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0% found this document useful (0 votes)
3 views33 pages

Solution (1)

The document contains a series of physics, chemistry, and mathematics questions, each with multiple-choice answers. It covers topics such as work and energy, potential energy, chemical bonding, and arithmetic progressions. The questions are structured to test knowledge and understanding of fundamental concepts in these subjects.

Uploaded by

shivampsankhe
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

02-08-2026

1103CJA101001260012 JA

PHYSICS

SECTION-I

1) A force F is applied on a lawn mover at an angle of 60° with the horizontal. If it moves through a
distance x, the work done by the force is:

(A) Fx/2
(B) F/2x
(C) 2Fx
(D) 2x/F

2) A body of mass 5 kg is moved up over 10 m along the line of greatest slope of a smooth inclined
plane of inclination 30° with the horizontal. If g = 10 m/s2, the work done will be :

(A) 500 J
(B) 2500 J
(C) 250 J
(D) 25 J

3) A man who is running has half the kinetic energy of the boy of half his mass. The man speeds up
by
1 m/s and then has the same kinetic energy as the boy. The original speed of the man was

(A) m/s
(B) ( – 1) m/s
(C) 2 m/s
(D) ( + 1) m/s

4) At time t = 0s particle starts moving along the x-axis. If its kinetic energy increases uniformly
with time 't', the net force acting on it must be proportional to :-

(A)
(B) constant
(C) t

(D)

5) A body of mass 2 kg is projected with an initial velocity of 5 ms–1 along a rough horizontal table.
The work done on the body by the frictional forces before it is brought to rest is:

(A) 250 J
(B) 25 J
(C) –250 J
(D) –25 J

6) A bullet fired into a trunk of a tree loses 1/4 of its kinetic energy in travelling a distance of 5 cm.
Before stopping it travels a further distance of:

(A) 150 cm
(B) 1.5 cm
(C) 1.25 cm
(D) 15 cm

7) A block of mass 4 kg slides on a horizontal frictionless surface with a speed of 2m/s. It is brought
to rest in compressing a spring in its path. If the force constant of the spring is 400 N/m, by how
much the spring will be compressed

(A) 2 × 10–2m
(B) 0.2m
(C) 20 m
(D) 200m

8) A 1 kg block situated on a rough inclined plane is connected to spring of a spring constant 100
Nm–1 as shown in figure. The block is released from rest with the spring in the unstretched position.
The block moves 10 cm down the incline before coming to rest. Find the coefficient of friction
between the block and the incline. Assume that the spring has a negligible mass and the pulley is

frictionless. (g = 10m/s2)

(A) 0.125
(B) 1.25
(C) 5.2
(D) 4.5

9) In the arrangement shown in figure , string is light and inextensible and friction is absent every
where. The speed of both blocks after the block ‘A’ has ascend a height of 1m will be (g = 10 m/s2)
(A) 2m/s
(B) 2.58m/s
(C) 3m/s
(D) 3.58 m/s

10) In a region of only gravitational field of mass 'M' a particle is shifted from A to B via three
different paths in the figure. The work done in different paths are W1, W2, W3 respectively then

(A) W1 = W2 = W3
(B) W1 = W2 > W3
(C) W1 > W2 > W3
(D) W1 < W2 < W3

11) A tank of size 10 m × 10 m × 10 m is full of water and built on the ground. If g = 10 ms–2, the
potential energy of the water in the tank is :

(A) 5 × 107J
(B) 1 × 108 J
(C) 5 × 104 J
(D) 5 × 105 J

12) Potential energy curve U of a particle as function of the position of a particle is shown. The
particle has total mechanical energy E of 3.0 joules.

(A) It can never be present at x = 0 m.


(B) It can never be present at x = 5 m
(C) At x = 2 its kinetic energy is 0 J
(D) At x = 1 its kinetic energy 3 J

13) The potential energy function for the force between two atoms in a diatomic molecule is

approximately given by U(x) = , where a and b are constant and x is the distance between
the atoms. if the dissociation energy of the molecule is D = [U(x = ∞) – Uat equilibrium], D is :

(A)

(B)

(C)

(D)

14) A body slides down a fixed curved track that is one quadrant of a circle of radius R, as in the
figure. If there is no friction and the body starts from rest, its speed at the bottom of the track is:

(A) 5gR
(B)
(C)
(D)

15) System shown in fig is released from rest with mass 2kg in contact with the ground. Pulley and
spring are massless and the friction is absent everywhere. The speed of 5kg block when 2kg block
leaves the contact with the ground is ( force constant of the spring k = 40 N/m and g = 10m/s2)
(A) m/s
(B) m/s
(C) 2 m/s
(D) 4 m/s

16) A body of mass 'm' dropped from a height 'h' reaches the ground with a speed of 0.8 . The
value of work done by the air-friction is :

(A) –0.68 mgh


(B) mgh
(C) 1.64 mgh
(D) 0.64 mgh

17) Two blocks of mass 3 kg and 6 kg respectively are placed on a smooth horizontal surface. They
are connected by a light spring of force constant k = 200 N/m. Initially the spring is unstretched.
The indicated velocities are imparted to the blocks. Find the maximum extension of the spring.

(A) 30 cm
(B) 10 cm
(C)
(D) 15 cm

18) The position of a body of mass 2 kg varies with time t as x = t2 + 2t, where x is in meters and t is
in seconds. The work done by all the forces acting on the body during the time interval [2s, 4s] is :

(A) 36 J
(B) 64 J
(C) 100 J
(D) 120 J

19) Given below are two statements :


Statement I : An object moves from position r1 to position r2 under a conservative force field .
The work done by the force is .
Statement II : Any object moving from one location to another location can follow infinite number
of paths. Therefore, the amount of work done by the object changes with the path it follows for a
conservative force.
In the light of the above statements, choose the correct answer from the options given below :

(A) Both Statement I and Statement II are true


(B) Statement I is false but Statement II is true
(C) Statement I is true but Statement II is false
(D) Both Statement I and Statement II are false

20) A spherical ball of mass 2 kg falls from a height of 10 m and is brought to rest after penetrating
10 cm into sand. The average force exerted by sand on the ball is ______N.

(A) 1980
(B) 2020
(C) 2000
(D) 1000

SECTION-II

1) Figure shows a smooth curved track terminating in a smooth horizontal part. A spring of spring
constant 25 N/m is attached at one end to a wedge fixed rigidly with the horizontal part. A 1kg mass
is released from rest at a height of 5 m on the curved track. Find the maximum compression (in m)

of the spring. (g = 10 m/s2)

2) x - t graph of a particle of mass 2kg moving on x-axis is shown in the figure. Find the net work
done (in J) by all forces on the particles from 0 to 4 seconds.

3) Power supplied to a particle of mass 2kg varies with time as P = 2t watt, t is in second. Velocity
of particle at t = 0 is 6 m/s. What is the velocity (in m/s) of particle at time t = s?

4) A particle of mass 2kg moves on a smooth horizontal plane under the action of a single force
N. Under this force it is displaced from (0,0) to (1m,1m). The initial speed of the particle
is √3 m/s and final speed is m/s. Find the value of k.

5) A point mass of 0.5 kg is moving along x-axis as x = t2 + 2t, where, x is in meters and t is in
seconds. Find the work done (in J) by all the forces acting on the body during the time interval [ 0,
2s].

CHEMISTRY

SECTION-I

1) C – C bond length is maximum in :

(A) C2H2
(B) C2H4
(C) C2H6
(D) C3H4

2) Find the maximum number of 90º identical bond angle in PCl5

(A) 4
(B) 3
(C) 6
(D) None of these

3) Among the following species, identify the isostructural pairs.

– +
(A) [NF3 , NO3 ] and [BF3, H3O ]
+ –
(B) [NF3, H3O ] and [NO3 , BF3]
(C) All are same
(D) None of these

4) In the following compound ,


, the C3 – C4 bond is of the type :

(A) sp – sp2
(B) sp3 – sp3
(C) sp3 – sp
(D) sp2 – sp3
5) The formal charge on central atom in Lewis dot structure of is equal to :-

(A) +6
(B) –2
(C) +2
(D) 0

6) Which of the following species have 10 lone pairs of electrons in their lewis dot structure?

(A)
(B)
(C)
(D) None of these

7) Molecule showing exception to lewis octet rule is

H2O,
(A)

(B) CO2, IF
(C) BCl3, XeF4
(D) PCl3, KCl

8) Which is NOT correctly matched against shape :

(A) SF4 : Tetrahedral


(B) XeO3 : Trigonal pyramidal
(C) ClF3 : Bent T-shape
(D) : Linear

9) Which of the following molecule/species has the square planner structure -

+
(A) NH4
(B) CCl4
(C) XeF4
(D) XeOF2

10) Pair of molecules or ions which are isostructural (similar molecular structure) is :


(A) CO2, I3
+
(B) PCl4 , PCl5
(C) XeO4, XeO3
+ –
(D) NO2 , NO2

11) Which of the following species have distorted octahedral structure ?


(A) XeF6
(B) PCl5
(C) BF3

(D) PF6

12) The formal charge of each O in O3 is.

(A) 0, +2, –2
(B) 0, +1, –1
(C) 0, 0, 0
(D) –1, +2, –1

13) According to VSEPR theory which of the following structure is INCORRECT ?

(A)

(B)

(C)

(D)

14)

The correct order of increasing C – O bond strength of CO, CO32–, CO2 is :

2–
(A) CO3 < CO2 < CO
2–
(B) CO2 < CO3 < CO
2–
(C) CO < CO3 < CO2
2–
(D) CO < CO2 < CO3

15) During the formation of a chemical bond:

(A) Electron-Electron repulsion becomes more than the nucleus - electron attraction
(B) Energy of the system does not change
(C) Energy increases
(D) Energy decreases

16) Which of the following overlapping results in π-bond formation?


(A)

(B)

(C)

(D)

17) In which of the following process hybridisation of the central atom changes -

(A)
(B)
(C)
(D)

18) Which of the following configuration shows second excitation state of Iodine :

(A)

(B)

(C)

(D)

19) The types of hybrid orbitals of nitrogen in respectively are expected to be

(A) sp, sp3 and sp2


(B) sp, sp2 and sp3
(C) sp2, sp and sp3
(D) sp2, sp3 and sp

20) Which is not true according to VBT

A covalent bond is formed by the overlapping of orbitals with unpaired electrons of opposite
(A)
spins.
(B) A covalent bond is formed by the over lapping of orbitals with unpaired electrons of same spin.
(C) The greater the extent of overlapping the stronger is the bond.
(D) Overlapping takes place only in the direction of maximum electron density of the orbital.

SECTION-II

1) How many molecules/ions out of following have equal number of lone pairs on central atom ?
XeF5+, SO2Cl2, NH2–, XeF4

2)
Out of given seven species, how many specie(s) is/are hypervalent?

BF3, SF4, ClF3, CH4, SiCl4, ,

3) Find the total number of compounds/species which have all the atoms in one plane.
SOF4, BF3, CH4, NH3, CH3

4) What are the total number of correct statements ?


(a) Order of electronic repulsion : lone pair - lone pair > lone pair – bond pair > bond pair – bond
pair
(b) Order of electronic repulsion : double bond - double bond < double bond – single bond < single
bond
– single bond
(c) Number of lone pair on central atom decreases, Bond angle increases
(d) Bond angle order : OF2 < OCl2 < OBr2

5) Sum of numbers of σ and π bond in toulene


Fill your answer as sum of digits till you get the single digit answer.

MATHEMATICS

SECTION-I

1) The geometric mean of two numbers is 6 and the arithmetic mean is 6.5, the numbers are :-

(A) (3, 12)


(B) (4, 9)
(C) (2, 18)
(D) (7, 6)

2) Along a road lie an odd number of stones placed at the interval of 10 mtrs. These stones have to
be assembled around the middle stone. A person can carry only one stone at a time. A man started a
job with one of the end stones by carrying them in succession. In carrying all the stones he covered a
distance of 3km. Then the total number of stones are ?

(A) 25
(B) 29
(C) 31
(D) 35

3) If the third term of an A.P. is 7 and its 7th term is 2 more than three times of its 3rd term, then sum
of its first 20 terms is -
(A) 228
(B) 74
(C) 740
(D) 1090

4) If and , then is equal to

(A)

(B) 1

(C)

(D)

5) The sum of first 20 terms of the sequence 0.7, 0.77, 0.777, ... is :-

(A)

(B)

(C)

(D)

6) The Harmonic mean of the roots of


equation x2 – 10x + 11 = 0 is

(A)

(B)

(C)

(D)

7) The sum of infinite series 1 – 3x + 5x2 – 7x3 +... ∞, |x| < 1 is equal to 2, then x is :-

(A)

(B)

(C)
(D) None of these

8) Let Tr be the rth term of an A.P. for r = 1, 2, 3, ........... If for some positive integers m, n we have
& , then Tmn equals -

(A)

(B)

(C) 1
(D) 0

9) Consider the ten numbers ar, ar2, ar3, .......... ar10. If their sum is 18 and the sum of their
reciprocals is 6 then the product of these ten numbers, is

(A) 324
(B) 343
(C) 243
(D) 729

10) If the (m + 1)th , (n +1)th & (r + 1)th terms of an AP are in GP & m, n, r are in HP, then the ratio
of the common difference to the first term of the AP is

(A)

(B)

(C)

(D) none of these

11) The quadratic equation whose roots are the A.M. and H.M. between the roots of the equation,
2x2 – 3x + 5 = 0 is -

(A) 4x2 – 25x + 10 = 0


(B) 12x2 – 49x + 30 = 0
(C) 14x2 – 12x + 35 = 0
(D) 2x2 + 3x + 5 = 0

12) If the sum of the first n natural numbers is 1/5 times the sum of the their squares, then the value
of n is -

(A) 5
(B) 6
(C) 7
(D) 8

13) If for an A.P. a1 , a2 , a3 ,.... , an ,....


a1 + a3 + a5 = – 12 and a1 a2 a3 = 8
then the value of a2 + a4 + a6 equals

(A) -12
(B) -16
(C) -18
(D) -21

14) Consider a decreasing G.P. : g1, g2, g3, ...... gn ....... such that g1 + g2 + g3 = 13 and
= 91 then which of the following does not hold?

(A) The greatest term of the G.P. is 9.


(B) 3g4 = g3
(C) g1 = 1
(D) g2 = 3

15) If a, a1, a2,.....,a10, b are in A.P. and a, g1, g2,.....g10 , b are in G.P. and h is the H.M. between a and

b, then is -

(A)

(B)

(C)

(D)

16) The sum of the first 100 terms common to the


series 17, 21, 25, ......... and 16, 21, 26, .......is

(A) 101100
(B) 111000
(C) 110010
(D) 100101

17) If the 4th, 7th and 10th terms of a G.P. be a, b, c respectively, then the relation between a, b, c is
:-

(A)
b=
(B) a2 = bc
(C) b2 = ac
(D) c2 = ab

18) If the A.M. between pth and qth terms of an A.P. is equal to the A.M. between rth and sth terms of
the same A.P., then p + q is equal to :
(A) r + s
(B) r + s – 1
(C) r + s + 1
(D) r + s – 2

19) The value of is equal to :

(A) 7770
(B) 7780
(C) 7785
(D) 7775

20) The sums of n terms of two arithmetic series are in the ratio 2n + 3 : 6n + 5, then the ratio of
their 13th terms is :

(A) 53 : 155
(B) 27 : 77
(C) 29 : 83
(D) 31 : 89

SECTION-II

1) The product of three geometric means between 4 and is

2) Given n ∈ N, p be a prime number such that np, 6n, 75 form an H.P., then the value of is

3) The product ..... to ∞ is P, then the value of P2 is equal to________.

4) If , then sum of digits in S is

5) Three numbers are in arithemetic progression whose sum is 33 and product is 792, then the
smallest number among these numbers is
ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C D D D D B A B A A A D C B A A B D B

SECTION-II

Q. 21 22 23 24 25
A. 2.00 8.00 7.00 2.00 8.00

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C C B C C C C A C A A B C A D D C C B B

SECTION-II

Q. 46 47 48 49 50
A. 2.00 3.00 2.00 3.00 9.00

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A C C C D C C C C B C D C C A C A B A

SECTION-II

Q. 71 72 73 74 75
A. 1.00 6.00 2.00 9.00 4.00
SOLUTIONS

PHYSICS

6)

Correct Answer is Option (D).

7)

Correct Answer is Option (B).

8)

Correct Answer is Option (A).

9)

Correct Answer is Option (B).

10)

Correct Answer is Option (A).

11)

Correct Answer is Option (A).

12)

Correct Answer is Option (A).

13)

Correct Answer is Option (D).

14)

Correct Answer is Option (C).

16)

Correct Answer is Option (A).


17)

Correct Answer is Option (A).

18)

x = t2 + 2t

= 2t + 2
Time interval from t = 2s to 4s
At t = 2s, vi = 2(2) + 2 = 6 m/s
At t = 4s, vf = 2(4) + 2 = 10 m/s
using work-energy theorem

wall = ΔKE = KEf – KEi =

= (2)(10)2 – (2)(6)2
= 100 – 36 = 64 J
The work done by all the force acting on the body during the time intervals [2S, 4S] is 64J

19) Statement-I : Incorrect

Correct equation is
Statement-II : Incorrect

20) (W.D.)g + (W.D.)sand = ΔK

=0
Fsand = 2(10 + 0.1) ×100 = 2020

21)

Explanation Question: Find max spring compression

Concept: (Energy conservation)


Solution: Equating the initial gravitational potential energy to the final elastic potential
energy :

Final Answer : 2m

22) vi = 1 m/s
vf =

w = Δk = = 8J.

23)

⇒ v2 = 49 ⇒ v = 7

24) W = ΔKE =
Here W =

25) Method I : Wall = ΔKE =

v2 = 6 m/s, v0 = 2 m/s

Method II : x = t2 + 2t

= 2 m/s2 = constant
so F = m(A) = 1 N = constant
so, W = F.S = (1) (8–0) = 8J

CHEMISTRY

26) Explain the Question : Find the molecule with the longest C-C bond.
Concept : This question is based on both length vs. bond order.
Solution :
(A)
(B)
(C)
(D)

Bond length
Final Answer : 3
27)

Question Explanation: The question asks for the maximum number of identical bond angles
measuring 90º present in a molecule of phosphorus pentachloride (PCl5).

Concept:
The molecular geometry of PCl5 is trigonal bipyramidal (TBP) based on VSEPR theory. This
structure has two types of positions: three equatorial positions (forming a triangle) and two
axial positions (above and below the plane).

Solution:

A. The bond angles between the equatorial chlorine atoms are 120º.
B. The bond angles between an axial chlorine atom and any of the three equatorial chlorine
atoms are 90º.
C. Since there are two axial positions and three equatorial bonds that each axial position
interacts with, there are a total of identical bond angles that measure exactly 90º.

The provided solution key in the image indicates option 3 is the correct choice, which
corresponds to the value 6.

Final Answer: Option (3)

28) Explain the question : Find isostructural pair from following.


NF3, NO3–, BF3 and H3O+
Concept : This question is based on VEPRT
Solution :
Isostructural Pair

(I) sp3 Geometry pyramidal shape.

(II) sp2 Trigonal planner

(III) sp2 Trigonal planner

(IV) sp3 Pyramidal

(I, IV) (II, III)


Option (B) is correct.
Final answer : 2
29) Explanation:
Find hybridization of C3 and C4 carbon.

Concept:
Hybridisation of hydro-carbon.

Solution:

Final Answer:
option (3) is correct.

30)

Correct Answer is Option (C).

31)

Correct Answer is Option (C).

32)

Explain the Question :


Question is asking so choose molecule which is exception of octet rule.
Concept : This question is based on octet rule.
Solution :

Final Answer : 3

33)

Correct Answer is Option (A).

34)

Correct Answer is Option (C).

35)

Question Explanation: Identify the pair of chemical species that possess the same molecular
geometry and structure.
Concept: VSEPR Theory and Molecular Geometry.
Solution: To determine if a pair is isostructural, we calculate the number of bond pairs and
lone pairs around the central atom to find the molecular shape.

A. Option 1: CO2 and (Correct)


B. : The Carbon atom has 4 valence electrons and forms two double bonds with Oxygen. It
has 0 lone pairs, resulting in a Linear geometry.
C. : The central Iodine atom has 7 valence electrons +1 from the negative charge (= 8). It forms
two single bonds with the other Iodine atoms and retains 3 lone pairs. In a trigonal
bipyramidal electron geometry, the 3 lone pairs occupy equatorial positions, making the
molecular shape Linear.

A. Option 2: PCl4+ and PCl5


B. : 4 bond pairs, 0 lone pairs. Geometry: Tetrahedral.
C. : 5 bond pairs, 0 lone pairs. Geometry: Trigonal Bipyramidal.

A. Option 3: XeO4 and XeO3


B. : 4 bond pairs, 0 lone pairs. Geometry: Tetrahedral.
C. : 3 bond pairs, 1 lone pair. Geometry: Pyramidal.

A. Option 4: and
B. : 2 bond pairs, 0 lone pairs. Geometry: Linear.
C. : 2 bond pairs, 1 lone pair. Geometry: Bent.

Final Answer: Option 1

36)

Question Explanation:
Find the species with a distorted octahedral structure.

Concept:
VSEPR theory and molecular geometry.

Solution:
Distorted Octahedral

XeF₆: Xe has 8 valence electrons. In XeF₆, there are 6 bond pairs + 1 lone pair on Xe (AX₆E).
The electron-pair arrangement is based on 7 regions, and the lone pair causes distortion, so
the structure is described as distorted octahedral.
PCl₅: AX₅, trigonal bipyramidal, not octahedral.
BF₃: AX₃, trigonal planar, not octahedral.
PF₆⁻: AX₆, perfect octahedral (no lone pair), so not distorted.

Final Answer: Option(1)

37)

Question Explanation: Question is asking about to find formal charge on all three atom in O3

Concept: This question is based on formal charge.


Solution:

Valence – Non bonding – × Bonding = Formal


electron electron electron charge

I 6 – 6 – ×2 =–1

II 6 – 2 – ×6 =+1

III 6 – 2 – ×4 =0
Hence formal charge is 0, +1, –1

The correct option is (B)

39)

Question Explanation: Question is asking about to arrange given compounds in correct


order of bond strength.
Concept: This question is based on resonance, bond parameter.
Solution:

, B.O. = 3 ;

, B.O. = 1 + 1/3 = 1.34;


O = C = O , B.O. = 2
Bond strength α bond order
Bond order CO > CO2 > CO32–
Bond strength CO > CO2 > CO32–
The correct option is (1)

40) Question Explanation: During the formation of a chemical bond:

Concept: thermodynamic approach for bond formation

Solution: During the formation of a chemical bond, atoms move into a more stable, lower-
energy state.
The potential energy of the system decreases as the electrostatic attraction between the
nucleus of one atom and the electron of another atom outweighs the repulsion forces, leading
to a net release of energy.

Final Answer: Option (4)

41)

Explanation Question: Question is asking about overlapping which results in π-bond


formation.
Concept: This question is based on VBT
Solution:

(4)

Final Answer
The correct option is (4)

42)

Question Explanation: The question asks to identify the process among the options where
the hybridization of the central atom changes during the reaction.
Concept: Hybridization is determined by the number of electron domains (bonding pairs and
lone pairs) around the central atom using VSEPR theory.

Solution:
1. : The central O atom remains hybridized (4 domains).
2. : The central N atom remains hybridized (4 domains).
3. : The central B atom changes from hybridization (3 domains) to
hybridization (4 domains).
4. : The central N atom remains hybridized (4 domains).

Final Answer: Option (3)

0
43) Ground state electronic configuration of Iodine : 5s25p55d
44)

45) Explain Question:


Identifying zero overlap and incorrect VBT postulates.

Concept:
Valence Bond Theory (VBT) Overlap Criteria

Solution:
1. Zero Overlap: Occurs when the total constructive overlap equals the total destructive
overlap due to symmetry mismatch. Along the y-axis, py is axial while dxy is non-axial; their
interaction cancels out.
2. Bonding Postulates: VBT states that a stable covalent bond requires the overlapping of
orbitals containing electrons with opposite spins to satisfy the Pauli Exclusion Principle.
Overlapping with the same spin is not permissible.
Calculation:
Question 1: Internuclear axis = y. dxy lobes are at 45° to axes. py is on the axis. Net Overlap =
0.
Question 2: Condition for bond = Unpaired electrons + Opposite spins. Option 2 states "Same
spin," which is false.

Final Answer: Option (2)

46)

Correct Answer is 2.00

47)

Correct Answer is 3.00

48)

Correct Answer is 2.00


49) Explain the question : The correct statements among following.
Concept : This question is based on VSEPR theory.
Solution :
'b' option is incorrect
The correct order is of electronic repulsion is
double bond – double bond > double bond – single bond > single bond – single bond.
Final answer : 3

50)

Question Explanation: Question is asking about to tell sum of σ bond and π bond in
Concept: This question is based on Lewis dot structure.
Solution:

σ = 15, π = 3 ⇒ 15 + 3 = 18 ⇒ 1 + 8 = 9
Final answer: (9)

MATHEMATICS

51) = 6.5 and =6

52)

Question Explanation: Finding the number of stones using Arithmetic Progression.

Concept: Sum of Arithmetic Progression (A.P.).

Solution:
Total distance: 3 km = 3000 m
Distance for first side (n stones): 10n + 2[10(n – 1) + 10(n – 2) + + 10(1)]
Distance for second side (n stones): 2[10(1) + 10(2) + + 10(n)]

Total Equation:
10n + 10n2 – 10n + 10n2 + 10n = 3000
20n2 + 10n – 3000 = 0 ⇒ 2n2 + n – 300 = 0
Solving the quadratic: (n – 12)(2n + 25) = 0 ⇒ n = 12
Total stones: 2n + 1 = 2(12) + 1 = 25

Final Answer: 25
53)

a + 2d = 7 ...(1)
T7 = 2 + 3T3
⇒ a + 6d = 2 + 3(7) = 23 ...(2)

from (1) and (2) d = 4 and a = –1

∴ = 740

54)

⇒ ⇒

55) Required sum


= 0.7 + 0.77 + 0.777 + ... upto 20 terms

= {0.9 + 0.99 + 0.999 + ... upto 20 terms}

= {(1–0.1) + (1–0.01) + (1–0.001)


+ ... upto 20 terms}

= {20–(0.1+0.01+0.001 + ... upto 20 terms}

=
=

56)

Let α, β are the roots, then


αβ = 11 and α + β = 10

Now H.M. of α, β =

57) S = 1 – 3x + 5x2 – 7x3 + ....


xS = x – 3x2 + 5x3 – .....
(1 + x)S = 1 – 2[x – x2 + x3.....]

⇒ S= = = 2 [∴ |x| < 1]
2
⇒ 2x + 5x + 1 = 0 Þ x = (–5 ± )/4

⇒ x=( – 5)/4 as > 1.

58)

Let first term is a and common difference is d.

Tm = a + (m – 1)d = ... (1)

Tn = a + (n – 1)d = ... (2)


Tmn = a + (mn – 1)d = ?
Subtract (2) from (1).

; and ;

59)

Given = 18 ....(1)

Also =6

⇒ =6

=6 ....(2)
from (1) and (2)

· 18 = 6 ⇒ a2r11 = 3
now P = a10r55 = (a2r11)5 = 35 = 243 Ans.

60)

Let a and d are first term and common difference of an A.P. respectively.
Tm + 1 = a + md
Tn + 1 = a + nd
Tr + 1 = a + rd
(a + nd)2 = (a + md)(a + rd) (Given) ... (1)

... (2)
From (1) & (2)

Let
x2 + 2nx = x(m + r) + mr

⇒ ⇒

⇒ ⇒

i.e.

61)

2x2 – 3x + 5 = 0

Let roots are α and β then ,

1st roots A.M. of α and β

2nd root H.M. of α and β

Sum of roots are

Products of root are


Now equation is

⇒ 12x2 – 49x + 30 = 0

62)

(1 + 2 + 3 + ..... + n) (12 + 22 + 32 + .... + n2)


15 = 2n + 1
2n = 14
n=7

63)

Let the 1st 5 terms of the A.P. are


a – 2d , a – d , a , a + d , a + 2d
now a1 + a3 + a5 = – 12
∴ 3a = – 12
⇒ a=–4
also a1. a2. a3 = 8
(a – 2d) ( a – d)a = 8
– 4 (– 4 – 2d) (– 4 – d) = 8 ⇒ d = – 3
Hence the A.P. is 2 , – 1 , – 4, – 7, – 10, – 13 ,......
Hence a2 + a4 + a6 = – 21 ]

64)

Let the first three terms of the G.P. be g1 = a, g2 = ar, and g3 = ar2. Since it is a decreasing G.P.,
we expect 0 < r < 1.

Divide this by the square of the first equation :

Cross-multiply to solve for

a = 3 and r = or 3 (rejected)

G.P. is 9, 3, 1, , ...... ⇒ C is not correct.

Final Answer: The correct option is (3).

65)

a1, a2, a3, ........ a10 are 10 A.M's between a and b.


g1, g2, g3 .......... g10 are 10 G.M's between a and b.
So a1 + a2 + .... + a10 = 5 (a + b)
a2 + .......... + a9 = 4 (a + b)
a3 + .......... + a8 = 3 (a + b)
a4 + .......... + a7 = 2(a + b)
a5 + a6 = (a + b)
and
g1g10 = g2g9 = g3g7 = ......... =g5g6 = ab

Now ⇒

66)

Common terms will also form an A.P.


21, 41, 61, .............., 100 terms

= 50[42 + 1980] = 101100

67) Let first term of G.P. = A and common ratio = r


We know that nth term of G.P. = Arn–1
Now t4 = a = Ar3, t7 = b = Ar6 and t10 = c = Ar9
Relation b2 = ac is true because b2 = (Ar6)2 = A2r12 and ac = (Ar3) (Ar9) = A2r12
Aliter : As we know, if p, q, r in A.P., then pth, qth, rth terms of a G.P. are always in G.P.,
therefore,
a, b, c will be in G.P. i.e. b2 = ac.

68)

Let ap= a + (p –1)d


aq = a + (q–1)d

and ar = a+(r–1)d, as = (s–1)d ⇒ AM =


⇒ p+q–2 = r+s–2 ⇒ p+q= r +s

69) =

=
= 5.(31)61 – 5.8.31 – 15.31+15.8 – 90
Final Answer: Option (2)
70)

We have

Put n = 25 then

71)

72)

73)

74) S = 3.32/2.33/4.34/8……∞

.....(1)

.....(2)
Subtract (2) from (1)

S’ =
S = 34 = 81
75) a – d + a + a +d = 33
a = 11
a(a2 – d2) = 792
11(121 – d2) = 792
d2 = 121 – 72 = 49
d = 7, – 7

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