26-07-2026

2701CJA101002260009 JA

PART-1 : PHYSICS

SECTION - I(i)

1) A vector makes an angle of 60º with X-axis and 120° with Z-Axis. Find its angle with Y-Axis.

(A) 45°
(B) 60°
(C) 0°
(D) 90°

2) Two vectors and have equal magnitudes. The magnitude of is equal to n times the
magnitude of , then the angle between and is :-

(A)

(B)

(C)

(D)

3) Find vector which is perpendicular to both vectors and and having magnitude
.

(A)
(B)
(C)
(D)

4) A body starts from rest at time t = 0, the acceleration-time graph is shown in figure.

The maximum velocity attained by the body will be:

(A) 110 m/s
(B) 55 m/s
(C) 650 m/s
(D) 550 m/s

5)

A small block slides, without friction, down an inclined plane starting from rest. Let sn be the

distance travelled from. to t = n. Then is

(A)

(B)

(C)

(D)

6) The velocity-displacement graph of a particle moving along a straight line is shown. The most
suitable acceleration-displacement graph will be:

(A)

(B)

(C)

(D)

SECTION - I(ii)

1) A ball is dropped from a building. Somewhere down it crosses a window of length 4 m in 0.5 sec.
Speed of ball at top of window is v1 and at bottom v2, then choose the CORRECT option(s)
 :-

(A)
(B)

(C)

(D)

2) If velocity of the particle is given by , where x denotes the position of the particle and
initially particle was at x = 4 m, then which of the following are correct.

(A) At t = 2 s, the position of the particle is at x = 9 m

(B) Particle acceleration at t = 2 s is 1 m/s2
(C) Particle acceleration is 1/2 m/s2 through out the motion
(D) Particle will never go in negative direction from its starting position

3) The motion of a body is given by the equation , where v is speed in m s-1 and t is in
second. If body was at rest at t = 0, then

(A) the speed varies with the time as

(B) the terminal speed is 1.0 m s-1
(C) the magnitude of the initial acceleration is 2.0 m s-2
(D) the speed is 1 ms-1 when the acceleration is half the initial value.

4) A particle moves with an initial velocity v0 and retardation βv, where v is its velocity at any time t
(β is a positive constant).

(A) the particle will cover a total distance of

(B) the particle will continue to move for a very long time.
(C) the particle will stop shortly.
(D) the velocity of particle will become v0/2 after time 1/β.

5) A particle moving along a straight line with uniform acceleration has velocities 7 m/s at A and 17
m/s at C. B is the mid point of AC. Then

(A) The velocity at B is 12 m/s.

(B) The average velocity between A and B is 10 m/s.
(C) The ratio of the time to go from A to B to that from B to C is 3 : 2.
(D) The average velocity between B and C is 15 m/s.

6) A car has to cover a distance of 400 m along a straight line starting from rest and stopping at the
end. The maximum acceleration and deceleration the car can attain both have magnitude equal to 1
m/s², and the car can attain a maximum speed of 30 m/s. Car has to complete its journey in shortest
time, then :-
(A)

Velocity–time graph of car is

Velocity–time graph of car is

(B)

(C) The time of journey of car is 20 s.

(D) The time of journey of car is 40 s.

SECTION-II

1) If vector is perpendicular to vector , then value of a is.

2) Two vectors and are such that and are perpendicular. If units and

units is equal to :

3) The angle between and is and the magnitude of their resultant is .

The value of x is

4) The sum of magnitudes of two forces acting at a point is 16N. Their resultant is normal to the
smaller force and has a magnitude of 8N. If the magnitude of two forces are P and Q then find the

value of where Q is force of greater magnitude.

5) In the figure shown a cube of side length a. If

 , find the value of k.

6) A vector which has a magnitude 8.0 is added to a vector which lie along the x-axis. The sum
of these two vectors is a third vector which lie along the y-axis and has a magnitude that is twice the
magnitude of . If magnitude of is A, then ( × A) is equal to

PART-2 : CHEMISTRY

SECTION - I(i)

1)

Ionic mobility order for following species will be :

Ca2+(aq), Mg2+(aq), Sr+2(aq)

(A) Sr+2(aq) > Ca2+(aq) > Mg2+(aq)

(B) Ca2+(aq) > Sr2+(aq) > Mg2+
(C) Ca2+(aq) > Mg2+ > Sr+(aq)
(D) Sr+2(aq) > Mg2+(aq) > Ca+(aq)

2)

Out of Na+, Mg+2, O–2 and N–3, the pair of species showing minimum and maximum IP would be.

(A) Na+, Mg+2

(B) Mg+2, N–3
(C) N–3, Mg+2
(D) O–2, N–3

3) Maximum change in percentage s-character of bonding orbital of central atom occurs in which of
the following transformation (consider the underlined product) :

(A) BF3 + F– →
(B) NH3 + H+ →
N2O5 →
(C)

–2
(D) BeF2 → [BeF4]

4) Incorrect order of bond angle ?

(A)
(B) CH4> NH3 > H2O
(C)
(D) None of these

5)

Match the column

Column-I Column-II
(molecules) (correct about molecule)
A IF7 (θ' = 72º) 1 Number of the given bond angle (θ or θ') is = One
B NH3(θ = 107º) 2 Number of the given bond angle (θ or θ') is = Three
C SiH4(θ = 109º 28') 3 Number of the given bond angle (θ or θ') is = Six
d-orbital(s) is/are involved in hybrdisation of central
D SO2(θ = 116º) 4
atom
(A) A–3 B–4 C–1 D–2
(B) A–4 B–2 C–3 D–1
(C) A–1 B–2 C–4 D–3
(D) A–4 B–1 C–2 D–3

6) The incorrect about the dipole moment is:

(A)

(B)

(C) CCl4 = CH4

(D)

SECTION - I(ii)

1) As per Fajan's rule polarization (covalent character) will be increased by?

(A) High charge and small size cation

(B) High charge and large size anion
(C) Low charge and small size anion
(D) Low charge and large size cation

2)

Which of the following orders are correct for Sc, Y and La :-

(A) Sc < Y < La : Atomic radius order

(B) Sc < Y ≈ La : Atomic radius order
(C) Sc > Y < La : Ist ionisation energy order
(D) Sc > Y = La : Spin only magnetic moment order

3) In which of the following compounds all atoms are present in the same plane ?

(A) I3¯
(B) ICl4¯
(C) XeF4
+
(D) XeF5

4) Which of the following order of bond angle is/are incorrect ?

(A)
(B)
(C)

(D) CO2 < NH3 < CH4

5) In which of the following molecule(s) octet of central atom is expanded ?

(A) CH4
(B) SF6
(C) PCl5
(D) BeCl2

6) Which of the following is correct order of the bond angles ?

(A) NH3 > NF3

(B) PH3 > PF3
(C) H2O > OF2
(D) H2O > Cl2O

SECTION-II

1) Sum of pπ–dπ bonds in SO2(g) and SO3(g) is :

2) The number of σ and π bonds present in
HC C – CH2 – CH = CH2 are (10σ, Xπ).
Find the value of X.

3) Total number of planar molecule in which d-orbital(s) is/are use in their bonding.
SO2, SO3, XeF2, XeF4, XeF6, PH3, ICl4– , PCl5, I3–

4) Find the total number number of dπ–pπ bonds in the given molecules.
(i) SO2 (ii) SO3 (iii) CO2 (iv) NO2 (v) N2O5

5) Choose the number of correct statements(s) from the following:

(a) Ist ionisation potential of ‘B’ is higher than that of ‘Be’.
(b) Electron affinity of ‘O’ is higher than that of ‘Be’.
(c) [Ar]4s23d3 is the electronic configuration of Mn2+.
(d) IInd ionisation potential of Na > Ist ionisation potential of Na.
(e) Ist ionisation potential of N > IInd ionisation potential of N.
(f) Electronegativity of Cl > Eelectronegativity of F.
(g) C → C2+ change is called IInd ionisation potential of carbon.
(h) Energy is required to convert He → He+.
(i) Conversion of O → O2– is exothermic.

6) Number of molecules which are planar as well as polar are :

SO3, XeF2, IF3, SO2, H2O, XeF4, BF2Cl, NO2, O3, PF3

PART-3 : MATHEMATICS

SECTION - I(i)

1) The value of is

(A) 2
(B) 4
(C) 8
(D) 16

2) The incorrect statement for the equation

|x – 1| + |x – 2| + |x – 3| = k is

(A) one solution if k = 2

(B) 2 solutions if k > 4
(C) no solution if k < 1
(D) 2 solutions ∀ k < 3
3) If a, b, c ≠ 0 and belong to the set {0, 1, 2, 3, ......, 9}, then log10 is
equal to

(A) 1
(B) 2
(C) 3
(D) 4

4) If 9x + 6x = 2 × 4x, then the value of x3 + 64 will be:

(A) 30
(B) 56
(C) 64
(D) 70

5) Sum of real roots of equation

is

(A) 5

(B)
–
(C) 1
(D) 0

6) Simplified value of the expression is

(A) greater than

(B) less than

(C) greater than log4 16

(D) less than

SECTION - I(ii)

1) Let . Then N is

(A) a natural number

(B) a prime number
(C) a rational number
(D) an integer
2) If 3x = 4x – 1 then x equals

(A)

(B)

(C)

(D)

3) If 1 + 2log2(4x – 8) = 2x + 3, then-

(A) number of solutions is 1

(B) number of solutions is 2
(C) sum of all solutions is 6
(D) sum of all solutions is 2

4) Let x, y and z are three integers satisfying the system of simultaneous equations
, and .
Then which of the following option is/are correct?

(A) x + y + z = 29
(B) x + y + z = -28
(C) xy + yz + zx = 276
(D) xy + yz + zx = 275

5) If x3 + y3 = 35 and x2y + xy2 = 30 then

(A) x = 2, y = 3
(B) x = –2, y = –3
(C) x = 3, y = 2
(D) x = –1, y = –2

6) Which of the following is positive :

(A) log37
(B) log150100

(C)

(D)

SECTION-II
1)

2) Number of integral value of ' x ' satisfying is

3) Number of solutions of equation

| x – 1 | + | x + 1 | = 3 is

4) If log(x–1)9 + log9(x – 1) = 2, then the value of log10x, is

5) If log5 log5 log2 x = 0, then value of x is

6) If a3 + b3 + 3ab = 1 where a and b are positive then value of a + b is

 ANSWER KEYS

PART-1 : PHYSICS

SECTION - I(i)

Q. 1 2 3 4 5 6
A. A B B B C A

SECTION - I(ii)

Q. 7 8 9 10 11 12
A. A,B,D A,C,D A,D A,B B,C,D B,D

SECTION-II

Q. 13 14 15 16 17 18
A. 4.00 5.00 2.00 5.00 2.00 8.00

PART-2 : CHEMISTRY

SECTION - I(i)

Q. 19 20 21 22 23 24
A. A C D D B A

SECTION - I(ii)

Q. 25 26 27 28 29 30
A. A,B A A,B,C B,D B,C A,C

SECTION-II

Q. 31 32 33 34 35 36
A. 3.00 3.00 6.00 3.00 3.00 6

PART-3 : MATHEMATICS

SECTION - I(i)

Q. 37 38 39 40 41 42
A. D D D C B B

SECTION - I(ii)

Q. 43 44 45 46 47 48
A. A,B,C,D A,B,C A,D A,C A,C A,B,C
 SECTION-II

Q. 49 50 51 52 53 54
A. 890.00 9 2.00 1.00 32.00 1.00
 SOLUTIONS

PART-1 : PHYSICS

1) cos2α + cos2β + cos2γ = 1

⇒ cos2β = 1 – cos2α – cos2γ
= 1 – cos2 60° – cos2 120°

=1–

⇒ cosβ = ± ∴ β = 45°

2) Let θ be angle between vectors .

(Given)
Then,
A2 + 2AB cosθ + B2 = n2 [A2– 2AB cosθ + B2]
A2 + 2A2 cosθ + A2 = n2 [A2– 2A2 cosθ + A2]

2A2 + 2A2 cosθ = n2[2A2 – 2A2 cosθ]

(n2 + 1)cosθ = (n2 – 1)

or

3)

vector along
=

4) ANS: 55 m/s

5) Answer:
6)

7) ANSWER: A, B,D

8) ANSWER: A,C,D

9) ANSWER: A,D

10) Answer: A, B

11) ANSWER: B,C,D

12) Answer: b,d

13) ANSWER: 4.00

14) ⇒ a2 – b2 = 0
......(1)
a2 + b2 – 2 abc cosθ = (48)2 ......(2)
a2 + b2 + 2 abc cosθ = (14)2 ......(3)
= a2 = b2 = 625

15)

B=A

16)
 = tan90° = ∞
⇒ cosθ = – P/Q

P2 + Q2 + 2PQcosθ = 64

P2 + Q2 – 2PQ × = 64
P2 + Q2 – 2P2 = 64
(16 – P)2 – P2 = 64
{∵ Q2 – P2 = 64
⇒ P + Q = 16
⇒ Q = (16 – P)}
(16 – P + P)(16 – P – P) = 64
16 – 2P = 4
⇒ 2P = 12
⇒P=6N
Thus Q = 10 N

17)

k=2

18) Given = 2A
∴ A2 + (2A)2 = 82

⇒A=

PART-2 : CHEMISTRY

19)

Conceptual

20)

N–3, Mg+2
21)

23)

(P) Number of 72º bond angle = 5

(Q) Number of 107º bond angles = 3
(R) Number of 109º 28' bond angles= 6
(S) Number of 116º bond angle = 1

24)

25) Concept:
Fajan's Rules of Polarization

Solution:
Polarization occurs when a cation distorts the electron cloud of an anion. Higher
polarization leads to greater sharing of electrons, increasing the covalent character. This is
favored by a cation with high polarizing power and an anion that is easily polarizable.
Calculation:
According to Fajan's Rules, covalent character increases when:
• Cation size is small: Smaller cations have higher charge density to pull electrons.
• Anion size is large: Larger anions have valence electrons further from the nucleus,
making them easy to distort.
• Charge on ions is high: Higher positive or negative charges increase the electrostatic
forces involved in polarization.
Comparing the given options, both 1 and 2 describe conditions that increase covalent
character. However, in standard objective formats, the most fundamental driver is often
identified as the properties of the cation.

Final answer: option (1, 2)

26) Question Explanation : Determine correct trends for Sc, Y, and La

Concept: Periodic trends: atomic radius, ionization energy, magnetic moment
Solution:
• Atomic radius: Sc < Y < La (Y and La are not similar due to absence 4f electrons lanthanide
contraction is unaffected.)
Final Answer: Option (1)

27) Explain question:

Species which are planer.

Concept:
Use VSEPR theory and find Hyb and check weather all atoms lie in one plane.

Solution:
1. = Hyb = SP3d (lp = 2)
shape → Linear all are atom in one plane

3. XeF4 = Hyb = sp3d2 (lp =2)

shape = square planar all atoms Lie in one plane.

2. = Hyb Sp3d2 (lp = 2)

shape = square planar all atoms Lie in one plane.
4. = SP3d2 (lp = 1) shape = sq. pyramidal all atoms are not Lie in one plane.

Final answer: option (A, B, C)

28) Explain question:

Find correct order of bond angle of compound.
Concept:
Hybridization, VSEPR Theory.
Solution:
Bond angle ∝ % S character
If hybridization is same then

Bond angle
Bond angle order

Final Answer: Option (2) and (4)

29) SF6 and PCl5

30) NH3 = 107; NF3 = 103° more electronegative F, pull away electron from N
H2O = 104°; OF2 = 103° more electronegative F, pull away electron from O

31)

32)
 33)

CONCEPTUAL

34) SO2 has one dπ–pπ bond & SO3 has two dπ–pπ bonds.

35) b,d,h are correct.

36)

CONCEPTUAL

PART-3 : MATHEMATICS

37) ∵ log39 = 2 ⇒ 162 = 44

⇒ log444 = 4 ∴ 24 = 16

38)

39)

=
= 1010104 = 4

40) 9x + 6x = 2 × 4x

Let ,t>0
2
∴t +t–2=0
t = 1 or t = –2 (rejected)

⇒x=0
∴ x3 + 64 = 64

41) The Correct Answer is (B)

42) Expression

Now

43) N = (log223 × 3) (log225 × 3) – (log226 ×3) (log222 ×3)

= (3 + log23) (5 + log23) – (6 + log23) (2 + log23)
Let log23 = t
= (t + 3) (t + 5) – (t + 6) (t + 2)
= t2 + 8t + 15 – t2 – 8t – 12
=3

44)

CONCEPTUAL

45) 1 + 2log2(4x – 8) = 2x + 3
2log2(4x – 8) = 2x + 2
log2(4x – 8) = x + 1
4x – 8 = 2x+1
4x – 8 = 2x.21
Let 2x = t
t2 – 2t – 8 = 0
t = 4 or t = –2
⇒ 2x = 4 or 2x = – 2 (reject)
⇒x=2

46)

CONCEPTUAL

47)

x2y + xy2 = 30
⇒ xy(x + y) = 30 ...(1)
x3 + y3 = 35
⇒ (x + y)3 – 3xy(x + y) = 35
⇒ (x + y)3 – 3 × 30 = 35
⇒ (x + y)3 = 125
⇒x+y=5 ...(2)
from equation (1) and (2)
xy = 6 ...(3)
Solving the equation (2) and (3)
We get x = 2, y = 3
or x = 3, y = 2

48) If base and argument of log are on same side of unity then value of log will always be
positive.

49)

Correct Ans is 890.00

50)

Correct answer is 9

51) Question Explain:

We have to find number of solution of the given modulus equation.
Concept: This question is based on modulus equation
Solution:
Cases :-
(i) x ≤ –1 –(x – 1) – (x + 1) = 3
–2x = 3
x = –3/2
(ii) –1 < x ≤ 1 –(x – 1) + (x + 1) = 3
2≠3
x∈ϕ
(iii) x > 1 (x – 1) + (x + 1) = 3
x = 3/2
∴ 2 values of x
Final Answer: (2)

52) logx–19 = t ⇒ ⇒ t=1

⇒ logx–19 = 1 ⇒ 9=x–1
⇒ x = 10 ⇒ log10x = 1

0
53) log5 log5 log2 x = 0 ⇒ log5 log2 x = 5
⇒ log2 x = 51
⇒ log x = 5log 2 ⇒ x = 25 = 32.

54) a3 + b3 + (–1)3 = 3ab (–1)

using theorem, we can say that it is only possible when
a = b = – 1 or a + b + (–1) = 0