09-08-2026

1001CJA101017260008 JA

PART-1 : MATHEMATICS

SECTION-I

1) Number of solutions of equation in [–2π,2π] is equal to-

(A) 2
(B) 4
(C) 8
(D) none of these

2) If P = (tan(3n + 1θ) – tanθ) and Q = , then

(A) P = 2Q
(B) P = 3Q
(C) 2P = Q
(D) 3P = Q

3) Assertion-A : In a ΔABC, given that tanA : tanB : tanC = 3 : 4 : 5, then the value of sinAsinBsinC

is .
and
Reason-R : In any non right angle ΔABC, tanA + tanB + tanC = tanA tanB tanC.

(A) A is True, R is True ; R is a correct explanation for A.

(B) A is True, R is True ; R is not a correct explanation for A.
(C) A is True, R is False.
(D) A is False, R is True.

4) The number of solutions of the equation 3 cos2x = 8 sinx in [0, π] is -

(A) 1
(B) 2
(C) 3
(D) 4

5) The value of the expression , where is equal to :

(A)

(B)

(C)

(D)

6) Value of sin 10° + sin 20° + ... + sin 360° is

(A) 0
(B) 1
(C)
(D) 2

7) Given & , then

(A) S + P < 0
(B) S.P > 0
(C)
(D) logP(1+S) > 0

8) The value of is

(A)

(B)
(C)
(D) 1

9) Consider equation, x2 + 2(k – 3)x + 9 = 0, k ∈ R, then match the list.

List-I contains location of roots. List-II contains complete set of values of k.

List-I List-II

(A) Both roots are opposite in sign (I) k ∈ (–∞, 0]

(B) Exactly one root lies in (0, 1) (II) k∈ϕ

(C) Both roots are positive (III) k ∈ (–∞, –2)

(D) Both roots are negative (IV) k ∈ [6, ∞)

(A) (A) – II, (B) – III, (C) – I, (D) – IV
(B) (A) – II, (B) – IV, (C) – I, (D) – III
(C) (A) – IV, (B) – I, (C) – II, (D) – III
(D) (A) – III, (B) – I, (C) – IV, (D) – II

10) Let a, b, c be the three numbers such that (a – b)2, (b – c)2, (c – a)2 are in A.P. Then a – b, b – c, c –
a are always in (a ≠ b ≠ c)

(A) A.P.
(B) G.P.
(C) H.P.
(D) A.G.P.

11) The sum of the product of the 2n numbers ±1,±2,±3,........,±n taken two at a time is -

(A)

(B)

(C)

(D)

12) The sum of infinite number of terms of a G.P. is 2 and the sum of their cubes is 24, then second
term of G.P. is -

(A)

(B)

(C)

(D)

13)

Roots of the equation

(x – a)2 + (x – b)2 + (x – c)2 + 4(a + b + c)x = 0 are (where a ≠ b ≠ c & a,b,c ∈ R)

(A) always real
(B) imaginary
(C) real & equal
(D) can't say

14) Roots of the equation

(where p,q,r ∈ R0 but p ≠ q ≠ r) -

(A) are always real

(B) imaginary
(C) are of opposite sign
(D) are of same sign

15) Statement-1 : If cotθ + tanθ + cot2θ + tan2θ + cot4θ + tan4θ = acotθ + bcot(cθ) ; a, b, c ∈ I,
then a + b + c = 6.
and
Statement-2 : cotθ – tanθ = 2cot2θ.

(A) Statement-1 is True, Statement-2 is True

(B) Statement-1 is False, Statement-2 is False
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

16) Two sides 'a' and 'b' of triangle ABC are given by the roots of the equation x2 – 4x + 1 = 0

and the included angle between them is , then the value is (where c is third side of the
triangle ABC) -

(A)

(B)

(C)

(D) 4

17) In a , if , then cos C =

(A)

(B)

(C)

(D)

18) If A = 45°, B = 75° and C = 60° then :

(A) a + c = 2b
(B)
(C)
(D) None of these

19) If , then x is -
(In all the choices k ∈ I)
(A)

(B)

(C) ϕ

(D)

20) In a triangle ABC, given b = 2, , ∠A = 30° (Where symbols used have usual meaning),
then in radius of ΔABC is

(A)

(B)

(C)
(D)

SECTION-II

1) The lengths of the altitudes from the vertices of a triangle to the opposite sides are 3 cm, 3 cm

and 4 cm. If the area of the triangle is A then is

2) In ∆ABC with usual notations and (where x, z are

prime numbers and y ∈ N), then the value of (x + y – z) is

3) The value of is :

4) If , then the value of log2(16 + 48 log2x) is -

5) If x,y,z are positive real numbers such that , then value

of , is

PART-2 : PHYSICS

SECTION-I
1) The speed (v) of wave on surface of water is given by . The dimensional formula
for a and b respectively. Where λ is the wavelength and ρ is density of water.

0
(A) L1T–2, M1L T–2
(B) LT–2, L–1T2
(C) LT–2, L1T–2
0 0 0
(D) L–1T2, M L T

2) A regular hexagon of side 'a' shown in figure. If , the value of K is

:-

(A) 3
(B) 4
(C) 5
(D) 6

3) A particle moves along x-axis such that its position at time t is x = (3t2 – t3)m. Total path length
covered in first 4 sec is :-

(A) 16 m
(B) 24 m
(C) 12 m
(D) None of above

4) A particle starts from rest. Its acceleration (a) versus time (t) is as shown in the figure. The

maximum speed of the particle will be :

(A) 110 m/s

(B) 55 m/s
(C) 550 m/s
(D) 660 m/s

5) Two particles are moving with velocity v1 and v2 respectively which of the following is correct
about relative velocity :- (v1, v2 ≠ 0)
(A) Magnitude of velocity of 1 w.r.t. 2 can not be equal to |v1|
(B) Magnitude of velocity of 1 w.r.t. 2 can be smaller than |v1| – |v2|
(C) Magnitude of velocity of 1 w.r.t. 2 can not be greater than |v1| + |v2|
(D) Magnitude of velocity of 1 w.r.t. 2 can not be equal to |v2|

6) Displacement-time graph of an object is given. It's velocity-time graph can be:

(A)

(B)

(C)

(D)
7) Two balls are projected from an inclined plane from point Q & P respectively as shown. Select the

incorrect statement. (During the time both remain in air)

(A) Path of A w.r.t. B is straight line

(B) Velocity of A w.r.t. B is constant
(C) Path of A w.r.t. B is parabolic
(D) Acceleration of A w.r.t. B is zero

8) In the figure shown, a person wants to raise a block lying on the ground to a height h slowly. In
which case he has to exert more force. Assume pulleys and strings are light.

(A) Figure (i)

(B) Figure (ii)
(C) Same in both
(D) Cannot be determined

9) Match the lists (All observation are seen from ground). There is no slipping between man and bus
in all cases.

List-I List-II

Man pushing the wall and the bus is

moving with constant velocity
Work done by
(P) normal force on (1)
man ≠ 0
 Man standing in bus and bus is moving
with constant velocity
Work done by
(Q) normal force on (2)
man = 0

Man standing in bus and bus is accelerated

with constant acceleration a
Work done by
(R) friction force (3)
on man = 0

Man standing in bus and bus is moving

with constant velocity on an inclined plane
having inclination θ.
Work done by
(S) friction force (4)
on man ≠ 0

(A) P→1, Q→2,3,4, R→2, S→1,3,4

(B) P→1, Q→3,4, R→2,3, S→4
(C) P→2, Q→2,4, R→2, S→1,3
(D) P→1,2, Q→3,4, R→2, S→1,4

10) In the figure shown, the wedge is pushed with an acceleration of . The time taken by
the block to reach the top of inclined plane is :- (System starts from rest) (Take : g = 10m/s2)

(A)

(B)

(C)

(D)

11) In the arrangement shown in figure, coefficient of friction between the two blocks is . The
force of friction acting between the two blocks is :- (Ground is smooth)

(A) 8 N
(B) 10 N
(C) 6 N
(D) 4 N

12) A uniform heavy rope of mass 8 kg and length 100 cm is being pulled as shown. Find tension in

rope at 25 cm from it's left corner :-

(A) 10 N
(B) 20 N
(C) 30 N
(D) 40 N

13)

A force acts on block shown. The force of friction acting on the block is :

(A)
(B)
(C)
(D)

14) The angular velocity of a body moving in a circular path is shown in graph below. What is the

average angular velocity (in rad/s) for the entire motion?

(A) 9
(B) 18
(C) 27
(D) 36
15) Which of the following statements is false for a particle moving in a circle with a constant
angular speed ?

(A) The velocity vector is tangent to the circle.

(B) The acceleration vector is tangent to the circle.
(C) The velocity and acceleration vectors are perpendicular to each other.
(D) The acceleration vector points to the centre of circle.

16) If breaking strength of string is 3 mg. The maximum speed of projection v can be :-

(A)
(B)
(C)
(D)

17) A block of mass 2kg is placed on wedge having an angle 37° with horizontal. Wedge rotates
about an axis as shown with angular velocity 5 rad/s. If block just start accelerating upward w.r.t.
wedge with acceleration of 1 m/s2 at the given instant find friction force acting on block. (Distance of

block is 1m at the given instant) :-

(A) 16 N
(B) 8 N
(C) 26 N
(D) 38 N

18) The kinetic energy K of a particle moving along a circle of radius R depends on the distance
covered s as k = as2 where a is a constant. The force acting on the particle is

(A)

(B)

(C) 2as

(D)
19) The force F acting on a particle moving in a straight line as shown in figure. What is the work
done by the force on the particle during the 1 m of the displacement when particle is moving from x

= 0 to x = 1 m?

(A) 5 J
(B) 10 J
(C) 15 J
(D) 2.5 J

20) Velocity-time graph of a particle moving in a straight line is as shown in figure. Mass of the
particle is 2 kg. Work done by all the forces acting on the particle in time interval between t = 0 to t

= 10 s is :-

(A) 300J
(B) –300J
(C) 400J
(D) –400J

SECTION-II

1) A circular platform rotates around a vertical axis with angular velocity ω = 10 rad/s. On the
platform is a ball of mass 100 gram, attached to the long axis of the platform by a thin rod of length
12 cm (α = 30°). The normal force exerted by the ball on the platform is x (in N). Find 10x. Friction

is absent. (g = 10 m/s2)

2) The figure shows the velocity and acceleration of a point like body at the initial moment of its
motion. The acceleration vector of the body remain constant. The minimum radius of curvature (in
m) of trajectory of the body is :-

3) A thin rod of length 1m is fixed in a vertical position inside a train, which is moving horizontally
with constant acceleration 8 m/s2. A bead can slide on the rod, and friction coefficient μs = 0.5 and μk
= 0.25. If the bead is released from rest at the top of the rod, it will reach the bottom in t seconds.
Find '2t'.

4) A mass m is connected to the end of a massless string of length ℓ = 12.5m. The top end of the
string is attached to a ceiling that is a distance ℓ above the floor. Initial conditions have been set up
so that the mass swings around in a horizontal circle, with the string always making an angle 53°
with respective to the vertical, as shown in figure. If the string is cut, then the time (in sec) after

which mass m hit the floor is:

5) The longest six hit by CHRIS GAYLE in IPL just misses a building of length 80 m as shown in
figure. The angle of projection with horizontal (in degrees) is :-

PART-3 : CHEMISTRY

SECTION-I

1) The IUPAC name of the following compound is

(A) 4‑Bromo‑3‑cyanophenol
(B) 2‑Bromo‑5‑hydroxybenzonitrile
(C) 2‑Cyano‑4‑hydroxybromobenzene
(D) 6‑Bromo‑3‑hydroxybenzonitrile

2) The IUPAC name of the following is:

(A) 2-Chloro-3-methoxy cyclohex-5-ene carboxylic acid

(B) 6-Chloro-5-methoxy cyclohex-2-ene carboxylic acid
(C) 6-Chloro-5-methoxy cyclohex-2-enoic acid
(D) 2-Chloro-3-methoxy cyclohex-5-enoic acid

3) Which of the following order given below is incorrect :

(A) (Stability order of cation)

Priority order of functional group in IUPAC naming
(B)
–SO3H > –CN > –CHO > –OH
Order of –I :
(C)

Order of +I :
(D)

4) 30 mL of a mixture of CO and H2 were mixed with excess of O2 and exploded & cooled. There was
a volume contraction of 33 mL. All volume measurements corresponds to room temperature (27°C)
and one atmospheric pressure. Determine the volume ratio V1 : V2 of CO and H2 in the original
mixture

(A) 6 : 13
(B) 1 : 3
(C) 2 : 3
(D) 7 : 13

5) The molecular weights of two elements A2 and B3 are 40 and 80 respectively. If x g of A2 contains y
atoms of 'A', how many atoms of 'B' are present in 2x g of B3 ?

(A)

(B)

(C)

(D) 2y
6) Given x = Magnitude of % change in volume due to reaction at constant pressure & temperature

List-I
List-II
(Extent of reaction = 100%)

(P) (1) x = 33.33%

NH3(g) —→ N2(g) + H2(g)

(Q) (2) x = 66.66%

SO3(g) —→ SO2(g) + O2(g)

(R) PCl5(g) —→ PCl3(g) + Cl2(g) (3) x = 100%

(S) (4) x = 50%

Which of the following is CORRECT combination :
(A) (P)-(4), (Q)-(3), (R)-(3), (S)-(2)
(B) (P)-(2), (Q)-(1), (R)-(2), (S)-(3)
(C) (P)-(3), (Q)-(2), (R)-(3), (S)-(1)
(D) (P)-(3), (Q)-(4), (R)-(3), (S)-(2)

7) What volume of 11 M and 1 M sulphuric acid must be mixed with to get 1 L of 6M sulphuric acid :

(A) Volume of 11 M H2SO4 solution is 400 mL and volume of 1M is 600 mL

(B) Volume of 11 M H2SO4 solution is 600 mL and volume of 1M is 400 mL
(C) Volume of 11 M H2SO4 solution is 300 mL and volume of 1M is 700 mL
(D) Volume of 11 M H2SO4 solution is 500 mL and volume of 1M is 500 mL

8) What weight of CaCO3 must be decomposed to produce the sufficient quantity of carbon dioxide to
convert 21.2 kg of Na2CO3 completely in to NaHCO3. [Atomic mass Na = 23, Ca = 40]
CaCO3 → CaO + CO2
Na2 CO3 + CO2 + H2O → 2NaHCO3

(A) 100 kg
(B) 20 kg
(C) 120 kg
(D) 30 kg

9)

5 moles of A, 6 moles of B and excess of C are mixed together to produce D, i.e.

A + 2B → E
E + C → B + 2D

Calculate the maximum moles of D produced (assuming that the products formed can also be reused
in the reaction)
(A) 10
(B) 6
(C) 3
(D) 12
10) 92 g mixture of CaCO3 and MgCO3 heated strongly in an open vessel. After complete
decomposition of the carbonates it was found that the weight of residue left behind is 48 g. Find the
mass of MgCO3 (in grams) present in the original mixture.

(A) 45 g
(B) 42 g
(C) 50 g
(D) 48 g

11) How many total oxygen corner are unshared in given silicate (Si4O12)8–

(A) 7
(B) 5
(C) 6
(D) 8

12) The correct statement(s) about hydrogen bonding is/are:

(A) Hydrogen bonding exists when H is covalently bonded to the highly electronegative atom.
(B) Intermolecular H bonding is present in o-nitro phenol.
(C) Intramolecular H Bonding is present in HF.
(D) The magnitude of H bonding depends on the physical state of the compound.
(E) H-bonding has a powerful effect on the structure and properties of compounds.
Choose the correct answer from the options given below:

(A) A only
(B) A, D, E only
(C) A, B, D only
(D) A, B, C only

13)

Which of the following statement is correct for

(A) It contain pπ–pπ & pπ–dπ bonding

(B) It has regular tetrahedral geometry with all same bond lengths.
3
(C) sp hybridised central atom
(D) Maximum four atoms can lie in a plane.

14) Which of the following order is incorrect :

(A) C–C > Si–Si > Ge–Ge (bond enthalpy)

(B) H–F < H–Cl < H–Br (Acidic nature)
(C) Cl–OH > Br–OH > I–OH (Acidic nature)
(D) OF2 < Cl2O < H2O (bond angles)
15) Statement-I : The third period contains only 8 elements and not 18 elements like 4th period.
Statement-II : In III period filling starts from 3s1 and complete at 3p6 whereas in IV period it starts
from 4s1 and complete after 3d10 and 4p6.

(A) Statement-I is true, Statement-II is true

(B) Statement-I is false, Statement-II is true
(C) Statement-I is true, Statement-II is false
(D) Statement-I is false, Statement-II is false

16) Which of the following is incorrect ?

Catechol

(A)

(B)

p-Xylene

(C)

Pyrrole
Naphthalene

(D)

17) Given below are two statements, one is labelled as Assertion and the other is labelled as
Reason.
Assertion : Order of stability of carbocations is C > A > B.

Reason : Fluoro is a stronger electron withdrawing group than Chloro group.

In the light of the above statements, choose the correct answer from the options given below:

(A) Assertion is false but Reason is true

(B) Both Assertion and Reason are correct and Reason is the correct explanation of Assertion
 Both Assertion and Reason are correct but Reason is NOT the correct explanation of
(C)
Assertion
(D) Assertion is true but Reason is false

18) In the given structure, number of sp and sp2 hybridized carbon atoms present respectively are

(A) 3 and 6
(B) 3 and 5
(C) 4 and 6
(D) 4 and 5

19) Select the CORRECT shape of XeO3 molecule?

(A) T-shape
(B) Trigonal planar
(C) Pyramidal
(D) See-saw

20) Which of the following order(s) is incorrect?

(A) Cl > F > Br > I (Electron affinity)

(B) Li < Be < B < C (IE1)
(C) O > F > N (Second ionisation energy)
(D) Li+ < Na+ < K+ < Rb+ (Ionic radius)

SECTION-II

1) The number of compounds for which suffix carboxylic acid is used in its IUPAC name

(i) (ii)
(iii) HOOC – (CH2)3–COOH (iv)

(v) (vi)

2) How many of the following will show resonance

(a) (b) (c) (d) (e)

(f) (g) (h) CH2=CH–CH2–CH3 (i)

3) In sulphur estimation, 0.16 g of an organic compound gave 0.466 g of barium sulphate (BaSO4).
The mass percentage of sulphur in compound is (Given Gram atomic mass of Ba = 137 g/mol)

4) A sample of 280 ml H2O2 (aq) solution required 100 ml 0.1M KMnO4 for the complete reaction.
Calculate volume strength of H2O2 solution at 1 atm, 273 K.
2KMnO4 + 3H2SO4 + 5H2O2 K2SO4 + 2MnSO4 + 3H2O + 5O2

5) Calculate maximum number of electrons in Pd (Z = 46) which are having mℓ = 0 (mℓ = magnetic
quantum number)
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D A A B C A C D A C C A B A D B B C A A

SECTION-II

Q. 21 22 23 24 25
A. 6 1 425 4 5

PART-2 : PHYSICS

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A A B B C C C A A B A A A A B D C B D A

SECTION-II

Q. 46 47 48 49 50
A. 4 8 1 1 45

PART-3 : CHEMISTRY

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B B D C C D D B A B D B C D A D B B C B

SECTION-II

Q. 71 72 73 74 75
A. 2 5 40 1 18
 SOLUTIONS

PART-1 : MATHEMATICS

1)

Given equation is tan(3x – 2x) = 1

⇒ tanx = 1 ⇒
but at this value tan2x is underfined, hence there is no solution.

2)

3)
∴ tanA = 3λ, tanB = 4λ, tanC = 5λ
In any ΔABC tanA + tanB + tanC = tanA tanB tanC
3λ + 4λ + 5λ = 60λ3

∴ 12λ = 60λ3 ∴

tanA = , tanB = , tanC =

∴ sinA = , sinB = , sinC =

sinAsinBsinC =
Hence A and R both are true and R is a correct explanation for A.

4) Question Explanation:
Solve trigonometric equation in given interval

Concept:
Types of trigonometry equation.

Solution:
Express cos2 x in terms of sin x.

–3 is invalid
sin x = 1/3 gives two solutions in [0, π]

Final Answer: Option (2)

5)

6)

Question Explanation: Finding the sum of a sine series with angles in arithmetic
progression.

Concept: Trigonometric Identities and Periodicity.

Solution:
The given expression is:

We know that .
Therefore:

...and so on, until .

All terms from to cancel with terms from to .
Remaining terms: sin 180° and sin 360°.
Since sin 180° = 0 and sin 360° = 0, the total sum is 0 + 0 = 0.

Final Answer: 0

7)

Question Explanation: Evaluate the product of sine terms and sum of cosine terms.

Concept: Trigonometric Identities and Summation/Product Series.

Solution:
For S:

The angles are

Using symmetry: and

Since , we get
For P:

When r = 3, the term is .

The remaining terms are
Using , and

Checking Option 3:

Since S = 0, the equation holds true.

Final Answer: Option(3)

8)

Question Explanation: Evaluate the ratio of the sum and product of three tangent values.

Concept: Conditional Trigonometric Identities for .

Solution:

Since , we use the identity:

Substituting this into the given expression:

Final Answer: 1

9) (A)
f(0) < 0

k∈ϕ⇒Q

(B)
⇒ f(0).f(1) < 0
9.(1 + 2k – 6 + 9) < 0
k < –2 ⇒ S
(C)

D≥0

1.9 > 0 4(k – 3)2 – 4.9 ≥ 0

k<3 k∈R k ∈ (–∞, 0] ∪ [6, ∞)
k ∈ (–∞, 0] ⇒ P

(D)
x2 + 2(k – 3)x + 9 = 0

a.f(0) > 0 D ≥ 0

1.9 > 0 4(k – 3)2 – 4.9 ≥ 0

k>3 k∈R k ∈ (–∞, 0] ∪ [6, ∞)
k ∈ [6, ∞) ⇒ T

10)

(b – c)2 – (a – b)2 = (c – a)2 – (b – c)2

(b – c + a – b)(b – c – a + b)
= (c – a + b – c)(c – a – b + c)
⇒ (a – c)(b – c) + (a – c)(b – a)
= (b – a)(c – a) + (b – a)(c – b)
divide by (a – b)(b – c)(c – a), then

11) 2 (required sum) = (1 – 1 + 2 – 2 + .... + n – n)2 – (12 + 12 + 22 + 22+....+n2 + n2)

12)

Question Explanation: Finding the second term of an infinite G.P. using sums of terms and
their cubes.

Concept: Sum of an Infinite Geometric Progression.

Solution:
 Given — (i)

Sum of cubes: — (ii)

Substitute (i) into (ii):

Solving the quadratic:

Since |r| < 1 for convergence,

Substitute r into (i):

Second term
Final Answer: Option (1)

13) Question Explanation: We have to check nature of roots of given quadratic equation.

Concept: This question is based on nature of roots.

Solution: (x – a)2 + (x – b)2 + (x – c)2 + 4(a + b + c)x = 0

⇒ x2 – 2ax + a2 + x2 – 2bx + b2 + x2 – 2cx + c2 + 4(a + b + c)x = 0
⇒ 3x2 – 2(a + b + c)x + 4(a + b + c)x + (a2 + b2 + c2) = 0
⇒ 3x2 + 2(a + b + c)x + (a2 + b2 + c2) = 0
⇒ x2 + 2ax + a2 + x2 + 2bx + b2 + x2 + 2cx + c2 = 0
(x + a)2 + (x + b)2 + (x + c)2 = 0
no solution as a ≠ b ≠ c
∴ Imaginary roots.

Final answer: Option (2)

14)

Sum of the coefficients = 0

⇒ one root = 1 ⇒ real roots.

15) Statement-2 :

cotθ – tanθ =
Statement-1 :
cotθ + tanθ + cot2θ + tan2θ + cot4θ + tan4θ
= cotθ + (cotθ – cot2θ) + (cot2θ – cot4θ) + tan4θ
= 2cotθ + tan4θ – cot4θ
= 2cotθ – 2cot8θ
a = 2, b = –2, c = 8
a+b+c=8
Statement-1 is false

16)

17) a + b = 13 k
b + c = 11 k
c + a = 12 k
add
a + b + c = 18k
a = 7k b = 6k c = 5k

18)

19)
1– sin2x + 2sin2x = 1 – (sin2x – 2sin2x)
= 3 – (sin2x + 2cos2x)

∴
Put

t2 – 28t + 27 = 0
t = 1, 27
∴ sin2x + 2cos2x = 0, 3
⇒ 2sinx cosx + 2cos2x = 0, 3
Case-I : 2cosx(sinx + cosx) = 0
⇒ cosx = 0, tanx = –1
Case-II : 2cosx(sinx + cosx) = 3
⇒ cos2x + sin2x = 2 which is not possible from case-I general solution is

x = (2K + 1)

20)

a=1
Now use

Where

a = 1, b = 2,

21) ha = 3
hb = 3
hc = 4

22)

⇒
 ∵ ΣtanA = ΠtanA
⇒ tanA = 1, tanB = 2, tanC = 3

23)
= 13 – 23 + 33 – 43 + 53 – 63 + 73 – 83 + 93
= (13 + 23 + 33 +............+93) – 2(23 + 43 + 63 + 83)
= (13 + 23 + 33 +............+93) – 2 × 23(13 + 23 + 33 + 43)

= – 16

= 452 – 16
= 452 – 1600
= 452 – 402
= 5 × 85
= 425

24) Given

Required

=4

25)

=
=
=
= 24 – 33 + 42 = 16 – 27 + 16 = 32 – 27 = 5

PART-2 : PHYSICS
 26)

∴ [a] =
0
and [b] = L2T–2 × ML–3 × L ⇒ [b] = M1L T–2

27)

Correct answer is (A).

28)

x = 3t2 – t3
first find when v become zero

v= = 6t – 3t2 = 0
t2 – 2t = 0
t(t – 2) = 0
t = 0 or t = 2 sec
⇒ V is position between 0 to 2 sec
⇒ V is –ve after 2 sec
∴ x(0) = 0, x(2) = 12 – 8 = +4 m
x(4) = 48 – 64 = –16 m

Total path length = 12 + 12 + 16 = 40 m

29) The area under the acceleration-time graph gives change in velocity. Since particle starts
with u = 0, therefore change in velocity
= vf – vi
= vmax – 0 area under a – t graph

30) Explanation :
Relative velocity of particle 1 with respect to 2 is

Its magnitude satisfies the triangle inequality:

Hence:
• It cannot be greater than v₁ + v₂ → always true
• It can be equal to v₁ (e.g., v₂ ⟂ v₁) → option 1 false
• It cannot be smaller than | v₁ − v₂ | → option 2 false
• It can be equal to |v₂| (e.g., v₁ ⟂ v₂ and |v₁| = |v₂|) → option 4 false
Final answer: Option (3)
31)

Explanation Question: Displacement time graph is given and we have to choose the correct
graph.
Concept: This question is based on kinematics.
Solution:
From given graph

(i) from 0 < t < t0, slope of graph positive and increases i.e. velocity positive and increases.
(ii) For t > t0, slope of graph negative and magnitude decreases i.e. velocity is negative whose
magnitude decreases with time.
Final Answer :
option: (3)

32) Explain Question : Choose the incorrect statement if the two projectiles in vertical plane
if they are projected from the inclined plane as shown.
Concept : projectile motion on Inclined plane.
Solution : Since acceleration of both is g downward hence relative acceleration will be zero
and relative velocity will remains constant & path will be straight line as seen by other.
Final answer: option (3).

33)

T1 > T2

T1 = Mg
2T2 = Mg

T2 =

34) Correct answer is (A).

35)

Correct answer is (B)

36) Maximum common acceleration which can move blocks together

amax = = 3 m/s2
Force of friction in case of maximum acceleration

f–2=2×3
f=8N

= limiting friction = µN = × 2g = 10 N
⇒ Friction acting is f = 8 N

37)

38)

Correct answer is (A).

39) Explain Question : We need to find the average angular velocity (in rad/s) for the entire
motion depicted in the group.
Concept : This question is based on average angular velocity, kinematics.
Solution :
 ωavg =
Angular displacement is represented by the area under the angular velocity-time graph.
Area under the graph = A1 + A2 + A3

= × 16 × 12 + (41 – 16) × 12 + (50 – 41) × 12

= 96 + 300 + 54 = 450 rad

ωavg = = 9 rad/s
Final answer : 1

40) Explain the Question :

We have to choose the incorrect option (s) for a particle moving in a circle with a constant
angular speed.
Concept : This question is based on kinematics of uniform circular motion.
Solution :

Uniform angular velocity, so tangential acceleration = 0. Only centripetal acceleration

Final Answer : 2

41)

Explanation of Question: We have to find the maximum speed of projection if breaking

strength of string is given.
Concept: “This question is based on dynamics of circular motion”
Solution:

Maximum tension occur at lower most point

T – mg = mac

T – mg = T = 3mg

3mg – mg =

2mg =

Final Answer: The correct option is (4)

42)
50cos37 – 20sin37 – fr = 2 × 1
40 – 12 – fr = 2
fr = 26 N

43)

K = as2

mv2 = kinetic energy

⇒ mv2 = 2as2

Fc = =

Ft =

V2 = ⇒V=

= = .V

= . .S =

Ft = M. =
Ft = 2as

Fnet = =

44)

work = Area under the curve for displacement 1m

45)

Correct answer is (A).

46) Question Explanation: We are given that a platform rotates with constant angular
velocity and a ball with the help of rod also perform circular motion as shown we have to
calculate normal force between platform and ball.
Concept: This question is based on dynamics of circular motion.
Solution: FBD of mass 'm' on platform

Tcos30 = m(Lcos30)ω2 ....(i)

Tsin30 + N = mg
N = mg – Tsin30 ....(ii)
Putting value of T from equation (i) in (ii) we get N.
Final answer is 0.40

47)

Correct answer is 8.

48) there is relative motion

49) Explanation:
A mass m is swinging in a horizontal circle at the end of a string making 53° with the vertical.
The string is cut and the mass falls freely to the floor. We need to find the time it takes to hit
the floor.
Concept:
This question is based on projectile motion.
Solution:
ℓ = 12.5 m, θ = 53°, g = 10 m/s²
Height of mass from floor: H = ℓ (1 - cosθ) = 12.5 × (1 - 0.6) = 5.0 m
Time of fall: t = √(2H / g) = √(2 × 5 / 10) = √1 = 1.0 s
Final Answer: t = 1.0 s

50)

Correct answer is 45.

PART-3 : CHEMISTRY

51) The correct answer is option (B)

52) The correct answer is option (B)

53)

The correct answer is option (D)

54)
x x/2 x

Vol cont. = + = 33
y = 18
x = 12

55) 2 × × NA = y

3× × NA = a

56) (I)
initially 1

Finally 0

x= × 100 = 100%

(II) SO3(g) → SO2(g) +

initially 1 mole

Finally 0 1

% change =
(III) PCl5(g) → PCl3(g) + Cl2(g)
t=0 1 mole
t=t 0 1 mole 1 mole

% change =
(IV) 3C2H2 → C6H6

% change =

57) Total volume = 1 L = 1000 mL

Let 11 M H2SO4 = x mL
1 M H2SO4 = (1000 – x)
x × 11 + (1000 –x) × 1 = 1000 × 6
11x + 1000 – x = 6000
1000 + 10x = 6000
10x = 5000
x = 500 mL

58)

59)

A + 2B → E
mole = 5 6 (L.R.)
Left = 2 mole 0 3 mole
E + C → B + 2D
3 excess 3 6 mole

A + 2B → E
mole = 2 3 (L.R.)

Left = mole 0 mole

E + C → B + 2D

excess 3 mole

A + 2B → E

mole = (L.R.)

Left = 0 mole mole

E + C → B + 2D

excess 1 mole
total mole of D = 6 + 3 + 1 = 10
 60)

Let mass of CaCO3 = x g, mass of MgCO3 = (92 – x) g

CaCO3(s) —→ CaO(s) + CO2(g)

mole

0 mole mole
MgCO3(s) —→ MgO(s) + CO2(g)

mole

0 mole mole
Weight of residue =

g
x = 50 g

61)

Question Explanation : Find the total number of unshared oxygen atoms in .

Concept : Cyclic Silicate Structure and Oxygen Sharing.
Solution :

A. Identify Silicate Type: The general formula for cyclic silicates is . For n = 4, the
formula is , which represents a 4 -membered cyclic (ring) silicate.
B. Total Oxygen Count: In this molecule, there are 4 Silicon atoms and 12 Oxygen atoms in total.
C. Shared Oxygen Atoms: In a cyclic silicate, each SiO4 tetrahedron shares 2 oxygen corners with
adjacent tetrahedra to form the ring. Since there are 4 tetrahedra, the total number of shared
oxygen atoms is 4 × 1 (each shared oxygen belongs to two units) = 4 shared oxygen atoms.
D. Unshared Oxygen Atoms: Each SiO4 tetrahedron has 4 corners. If 2 are shared, then 2 are
unshared (terminal) per tetrahedron.
E. Calculation: Total unshared corners = (Number of Silicon atoms) × (Unshared corners per
unit) =4 × 2 = 8.

Final Answer : Option (D)

62) Explain Question: Identifying correct characteristics and examples of Hydrogen bonding
(Intermolecular vs Intramolecular).
Concept: Chemical Bonding (Hydrogen Bonding)
Solution:

A. (A) Correct: H-bonding requires H bonded to electronegative atoms (F, O, N).

B. (B) Incorrect: o-nitrophenol forms intramolecular H-bonds (within the same molecule); p-
nitrophenol forms intermolecular bonds.
C. (C) Incorrect: HF molecules associate via intermolecular H-bonds (...H-F...H-F...).
D. (D) & (E) Correct: H-bonding strength varies with state (Solid > Liquid > Gas) and
drastically alters boiling points and viscosity.
63)

The correct answer is option (C)

64) Explain the question:

Find the incorrect given order
Concept:
Bond energy, acidity, bond angle trends
Solution:
• C–C > Si–Si > Ge–Ge is correct as bond enthalpy decreases down the group
• Acidic strength of hydrogen halides increases down the group: H–F < H–Cl < H–Br → correct
• Acidic nature of hypohalous acids follows electronegativity: Cl–OH > Br–OH > I–OH →
correct
• Bond angles: OF₂ ≈ 103°, H₂O ≈ 104.5°, Cl₂O ≈ 111°
• Correct order should be OF₂ < H₂O < Cl₂O, so the given order is wrong
Final Answer:
Option (D)

65) 3rd and 4th period have 8 and 18 elements respectively.

66) The correct answer is option (D)

67) The correct answer is option (B)

68)
Number of sp and sp2 hybridised carbon atom are 3 and 5.

69) 3σ + 1 ℓp → sp3 pyramidal

70)
71)

The correct answer is

ii, v

72)

The correct answer is

a, b, c, e, f

73)

Mass% of S =

74) Initially
0.1 × 100 × 10–3 mole
2KMnO4 + 3H2SO4 + 5H2O2 K2SO4 + 2MnSO4 + 3H2O + SO2
no. of moles of H2O2 reacted with KMnO4

= = 0.025

Molarity of H2O2 solution =

Volume strength = 11.2 × molarity

= 11.2 ×

75) Pd = 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 4d10
9 × 2 = 18 electrons