29-03-2026

5001CJA101001252609 JA

PHYSICS

SECTION I(i)

1) From a uniform semicircular thin disc of radius R, a semicircular portion of radius R/2 is removed
and placed in a new position as shown in figure. Taking O as origin and x and y axis as shown in

figure, centre of mass of new setup is at :-

(A)

(B)

(C)

(D)

2) Consider a U-shaped smooth wire placed horizontally over which a bead of mass (m) is thrown
with speed V as shown. The bead enters semi-circular part A and leaves at B. What is the magnitude
of average force exerted by the bead on the part AB of the wire.

(A) Zero

(B)

(C)

(D)

3) A particle is moving parallel to x-axis as shown in the figure such that at all instant the y
component of its position vector is constant and is equal to 'b'. The angular velocity of the particle
about origin is :-

(A)

(B)

(C)

(D) vb

4) A force F of constant magnitude acts on a block of mass 'm' and t = 0, initially along positive x-
direction. The direction of force F starts rotating with a constant angular velocity ω in anticlockwise
sense. Then the magnitude of velocity of the block as a function of time 't' is (initially block was at
rest)

(A)

(B)

(C)

(D)

SECTION I(ii)

1) The indicator diagram for two processes 1 and 2 carrying on an ideal gas is shown in figure. W
denotes work done by gas, ΔQ is heat given to gas and T is temperature of gas. Then :

(A) Wprocess 1 > Wprocess 2

(B) Tfinal process 2 > Tfinal process 1
(C) ΔQprocess 1 > ΔQprocess 2
(D) ΔQprocess 2 > ΔQprocess 1

2)
The wires A and B shown in the figure are made of the same material, and have radii rA and
rB respectively. The block between them has a mass m. When the force F is mg/3, one of the wires
breaks–

(A) A will break before B if rA = rB

(B) A will break before B if rA < 2rB
(C) Either A or B may break if rA = 2rB
(D) The lengths of A and B must be known to predict which wire will break

3) In ordinary Vernier calipers, 10th division of the Vernier scale coincides with 9th division of the
main scale. In a specially designed Vernier calipers the Vernier scale is so constructed that 10th
division on it coincides with 11th division on the main scale. Each division on the main scale equals
to 1 mm. The calipers have a zero error as shown in the figure-I. When the Vernier caliper is used to
measure a length, the concerned portion of its scale is shown in figure-II.

(7th division on main scale is perfectly coinciding in figure-1)

(5th division on main scale is perfectly coinciding in figure-2)

(A) Zero error in the calipers has magnitude 0.7 mm

(B) The length being measured is 1.08 cm
(C) The length being measured is 1.22 cm
Though the given Vernier scale does not follow the principle of Vernier scale, yet can be used
(D)
satisfactorily.

4) Figure shows a double chambered vessel with thermally insulated walls and partitions. On each
side there are n moles of an ideal monoatomic gas. Initially the pressure, volume and temperature in
each side is The heater in first chamber supplies heat very slowly till the gas in the first
chamber expands such that the pressure, volume and temperature of the gas on the left side is

respectively and on right chamber is and T2 respectively:

(A)
Volume of first chamber is

(B)
Temperature in second chamber is
Work done on the gas in second chamber in terms of molar heat capacity at constant volume
(C)
and
Work done on the gas in first chamber in terms of molar heat capacity at constant volume and
(D)

SECTION I(iii)

1) A cylinder of weight W is floating in two liquids as shown in figure. Net force on cylinder from top
is F1 and force on cylinder from the bottom is F2. Match the following two columns.

Column - I Column - II

(a) Net force on cylinder from liquid-1 (p) Zero

(b) F2 – F1 (q) W

(c) Net force on cylinder from liquid-2 (r) Net upthrust

(d) Net force on cylinder from atmosphere (s) None of these

(A) a → r;b → p;c → r;d → p
(B) a → p;b → q;c → r;d → s
(C) a → q;b → r;c → s;d → p
(D) a → r;b → s;c → p;d → q

2) Both the particles are projected simultaneously assuming that none of the projectiles fall to
ground and the projectiles collide in air.

The relation between u and v for the

(A) (P)
projectiles to dollide

The time after which the projectiles collide is: t

(B) (Q)
= xd/v. x is:

The horizontal distance covered by A before

(C) (R)
collision is: is

(D) The speed of B relative to A is: nv. n is (S)

(A) A → Q;B → R;C → S;D → P
(B) A → R;B → S;C → P;D → Q
(C) A → S;B → R;C → P;D → Q
(D) A → P;B → R;C → S;D → Q

3) In the given diagram either spring or string is cut one at a time, answer the following immediately
after the cut.
(Example: If spring 1 is cut then it is completely removed but if cut at A then it is still attached to
ceiling, only free from '2m' mass) assume acceleration of )

Now answer the following [all springs and strings are ideal]

List-I List-II

(P) If spring is cut at point A (1) a1 = a2 = g a3 = 0,

(Q) If spring is cut at B (2) a1 = a2 = 2g ↓ a3 = 0,

 (R) If spring 2 is cut (3) a1 = 4g ↓ a2 = 2g a3 = 0,

(S) If string connectring mass m&2m is cut (4) a1 = a2 = g a3 = g ↓

(A) P → 4;Q → 3;R → 1;S → 2
(B) P → 2;Q → 4;R → 4;S → 3
(C) P → 3;Q → 2;R → 1;S → 4
(D) P → 2;Q → 1;R → 4;S → 3

SECTION II

1) Two blocks A and B are placed one over other. Block B is acted upon by a force of 20 N which
displaces it through 5 m. Find work done (in J) by frictional force on block A.

2) A string of length 1m and mass 5g is fixed at both ends. The tension in the string is 8.0 N. The
string is set into vibration using an external vibrator of frequency 100 Hz. The separation between
successive nodes on the string (in m) is close to ______ .

3) Find the acceleration of solid right circular roller (cylinder) A, weighing 12 kg when it is being
pulled by another weight B (6 kg) along the horizontal plane as in figure. The weight B is attached to
the end of a string wound around the circumference of cylinder. Assume there is no slipping of the

cylinder and the string is inextensible. Fixed pulley is massless. Find answer in the form m/s2 and

fill value of X. (g = 10 m/s2).

4) The moment of inertia of the plate in fig(a) about the about axis shown is I. The moment of inertia
of the hexagonal plate of same material shown in figure(b) about the axis given in figure(b) is 10α I,
find value of α.

5) A police car moving at 22m/s, chases a motorcyclist. The police man sounds his horn at 176Hz,
while both of them move towards a stationary siren of frequency 165Hz. Calculate the speed of the
motorcycle, if it is given that he does not observes any beats

6) The resistance , where V = (50 ± 2)V and I = (20 ± 0.2)A. The percentage error in R is 'x'
%. The value of 'x' to the nearest integer is:

CHEMISTRY

SECTION I(i)

1) 1 mole each of SO2, CH4, He, is kept in container. A hole was made in the container. After 2
minute, the order of partial pressure in the container will be -

(A)
(B)
(C)
(D)

2) Consider the ground state of Cr. The number of electron with azimuthal quantum numbers ℓ = 1
and 2 respectively are :

(A) 16 and 4
(B) 12 and 5
(C) 12 and 4
(D) 16 and 5

3) The IUPAC name of the following compound is :

(A) n-propylethanoate
(B) ethylpropanoate
(C) Pentanoic anhydride
(D) n-propylpropanoate

4) Species in which maximum number of atoms present in one plane is :-

(A) XeF4
(B)
(C) C2H4
(D) SiF4

SECTION I(ii)

1) The thermal dissociation equilibrium of CaCO3(s) is studied under different conditions.

CaCO3(s) ⇌ CaO(s) + CO2(g)
For this equilibrium, the correct statement(s) is(are)

(A) Keq. is dependent on T

(B) K is independent of the initial amount of CaCO3
(C) K is dependent on the pressure of CO2 at a given T
(D) ΔH is independent of the catalyst if any

2) If 27 g of Carbon is mixed with 88 g of Oxygen gas and is allowed to burn to produce CO2 gas as
only product , then choose the correct option(s) :

(A) Oxygen is the limiting reagent.

(B) Volume of CO2 gas produced at 0°C and 1 atm is 50.4 L.
(C) C and O combine in 3 : 8 mass ratio .
(D) Volume of unreacted O2 at 0°C and 1 atm is 11.2 L.

3) Select correct order of size :

(A) Ti2+ < Ti < Zr

(B) Ti2+ < Ti < Hf
(C) Zr2+ < Zr ≈ Hf
(D) Hf2+ < Hf ≈ Zr

4) Select incorrect order out of given options:

(A) covalent character

(B) BeO > SrO : lattice energy
(C) Hydration energy
(D) Ionic mobility

SECTION I(iii)

1) Match the following :

 List-II
List-I
(Equivalent weight
(Process)
of Cl2)

(P) (1) 71

(Q) (2) 35.5

(R) (3) 42.6

(S) (4) 7.1

(5) 8.875
(A) P → 2;Q → 4;R → 3;S → 1
(B) P → 1;Q → 3;R → 2;S → 4
(C) P → 2;Q → 4;R → 1;S → 3
(D) P → 1;Q → 3;R → 4;S → 2

2)

List-I List-II

Species Type of bond(s)

(P) O3 (1) Covalent + dative bond

(Q) NH4Cl (2) Covalent + ionic bond

(R) CO (3) Covalent + ionic + dative bond

(S) CH4 (4) Covalent only

Select the correct option
(A) P → 2;Q → 3;R → 1;S → 4
(B) P → 3;Q → 1;R → 2;S → 4
(C) P → 1;Q → 3;R → 1;S → 4
(D) P → 1;Q → 3;R → 4;S → 2

3) Which of the following is correctly matched : List-I List–II

List-I List–II

(P) —O– (1) +I, +M

(Q) (2) –I, +M

(R) —OCH3 (3) –I, –M

(S) —NO2 (4) +I, –M

(5) Only –I
(A) P → 1;Q → 5;R → 2;S → 3
(B) P → 2;Q → 3;R → 4;S → 2
(C) P → 3;Q → 4;R → 2;S → 1
(D) P → 1;Q → 4;R → 2;S → 2

SECTION II

1) For a certain orbital

– 8σ + 12) e–σ/2 ,&nbsp = constant}

The distance of nearest radial node from nucleus is xa0 while farthest radial node from nucleus is

ya0. Find&nbsp /.

2) Calculate the percentage of covalent character of HX having bond length = 1.62 Å and observed
dipole moment = 0.39 D.

3) How many of the following compound the central atom can have minimum 2 lone pair on it ?
XeF2, XeF4, ClF3, ICl3, NO3–, H2S, XeF3–

4) The total number of contributing structures showing hyperconjugation (involving C–H bonds) for

the following carbocation is.

5) Total number of groups which can show – I effect when attached to benzene ring :

(a) – OH (b) – NH2 (c)

(d) – Cl (e) (f) –OΘ

(g) –CH3 (h)

(i) (j) –C ≡ N

(k)

6) 20 ml of a mixture of C2H4 and C2H6 gases is burnt completely in excess of O2 . The volume of CO2
gas formed is :
 MATHEMATICS

SECTION I(i)

1) The sum of all possible value(s) of 'r' for which the coefficient of (2r + 3)th term is equal to the
coefficient of (r + 5)th term in the expansion of (1 + x)15 is

(A) 2
(B) 3
(C) 4
(D) 5

2)

Roots of the equation

(x – a)2 + (x – b)2 + (x – c)2 + 4(a + b + c)x = 0 are (where a ≠ b ≠ c & a,b,c ∈ R)

(A) always real
(B) imaginary
(C) real & equal
(D) can't say

3) If the quadratic polynomial ƒ(x) = x2 – 2ax + a2 + a – 3 is negative for at least one real x, then
greatest integral value of a is

(A) 1
(B) 2
(C) 3
(D) 4

4) Number of solutions of , θ ∈ [0, 2π] is equal to

(A) 2
(B) 4
(C) 5
(D) 7

SECTION I(ii)

1) If cos2x + cos22x + cos23x = 1 then -

(A)
x = (2n + 1) , n ∈ I

(B)
x = (2n + 1) , n ∈ I
(C)

(D) None of these

2) Eccentric angle of a point on the ellipse at a distance 2 units from the centre of the
ellipse is

(A)

(B)

(C)

(D)

3) The distance of a point on the ellipse x2 + 3y2 = 24 from the centre is 4. The eccentric angle of the
point is

(A)

(B)

(C)

(D)

4) Let the eccentricity of the hyperbola be reciprocal to that of the ellipse x2 + 4y2 = 4. If
the hyperbola passes through a focus of the ellipse, then -

the equation of the hyperbola is

(A)

(B) a focus of the hyperbola is (2,0)

(C)
the eccentricity of the hyperbola is
(D) the equation of the hyperbola is x2 – 3y2 = 3

SECTION I(iii)

1) Given a,b,c,d are distinct real numbers

Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

if a,b,c,d are in A.P.,

(A) (1) bc > ad
then (where a,b,c,d > 0)
 if a,b,c,d are in G.P.,
(B) (2) bc < ad
then (where a,b,c,d > 0)

if a,b,c,d are in H.P.,

(C) (3) b + c > a + d
then (where a,b,c,d > 0)

if a,b,c,d are in A.P.,

(D) (4) b + c < a + d
then (where a,b,c,d < 0)

(5) b2 + c2 < a2 + d2

(A) P → 1,5;Q → 4,5;R → 2,4,5;S → 1,5

(B) P → 1;Q → 2,4;R → 1,3;S → 1,4
(C) P → 1;Q → 2,3;R → 2,4;S → 3
(D) P → 1;Q → 1,3;R → 2,4;S → 5

2) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

If the point (a, 2) lies between

the lines x - y - 1 = 0 and 2(x -
(P) (1)
y) + 5 = 0, then complete set
of values of ‘a’ is

If the point (2a - 5, a2) is on

the same side of the line x + y
(Q) - 3 = 0 as that of the origin, (2) [0, 4]
then complete set of values of
‘a’ is

IF the point (a2, a + 1) lies in

the angle between the
lines 3x - y + 1 = 0 and x +
(R) (3)
2y - 5 = 0 containing the
origin, then complete set of
values of 'a' is

The range of values of β such

that (0, β) lies on or inside the
(S) triangle formed by the lines y (4) (-4, 2)
= 0, 4x - 3y + 12 = 0 and x +
y = 4 is
(A) P → 3;Q → 1;R → 4;S → 2
(B) P → 3;Q → 4;R → 1;S → 2
(C) P → 3;Q → 2;R → 1;S → 4
(D) P → 4;Q → 4;R → 1;S → 2

3)

List–I List-II
 (P) In the expansion of , if the number of irrational terms is λ (1) 29
then λ is greater than

(Q) If numerically greatest term in the expansion of (1 – 3x)8 for is Tr, (2) 58
then (9r + 4) is factor of

(R) The coefficient of x10 in (1 + x2 – x3)8 is K, then is greater than or (3) 82

equal to

(S) If the
5
sum of coefficients in the expansion of
2017
(17x – (4) 97
17x + 3) is n, then the number of dissimilar terms in the expansion of
(1 + x)n is less than

(5) 98
(A) P → 1,3;Q → 2,4;R → 1,2,3;S → 1,2
(B) P → 1,2,3;Q → 2;R → 1,2,3,4,5;S → 4,5
(C) P → 2,3,4;Q → 3;R → 1,2,3;S → 1,3,5
(D) P → 3,4,5;Q → 2,3;R → 1,3;S → 1,4

SECTION II

1) If the coefficient of x3 in the expansion of (1 + x)n is 20, then is

2) Number of solutions of the equation in

3) If θ be the angle between two tangents which are drawn to the circle x2 + y2 – 6 x – 6y + 27 = 0
from the origin, then 2 tan θ equals to

4) If the line x – y – 1 = 0 intersect the parabola y2 = 8x at P & Q. The point of intersection of

tangents at P & Q is (a, b) then a + b is:

5) If a, b, c ∈ R – {0} and equation ax2 + bx + c = 0 and x2 + 3x + 4 = 0 have common roots, then

value of is

6) One root of mx2 – 10x + 3 = 0 is two third of the other root. The sum of the roots equals to
 ANSWER KEYS

PHYSICS

SECTION I(i)

Q. 1 2 3 4
A. C C A B

SECTION I(ii)

Q. 5 6 7 8
A. A,C A,B,C A,C A,B,C

SECTION I(iii)

Q. 9 10 11
A. B A D

SECTION II

Q. 12 13 14 15 16 17
A. 40.00 20.00 20.00 3.00 22.00 5.00

CHEMISTRY

SECTION I(i)

Q. 18 19 20 21
A. A B D C

SECTION I(ii)

Q. 22 23 24 25
A. A,B,D B,C,D A,B,C,D A,C,D

SECTION I(iii)

Q. 26 27 28
A. A C A

SECTION II

Q. 29 30 31 32 33 34
A. 3.00 95.00 6.00 6.00 8.00 40.00

MATHEMATICS
 SECTION I(i)

Q. 35 36 37 38
A. D B B C

SECTION I(ii)

Q. 39 40 41 42
A. A,B,C A,C A,B,C,D B,D

SECTION I(iii)

Q. 43 44 45
A. A B B

SECTION II

Q. 46 47 48 49 50 51
A. 1.5 6.00 6.00 3.00 0.60 1.25
 SOLUTIONS

PHYSICS

1)

Explanation Question: A portion of disc is removed and we have to find centre of mass
Concept: This question is based on calculation of COM
Solution:

mass of removed = =m

Centre of mass initially at 0,

Now =

∴ Now position = =
Final Answer
The correct option is (3)

2) Explain Question:
We have to calculate magnitude of average force exerted by the bead on the part AB of the
wire.

Concept:
Impulse and average force.

Solution:

Final answer: Option (3)

3) Question Explanation: Find the tension in the string of a conical pendulum.

Concept: Dynamics of a conical pendulum.
Final Answer :

5)

Area of PV curve in process 1 > area of PV curve in process 2

Means wprocess 1 > wprocess 2
As final volume in both process is same P ∝ T
Tfinal process 2 < Tfinal process 1

7) VSD = 1.1 mm and 1 MSD = 1.0 mm

Least count = LC = MSD ~ VSD = 0.1 mm
For (A) : Zero error = – (No. of divisions of vernier scale coincident) × LC = –7 × 0.1 = – 0.7
mm
For (C) : Reading = (No. of divisions coincident on main scale) × MSD – (No. of divisions
coincident on vernier scale ) LC– zero error = 1.22 cm

8)

Since the process in chamber 2 is adiabatic

9)

(B) (a)- p; (b)- q; (c)- r; (d)- s

10) A – Q; B – R; C – S; D – P
(A) For collision veritcal components should cancel out

(B) Distance from A to B

Time taken =

11)

12) Explanation Question: We have to find the work done (in J) by frictional force on block A
in the given arrangement.
Concept: This question is based on work done by friction and block over block problem
Solution: Assuming both blocks are moving with common acceleration a

the value of required friction acting on block A = ma = 2 × 4 = 8N

(fs)max = μN = 0.5 × 20 = 10N
frequired < (fs)max : It means our assumption is correct i.e. both blocks will move together with a =
4m/s2 and friction acting on block A would be 8N.
Displacement of block A = 5m

work done (in J) by frictional force on block A :

Final Answer: 40

13) Velocity if the wave on the string

v = 40 m/s
Here, T = tension and μ= mass/length
Wavelength of the wave λ=v/n=40/100
Separation between successive nodes,
λ/2 = 40(2x100) = 20 cm

14) If acceleration of COM of roller is a then acceleration of the block will be (a + R )

downward. Equation of linear motion
For Block 60 – T = 6(a + R ) .........(1)
For Cylinder T – f = 12.a .........(2)
For Rotation a = R .........(3)
Using for roller

.........(4)
.........(5)
.........(6)
 Multi 5 by 2 & add all

15)

= 301

16) n1 = Frequency of the police car horn observer heard by motorcyclist

n2 = Frequency of the siren heard by motorcyclist
v2 = Speed of motor cyclist

17) V = 50 volt
Δv = 2 volt
I = 20 A
ΔI = 0.2 A

% error in

= 4 + 1 = 5%
Therefore, value of x is 5.

CHEMISTRY

18)

Question Explanation: Order of partial pressures in a container after effusion.

Concept: Selective Effusion of Gases.
Solution: Lighter gases effuse faster, leaving fewer moles behind; thus, heavier gases
maintain higher partial pressure.
Molar masses: He . He leaves fastest, SO2 slowest.
Final Answer:
19) Explain the question: Determine the count of electrons in the and
subshells for Chromium.

Concept: Ground state electronic configuration and azimuthal quantum numbers.

Solution: Chromium has an exceptional electronic configuration in its ground state to

achieve the extra stability of a half-filled d-subshell. Its configuration is
. The azimuthal quantum number corresponds to the p-subshell.
In the configuration, there are electrons in the 2p and 3p subshells, so the total number of p-
electrons is 6+6=12. The quantum number l = 2 corresponds to the d-subshell. Chromium has
five electrons in its 3d subshell. Therefore, the respective counts for l = 1 and l = 2 are 12 and
5.

Final Answer: Option 2 (12 and 5)

20) Question Explanation : To write UIPAC name of the given compound.

Concept : This question is based on Nomenclature of esters.
Solution :

Propyl propanoate
Final Answer : (D)

21)

Explain question:
Identify molecular with max. atom in one.

Concept:
Hybridisation and molecular structure plane.

Solution:

Final answer: Option (3)

22)

(A) The expression for the enthalpy change is ΔH = CPΔT

Hence, the enthalpy of the reaction is temperature-dependent.
(B) Equilibrium constant, K is independent of initial amount of calcium carbonate and is
dependent only on temperature.
(C) Equilibrium constant depends on temperature but it is independent of pressure.
(D) Presence of catalyst lowers the activation energy but, the enthalpy of reaction is not
affected.

23)

Question Explanation:
Analyzing a combustion reaction to identify the limiting reagent and products.

Concept:
Stoichiometry and Limiting Reagent

Solution:
C + O2 CO2
mass 27 88

moles = 2.25 = 2.75

C is limiting reagent

Moles of CO2 produced = moles of C = = 2.25

∴ Volume of CO2 at STP = 2.25 × 22.4 = 50.4 L
Ratio of C and O = 12 : 32 = 3 : 8
Moles of unreacted O2 = 2.75 – 2.25 = 0.5
∴ Volume of unreacted O2 at STP = 0.5 × 22.4 = 11.2 L

Final answer: option (2, 3, 4)

24) Explain Question: Select correct order of size

Concept: Atomic size

Solution:
Option: 1 Ti2+ < Ti < Zr is correct. Cation is smaller than atom, and Ti is smaller than Zr.
Option: 2 Ti2+ < Ti < Hf is correct. Cation is smaller than atom, and Ti is smaller than Hf (since
Ti < Zr Hf).
Option: 3 Zr2+ < Zr Hf is correct. Cation is smaller than atom, and Zr and Hf have nearly the
same atomic size.
Option: 4 Hf2+ < Hf Zr is correct: Cation is smaller than atoms, and Hf and Zr have nearly
the same atomic size.

Final Answer: Option (1), (2), (3), (4)

25)

(A) Smaller size of cation, greater will be covalt character.

(B)
(C)
(D)

26) (A) (P)- 2; (Q)- 4; (R)- 1; (S)- 3

27) Explain the Question :

Question is asking if match compound from list-I with it's correct property in list-2.

Concept : This question is based on type of bond.

Solution :

O3 Covalent + dative
NH4Cl Cl–

Covalent + Ionic + dative

CO covalent + dative

CH4 covalent + only

Final Answer :
The correct option is (3)

28) Explaination - Asking about the correct match between groups and their electronic
effects.
Concept - Based on mesomeric, and inductive effects.
Solution -
(a) + I effect Electron releasing/donating effect.
Less electronegative and negatively charged atoms or groups of atoms exert + I effect.

(b) -I effect Electron withdrawing effect.

More electronegative and positively charged atoms or groups of atoms exert - I effect.

(c) +M effect Electron donation through conjugation.

(d) effect Electron withdraw through conjugation.

Correct match according to their effects is:

Correct match is P-1, Q-5, R-2, S-3

Final Answer: The correct option is (1).

29) At node,
Ψ2(r) = 0
⇒ Ψ(r) = 0
ℓ =0
n–ℓ–1=3 ⇒n=4
⇒ (1 – σ) (σ2 –8 σ +12) = 0
when 1 – σ = 0 ⇒ σ = 1

0
or, ⇒ r = 2a
2
when σ – 86 + 12 = 0

⇒σ=

or, σ = = 6 and 2
when σ = 6

0
or, ⇒ r = 12a
when σ = 2

0
⇒ ⇒ ⇒ r = 4a
∴ distance of nearest radial node = 4a0 = xa0
⇒x = 4
and distance of farthest radial node = 12a0 = ya0
⇒ y = 12
∴ y/x = 12/4 = 3.

30)

Calculated μ = 4.8 × 10–10 esu × 1.62 × 10–8 cm = 7.776 D

Percentage ionic character × 100 = 5%

Percentage covalent character = 100 – 5 = 95%.

31) Fact

32) Total number of contributing structures showing hyper conjugation involving C–H bonds =
number of α–H = 6
 33)

Ans. (8.00)
(8.00) is the correct answer

34) Explain Question:

Identify the volume of CO2 produced.

Concept:
Eudiometry.

Solution:

total CO2 produced

= 2V + 2 (20–V) = 40 ml

Final Answer: 40

MATHEMATICS

35) r = 2 or r = 3

36) Question Explanation: We have to check nature of roots of given quadratic equation.

Concept: This question is based on nature of roots.

Solution: (x – a)2 + (x – b)2 + (x – c)2 + 4(a + b + c)x = 0

⇒ x2 – 2ax + a2 + x2 – 2bx + b2 + x2 – 2cx + c2 + 4(a + b + c)x = 0
⇒ 3x2 – 2(a + b + c)x + 4(a + b + c)x + (a2 + b2 + c2) = 0
⇒ 3x2 + 2(a + b + c)x + (a2 + b2 + c2) = 0
⇒ x2 + 2ax + a2 + x2 + 2bx + b2 + x2 + 2cx + c2 = 0
(x + a)2 + (x + b)2 + (x + c)2 = 0
no solution as a ≠ b ≠ c
∴ Imaginary roots.

Final answer: Option (2)

37)
D>0
–4a + 12 > 0
a<3
⇒ a ∈ (–∞, 3)
Final Answer: Option (2)

39) Question Explanation: Find the values of x that satisfy the given trigonometric equation.
Concept: Base on general soln & Half angle formula.
Solution:
Given, cos2x + cos22x + cos23x = 1
cos2x + (2cos2 x–1)2 + (4 cos3x – 3cosx)2 = 1
2 4 2 6 2 4
⇒ cos x + 4cos x + 1 – 4 cos x + 16cos x + 9cos x – 24 cos x = 1
⇒ 16cos6x – 20cos4x + 6cos2x = 0
Let cos2x = t then,
16t3 – 20t2 + 6t = 0
⇒ 2t (8t2 – 10t + 3) = 0
⇒ 2t (4t –3) (2t – 1) = 0
either, 2t = 0
⇒ 2cos2x = 0

or, 2t – 1 = 0
⇒ 2cos2 x – 1 = 0

cos2x =

or, 4t – 3 = 0
⇒ 4 cos2 x – 3 = 0

⇒ cos2 x =

Hence,
Final Answer: Option (1, 2, 3)

40)

x2 + 3y2 = 6

a2 = 6 & b2 = 2
 ⇒e=
Centre : (0, 0)

Let point be

4cos2 θ = 2

Final Answer: option (1), (3)

41)

Question Explanation: Finding the eccentric angle of a point on an ellipse at a specific

distance from the center.
Concept: Parametric Coordinates of an Ellipse.
Solution:
Let point of ellipse is

Given OP = 4

All options are correct

Final Answer:

42)

Solution :

Given ellipse is .

Eccentricity of the ellipse

Focus of the ellipse

Eccentricity of the hyperbola

So,

Since the hyperbola passes through the focus of the ellipse,

⇒a2 = 3 and b2 = 1

Thus, the equation of the hyperbola is

Focus of hyperbola is (±2,0).

Final Answer : Option (2),(4)

43)

Question Explanation:
Matching properties of sequences (AP, GP, HP) with inequalities.

Concept:
Inequalities in Progressions and A.M , G.M concept.

Solution:
(A) If a,b,c,d > 0 are in A.P.
then & ⇒ bc > ad

&
⇒ b2 + c2 < a2 + d2
(B) If a,b,c,d > 0 are in G.P.

then
⇒ b+c<a+d

⇒ b2 + c2 < a2 + d2
(C) a, b, c, d in HP (>0): bc < ad (inverse of AP property) and b + c < a + d.
(D) a, b, c, d in AP (<0): Signs flip; bc > ad remains true.
P → 1, 5; Q → 4, 5; R → 2, 4, 5; S → 1, 5

Final Answer: Option (1)

44) (P) (a - 3) (2a + 1) < 0 ⇒

(Q) (a + 4) (a - 2) < 0 ⇒ - 4 < a < 2
(R) \(\left. \begin{gathered} a\left( {a - \frac{1}{3}} \right) > 0 & & \Rightarrow a <
0,\,\,\,a > \frac{1}{3} \hfill \\ (a + 3)(a - 1) < 0 & & \Rightarrow - 3 < a < 1 \hfill \\
\end{gathered} \right\}\,\,\,a \in ( - 3,\,\,\,0) \cup \left( {\frac{1}{3},\,\,\,1} \right)\)
(S) \(\left. \begin{gathered} 3\pi - 5 \geqslant 0 & \,\beta \geqslant 5/3 \hfill \\ \beta + 2
\geqslant 0 & & \beta \geqslant - 2 \hfill \\ 4\beta - 14 \leqslant 0 & \beta \leqslant 7/2\, \hfill \\

\end{gathered} \right\}\)

45)

Explain question : In this question we have given 4 questions M list -I solve each question
 seperately and match the answer with List - II
Concept : This question is based on general term in binomial expansion, numerically greatest
term in binomial expansion and multinomial theorem.
Solution :-

(P)

For

For
∴ 4 rational and 97 irrational terms

(Q)
27 > 5r
for r = 5, T6 > T5
for r = 6, T7 < T6
∴ T6 is numerically greatest
Hence, (9r + 4) = 58.
(1 + x2 – x3)8 = (1 + x2 (1 – x))8
= 1 + 8C1 x2(1 – x) + 8C2 x4(1–x)2 +......
∴ Coefficient of x10 = 8C4 4C2(–1)2 + 8C5 = 476
Final answer :- 2

46) Question Explain: In a given binomial (1 + x)n, the coeff of xr is nCr,

Concept: This question is based on General Terms.
Solution: The coeff. of x3 in (1 + x)n is nC3.
So, nC3 = 20

⇒
⇒n=6

Final Answer: (n = 1.5)

47) Number of solutions of the equation

;
 48)

Question Explanation: Calculating the angle between two tangents drawn from the origin to
a circle.
Concept: Pair of tangents from an external point to a circle.
Solution : x2 + y2 – – 6y + 27 = 0

Equation of the pair of tangent is given by

T2 = SS1

⇒ = (x2 + y2 – – 6y + 27) (0 + 27)

2 2 2
⇒ (–3 – 3y + 27) = 27 (x + y – 6 – 6y + 27)
2 2
⇒ 27x + 9y + 729 + 18 xy – 6 × 27 – 6 × 27y = 27x2 + 27y2 – 6 × 27 x – 6 × 27 y + 729
2
⇒ 18y – 18 xy = 0
the tangents are y = 0 and y = x

angle between the tangents is

2 tan θ = × =6
Final Answer: 6

49)

Question Explanation: Finding the point of intersection of tangents using the chord of
contact.
Concept: Chord of contact of a parabola.
Solution:
⇒
Chord of contact from (a, b) is
⇒
Given line equation x – y – 1 = 0
comparing coefficients

⇒
⇒b=4
⇒
a + b = –1 + 4 = 3

Final Answer: 3

50) Question Explanation: Finding the value of a coefficient ratio for common roots.
Concept: Condition for common roots with imaginary solutions.
Solution:
∵ x2 + 3x + 4 = 0 has both roots imaginary
∴ Both roots of both equation are equal

(Let)
Final Answer: 0.60

51) α + =

⇒ =

⇒α= ; also α · =

⇒ 2α2 =

⇒ =3⇒m=8

∴ sum = = = Ans.