Na < Al < Mg < Si

496 575 737 786

42) Question Explanation : Arrange ions in decreasing order of ionic radii

Concept: Ionic radius: anions > neutral atoms > cations; higher positive charge → smaller
radius
Solution:
• S²⁻ → largest radius (anion)
• K⁺ → cation, larger than highly charged cations
• Sc³⁺ → smaller than K⁺ due to higher charge
• V⁵⁺, Cr⁶⁺ → highly charged cations → very small radii
• Correct decreasing order: S²⁻ > K⁺ > Sc³⁺ > V⁵⁺ > Cr⁶⁺
Final Answer: Option (2)

43) ⇒ On moving left to right in a period IE increases and from top to bottom in a group IE
decreases.
F > P > S > B (IE order)
⇒ On moving left to right in a period metallic and basic character decreases.
K > Mg > Al > B (Metallic character order)
⇒ On moving top to bottom in a group metallic and basic character increases.
K2O > Na2O > MgO > Al2O3
⇒ EA : Group 17 > Group 16 > Group 15
Cl > F > S > P

44)

O+, O, O– ⇒ Z same but different Zeff.

Zeff ∝ positive charge ∝
Zeff ∝ electronegativity,
So, order of electro negativity O+ > O > O–

45)

Fe+2 → 1s2 2s2 2p6 3s2 3p6 3d6 4s°

no. of d e– = 6
Cl → 1s2 2s2 2p6 3s2 3p5
no of p e– = 11e–
Ne = 1s2 2s2 2p6

no of P e– = 6

47) Question Explanation: Calculate ratio of (E2 – E1) to (E4 – E3) for H - atom.
Concept : This question is based on Bohr atomic Model

Solution:

=
Final Answer 15.

48)

Correct answer is 4

49)

Correct answer is 6

50) Question Explanation:

Question is asking about to calculate E.N. on Pauling scale.

Concept:
This question is based on electronegativity.

Solution :
E.N. on Pauling scale

E.N. =

=
 =3

Final Answer: 3

PART-3 : MATHEMATICS

51) Explain Question : α and β are roots of given equation. We have to solve given options.
Concept : Newton's formula
Solution :
α + β = 1, αβ = –1

⇒
&
⇒
⇒
⇒
⇒
⇒
⇒
Final Answer : (D)

52) Solution:
A : x ∈ (–2, 2); B : x ∈ (–∞, –1] [5, ∞)

From real number line

A∪B = R– [2, 5)
A∩B = (–2, –1]
A –B = (–1, 2)
B – A = R – (–2, 5)

So, correct option is B – A = R – (–2, 5)

Final Answer: option (3)

53) Solution:
Let α and β are zeros of ax2 + bx + c = 0
since β > α, a > 0, b < 0 and c < 0

then α + β = is positive; α β = is negative

so one root is negative and other is positive
α is negative, β is positive and |α| < β
so 0 < |α| < β
Final Answer: option (2)

54) Correct answer is

x2 – 3x + 2 = 0

55) Correct answer is

–7

56) Correct answer is A

57) Correct answer is C

58) Correct answer is A

59) Correct answer is A

60) Correct answer is C

61) Sum of Coeff = 0. so one root is 1

and other root is

62)

will get Irrational roots

Product of all roots = 14

63) Let f(x) =

f(1) > 0
f(2) < 0
f(3) > 0
Now,
f(1) > 0 2-8+k>0 k > 6 .....(1)
f(2) < 0 8 - 16 + k < 0 k < 8 .....(2)
f(3) > 0 18 - 24 + k > 0 k > 6 ........ (3)
From equations (1), (2) & (3),

Integral value of k = 7
64)

Subtract the equation

2x2 + (r1 – q1) = 0
α+β=0
α + β + γ = –5 & α + β + δ = –7
γ = –5 & δ = –7

65)
x2y + 2xy + 4y = x2 – 6x + 4
x2(y – 1) + 2x (y + 3) + 4 (y – 1) = 0
D≥0
4(y + 3)2 – 4.4(y – 1)2 ≥ 0
y2 + 6y + 9 – 4y2 + 8y – 4 ≥ 0
–3y2 + 14y + 5 ≥ 0
3y2 – 14y – 5 ≤ 0
(3y + 1) (y – 5) ≤ 0
ymin = ymax = 5

66)

Question Explanation: Finding roots by relating quadratic expressions and their factors.

Concept: Factor Theorem and Roots of Quadratic Equations.

Solution:
Let α, β be the roots of the equation (x – m)(x – n) + c = 0
⇒ (x – m)(x – n) + c = (x – α)(x – β)
⇒ (x – α)(x – β) – c = (x – m)(x – n)
∴ roots are m, n of the equation (x – α)(x – β) – c = 0
∴ roots of the equation (x – α)(x – β) = c are m, n
Final Answer: Option (2)

67)

for inequality
∴ coff(m2) > 0
so 15k2–2k–7 > 0 and D < 0
15k2–2k–7 > 0
D<0
⇒ 4x(4k–1)2 –4(1) (15x2–2k–7)
⇒ k2–6k+8 < 0

so least integral value of x = 3

68) x4 – 100x3 + 2x2 + 4x + 10 = 0 → α, β, γ, δ

equation whose roots are , , , is

10x4 + 4x3 + 2x2 – 100x + 1 = 0

→ , , ,

So, R ⇒ + + + =– =–

69) f(–2) > 0 ⇒ m ∈ (–∞, –3) ∪ (–1, ∞)

f(4) > 0 ⇒ m ∈ (–∞, 3) ∪ (5, ∞)

–2 < – < 4 ⇒ m ∈ (–2, 4)

and D ≥ 0 ⇒ m ∈ (–∞, ∞)
taking intersection of all four results gives m ∈ (–1, 3)

70) (35 + 21)2 = (k – 3k) (–35k – 63k)

⇒ k2 = 16 ⇒ k=±4

71) (Reference to Jee-Main 2020)

Therefore, Number of distinct real roots = 1.

72)

Clearly have Roots

73) D = 0
(m + 5)2 – 4(1)(5m + 1) = 0
m2 + 25 + 10m – 20m – 4 = 0
m2 – 10m + 21 = 0
m1 + m2 = 10

74) (x > 0) ⇒ x2 = 6 + x
2
⇒ x – x – 6 = 0 ⇒ x = 3 or x = – 2

75)
(y – 1)x2 + 3(y + 1)x + 4(y – 1) = 0
Case-I : y ≠ 1 above equation is a Q.E

So for

Case-II :

Hence, y = 1 for real value of x

So, range
a = 7, b = 7