APPENDIX C TO §1910.

1200 – ALLOCATION OF LABEL ELEMENTS

(MANDATORY)
C.1 The label for each hazardous chemical shall include the product identifier used on
the safety data sheet.

C.1.1 The labels on shipped containers shall also include the name, address, and
telephone number of the chemical manufacturer, importer, or responsible party.

C.2 The label for each hazardous chemical that is classified shall include the signal
word, hazard statement(s), pictogram(s), and precautionary statement(s) specified in C.4 for each
hazard class and associated hazard category, except as provided for in C.2.1 through C.2.4.

C.2.1 Precedence of hazard information

C.2.1.1 If the signal word “Danger” is included, the signal word “Warning” shall not
appear;

C.2.1.2 If the skull and crossbones pictogram is included, the exclamation mark pictogram
shall not appear where it is used for acute toxicity;

C.2.1.3 If the corrosive pictogram is included, the exclamation mark pictogram shall not
appear where it is used for skin or eye irritation;

C.2.1.4 If the health hazard pictogram is included for respiratory sensitization, the
exclamation mark pictogram shall not appear where it is used for skin sensitization or for skin or
eye irritation.

C.2.2 Hazard statement text

C.2.2.1 The text of all applicable hazard statements shall appear on the label, except as
otherwise specified. The information in italics shall be included as part of the hazard statement
as provided. For example: “causes damage to organs (state all organs affected) through
prolonged or repeated exposure (state route of exposure if no other routes of exposure cause the
hazard)”. Hazard statements may be combined where appropriate to reduce the information on
the label and improve readability, as long as all of the hazards are conveyed as required.

C.2.2.2 If the chemical manufacturer, importer, or responsible party can demonstrate that
all or part of the hazard statement is inappropriate to a specific substance or mixture, the
corresponding statement may be omitted from the label.

C.2.3 Pictograms

C.2.3.1 Pictograms shall be in the shape of a square set at a point and shall include a black
hazard symbol on a white background with a red frame sufficiently wide to be clearly visible. A
square red frame set at a point without a hazard symbol is not a pictogram and is not permitted
on the label.

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 C.2.3.2 One of eight standard hazard symbols shall be used in each pictogram. The eight
hazard symbols are depicted in Figure C.1. A pictogram using the exclamation mark symbol is
presented in Figure C.2, for the purpose of illustration.

Figure C.1 – Hazard Symbols and Classes

Flame Flame Over Circle Exclamation Mark Exploding Bomb

Explosives
Flammables Oxidizers Irritant Self Reactives
Self Reactives Dermal Sensitizer Organic Peroxides
Pyrophorics Acute Toxicity (harmful)
Self-heating Narcotic Effects
Emits Flammable Gas Respiratory Tract Irritation
Organic Peroxides

Corrosion Gas Cylinder Health Hazard Skull and Crossbones

Corrosives Gases Under Pressure

Carcinogen Acute Toxicity (severe)
Respiratory Sensitizer
Reproductive Toxicity
Target Organ Toxicity
Mutagenicity
Aspiration Toxicity

Figure C.2 – Exclamation Mark Pictogram

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C.2.3.3 Where a pictogram required by the Department of Transportation under Title 49
of the Code of Federal Regulations appears on a shipped container, the pictogram specified in
C.4 for the same hazard shall not appear.

C.2.4 Precautionary statement text

C.2.4.1 There are four types of precautionary statements presented, “prevention,”

“response,” “storage,” and “disposal.” The core part of the precautionary statement is presented
in bold print. This is the text, except as otherwise specified, that shall appear on the label. Where
additional information is required, it is indicated in plain text.

C.2.4.2 When a backslash or diagonal mark ( / ) appears in the precautionary statement

text, it indicates that a choice has to be made between the separated phrases. In such cases, the
chemical manufacturer, importer, or responsible party can choose the most appropriate phrase(s).
For example, “Wear protective gloves/protective clothing/eye protection/face protection” could
read “wear eye protection”.

C.2.4.3 When three full stops (…) appear in the precautionary statement text, they
indicate that all applicable conditions are not listed. For example, in “Use explosion-proof
electrical/ventilating/lighting/.../equipment”, the use of “...” indicates that other equipment may
need to be specified. In such cases, the chemical manufacturer, importer, or responsible party
can choose the other conditions to be specified.

C.2.4.4 When text in italics is used in a precautionary statement, this indicates specific
conditions applying to the use or allocation of the precautionary statement. For example, “Use
explosion-proof electrical/ventilating/lighting/.../equipment” is only required for flammable
solids “if dust clouds can occur”. Text in italics is intended to be an explanatory, conditional note
and is not intended to appear on the label.

C.2.4.5 Where square brackets ( [ ] ) appear around text in a precautionary statement,

this indicates that the text in square brackets is not appropriate in every case and should be used
only in certain circumstances. In these cases, conditions for use explaining when the text should
be used are provided. For example, one precautionary statement states: “[In case of inadequate
ventilation] wear respiratory protection.” This statement is given with the condition for use “–
text in square brackets may be used if additional information is provided with the chemical at the
point of use that explains what type of ventilation would be adequate for safe use”. This means
that, if additional information is provided with the chemical explaining what type of ventilation
would be adequate for safe use, the text in square brackets should be used and the statement
would read: “In case of inadequate ventilation wear respiratory protection.” However, if the
chemical is supplied without such ventilation information, the text in square brackets should not
be used, and the precautionary statement should read: “Wear respiratory protection.”

C.2.4.6 Precautionary statements may be combined or consolidated to save label space

and improve readability. For example, “Keep away from heat, sparks and open flame,” “Store in
a well-ventilated place” and “Keep cool” can be combined to read “Keep away from heat, sparks
and open flame and store in a cool, well-ventilated place.”

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C.2.4.7 In most cases, the precautionary statements are independent (e.g., the phrases for
explosive hazards do not modify those related to certain health hazards, and products that are
classified for both hazard classes shall bear appropriate precautionary statements for both).
Where a chemical is classified for a number of hazards, and the precautionary statements are
similar, the most stringent shall be included on the label (this will be applicable mainly to
preventive measures). An order of precedence may be imposed by the chemical manufacturer,
importer or responsible party in situations where phrases concern “Response.” Rapid action may
be crucial. For example, if a chemical is carcinogenic and acutely toxic, rapid action may be
crucial, and first aid measures for acute toxicity will take precedence over those for long-term
effects. In addition, medical attention to delayed health effects may be required in cases of
incidental exposure, even if not associated with immediate symptoms of intoxication.

C.2.4.8 If the chemical manufacturer, importer, or responsible party can demonstrate that
a precautionary statement is inappropriate to a specific substance or mixture, the precautionary
statement may be omitted from the label.

C.3 Supplementary hazard information

C.3.1 To ensure that non-standardized information does not lead to unnecessarily wide
variation or undermine the required information, supplementary information on the label is
limited to when it provides further detail and does not contradict or cast doubt on the validity of
the standardized hazard information.

C.3.2 Where the chemical manufacturer, importer, or distributor chooses to add

supplementary information on the label, the placement of supplemental information shall not
impede identification of information required by this section.

C.3.3 Where an ingredient with unknown acute toxicity is used in a mixture at a

concentration ≥ 1%, and the mixture is not classified based on testing of the mixture as a whole,
a statement that X% of the mixture consists of ingredient(s) of unknown acute toxicity is
required on the label.

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 C.4 REQUIREMENTS FOR SIGNAL WORDS, HAZARD STATEMENTS, PICTOGRAMS, AND PRECAUTIONARY
STATEMENTS

C.4.1 ACUTE TOXICITY – ORAL

(Classified in Accordance with Appendix A.1)
Pictogram
Skull and crossbones
Hazard category Signal word Hazard statement
1 Danger Fatal if swallowed
2 Danger Fatal if swallowed

Precautionary statements
Prevention Response Storage Disposal

Wash …thoroughly after handling. If swallowed: Immediately call a Store locked up. Dispose of contents/container to…
… Chemical manufacturer, importer, or poison center/doctor/… ... in accordance with
distributor to specify parts of the body to … Chemical manufacturer, importer, or local/regional/national/international
be washed after handling. distributor to specify the appropriate regulations (to be specified).
source of emergency medical advice.
Do not eat, drink or smoke when using
this product. Specific treatment (see … on this label)
… Reference to supplemental first aid
instruction.
- if immediate administration of antidote
is required.

Rinse mouth.

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 C.4.1 ACUTE TOXICITY – ORAL (CONTINUED)
(Classified in Accordance with Appendix A.1)
Pictogram
Skull and crossbones
Hazard category Signal word Hazard statement
3 Danger Toxic if swallowed

Precautionary statements
Prevention Response Storage Disposal

Wash … thoroughly after handling. If swallowed: Immediately call a Store locked up. Dispose of contents/container to...
… Chemical manufacturer, importer, or poison center/doctor/... ... in accordance with
distributor to specify parts of the body to … Chemical manufacturer, importer, or local/regional/national/international
be washed after handling. distributor to specify the appropriate regulations (to be specified).
source of emergency medical advice.
Do not eat, drink or smoke when using
this product. Specific treatment (see ... on this label)
... Reference to supplemental first aid
instruction.
- if immediate administration of antidote
is required.

Rinse mouth.

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 C.4.1 ACUTE TOXICITY – ORAL (CONTINUED)
(Classified in Accordance with Appendix A.1)
Pictogram
Exclamation mark
Hazard category Signal word Hazard statement
4 Warning Harmful if swallowed

Precautionary statements
Prevention Response Storage Disposal

Wash … thoroughly after handling. If swallowed: Call a poison Dispose of contents/container to...
… Chemical manufacturer, importer, or center/doctor/…/ if you feel unwell. ... in accordance with
distributor to specify parts of the body to … Chemical manufacturer, importer, or local/regional/national/international
be washed after handling. distributor to specify the appropriate regulations (to be specified).
source of emergency medical advice.

Do not eat, drink or smoke when using

this product. Rinse mouth.

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 C.4.2 ACUTE TOXICITY - DERMAL
(Classified in Accordance with Appendix A.1)
Pictogram
Skull and crossbones
Hazard category Signal word Hazard statement
1 Danger Fatal in contact with skin
2 Danger Fatal in contact with skin

Precautionary statements
Prevention Response Storage Disposal
Do not get in eyes, on skin, or on If on skin: Wash with plenty of Store locked up. Dispose of contents/container to...
clothing. water/... ... in accordance with
… Chemical manufacturer, importer, or local/regional/national/international
Wash … thoroughly after handling. distributor may specify a cleansing agent regulations (to be specified).
… Chemical manufacturer, importer, or if appropriate, or may recommend an
distributor to specify parts of the body to alternative agent in exceptional cases if
be washed after handling. water is clearly inappropriate.

Do not eat, drink or smoke when using Immediately call a poison

this product. center/doctor/…
… Chemical manufacturer, importer, or
distributor to specify the appropriate
Wear protective gloves/protective
source of emergency medical advice.
clothing.
Chemical manufacturer, importer, or
distributor to specify type of equipment. Specific treatment (see ... on this label)
... Reference to supplemental first aid
instruction.
- if immediate measures such as specific
cleansing agent is advised.

Take off immediately all contaminated

clothing and wash it before reuse.

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 C.4.2 ACUTE TOXICITY – DERMAL (CONTINUED)
(Classified in Accordance with Appendix A.1)
Pictogram
Skull and crossbones
Hazard category Signal word Hazard statement
3 Danger Toxic in contact with skin

Precautionary statements
Prevention Response Storage Disposal
Wear protective gloves/protective If on skin: Wash with plenty of Store locked up. Dispose of contents/container to...
clothing. water/… ... in accordance with
Chemical manufacturer, importer, or … Chemical manufacturer, importer, or local/regional/national/international
distributor to specify type of equipment. distributor may specify a cleansing agent regulations (to be specified).
if appropriate, or may recommend an
alternative agent in exceptional cases if
water is clearly inappropriate.

Call a poison center/doctor/…/if you

feel unwell.
… Chemical manufacturer, importer, or
distributor to specify the appropriate
source of emergency medical advice.

Specific treatment (see ... on this label)

... Reference to supplemental first aid
instruction.
- if measures such as specific cleansing
agent is advised.

Take off immediately all contaminated

clothing and wash it before reuse.

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 C.4.2 ACUTE TOXICITY – DERMAL (CONTINUED)
(Classified in Accordance with Appendix A.1)
Pictogram
Exclamation mark
Hazard category Signal word Hazard statement
4 Warning Harmful in contact with skin

Precautionary statements
Prevention Response Storage Disposal
Wear protective gloves/protective If on skin: Wash with plenty of water... Dispose of contents/container to...
clothing. … Chemical manufacturer, importer, or ... in accordance with
Chemical manufacturer, importer, or distributor may specify a cleansing agent local/regional/national/international
distributor to specify type of equipment. if appropriate, or may recommend an regulations (to be specified).
alternative agent in exceptional cases if
water is clearly inappropriate.

Call a poison center/doctor/…/if you

feel unwell.
… Chemical manufacturer, importer, or
distributor to specify the appropriate
source of emergency medical advice.

Specific treatment (see ... on this label)

... Reference to supplemental first aid
instruction.
- if measures such as specific cleansing
agent is advised.

Take off contaminated clothing and

wash it before reuse.

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 C.4.3 ACUTE TOXICITY - INHALATION
(Classified in Accordance with Appendix A.1)
Pictogram
Skull and crossbones
Hazard category Signal word Hazard statement
1 Danger Fatal if inhaled
2 Danger Fatal if inhaled

Precautionary statements
Prevention Response Storage Disposal

Do not breathe dust/fume/gas/mist/ If inhaled: Remove person to fresh air Store in a well- Dispose of contents/container to...
vapors/spray. and keep comfortable for breathing. ventilated place. Keep ... in accordance with
Chemical manufacturer, importer, or container tightly local/regional/national/international
distributor to specify applicable closed. regulations (to be specified).
Immediately call a poison
conditions. - if product is volatile
center/doctor…
as to generate
… Chemical manufacturer, importer, or
hazardous atmosphere.
Use only outdoors or in a well- distributor to specify the appropriate
ventilated area. source of emergency medical advice.
Store locked up.
[In case of inadequate ventilation] Specific treatment is urgent (see ... on
Wear respiratory protection. this label)
Chemical manufacturer, importer, or ... Reference to supplemental first aid
distributor to specify equipment. instruction.
- Text in square brackets may be used if - if immediate administration of
additional information is provided with antidote is required.
the chemical at the point of use that
explains what type of ventilation would
be adequate for safe use.

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 C.4.3 ACUTE TOXICITY – INHALATION (CONTINUED)
(Classified in Accordance with Appendix A.1)
Pictogram
Skull and crossbones
Hazard category Signal word Hazard statement
3 Danger Toxic if inhaled

Precautionary statements
Prevention Response Storage Disposal

Avoid breathing dust/fume/gas/mist/ If inhaled: Remove person to fresh air Store in a well- Dispose of content/container to…
vapors/spray. and keep comfortable for breathing. ventilated place. Keep … in accordance with
Chemical manufacturer, importer, or container tightly local/regional/national/international
distributor to specify applicable closed. regulations (to be specified).
Call a poison center/doctor/...
conditions. - if product is volatile
… Chemical manufacturer, importer, or
so as to generate
distributor to specify the appropriate
hazardous atmosphere.
Use only outdoors or in a well- source of emergency medical advice.
ventilated area.
Store locked up.
Specific treatment (see ... on this label)
... Reference to supplemental first aid
instruction.
- if immediate specific measures are
required.

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 C.4.3 ACUTE TOXICITY – INHALATION (CONTINUED)
(Classified in Accordance with Appendix A.1)
Pictogram
Exclamation mark
Hazard category Signal word Hazard statement
4 Warning Harmful if inhaled

Precautionary statements
Prevention Response Storage Disposal

Avoid breathing dust/fume/gas/mist/ If inhaled: Remove person to fresh air

vapors/spray. and keep comfortable for breathing.
Chemical manufacturer, importer, or
distributor to specify applicable
Call a poison center/doctor/…/if you
conditions.
feel unwell.
… Chemical manufacturer, importer, or
Use only outdoors or in a well- distributor to specify the appropriate
ventilated area. source of emergency medical advice.

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 C.4.4 SKIN CORROSION/IRRITATION
(Classified in Accordance with Appendix A.2)
Pictogram
Corrosion
Hazard category Signal word Hazard statement
1A to 1C Danger Causes severe skin burns and eye damage

Precautionary statements
Prevention Response Storage Disposal
Do not breathe dusts or mists. If swallowed: Rinse mouth. Do NOT induce vomiting. Store Dispose of contents/container
- if inhalable particles of dusts or locked to...
mists may occur during use. If on skin (or hair): Take off immediately all contaminated up. ... in accordance with
clothing. Rinse skin with water/shower. local/regional/national/internatio
Wash …thoroughly after nal regulations (to be specified).
handling. Wash contaminated clothing before reuse.
…Chemical manufacturer,
importer, or distributor to specify
If inhaled: Remove person to fresh air and keep comfortable for
parts of the body to be washed
breathing.
after handling.

Immediately call a poison center/doctor/…

Wear protective … Chemical manufacturer, importer, or distributor to specify the
gloves/protective clothing/eye appropriate source of emergency medical advice.
protection/face protection.
Chemical manufacturer, importer,
or distributor to specify type of Specific treatment (see ... on this label)
equipment. ... Reference to supplemental first aid instruction.
- Manufacturer, importer, or distributor may specify a cleansing
agent if appropriate.

If in eyes: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

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 C.4.4 SKIN CORROSION/IRRITATION (CONTINUED)
(Classified in Accordance with Appendix A.2)
Pictogram
Exclamation mark
Hazard category Signal word Hazard statement
2 Warning Causes skin irritation

Precautionary statements
Prevention Response Storage Disposal

Wash … thoroughly after handling. If on skin: Wash with plenty of

… Chemical manufacturer, importer, or water/...
distributor to specify parts of the body to … Chemical manufacturer, importer, or
be washed after handling. distributor may specify a cleansing agent
if appropriate, or may recommend an
alternative agent in exceptional cases if
Wear protective gloves.
water is clearly inappropriate.
Chemical manufacturer, importer, or
distributor to specify type of equipment.
Specific treatment (see ... on this label)
... Reference to supplemental first aid
instruction.
- Manufacturer, importer, or distributor
may specify a cleansing agent if
appropriate.

If skin irritation occurs: Get medical

advice/attention.

Take off contaminated clothing and

wash it before reuse.

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 C.4.5 EYE DAMAGE/IRRITATION
(Classified in Accordance with Appendix A.3)
Pictogram
Corrosion
Hazard category Signal word Hazard statement
1 Danger Causes serious eye damage

Precautionary statements
Prevention Response Storage Disposal

Wear eye protection/face If in eyes: Rinse cautiously with water

protection. for several minutes. Remove contact
Chemical manufacturer, importer, lenses, if present and easy to do.
or distributor to specify type of Continue rinsing.
equipment.
Immediately call a poison
center/doctor/…
… Chemical manufacturer, importer, or
distributor to specify the appropriate
source of emergency medical advice.

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 C.4.5 EYE DAMAGE/IRRITATION (CONTINUED)
(Classified in Accordance with Appendix A.3)
Pictogram
Exclamation mark
Hazard category Signal word Hazard statement
2A Warning Causes serious eye irritation

Precautionary statements
Prevention Response Storage Disposal

Wash … thoroughly after handling. If in eyes: Rinse cautiously with water

… Chemical manufacturer, importer, or for several minutes. Remove contact
distributor to specify parts of the body to lenses, if present and easy to do.
be washed after handling. Continue rinsing.

Wear eye protection/face protection. If eye irritation persists: Get medical

Chemical manufacturer, importer, or advice/attention.
distributor to specify type of equipment.

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 C.4.5 EYE DAMAGE/IRRITATION (CONTINUED)
(Classified in Accordance with Appendix A.3)
Pictogram
No Pictogram
Hazard category Signal word Hazard statement
2B Warning Causes eye irritation

Precautionary statements
Prevention Response Storage Disposal

Wash … thoroughly after handling. If in eyes: Rinse cautiously with water

… Chemical manufacturer, importer, or for several minutes. Remove contact
distributor to specify parts of the body to lenses, if present and easy to do.
be washed after handling. Continue rinsing.

If eye irritation persists: Get medical

advice/attention.

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 C.4.6 SENSITIZATION - RESPIRATORY
(Classified in Accordance with Appendix A.4)
Pictogram
Health hazard
Hazard category Signal word Hazard statement
1 (including both sub- Danger May cause allergy or asthma symptoms or breathing difficulties if
categories 1A and 1B) inhaled

Precautionary statements
Prevention Response Storage Disposal

Avoid breathing dust/fume/gas/mist/ If inhaled: If breathing is difficult, Dispose of contents/container to...

vapors/spray. remove person to fresh air and keep ... in accordance with
Chemical manufacturer, importer, or comfortable for breathing. local/regional/national/international
distributor to specify applicable regulations (to be specified).
conditions.
If experiencing respiratory symptoms:
Call a poison center/doctor/…
[In case of inadequate ventilation] … Chemical manufacturer, importer, or
wear respiratory protection. distributor to specify the appropriate
Chemical manufacturer, importer, or source of emergency medical advice.
distributor to specify equipment
- Text in square brackets may be used if
additional information is provided with
the chemical at the point of use that
explains what type of ventilation would be
adequate for safe use.

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 C.4.7 SENSITIZATION - SKIN
(Classified in Accordance with Appendix A.4)
Pictogram
Exclamation mark
Hazard category Signal word Hazard statement
1 (including both sub- Warning May cause an allergic skin reaction
categories 1A and 1B)

Precautionary statements
Prevention Response Storage Disposal

Avoid breathing dust/fume/gas/mist/ If on skin: Wash with plenty of Dispose of contents/container to...
vapors/spray. water/... ... in accordance with
Chemical manufacturer, importer, or … Chemical manufacturer, importer, or local/regional/national/international
distributor to specify applicable distributor may specify a cleansing agent regulations (to be specified).
conditions. if appropriate, or may recommend an
alternative agent in exceptional cases if
water is clearly inappropriate.
Contaminated work clothing must not
be allowed out of the workplace.
If skin irritation or rash occurs: Get
medical advice/attention.
Wear protective gloves.
Chemical manufacturer, importer, or
distributor to specify type of equipment. Specific treatment (see ... on this label)
... Reference to supplemental first aid
instruction.
- Manufacturer, importer, or distributor
may specify a cleansing agent if
appropriate.

Wash contaminated clothing before

reuse.

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 C.4.8 GERM CELL MUTAGENICITY
(Classified in Accordance with Appendix A.5)
Pictogram
Health hazard
Hazard category Signal word Hazard statement

1A and 1B Danger May cause genetic defects <...>

2 Warning Suspected of causing genetic defects <...>
(state route of exposure if no other routes of exposure cause the
hazard)
Precautionary statements
Prevention Response Storage Disposal

Obtain special instructions before use. If exposed or concerned: Get medical Store locked up. Dispose of contents/container to...
advice/attention. ... in accordance with
local/regional/national/international
Do not handle until all safety
regulations (to be specified).
precautions have been read and
understood.

Wear protective gloves/protective

clothing/eye protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment,
as required.

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 C.4.9 CARCINOGENICITY
(Classified in Accordance with Appendix A.6)
Pictogram
Health hazard
Hazard category Signal word Hazard statement
1A and 1B Danger May cause cancer <...>
2 Warning Suspected of causing cancer <...>
(state route of exposure if no other routes of exposure cause the
hazard)

Precautionary statements
Prevention Response Storage Disposal

Obtain special instructions before use. If exposed or concerned: Get medical Store locked up. Dispose of contents/container to...
advice/attention. ... in accordance with
local/regional/national/international
Do not handle until all safety
regulations (to be specified).
precautions have been read and
understood.

Wear protective gloves/protective

clothing/eye protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment,
as required.

Note: If a Category 2 carcinogen ingredient is present in the mixture at a concentration between 0.1% and 1%, information is required on the SDS for a product;
however, a label warning is optional. If a Category 2 carcinogen ingredient is present in the mixture at a concentration of ≥ 1%, both an SDS and a label is
required and the information must be included on each.

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 C.4.10 TOXIC TO REPRODUCTION
(Classified in Accordance with Appendix A.7)
Pictogram
Health hazard
Hazard category Signal word Hazard statement
1A and 1B Danger May damage fertility or the unborn child <...> <<...>>
2 Warning Suspected of damaging fertility or the unborn child <...> <<...>>
(state specific effect if known)
(state route of exposure if no other routes of exposure cause the
hazard)
Precautionary statements
Prevention Response Storage Disposal

Obtain special instructions before use. If exposed or concerned: Get medical Store locked up. Dispose of contents/container to...
advice/attention. ... in accordance with
local/regional/national/international
Do not handle until all safety
regulations (to be specified).
precautions have been read and
understood.

Wear protective gloves/protective

clothing/eye protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment,
as required.

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 C.4.10 TOXIC TO REPRODUCTION (CONTINUED)
(Classified in Accordance with Appendix A.7)
(EFFECTS ON OR VIA LACTATION)
Pictogram
No Pictogram

Hazard category Signal word Hazard statement

No designated number No signal word May cause harm to breast-fed children

(See Table A.7.1 in

Appendix A.7)

Precautionary statements
Prevention Response Storage Disposal

Obtain special instructions before use. If exposed or concerned: Get medical

advice/attention.
Do not breathe dusts or mists.
- if inhalable particles of dusts or mists
may occur during use.

Avoid contact during pregnancy/while

nursing.

Wash … thoroughly after handling.

…Chemical manufacturer, importer, or
distributor to specify parts of the body to be
washed after handling.

Do not eat, drink or smoke when using

this product.

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 C.4.11 SPECIFIC TARGET ORGAN TOXICITY (Single Exposure)
(Classified in Accordance with Appendix A.8)
Pictogram
Health hazard
Hazard category Signal word Hazard statement
1 Danger Causes damage to organs <...> <<...>>
<...> (or state all organs affected if known)
<<...>> (state route of exposure if no other routes of exposure cause
the hazard)
Precautionary statements
Prevention Response Storage Disposal

Do not breathe dust/fume/gas/mist/ If exposed: Call a poison Store locked up. Dispose of contents/container to...
vapors/spray. center/doctor/… ... in accordance with
Chemical manufacturer, importer, or … Chemical manufacturer, importer, or local/regional/national/international
distributor to specify applicable distributor to specify the appropriate regulations (to be specified).
conditions. source of emergency medical advice.

Wash …thoroughly after handling.

Specific treatment (see ... on this label)
… Chemical manufacturer, importer, or
... Reference to supplemental first aid
distributor to specify parts of the body to
instruction.
be washed after handling.
- if immediate measures are required.

Do not eat, drink or smoke when using

this product.

25
 C.4.11 SPECIFIC TARGET ORGAN TOXICITY (Single Exposure) (CONTINUED)
(Classified in Accordance with Appendix A.8)
Pictogram
Health hazard
Hazard category Signal word Hazard statement
2 Warning May cause damage to organs <...> <<...>>
<...> (or state all organs affected, if known)
<<...>> (state route of exposure if no other routes of exposure cause
the hazard)

Precautionary statements
Prevention Response Storage Disposal

Do not breathe dust/fume/gas/mist/ If exposed or concerned: Call a poison Store locked up. Dispose of contents/container to...
vapors/spray. center/doctor/… ... in accordance with
Chemical manufacturer, importer, or … Chemical manufacturer, importer, or local/regional/national/international
distributor to specify applicable distributor to specify the appropriate regulations (to be specified).
conditions. source of emergency medical advice.

Wash … thoroughly after handling.

… Chemical manufacturer, importer, or
distributor to specify parts of the body to
be washed after handling.

Do not eat, drink or smoke when using

this product.

26
 C.4.11 SPECIFIC TARGET ORGAN TOXICITY (Single Exposure) (CONTINUED)
(Classified in Accordance with Appendix A.8)
Pictogram
Exclamation mark
Hazard category Signal word Hazard statement
3 Warning May cause respiratory irritation; or
May cause drowsiness or dizziness

Precautionary statements
Prevention Response Storage Disposal

Avoid breathing dust/fume/gas/mist/ If inhaled: Remove person to fresh air Store in a well- Dispose of contents/container to...
vapors/spray. and keep comfortable for breathing. ventilated place. Keep ... in accordance with
Chemical manufacturer, importer, or container tightly local/regional/national/international
distributor to specify applicable closed. regulations (to be specified).
Call a poison center/doctor/…/if you
conditions. - if product is volatile
feel unwell.
so as to generate
… Chemical manufacturer, importer, or
hazardous atmosphere.
Use only outdoors or in a well- distributor to specify the appropriate
ventilated area. source of emergency medical advice.
Store locked up.

27
 C.4.12 SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure)
(Classified in Accordance with Appendix A.9)
Pictogram
Health hazard
Hazard category Signal word Hazard statement
1 Danger Causes damage to organs <...> through prolonged or repeated
exposure <<...>>
<...> (state all organs affected, if known)
<<...>> (state route of exposure if no other routes of exposure cause
the hazard)
Precautionary statements
Prevention Response Storage Disposal

Do not breathe dust/fume/gas/mist/ Get medical advice/attention if you feel Dispose of contents/container to...
vapors/spray. unwell. ... in accordance with
Chemical manufacturer, importer, or local/regional/national/international
distributor to specify applicable regulations (to be specified).
conditions.

Wash … thoroughly after handling.

…Chemical manufacturer, importer, or
distributor to specify parts of the body to
be washed after handling.

Do not eat, drink or smoke when using

this product.

28
 C.4.12 SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure) (CONTINUED)
(Classified in Accordance with Appendix A.9)
Pictogram
Health hazard
Hazard category Signal word Hazard statement
2 Warning May cause damage to organs <...> through prolonged or repeated
exposure <<...>>
<...> (state all organs affected, if known)
<<...>> (state route of exposure if no other routes of exposure cause
the hazard)
Precautionary statements
Prevention Response Storage Disposal

Do not breathe dust/fume/gas/mist/ Get medical advice/attention if you feel Dispose of contents/container to...
vapors/spray. unwell. ... in accordance with
Chemical manufacturer, importer, or local/regional/national/international
distributor to specify applicable regulations (to be specified).
conditions.

29
 C.4.13 ASPIRATION HAZARD
(Classified in Accordance with Appendix A.10)
Pictogram
Health hazard
Hazard category Signal word Hazard statement
1 Danger May be fatal if swallowed and enters airways

Precautionary statements
Prevention Response Storage Disposal

If swallowed: Immediately call a poison Store locked up. Dispose of contents/container to...
center/doctor/… ... in accordance with
… Chemical manufacturer, importer, or local/regional/national/international
distributor to specify the appropriate regulations (to be specified).
source of emergency medical advice.

Do NOT induce vomiting.

30
 C.4.14 EXPLOSIVES
(Classified in Accordance with Appendix B.1)
Pictogram
Exploding bomb
Hazard category Signal word Hazard statement
Unstable explosive Danger Unstable explosive

Precautionary statements
Prevention Response Storage Disposal

Obtain special instructions before use. Explosion risk in case of fire. Store ... Dispose of contents/container to ...
…in accordance with …in accordance with local/regional/
local/regional/ national/international regulations (to be
Do not handle until all safety Do NOT fight fire when fire reaches
national/international specified).
precautions have been read and explosives.
regulations (to be
understood.
specified).
Evacuate area.
Wear personal protective
equipment/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment,
as required.

31
 C.4.14 EXPLOSIVES (CONTINUED)
(Classified in Accordance with Appendix B.1)
Pictogram
Exploding bomb
Hazard category Signal word Hazard statement
Division 1.1 Danger Explosive; mass explosion hazard
Division 1.2 Danger Explosive; severe projection hazard
Division 1.3 Danger Explosive; fire, blast or projection hazard

Precautionary statements
Prevention Response Storage Disposal
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. In case of fire: Store ... Dispose of
Chemical manufacturer, importer, or distributor to specify applicable ignition evacuate area. …in accordance with contents/container to ...
source(s). local/regional/national/ … in accordance with
Explosion risk in case international local/ regional/national/
Keep wetted with... of fire. regulations (to be international regulations
… Chemical manufacturer, importer, or distributor to specify appropriate specified). (to be specified).
material. Do NOT fight fire
- if drying out increases explosion hazard, except as needed for when fire reaches
manufacturing or operating processes (e.g., nitrocellulose). explosives.

Ground/bond container and receiving equipment.

- if the explosive is electrostatically sensitive.

Do not subject to grinding/shock/…/friction.

…Chemical manufacturer, importer, or distributor to specify applicable rough
handling.

Wear face protection.

Chemical manufacturer, importer, or distributor to specify type of equipment.

Note: Unpackaged explosives or explosives repacked in packagings other than the original or similar packaging shall have the label elements assigned to
Division 1.1 unless the hazard is shown to correspond to one of the hazard categories in Appendix B.1, in which case the corresponding symbol, signal word
and/or the hazard statement shall be assigned.

32
 C.4.14 EXPLOSIVES (CONTINUED)
(Classified in Accordance with Appendix B.1)
Pictogram
Exploding bomb 1
Hazard category Signal word Hazard statement
Division 1.4 Warning Fire or projection hazard

Precautionary statements1
Prevention Response Storage Disposal
Keep away from heat/sparks/open flames/hot In case of fire: Evacuate area. Store ... Dispose of
surfaces. - No smoking. …in accordance contents/container
Chemical manufacturer, importer, or distributor to Explosion risk in case of fire. with local/regional/ to...
specify applicable ignition source(s). national/internation … in accordance with
- except if explosives are 1.4S ammunition and
al regulations (to local/regional/national/i
components thereof.
Ground/bond container and receiving equipment. be specified). nternational regulations
- if the explosive is electrostatically sensitive. (to be specified).
Do NOT fight fire when fire reaches
explosives.
Do not subject to grinding/shock/…/friction.
Chemical manufacturer, importer, or distributor to
Fight fire with normal precautions from a
specify applicable rough handling.
reasonable distance
- if explosives are 1.4S ammunition and
Wear face protection.
components thereof.
Chemical manufacturer, importer, or distributor to
specify type of equipment.

Note: Unpackaged explosives or explosives repacked in packagings other than the original or similar packaging shall have the label elements assigned to
Division 1.1 unless the hazard is shown to correspond to one of the hazard categories in Appendix B.1, in which case the corresponding symbol, signal word
and/or the hazard statement shall be assigned.1

1
Except no pictogram is required for explosives that are 1.4S small arms ammunition and components thereof. Labels for 1.4S small arms ammunition and
components shall include appropriate precautionary statements.

33
 C.4.14 EXPLOSIVES (CONTINUED)
(Classified in Accordance with Appendix B.1)
Pictogram
No pictogram
Hazard category Signal word Hazard statement
Division 1.5 Danger May mass explode in fire

Precautionary statements
Prevention Response Storage Disposal
Keep away from heat/sparks/open flames/hot In case of fire: Evacuate area. Store ... Dispose of contents/container to ...
surfaces. - No smoking. …in accordance with … in accordance with local/regional/
Chemical manufacturer, importer, or distributor to Explosion risk in case of fire. local/regional/ national/international regulations (to be
specify applicable ignition source(s). national/international specified).
regulations (to be
Do NOT fight fire when fire
Keep wetted with... specified).
reaches explosives.
… Chemical manufacturer, importer, or distributor to
specify appropriate material.
- if drying out increases explosion hazard, except
as needed for manufacturing or operating processes
(e.g., nitrocellulose).

Ground/bond container and receiving equipment

- if the explosive is electrostatically sensitive.

Do not subject to grinding/shock/…/friction.

…Chemical manufacturer, importer, or distributor to
specify applicable rough handling.

Wear face protection.

Chemical manufacturer, importer, or distributor to
specify type of equipment.

Note: Unpackaged explosives or explosives repacked in packagings other than the original or similar packaging shall have the label elements assigned to
Division 1.1 unless the hazard is shown to correspond to one of the hazard categories in Appendix B.1, in which case the corresponding symbol, signal word
and/or the hazard statement shall be assigned.

34
 C.4.14 EXPLOSIVES (CONTINUED)
(Classified in Accordance with Appendix B.1)
Pictogram
No pictogram
Hazard category Signal word Hazard statement
Division 1.6 No signal word No hazard statement

Precautionary statements
Prevention Response Storage Disposal

None assigned None assigned None assigned None assigned

Note: Unpackaged explosives or explosives repacked in packagings other than the original or similar packaging shall have the label elements assigned to
Division 1.1 unless the hazard is shown to correspond to one of the hazard categories in Appendix B.1, in which case the corresponding symbol, signal word
and/or the hazard statement shall be assigned.

35
 C.4.15 FLAMMABLE GASES
(Classified in Accordance with Appendix B.2)
Pictogram
Flame
Hazard category Signal word Hazard statement
1 Danger Extremely flammable gas

Precautionary statements
Prevention Response Storage Disposal

Keep away from heat/sparks/open Leaking gas fire: Store in well-

flames/hot surfaces. -No smoking. Do not extinguish, unless leak can be ventilated place.
Chemical manufacturer, importer, or stopped safely.
distributor to specify applicable ignition
source(s).
Eliminate all ignition sources if safe to
do so.

36
 C.4.15 FLAMMABLE GASES (CONTINUED)
(Classified in Accordance with Appendix B.2)
Pictogram
No Pictogram
Hazard category Signal word Hazard statement
2 Warning Flammable gas

Precautionary statements
Prevention Response Storage Disposal

Keep away from heat/sparks/open Leaking gas fire: Do not extinguish, Store in well-
flames/hot surfaces. -No smoking. unless leak can be stopped safely. ventilated place.
Chemical manufacturer, importer, or
distributor to specify applicable ignition
Eliminate all ignition sources if safe to
sources(s).
do so.

37
 C.4.16 FLAMMABLE AEROSOLS
(Classified in Accordance with Appendix B.3)
Pictogram
Flame
Hazard category Signal word Hazard statement
1 Danger Extremely flammable aerosol
2 Warning Flammable aerosol

Precautionary statements
Prevention Response Storage Disposal
Keep away from heat/sparks/open Protect from sunlight.
flames/hot surfaces. -No smoking. Do not expose to
Chemical manufacturer, importer, or temperatures
distributor to specify applicable ignition exceeding
sources(s). 50 ºC/122 ºF.

Do not spray on an open flame or other

ignition source.

Pressurized container: Do not pierce or

burn, even after use.

38
 C.4.17 OXIDIZING GASES
(Classified in Accordance with Appendix B.4)
Pictogram
Flame over circle
Hazard category Signal word Hazard statement
1 Danger May cause or intensify fire; oxidizer

Precautionary statements
Prevention Response Storage Disposal

Keep/Store away from In case of fire: Stop leak if safe to do so. Store in well-
clothing/…/combustible materials. ventilated place.
…Chemical manufacturer, importer, or
distributor to specify other incompatible
materials.

Keep reduction valves/valves and

fittings free from oil and grease.

39
 C.4.18 GASES UNDER PRESSURE
(Classified in Accordance with Appendix B.5)
Pictogram
Gas cylinder
Hazard category Signal word Hazard statement
Compressed gas Warning Contains gas under pressure; may explode if heated
Liquefied gas Warning Contains gas under pressure; may explode if heated
Dissolved gas Warning Contains gas under pressure; may explode if heated

Precautionary statements
Prevention Response Storage Disposal

Protect from sunlight.

Store in a well-
ventilated place.

40
 C.4.18 GASES UNDER PRESSURE (CONTINUED)
(Classified in Accordance with Appendix B.5)
Pictogram
Gas cylinder
Hazard category Signal word Hazard statement
Refrigerated liquefied gas Warning Contains refrigerated gas; may cause cryogenic burns or injury

Precautionary statements
Prevention Response Storage Disposal

Wear cold insulating gloves/face Thaw frosted parts with lukewarm Store in well-
shield/eye protection. water. Do not rub affected area. ventilated place.

Get immediate medical

advice/attention

41
 C.4.19 FLAMMABLE LIQUIDS
(Classified in Accordance with Appendix B.6)
Pictogram
Flame
Hazard category Signal word Hazard statement
1 Danger Extremely flammable liquid and vapor
2 Danger Highly flammable liquid and vapor
3 Warning Flammable liquid and vapor

Precautionary statements
Prevention Response Storage Disposal
Keep away from heat/sparks/open flames/hot surfaces.– No smoking. If on skin (or hair): Store in a well- Dispose of
Chemical manufacturer, importer, or distributor to specify applicable ignition Take off immediately ventilated place. contents/container to...
source(s). all contaminated Keep cool. … in accordance with
clothing. Rinse skin local/regional/national/
with water/shower. international regulations (to
Keep container tightly closed.
be specified).
In case of fire: Use ... to
Ground/Bond container and receiving equipment
extinguish.
- if electrostatically sensitive material is for reloading.
... Chemical
- if product is volatile so as to generate hazardous atmosphere.
manufacturer, importer,
or distributor to specify
Use explosion-proof electrical/ventilating/ appropriate media.
lighting/.../equipment. - if water increases
... Chemical manufacturer, importer, or distributor to specify other equipment. risk.

Use only non-sparking tools.

Take precautionary measures against static discharge.

Wear protective gloves/eye protection/face protection

Chemical manufacturer, importer, or distributor to specify type of equipment.

42
 C.4.19 FLAMMABLE LIQUIDS (CONTINUED)
(Classified in Accordance with Appendix B.6)
Pictogram
No Pictogram
Hazard category Signal word Hazard statement
4 Warning Combustible liquid

Precautionary statements
Prevention Response Storage Disposal
Keep away from flames and hot In case of fire: Use ... to extinguish. Store in a well- Dispose of contents/container to...
surfaces. – No smoking. ... Chemical manufacturer, importer, or ventilated place. Keep in accordance with local/regional/
distributor to specify appropriate media. cool. national/international regulations (to be
- if water increases risk. specified).
Wear protective gloves/eye
protection/face protection
Chemical manufacturer, importer, or
distributor to specify type of equipment.

43
 C.4.20 FLAMMABLE SOLIDS
(Classified in Accordance with Appendix B.7)
Pictogram
Flame
Hazard category Signal word Hazard statement
1 Danger Flammable solid
2 Warning Flammable solid

Precautionary statements
Prevention Response Storage Disposal
Keep away from heat/sparks/open In case of fire: Use ... to extinguish
flames/hot surfaces. - No smoking. ... Chemical manufacturer, importer, or
Chemical manufacturer, importer, or distributor to specify appropriate media.
distributor to specify applicable ignition - if water increases risk.
source(s).

Ground/Bond container and receiving

equipment.
- if electrostatically sensitive material is
for reloading.

Use explosion-proof
electrical/ventilating/ lighting/...
/equipment.
... Chemical manufacturer, importer, or
distributor to specify other equipment.
- if dust clouds can occur.

Wear protective gloves/eye

protection/face protection
Chemical manufacturer, importer, or
distributor to specify type of equipment.

44
 C.4.21 SELF-REACTIVE SUBSTANCES AND MIXTURES
(Classified in Accordance with Appendix B.8)
Pictogram
Exploding bomb
Hazard category Signal word Hazard statement
Type A Danger Heating may cause an explosion

Precautionary statements
Prevention Response Storage Disposal
Keep away from heat/sparks/open In case of fire: Use ... to extinguish Store in a well- Dispose of contents/container to...
flames/hot surfaces. - No smoking. ... Chemical manufacturer, importer, or ventilated place. Keep … in accordance with
Chemical manufacturer, importer, or distributor to specify appropriate media. cool. local/regional/national/international
distributor to specify applicable ignition - if water increases risk. regulations (to be specified).
source(s).
Store at temperatures
In case of fire: Evacuate area. Fight not exceeding
Keep/Store away from fire remotely due to the risk of …°C/…°F.
clothing/…/combustible materials. explosion. ... Chemical
... Chemical manufacturer, importer, or manufacturer, importer,
distributor to specify other incompatible or distributor to specify
materials. temperature.

Keep only in original container. Store away from other

materials.
Wear protective gloves/eye
protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment.

45
 C.4.21 SELF-REACTIVE SUBSTANCES AND MIXTURES (CONTINUED)
(Classified in Accordance with Appendix B.8)

Pictograms
Exploding bomb and flame
Hazard category Signal word Hazard statement
Type B Danger Heating may cause a fire or explosion

Precautionary statements
Prevention Response Storage Disposal
Keep away from heat/sparks/open In case of fire: Use ... to extinguish. Store in a well- Dispose of contents/container to...
flames/hot surfaces. - No smoking. ... Chemical manufacturer, importer, or ventilated place. Keep …in accordance with
Chemical manufacturer, importer, or distributor to specify appropriate media. cool. local/regional/national/international
distributor to specify applicable ignition - if water increases risk. regulations (to be specified).
source(s).
Store at temperatures
In case of fire: Evacuate area. Fight not exceeding
Keep/Store away from fire remotely due to the risk of …°C/…°F.
clothing/.../combustible materials. explosion. ... Chemical
... Chemical manufacturer, importer, or manufacturer, importer,
distributor to specify other incompatible or distributor to specify
materials. temperature.

Keep only in original container. Store away from other

materials.
Wear protective gloves/eye
protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment.

46
 C.4.21 SELF-REACTIVE SUBSTANCES AND MIXTURES(CONTINUED)
(Classified in Accordance with Appendix B.8)
Pictogram
Flame
Hazard category Signal word Hazard statement
Type C Danger Heating may cause a fire
Type D Danger Heating may cause a fire
Type E Warning Heating may cause a fire
Type F Warning Heating may cause a fire
Precautionary statements
Prevention Response Storage Disposal
Keep away from heat/sparks/open In case of fire: Use ... to extinguish Store in a well- Dispose of contents/container to...
flames/hot surfaces. - No smoking. ... Chemical manufacturer, importer, or ventilated place. Keep …in accordance with
distributor to specify appropriate media. cool. local/regional/national/international
Chemical manufacturer, importer, or
- if water increases risk. regulations (to be specified).
distributor to specify applicable ignition
source(s). Store at temperatures
not exceeding
…°C/…°F.
Keep/Store away from
...Chemical
clothing/…/combustible materials.
manufacturer, importer,
…Chemical manufacturer, importer, or
or distributor to specify
distributor to specify other incompatible
temperature.
materials.

Store away from other

Keep only in original container.
materials.

Wear protective gloves/eye

protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment.

47
 C.4.22 PYROPHORIC LIQUIDS
(Classified in Accordance with Appendix B.9)
Pictogram
Flame
Hazard category Signal word Hazard statement
1 Danger Catches fire spontaneously if exposed to air

Precautionary statements
Prevention Response Storage Disposal
Keep away from heat/sparks/open If on skin: Immerse in cool water/wrap Store contents under
flames/hot surfaces. - No smoking. with wet bandages ...
Chemical manufacturer, importer, or ... Chemical
distributor to specify applicable ignition manufacturer, importer,
In case of fire: Use ... to extinguish
sources(s). or distributor to specify
... Chemical manufacturer, importer, or
appropriate liquid or
distributor to specify appropriate media.
inert gas.
Do not allow contact with air. - if water increases risk.

Wear protective gloves/eye

protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment.

48
 C.4.23 PYROPHORIC SOLIDS
(Classified in Accordance with Appendix B.10)
Pictogram
Flame
Hazard category Signal word Hazard statement
1 Danger Catches fire spontaneously if exposed to air

Precautionary statements
Prevention Response Storage Disposal
Keep away from heat/sparks/open Brush off loose particles from skin. Store contents under
flames/hot surfaces. - No smoking. Immerse in cool water/wrap in wet ...
Chemical manufacturer, importer, or bandages. …Chemical
distributor to specify applicable ignition manufacturer, importer,
source(s). or distributor to specify
In case of fire: Use ... to extinguish
appropriate liquid or
... Chemical manufacturer, importer, or
inert gas.
Do not allow contact with air. distributor to specify appropriate media.
- if water increases risk.
Wear protective gloves/eye
protection/face protection
Chemical manufacturer, importer, or
distributor to specify type of equipment.

49
 C.4.24 SELF-HEATING SUBSTANCES AND MIXTURES
(Classified in Accordance with Appendix B.11)
Pictogram
Flame
Hazard category Signal word Hazard statement
1 Danger Self-heating; may catch fire
2 Warning Self-heating in large quantities; may catch fire

Precautionary statements
Prevention Response Storage Disposal
Keep cool. Protect from sunlight. Maintain air gap
between stacks/pallets.
Wear protective gloves/eye
protection/face protection. Store bulk masses
Chemical manufacturer, importer, or greater than …
distributor to specify type of equipment. kg/…lbs at
temperatures not
exceeding …°C/…°F.
... Chemical
manufacturer, importer,
or distributor to specify
mass and temperature.

Store away from other

materials.

50
 C.4.25 SUBSTANCES AND MIXTURES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES
(Classified in Accordance with Appendix B.12)
Pictogram
Flame
Hazard category Signal word Hazard statement
1 Danger In contact with water releases flammable gases, which may ignite
spontaneously
2 Danger In contact with water releases flammable gas

Precautionary statements
Prevention Response Storage Disposal
Do not allow contact with water. Brush off loose particles from skin and Store in a dry place. Dispose of contents/container to...
immerse in cool water/wrap in wet Store in a closed …in accordance with
bandages. container. local/regional/national/ international
Handle under inert gas. Protect from
regulations (to be specified).
moisture.
In case of fire: Use ... to extinguish
... Chemical manufacturer, importer, or
Wear protective gloves/eye
distributor to specify appropriate media.
protection/face protection.
- if water increases risk.
Chemical manufacturer, importer, or
distributor to specify type of equipment.

51
 C.4.25 SUBSTANCES AND MIXTURES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES
(CONTINUED)
(Classified in Accordance with Appendix B.12)
Pictogram
Flame
Hazard category Signal word Hazard statement
3 Warning In contact with water releases flammable gas

Precautionary statements
Prevention Response Storage Disposal
Handle under inert gas. Protect from In case of fire: Use ... to extinguish. Store in a dry place. Dispose of contents/container to...
moisture. ... Chemical manufacturer, importer, or Store in a closed ... in accordance with
distributor to specify appropriate media. container. local/regional/national/international
- if water increases risk. regulations (to be specified).
Wear protective gloves/eye
protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment.

52
 C.4.26 OXIDIZING LIQUIDS
(Classified in Accordance with Appendix B.13)
Pictogram
Flame over circle
Hazard category Signal word Hazard statement
1 Danger May cause fire or explosion; strong oxidizer

Precautionary statements
Prevention Response Storage Disposal
Keep away from heat. If on clothing: Rinse immediately Dispose of contents/container to...
contaminated clothing and skin with …in accordance with local/regional/
plenty of water before removing national/international regulations (to be
Keep/Store away from clothing and
clothes. specified).
other combustible materials.

In case of major fire and large

Take any precaution to avoid mixing
quantities: Evacuate area. Fight fire
with combustibles/...
remotely due to the risk of explosion.
... Chemical manufacturer, importer, or
distributor to specify other incompatible
materials. In case of fire: Use ... to extinguish.
... Chemical manufacturer, importer, or
distributor to specify appropriate media.
Wear protective gloves /eye
- if water increases risk.
protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment.

Wear fire/flame resistant/retardant

clothing.

53
 C.4.26 OXIDIZING LIQUIDS (CONTINUED)
(Classified in Accordance with Appendix B.13)
Pictogram
Flame over circle
Hazard category Signal word Hazard statement
2 Danger May intensify fire; oxidizer
3 Warning May intensify fire; oxidizer

Precautionary statements
Prevention Response Storage Disposal
Keep away from heat. In case of fire: Use ... to extinguish. Dispose of contents/container to...
... Chemical manufacturer, importer, or …in accordance with local/regional/
distributor to specify appropriate media. national/international regulations (to be
Keep/Store away from
- if water increases risk. specified).
clothing/…/combustible materials.
…Chemical manufacturer, importer, or
distributor to specify other incompatible
materials.

Take any precaution to avoid mixing

with combustibles/...
... Chemical manufacturer, importer, or
distributor to specify other incompatible
materials.

Wear protective gloves/eye

protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment.

54
 C.4.27 OXIDIZING SOLIDS
(Classified in Accordance with Appendix B.14)
Pictogram
Flame over circle
Hazard category Signal word Hazard statement
1 Danger May cause fire or explosion; strong oxidizer

Precautionary statements
Prevention Response Storage Disposal
Keep away from heat. If on clothing: Rinse immediately Dispose of contents/container to...
contaminated clothing and skin with …in accordance with local/regional/
plenty of water before removing national/international regulations (to be
Keep away from clothing and other
clothes. specified).
combustible materials.

In case of major fire and large

Take any precaution to avoid mixing
quantities: Evacuate area. Fight fire
with combustibles/...
remotely due to the risk of explosion.
…Chemical manufacturer, importer, or
distributor to specify other incompatible
materials. In case of fire: Use ... to extinguish.
... Chemical manufacturer, importer, or
distributor to specify appropriate media.
Wear protective gloves/eye
- if water increases risk.
protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment.

Wear fire/flame resistant/retardant

clothing.

55
 C.4.27 OXIDIZING SOLIDS (CONTINUED)
(Classified in Accordance with Appendix B.14)
Pictogram
Flame over circle
Hazard category Signal word Hazard statement
2 Danger May intensify fire; oxidizer
3 Warning May intensify fire; oxidizer

Precautionary statements
Prevention Response Storage Disposal

Keep away from heat. In case of fire: Use ... to extinguish. Dispose of contents/container to...
... Chemical manufacturer, importer, or ... in accordance with
distributor to specify appropriate media. local/regional/national/international
Keep/Store away from clothing/…/
- if water increases risk. regulations (to be specified).
combustible materials.
… Chemical manufacturer, importer, or
distributor to specify incompatible
materials.

Take any precaution to avoid mixing

with combustibles/...
…Chemical manufacturer, importer, or
distributor to specify other incompatible
materials.

Wear protective gloves/eye

protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment.

56
 C.4.28 ORGANIC PEROXIDES
(Classified in Accordance with Appendix B.15)
Pictogram
Exploding bomb
Hazard category Signal word Hazard statement
Type A Danger Heating may cause an explosion

Precautionary statements
Prevention Response Storage Disposal

Keep away from heat/sparks/open Store at temperatures Dispose of contents/container to...

flames/hot surfaces.- No smoking. not exceeding ... in accordance with
Chemical manufacturer, importer, or …°C/…°F. Keep cool. local/regional/national/international
distributor to specify applicable ignition ... Chemical regulations (to be specified).
source(s). manufacturer, importer,
or distributor to specify
temperature.
Keep/Store away from
clothing/…/combustible materials.
... Chemical manufacturer, importer, or Protect from sunlight.
distributor to specify incompatible
materials.
Store away from other
materials.
Keep only in original container.

Wear protective gloves/eye

protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment.

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 C.4.28 ORGANIC PEROXIDES (CONTINUED)
(Classified in Accordance with Appendix B.15)
Pictograms
Exploding bomb and flame
Hazard category Signal word Hazard statement
Type B Danger Heating may cause a fire or explosion

Precautionary statements
Prevention Response Storage Disposal

Keep away from heat/sparks/open Store at temperatures Dispose of contents/container to...

flames/hot surfaces. - No smoking. not exceeding ... in accordance with
Chemical manufacturer, importer, or …°C/…°F. Keep cool. local/regional/national/international
distributor to specify applicable ignition Chemical manufacturer, regulations (to be specified).
source(s). importer, or distributor
to specify temperature.
Keep /Store away from
clothing/.../combustible materials. Protect from sunlight.
... Chemical manufacturer, importer, or
distributor to specify incompatible
Store away from other
materials.
materials.

Keep only in original container.

Wear protective gloves/eye

protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment.

58
 C.4.28 ORGANIC PEROXIDES (CONTINUED)
(Classified in Accordance with Appendix B.15)
Pictogram
Flame
Hazard category Signal word Hazard statement
Type C Danger Heating may cause a fire
Type D Danger Heating may cause a fire
Type E Warning Heating may cause a fire
Type F Warning Heating may cause a fire

Precautionary statements
Prevention Response Storage Disposal

Keep away from heat/sparks/open Store at temperatures Dispose of contents/container to...

flames/hot surfaces. - No smoking. not exceeding ... in accordance with
Chemical manufacturer, importer, or …°C/…°F. Keep cool. local/regional/national/international
distributor to specify applicable ignition ... Chemical regulations (to be specified).
source(s). manufacturer, importer,
or distributor to specify
temperature.
Keep/Store away from clothing/.../
combustible materials
... Chemical manufacturer, importer, or Protect from sunlight.
distributor to specify incompatible
materials.
Store away from other
materials.
Keep only in original container.

Wear protective gloves/eye

protection/face protection.
Chemical manufacturer, importer, or
distributor to specify type of equipment.

59
 C.4.29 CORROSIVE TO METALS
(Classified in Accordance with Appendix B.16)
Pictogram
Corrosion
Hazard category Signal word Hazard statement
1 Warning May be corrosive to metals

Precautionary statements
Prevention Response Storage Disposal

Keep only in original container. Absorb spillage to prevent material Store in corrosive
damage. resistant/... container
with a resistant inner
liner.
... Chemical
manufacturer, importer,
or distributor to specify
other compatible
materials.

60
 C.4.30 Label elements for OSHA defined hazards
Pictogram
Flame
Hazard Signal word Hazard statement
Pyrophoric Gas Danger Catches fire spontaneously if exposed to air

Pictogram
No Pictogram
Hazard Signal word Hazard statement
Simple Asphyxiant Warning May displace oxygen and cause rapid suffocation

Pictogram
No Pictogram
Hazard Signal word Hazard statement
Combustible Dust 2 Warning May form combustible dust concentrations in air

2
The chemical manufacturer or importer shall label chemicals that are shipped in dust form, and present a combustible dust hazard in that form when used
downstream, under paragraph (f)(1); 2) the chemical manufacturer or importer shipping chemicals that are in a form that is not yet a dust must provide a label
to customers under paragraph (f)(4) if, under normal conditions of use, the chemicals are processed in a downstream workplace in such a way that they present
a combustible dust hazard; and 3) the employer shall follow the workplace labeling requirements under paragraph (f)(6) where combustible dust hazards are
present.

61