26-07-2026

2331CJA101003260005 JM

PHYSICS

SECTION-I

1) Find out a unit vector perpendicular to both and

(A)

(B)

(C)

(D)

2) Three vectors and are shown in the figure. Let S be any point on the vector . The

distance between the points P and S is . The general relation among vectors and is :

(A)
(B)
(C)

(D)

3)

The unit vector in direction of is :

(A)

(B)

(C) Both (A) and (B)

(D) None

4) Two forces act on a particle simultaneously as shown in the figure. Find net force in milli newton

on the particle. [Dyne is the CGS unit of force]

(A) 1
(B) 2
(C) 3
(D) 4

5) The area of a regular octagon of side length 'a' is given by . Then the time rate
of change of area, if its side length is being increased at a constant rate β m/sec.

(A)

(B)

(C)

(D)

6)

For the equation of straight line 2x + 3y = 5 below statements are given

(a) y-intercept is at y =

(b) x-intercept is at x =

(c) Slope of the straight line is

(d) Angle made by straight line from horizontal 180º – tan–1

The combination of correct statement is

(A) a, c
(B) a, b, c, d
(C) a, b, c
(D) a, b
7)

(A)

(B)

(C)

(D)

8) A projectile travels at θ below horizontal 1 sec after projection as shown. What is the value of θ ?

(A) tan–1(2)
tan–1
(B)

(C) 37°
(D) 53°

9) A particle is projected at an angle to the horizontal, up and down a plane, inclined at an angle

to the horizontal. If the ratio of time of flights

be 1 : 2, then the ratio is.

(A) 2
(B) 3

(C)

(D)

10) The velocity(v) versus time (t) plot of a particle is shown in the figure, for a time interval of 40s.
The total distance travelled by the particle and the average velocity during this period are,
respectively _____

(A) 25 m and zero

(B) 50 m and zero
(C) 100 m and zero
(D) 100 m and 2.5 m/s

11) A body covers first part of its journey with a velocity of 2 m/s, next part with a velocity of 3
m/s and rest of the journey with a velocity 6m/s. The average velocity of the body will be

(A) 3 m/s

(B)
m/s

(C)
m/s

(D)
m/s

12) A river of width 200 m is flowing from west to east with a speed of 18 km/h. A boat, moving with
speed of 36 km/h in still water, is made to travel one-round trip (bank to bank of the river). Minimum
time taken by the boat for this journey and also the displacement along the river bank are ______ and
_____ respectively.

(A) 20 s and 100 m

(B) 40 s and 0 m
(C) 40 s and 200 m
(D) 40 s and 100 m

13) Rain is falling vertically with a speed of 4 m/s. After some time, wind starts blowing with a speed
of 3 m/s in the north to south direction. In order to protect himself from rain, a man standing on the
ground should hold his umbrella at an angle θ given by :-

(A)
with the vertical towards south

(B)
with the vertical towards north

(C)
with the vertical towards south

(D)
with the vertical towards north
14) All surfaces shown in figure are assumed to be frictionless and the pulleys and the string are

light. The acceleration of the block of mass 2 kg is :

(A) g

(B)

(C)

(D)

15) A string of negligible mass going over a clamped pulley of mass m supports a block of mass M

as shown in the figure. The force on the pulley by the clamp is given

(A) Mg
(B) mg

(C)
g

(D)
g

16) A painter of mass M stands on a platform of mass m and pulls himself up by two ropes which
hang over pulley as shown in figure. He pulls each rope with force F and moves upward with a
uniform acceleration a. Find a, neglecting the fact that no one could do this for long time :
(A)

(B)

(C)

(D)

17) The system shown below is in equilibrium. Find acceleration of block A immediately after spring

c is cut (mA = m & mB = 2m)

(A) Zero
(B)
(C)
(D)

18) A block of mass 1 kg is at rest relative to a smooth wedge being moved leftwards with constant
acceleration 5m/s2. Let N be the normal reaction between the block and the wedge. Then N and

tanθ are :

(A)
N= N and tan θ =

(B)
N = 15 N and tan θ =
(C) N = N and tan θ = 2
(D) N = 15 N and tan θ = 2
19) Find the tension in the horizontal string PQ in the given figure [take g = 10 m/s2]

(A) 70 N
(B) N
(C) N
(D) 140 N

20) The x–t graph of a particle moving along a straight line is shown in figure.
The v–t graph of the particle is correctly shown by

(A)

(B)

(C)

(D)

SECTION-II
1) What is the length of projection of on xy plane?

2) If the velocity of a particle is ( ) and its acceleration is ( ) and angle between

them (in radian) is . The value of n is :

3) A man jumps from a stationary helicopter which is situated at a height of 100 m. If the man opens
the parachute after falling a distance 80 m and finally reaches the ground at 10 m/s. If net

retardation by parachute is a (in m/s2) find .

4) The projectile motion of a particle of mass 5 g is shown in the figure. The initial velocity of the
particle is ms–1 and the air resistance is assumed to be negligible. The magnitude of the change
in momentum between the points A and B is x × 10–2 kgms–1. The value of x, to the nearest integer, is

_______.

5) From the graph shown, if magnitude of acceleration is m/s2. Then the value of n is.

CHEMISTRY

SECTION-I

1) Which orbital is not involved in the formation of PCl5 molecule :-

(A) s
(B)
(C)
(D) pz

2) Which of the following molecule has two lone pairs and bond angle < 109°28' :-

(A) SF2
(B) KrF4
(C)
(D) All of these

3) In the case of alkali metals, the covalent character decreases in the order :

(A) MI > MBr > MCl > MF

(B) MCl > MI > MBr > MF
(C) MF > MCl > MBr > MI
(D) MF > MCl > MI > MBr

4) Mark out the incorrect match of shape :-

(A) XeOF2 = Trigonal planar

(B) = Square planar
–2
(C) [SbF5] = Square pyramidal
(D) = Angular

5) Which of the following is INCORRECT?

(A) Na+(aq) < Cs+(aq) {Ionic mobility}

(B) S > O < Se (E.A.)
(C) Tl > Ga (I.E1)
(D) 3p < 3d {Energy in Li+2}

6) In a compound of x and y, x is 40% by mass of compound and atomic weight of x is 60% of y. Find
empirical formula ?

(A) X9Y10
(B) X5Y4
(C) X10Y9
(D) X4Y5

7)

How many gram of oxygen required to burn completely 570 g octane (C8H18) :-

(A) 2000 g
(B) 3000 g
(C) 4000 g
(D) 5000 g

8) Correct order for bond angle ?

(A) CH4 > NH3 < H2O

–
(B) ClO2 > ClO2 > OCl2
(C) < NH3 < NH4+
(D) All are incorrect

9) In an atom, the total number of electrons having quantum numbers n=4, |mℓ| = 1 and ms= – is:

(A) 2
(B) 10
(C) 12
(D) 6

10) The group having isoelectronic species is :-

(A) O2– , F–, Na+ , Mg2+

(B) O– , F–, Na, Mg+
(C) O2– , F–, Na, Mg2+
(D) O–, F–, Na+, Mg2+

11) The electronic configuration of Pt (atomic number 78) is:

(A) [Xe] 4f14 5d9 6s1

(B) [Kr] 4f14 5d10
(C) [Xe] 4f14 5d10
(D) [Xe] 4f14 5d8 6s2

12)

Given below are two statements :

Statement I : Rutherford's gold foil experiment cannot explain the line spectrum of hydrogen atom.
Statement II : Bohr's model of hydrogen atom contradicts Heisenberg's uncertainty principle.
In the light of the above statements, choose the most appropriate answer from the options given
below :

(A) Statement I is false but statement II is true

(B) Statement I is true but statement II is false
(C) Both statement I and statement II are false
(D) Both statement I and statement II are true

13) Calculate molality of one litre of solution containing 200 gm CaBr2. Given density of solution
equal to 1.0 gm/ml (Atomic mass of Ca = 40, Br = 80)

(A) 1m
(B) 1.25 m
(C) 0.8 m
(D) 1.4 m
14) A compound X with molar weight of 90 g is dissolved in a solvent Y of density of 0.58 g /ml,
Assuming no change in volume upon dissolution, the molarity of a 5 molal solution is.

(A) 2 M
(B) 0.65 M
(C) 2.9 M
(D) 1.5 M

15) A human patient suffering from a ulcer may show a hydrochloric acid concentration of 0.080
mol/L in his gastric juice. It is possible to neutralize this acid with aluminum hydroxide, Al(OH)3,
which reacts with HCl according to the chemical reaction shown below : [Atomic mass : Al = 27]
Al(OH)3 + HCl → AlCl3 + H2O
Find mass of Al(OH)3 which is required to neutralize 2 liters of his gastric juice :

(A) 2.08 g
(B) 6.20 g
(C) 0.693 g
(D) 4.16 g

16) Among the given elements, select those, which are at the peak of Lothar Meyer's curves ?

(A) La
(B) K
(C) Cl
(D) Xe

17) Photoelectric emission is observed from a surface for frequencies ν1 and ν2 of the incident
radiation (ν1 > ν2). If the maximum K.E. of the photoelectrons in two cases are in ratio 1 : K, then the
threshold frequency ν0 is given by

(A)

(B)

(C)

(D)

18) Statement-1 : Molarity and molality have almost same value for a very dilute aqueous solution.
Statement-2 : Normally In very dilute solution, the mass of solvent ( in gm) is equal to the volume
of solution ( in ml).

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
(B)
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
19) What approximate volume of 0.40 M Ba(OH)2 must be added to 50.0 mL of 0.30 M NaOH to get
a solution in which the molarity of the OH– ions is 0.50 M?

(A) 33 mL
(B) 66 mL
(C) 133 mL
(D) 100 mL

20)

Match the Column: (For molecular geometry)

Column-I Column-II

(a) SF4 (P) Tetrahedral

(b) BrF3 (Q) Pyramidal

(c) BrO3– (R) See-saw

(d) NH4+ (S) T-shape(Bent T)

(A) a–P, b–Q, c–R, d–S
(B) a–S, b–R, c–P, d–Q
(C) a–R, b–S, c–Q, d–P
(D) a–Q, b–S, c–R, d–P

SECTION-II

1) Number of correct bond angle order out of the following are (X = central atom)
(i) NH4+ < NH3 < NH2¯ ( )
+
(ii) NO2 > NO2¯ ( )
(iii) NH3 > PH3 > AsH3 ( )
+ + +
(iv) PCl4 < PBr4 < PI4 ( ) Where X' = halogen
(v) CH4 > NH3 > H2O ( )
(vi) NH3 > H2O ( )
–2
(vii) XeO4 = SiCl4 = SO4 (same bond angle)

2) Number of species having sp3 hybridized central atom -

SO3, SF4, SO3–2, SO4–2, CO3–2, CHCl3, XeF4, XeO3

3) A power source of 360 watt emits 50% of energy as light (λ = 331 nm). If photons are emitted out
by the source per second is x × 1020 then what is the value of x ? (Given : h = 6.62 × 10–34 Js, c = 3 ×
108 m/s)

4) A compound of vanadium has a magnetic moment (μ) of 1.73 BM. If the vanadium ion in the
compound is present as Vx+, then the value of x is ?
5) The number of elements from the following group having I.E. greater than O (Z = 8)
Li, Be, B, C, N, F, Ne, S, Si

MATHEMATICS

SECTION-I

1) Let A = {1, 2, 3,....,10} and B = and gcd (m, n) = 1}. Then n (B) is
equal to:

(A) 36
(B) 31
(C) 37
(D) 29

2) Each set Xr contains 5 elements and each set Yr contains 2 elements and
If each element of S belongs to exactly 10 of the and to exactly 4 of the , then n is:

(A) 10
(B) 20
(C) 100
(D) 50

3) If x2 + 4y2 + z2 - 2xy – 2yz – zx = 0 then x : y : z equals

(A) 1:2 :1
(B) 2 :1 :2
(C) 1:2 :3
(D) 1:1: 2

4) If , then x2(x – 14)2 =

(A) 1
(B) –1
(C) 2
(D) –2

5) Consider the inequality . If is the least non negative

integral value of x, then is
(A) 0
(B) 1
(C) 2
(D) 3

6)

The value of equal to ________.

(A) 49
(B) 625
(C) 216
(D) 890

7) Number of integral values of x satisfying the inequation , is/are

(A) 1
(B) 2
(C) 3
(D) No solution

8) If square root of, a1/a. (2a)1/2a . (4a)1/4a . (8a)1/8a ......... is , then the value of 'a' is

(A)

(B)

(C)

(D)

9) Solve for

(A) 1
(B) 2
(C) 3
(D) No solution

10) A software company sets up m number of computer systems of finish an assignment in 17 days.
If 4 computer systems crashed on the start of the second day, 4 more computer systems crashed on
the start of the third day and so on, then it took 8 more days to finish the assignment. The value of m
is equal to:

(A) 150
(B) 180
(C) 160
(D) 125

11) The interior angles of a convex polygon are in A.P. The smallest angle is 100o & the common
difference is 10o. Find the number of sides of the polygon.

(A) 8
(B) 9
(C) 12
(D) None of these

12) Consider the sequence 1,2,2,4,4,4,4,8,8,8,8,8,8,8,8,...., then 1025th term will be

(A) 29
(B) 211
(C) 210
(D) 212

13) If 19 arithmetic means A1, A2, A3, ..., A19 are inserted between 102 and 2 such that their sum is S,

then the value of is

(A) 1
(B) 3
(C) 5
(D) 6

14) Let . Then

(A)

(B)

(C)

(D) 1

15) The expression lies in the interval ; (x ∈ R)-

(A) [0, –1]

(B)
(C) [0, 1)
(D) None of these
16) The sum of the values of m for which the quadratic polynomial
P(x) = x2 + (m + 5)x + (5m + 1) is a perfect square (m ∈ R) is

(A) 3
(B) 7
(C) 8
(D) 10

17) The set of values of 'a' for which the quadratic ax2 + 2x(1 – a) – 4 is negative for exactly three
integral values of x, is:-

(A) (0, 2)
(B) (0, 1]
(C) [1, 2)
(D) [2, ∞)

18) Let and be the roots of . Then and are the roots of

(A)
(B)
(C)
(D)

19) If cosecθ + cotθ = 5, then sinθ is equal to :-

(A)

(B)

(C)

(D)

20) If sin x + sin2x = 1; then

cos8 x + 2 cos6x + cos4x =

(A) –1
(B) 0
(C) 1
(D) 2

SECTION-II

1) If are in A.P. , then the minimum value of a + b + c is ______.

2) If a and b are the roots of equation x2 – 7x – 1 = 0, then the value of is equal
to.

3) The value of is equal to ______.

4) If polynomial leaves same remainder, when divided by x – 1 and x + 2

respectively then value of 3A + B is equal to

5) Let
If and , then the number of elements
in the smallest subset of X containing both A and B is___.
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C C D C B A B C C A C B B D C D A C B

SECTION-II

Q. 21 22 23 24 25
A. 5 2 3 5 9

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C D A A D C A C D A A D B C D B B A A C

SECTION-II

Q. 46 47 48 49 50
A. 5 4 3 4 3

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B B B A B D A B D A A C A B C D C D B C

SECTION-II

Q. 71 72 73 74 75
A. 3 51 4 4 29
 SOLUTIONS

PHYSICS

1)

2) Let vector from point P to point S be

from triangle rule of vector addition

3) Sol.
Both (A) and (B)

4) Question Explanation : Two forces acts on a particle, we have to find resultant of the
vectors Concept : Addition of vector
Solution : 1 Newton = 105 dyne

= 400 dyne = 4 millinewton

Final Answer: Option (4)

5) Explain Question: Area of octagon is given as A = 2Area of octagon is given as A = 2

. In question it is asked to find time rate of change of area of it rate of increase of

is length is given In question it is asked to find time rate of change of area of it rate of increase
of is length is given
Concept : Differentiation
Solution :

Final Answer : correct option is 3

6)
or

(2nd quadrant)

θ = 180 – tan–1

7) Sol

8)

ux =

3 = uy × 1 – × 10 × 12
uy = 8 m/s

⇒ 4

9) Question Explanation: A particle is projected making angle α with the horizontal. It moves
up and down an inclined plane making angle β. Given the ratio of times of flight, we have find
tanβ / tanα.

Concept: This question is based on projectile motion on an inclined plane

Solution: Motion perpendicular to the plane is under acceleration g cosβ.

Time of flight up the plane:

Since displacement perpendicular to the plane is zero,

u sin(α − β) T₁ − (1/2) g cosβ T₁² = 0

Solving,
T₁ = [2u sin(α − β)] / (g cosβ)

Time of flight down the plane:

Since displacement perpendicular to the plane is zero,

u sin(α + β) T₂ − (1/2) g cosβ T₂² = 0

Solving,
T₂ = [2u sin(α + β)] / (g cosβ)

Given,
T₁ / T₂ = 1 / 2

So,
sin(α − β) / sin(α + β) = 1 / 2

2( sinα cosβ − cosα sinβ )

= sinα cosβ + cosα sinβ

sinα cosβ = 3 cosα sinβ

tanα = 3 tanβ
tanβ / tanα = 1 / 3

Final Answer: Option (3)

10)
Total distance travel

d=
d = 100 m

Average velocity =

<v> =

11)

t1 = t2 = t3 =

Average velocity =
=
= 3 m/s

12)
Minimum time :

For round trip = 40 sec.

Displacement along river bank = 40 × 5 = 200 m

13) Solution:

with the vertical towards north

Final Answer: The correct option is (2).

14)
40 – 2T = 4a
T – 10 = 4a ⇒ 20 = 12 a

⇒ a = 5/3 ⇒ 2a = ⇒
15)

force n pully = =

16) From figure,

2F + N – Mg = Ma

2F – mg – N = ma
4F – (M + m)g = (M + m)a

a=

17)

Question Explanation :
The question asks to find the acceleration of block mA immediately after spring C is cut. (mA =
m and mB = 2m). Given that system is in equilibrium.

Concept:
This question is based on spring & cutting of spring.

Solution:
Before cutting (equilibrium)
T1 = mBg
T2 = T1 + mAg
= mBg + mAg
= (mA + mB)g
After cutting (T1 = 0)
(mA + mB)g – mA g = mA⋅ aA
mBg - mAaA

aA =

Final Answer: The correct option is (4)

18) mg sin θ = ma cos θ

⇒ a = g tan θ ⇒ tan θ =
N = mg cos θ + ma sin θ = N

19) Question Explanation:

The question asks to find the tension in the horizontal string PQ in the given equilibrium
system, given g = 10 m/s2.

Concept:
This question is based on equilibrium, Lami's theorem.

Solution:

Final Answer:
The correct option is (3)

20) x = –t(t – 2T)

x = –t2 + 2Tt
and

21)

Length of projection on xy plane is =

22) Question Explanation: The question asks for the angle between velocity and acceleration
vectors.
Concept: Dot product of two vectors to find the angle.
Solution:

n=2
Final Answer: 2

23) Explanation: The problem describes a man jumping from a stationary helicopter at 100
m. He opens a parachute after falling 80 m and reaches the ground at 10 m/s. we need to find

the net retardation due to the porachute 'a' and then calculate
Concept:
Kinematics, free fall, Retardation.

Solution:
Velocity of man after falling 80 m under gravity (free fall)
V2 = 0 + 2 × (-10) (-80)
V = 40 m/s
downwards
Now the man travels next 20 m with
retardatioon due to parachute
Final velocity = 10 m/s, uinitial = 40 m/s
(–10)2 = (–40)2 + 2 × (a) (–20)
40a = 1600-100 = 1500

a= = m/s2
 So value of

Final answer : 3

24)

Question Explanation: A particle is projected at and lands back on the same horizontal
level; find the change in momentum between the points of projection (A) and landing (B).
Concept: Projectile motion (ground to ground) - horizontal velocity remains same, vertical
velocity reverses direction.
Solution:

... (1)
... (2)
... (3)

... (4)
ΔP = 2mu sin 45°

= 50 × 10–3
= 5 × 10–2
Final Answer : 5

25)

cot θ = ⇒ cot θ =

cot (–37) = ⇒

⇒a= ⇒α= or a =

a=

CHEMISTRY

26) In sp3d hybridisation s, px, py, pz and dz2 orbital involved.

27) SF2 KrF4 ICl4–

I.P. = 2 I.P. = 2 I. P. = 2
Hyb= sp3 Hyb=sp3d2 Hyb=sp3d2
B.A.<109°28' B.A.<109°28'

28) M = Alkali metal

29) XeOF2 {sp3d, 3bp, 2ℓp} T shape

30) Li+2 → single electron : energy : 3s = 3p = 3d

31)

32)

2C8H18 + 25O2 → 16CO2 + 18H2O

required oxygen ⇒

33)

34) For n = 4, orbitals are

Total number of orbitals having {|mℓ| = 1} = 6

Total number of electrons having {|mℓ| = 1 and ms = }=6

35) Explain Question:

Identify set of isoelectronic species.

Concept:
Isoelectronic species (Same e– count).

Solution:
* Isoelectronic species have equal number of electrons
* O2– : 8 + 2 = 10 electrons
* F– ; 9 + 1 = 10 electrons
* Na+ ; 11 – 1 = 10 electrons
* Mg2+: 12 – 1 = 10 electrons
* All species have 10 electrons

Final answer: Option (1)

36) Question Explanation : Identify ground state configuration of Platinum (Z=78).

Concept: Aufbau Exception
Solution : Platinum (Pt, Period 6, Group 10) deviates from the expected Aufbau configuration
([Xe]4f145d86s2). Due to stability and relativistic contraction effects, one electron shifts from
6s to 5d, resulting in a half-filled s-orbital and a nearly full d-orbital.
Expected: [Xe]4f145d86s2
Actual: [Xe]4f145d96s1
Final Answer : Option (3)

37) Rutherford's gold foil experiment only proved that electrons are held towards nucleus by
electrostatic forces of attraction and move in circular orbits with very high speeds.
Bohr's model gave exact formula for simultaneous calculation of speed & distance of electron
from the nucleus, something which was deemed impossible according to Heisenberg.

38) Question Explanation:

Find molality.

Concept:
This question is based on interconversion of concentration terms.

Solution:

mass of solution = d × v
= 1 × 1000 = 1000 g = 1 kg
mass of solvent = 1000 – 200 = 800 g

Final Answer: Option (2)

39)

Question Explanation:
 Calculate the molarity of a 5 molal solution of compound X (Molar weight 90 g) in solvent Y
(Density 0.58 g/mL ), assuming no volume change upon dissolution.

Concept:
Molarity is moles of solute per liter of solution, while molality is moles of solute per kilogram
of solvent.

Solution:

A. Given: 5 moles of X in 1000 g of solvent Y.

B. Volume of Solvent (V): Mass/Density = 1000 g/0.58 g/mL = 1724.13 mL = 1.724 L .
C. Molarity (M): Moles/Volume (L) = 5 mol/1.724 L ≈ 2.9 M.

Final Answer: Option (3)

40) Question Explanation:

Find mass of Al(OH)3

Concept:
This question is based on stoichiometry calculations.

Solution:
Al(OH)3 + 3HCl → AlCl3 + 3H2O

= × 78 × 2
⇒ 4.16 g

Final Answer:
The correct option is (4).

41) Question Explanation: Identifying elements that occupy the peaks of Lothar Meyer's
curves.

Concept: Lothar Meyer's Atomic Volume Curves.

Solution: Lothar Meyer plotted atomic volume against atomic weight. He observed that alkali
metals (Li, Na, K, Rb, Cs) occupy the peaks of these curves because they have the largest
atomic volumes in their respective periods.

Calculation:

A. Peaks: Alkali Metals (Group 1).

B. Given options: La (Lanthanide), K (Alkali Metal), Cl (Halogen), Xe (Noble Gas).
C. Potassium (K) is the only alkali metal in the list.

Final Answer: Option (2)

42) Question Explanation:

Question is asking about threshold frequency ν0

Concept:
This question is based on Photoelectric effect.

Solution:
In photoelectric effect max K.E can be written as
…(1)
…(2)
equation (1) ÷ equation (2)

or

Final Answer:
The correct option is (2)

43) Explain the question :

Concept : This question is based on
Solution :
For very dilute solutions:
msolution msolvent {Because solute is very less}
Now since, it is aq. solution hence solvent is water (d = 1gm/ml)
Let Molarity = M i.e. 1 litre solution.
Contain 'M' moles of solute.

Since the solution is very dilute: dsolution

Msolution = 1000 gm = MSolvent

molality =
* However, this is true only for very dilute a queous solution For very dilute solutions:
msolution msolvent {Because solute is very less}
Now since, it is aq. solution hence solvent is water (d = 1gm/ml)
Let Molarity = M i.e. 1 litre solution.
Contain 'M' moles of solute.
Since the solution is very dilute: dsolution
Msolution = 1000 gm = MSolvent
molality =
* However, this is true only for very dilute a queous solution

Final answer : Option(1)

44)

Let volume of Ba(OH)2 solution = V mL

millimoles of OH– from Ba(OH)2 = 2 × V × 0.4 = 0.8V
millimoles of OH– from NaOH = 50 × 0.3 = 15
Total millimoles of OH– = (50 + V) × 0.5
0.8 V + 15 = (50 + V)0.5 ⇒ V = 33.33 mL
45)

46) Explain the question : The number of species with correct bond order will be ?
Concept : This question is based on VSEPRT, bond parameters.
Solution :
(ii) NO2+ > NO2¯ ( )
(iii) NH3 > PH3 > AsH3 ( )
(v) CH4 > NH3 > H2O ( )
(vi) NH3 > H2O ( )
–2
(vii) XeO4 = SiCl4 = SO4 (same bond angle)
Final answer : 5

47) Explain Question :

Calculate the hybridization of the central atom in each given species.

Concept:
Steric Number Rule (sp3 hybridization requires Steric Number = 4).

Solution:
Hybridization is determined by the Steric Number (SN), which is the sum of sigma bonds and
lone pairs on the central atom. For sp3 hybridization, the SN must be 4.
• SO3​: 3 σ + 0 LP = 3 (sp2)
• SF4​: 4 σ + 1 LP=5 (sp3d)
• SO32−​: 3 σ +1 LP=4 (sp3)
• SO42−​: 4 σ + 0 LP=4 (sp3)
• CO32−​: 3 σ + 0 LP=3 (sp2)
• CHCl3​: 4 σ + 0 LP=4 (sp3)
• XeF4​: 4 σ + 2 LP=6 (sp3d2)
• XeO3​: 3 σ + 1 LP=4 (sp3)
The species with sp3 hybridization are: SO32−​,SO42−​,CHCl3​, and XeO3​.

Final Answer: 4

48) Ans. (3)

 49)
n = no. of unpaired e–
n=1

n = 1, verse four e–
x=4

50)

Question Explanation: Count elements whose first ionization energy (IE1) is greater than
oxygen (O).
Concept: IE increases across a period; exceptions include higher IE of N (half-filled p3 ) and
noble gases (Ne).

Solution (Summary Table):

Element IE1 compared to O Result

Li Lower x
Be Lower x
B Lower x
C Lower x
N Higher ü
F Higher ü
Ne Much higher ü
S Lower x
Si Lower x

Final answer: 3

MATHEMATICS

51) Ans. (31)

52) For distinct elements, number of elements in

X1 ∪ X2 ...... ∪ X20 = 20 × 5. But each element is repeated 10 times.

.....(1)

Similarly ....(2)

From (1) and (2),

53)
2 × (x2 + 4y2 + z2 – 2xy – 2yz – zx) = 0
⇒ x2 + 4y2 – 4xy + 4y2 + z2 – 4yz + x2 + z2 – 2zx = 0
⇒ (x – 2y)2 + (2y – z)2 + (z – x)2 = 0
⇒ x = 2y = z ⇒ x : y : z = 2y : y : 2y = 2 : 1 : 2.

54)

Correct Option is: (1)

55)

Correct Option Is: (2)

56)

Answer (D)

57)

58)

Now

and

59) No solution

60)
61)

62) Conceptual

63)

A17 = a + 17d = 102 + 17(–5) = 17

A10 = a + 10d = 102 + 10(–5) = 52

64)

65) Correct answer is C

66) D = 0
(m + 5)2 – 4(1)(5m + 1) = 0
m2 + 25 + 10m – 20m – 4 = 0
m2 – 10m + 21 = 0
m1 + m2 = 10
67)
ƒ(x) = ax2 + 2x(1 – a) – 4 = x(ax + 2) – 2(ax + 2) = (ax + 2) (x – 2)
If 'a' is negative then for infinite integral values of x expression will become negative
∴ a must be positive.
From the graph it is clear that to satisfy the given conditions.
ƒ(–1) < 0 and ƒ(–2) ≥ 0
solving these two we get a ∈ [1, 2).

68)

69)

cosec θ =

∴ sin θ =

70) sinx = 1 – sin2x ⇒ sin2x = cos4x

⇒ 1 – cos2x = cos4x ⇒ cos4x + cos2x = 1
squaring both sides; cos8x + cos4x + 2cos6x = 1.

71)

72) Since, a and b are roots of x2 – 7x – 1 = 0, so

a2 – 7a – 1 = 0
⇒ a2 – 1 = 7a
⇒ a4 + 1 – 2a2 = 49a2
⇒ a4 + 1 = 51a2 ....(1)
Similarly,
b4 + 1 = 51b2 ....(2)
Now,

= 51

73)

= =4

74) Remainder when is divided by x – 1 is

Remainder when
is divided by x + 2 is

Both remainder are equal

A + B + 9 = – 8A – 2B + 21
⇒ 9A + 3B = 12 ⇒ 3A + B = 4

75)
elements
elements
Here
=25+7-3=29