DAYANAND SCIENCE COLLEGE, LATUR
12th Board Level Assignment
CHEMISTRY
SOLUTIONS
DAYANAND SCIENCE COLLEGE, LATUR 2 SOLUTIONS
DAYANAND SCIENCE COLLEGE, LATUR 3 SOLUTIONS
DAYANAND SCIENCE COLLEGE, LATUR 4 SOLUTIONS
1. Write the relation between van’t Hoff factor and degree of dissociation of an electrolyte. [1]
(July 2024)
2. The normal boiling point of ethyl acetate is 77.06°C. A solution of 50 g of non-volatile solute
in 150g ethyl acetate boils at 82.60°C. Calculate molar mass of solute .[Kb = 2.77°C kg mol–1 ] [2]
(July 2024)
3. State Henry’s Law. Write four conditions for ideal solutions. [3]
(July 2024)
4. What is the molality of an aqueous solution of KBr having freezing point – 3.72°C
(Kf for water is 1.86 K kg mol–1 ) ? [1]
(Feb 2025)
5. (a)State Henry’s law
(b)Define : Osmotic pressure [2]
(Feb 2025)
6. Derive the equation of Raoult’s law for binary solution containing non-volatile solute. [2]
(Feb 2025)
7. Define the following terms :
(a)Isotonic solution
(b) Colligative properties [2]
(July 2025)
8. A mixture of benzne and toluene contains 30 % by mass of toluene. At 30°C, vapour press-
ure of pure toluene is 36.7 mm Hg and that of pure benzene is 118.2 mm Hg. Assuming that
the two liquids form ideal solutions, calculate partial pressure of each constituent in the above
solution at 30°C. [3]
(July 2025)
9. Calculate the osmotic pressure of solution containing 0.882 gm of sucrose in 300 mL of
water at 298 K.[Given : Molar mass of sucrose 342 g/mol, R = 0.08205 dm3 . atm.K–1 . m–1 ] [2]
(Feb 2026)
10. Unit of Henry’s constant is .......... [1]
(June 2026)
a) mol L–1 bar–1 b) mol L bar
c) mol L–1bar d) mol–1L–1bar–1
11. (a)State Raoult’s law
(b) Derive the relationship to determine molar mass of non volatile solute by depression of
freezing point [3]
(June 2026)
12. (a)0.01m aqueous formic acid solution freezes at – 0.021°C. Calculate its degree of
dissociation (Kf = 1.86 K. kg. mol–1) [4]
(June 2026)