02-08-2026

1701CJA101361260026 JA

PART-1 : MATHEMATICS

SECTION-I(i)

1) is equal to (where C is constant of integration)

(A)

(B)

(C)

(D)

2) If ƒ : R → R and ƒ(x) is a polynomial function of degree ten with ƒ(x) = 0 has all real and distinct
roots. Then the equation (ƒ'(x))2 – ƒ(x)ƒ''(x) = 0 has -

(A) no real roots

(B) 10 real roots
(C) 6 real roots
(D) 8 real roots

3) Let all 2024 zeroes of polynomial p(x) = a2024x2024 + a2023x2023 + ...... + a1x + a0 where ai ∈ R; are real
and distinct and all less than one, a2024 ≠ 0, for any such polynomial consider the function

0
+ ..... + ..... + a1ex + a x, then
Statement-1 : f ′ (x) has 2024 real zeroes in (0, ∞).
Statement-2 : f ″ (x) has no. real zeroes in (0, ∞).

(A) Statement 1 is True, Statement 2 is True.

(B) Statement 1 is False, Statement 2 is False.
(C) Statement 1 is True, Statement 2 is False.
(D) Statement 1 is False, Statement 2 is True.

4) The minimum value of is, where x1, x2 > 0

(A) 8
(B) 18
(C) 64
(D) 36

SECTION-I(ii)

1) and πg(π) + 1 = 0 then

(A) P = 2

(B)

(C)

(D) g(x) is even function

2) Let f : [0,3] → R be continuous and twice differentiable on (0,3). Further f(x) = 0 has exactly four
real roots as x = 0,1,2,3 and g(x) = f"(x) + 2f'(x) + f(x) never vanishes in any of the intervals (0,1) or
(1,2) or (2,3). Which of the following is/are true ?

(A) f'(x) + f(x) = 0, has exactly five solution in (0,1) ∪ (1,2) ∪ (2,3)
(B) f'(x) + f(x) = 0, has exactly one solution in (0,1)
(C) f'(x) + f(x) = 0, has exactly one solution in (2,3)
(D) f'(x) + f(x) = 0, has exactly two solution in (1,2)

3) Let f : → be given by

Which of the following options is/are correct ?

(A) f′(x) has a local maximum at x = 1

(B) f(x) is onto
(C) f(x) is increasing on (–∞,0)
(D) f′(x) is NOT differentiable at x = 1

4) If 4a2 – 5b2 + 6a + 1 = 0 and the line ax + by + 1 = 0 touches a fixed circle, then (where a,b ∈ R)

(A) centre of circle is (3, 0)

(B) radius of circle =
(C) circle passes through (0, 1)
(D) None of these

5) Let C1 ≡ x2 + y2 = 64 and C2 ≡ x2 + y2 – 24x + 108 = 0 intersect at point P and Q. A line through P

meets the circle C1 and C2 at R and S respectively. If PS = PR, then

(A) length of PR =

(B)
length of perpendicular from centre of C1 to PR is
length of perpendicular from centre of C2 to PR is
(C)

(D)
slope of PR =

6) Let C be the circle with centre (0, 0) touching at least one line of the family (x + 3y – 4) + λ(2x –
3y + 1) = 0 (where λ is a parameter), if radius of C is maximum, then correct option's are -

(A) radius of C is units

(B) radius of C is 1 unit
(C) C passes through (–1, –1)
(D) C passes through (–1, 0)

SECTION-II

1) If
(where 'λ' is rational number and C is constant of integration), then the value of cos–1cosλ is (aπ + b),
where a and b are integers then the value of (3a + b) is

2) Let + c, (where c is constant of integration) and f(1) = –1. If

, then the absolute value of is

3) Let f(x) be a polynomial function satisfying

then f(2) – f(1) is equal to

4) Let then number of points where ƒ(x) attains

its minimum value, is

5) For a polynomial P(x) with real coefficient, let np denote the number of distinct real roots of P(x).
Suppose M is the set of polynomials with real coefficients defined by
M = {(x – 2)2(x – 4)2 (α7x7 + α6x6 + α5x5 + α4x4 + α3x3 + α2x2 + α1x + α0) ;
Where α is ∈ R and α7, α0 > 0}
For a polynomial g, let g' and g'' denote its first and second order derivatives, respectively. Then the
minimum possible value of (ng + ng' + ng''), where g ∈ M, is

6) Let f(x) be a differentiable function on [0, 8] such that f(1) = 5, , f(3) = 6, f(4) = –3, f(5) =

4, and . If the minimum number of roots of the equation f ′ (x) – f ′ (x)(f(x))2 = 0 is λ,

then λ equals

7) Two circles of radius 1 and 4 touch each other externally. Another circle of radius r touches both

circles externally and also one direct common tangent of the two circles. Then _______ (Where
[·] donates geatest integer function)

2 2
8) From a point 'P' on the line 2x + y + 4 = 0 which is nearest to circle x + y – 12y + 35 = 0,
tangents are drawn to the given circle. If the area of quadrilateral formed by these pair of tangents
and pair of radii is k, then value of k2 is

PART-2 : PHYSICS

SECTION-I(i)

1) A small sphere of radius r and mass m is placed on a big hemisphere of mass 2m and radius R
which is kept on a smooth horizontal surface as shown in the figure. Find the displacement of
hemisphere when line joining between centre of small sphere and centre of big hemisphere makes
30° with the vertical (initially this line was vertical, and assume small sphere is not losing the
contact with hemisphere)

(A)

(B)

(C)

(D) None of these

2) The circuit shown in the diagram extends to the right into infinity. Each battery has the
electromotive force V (unknown) and the internal resistance r (known). Each resistor has the
resistance 4r. The reading of the ideal ammeter shown in the diagram is I. Find the value of V in

terms of I and r.

(A)

(B)

(C) V = 4.5 Ir
(D) V = 3.0 Ir

3) Consider a circuit shown in the figure. The emf of the battery is slowly increased to a final value
of E0 from zero. One plate of the capacitor is fixed while the other plate is tied to an elastic string of
natural length ℓ, Young's modulus Y & area of cross-section A :-

(A) Capacitance of the capacitor continuously decreases as time proceeds

Maximum value of elongation in the string is less than 'd' seperation between the plates initially
(B)
for any value of E0.
Energy stored in the capacitor is more as compared to the case when the plates of capacitor
(C)
were kept fixed.
(D) Extention in string increases linearly with value of emf of battery.

4) A dielectric slab of area A passes between the capacitor plates of area 2A with a constant speed v.
The variation of current (i) through the circuit as function of time (t) can be qualitatively represented

as :-

(A)
(B)

(C)

(D)

SECTION-I(ii)

1) Two square metal plates have sides of length L and thickness t (<< L). They are arranged parallel

to each other with their inner faces at a separation of . One of the plates is given a charge –Q and
the other one is given a charge +Q. A third rectangular metal plate of sides L and x, having

thickness is inserted between the plates as shown. The third plate is equidistant from the two

plates and parallel to them. Neglect edge effects

The ratio of charge density on lower plate at points 1 and 2 ( 2 is in between the bigger and
(A)
smaller plates) shown in Figure is 0.8.

(B)
Potential difference between the upper plate and the middle plate is .
Electric field between the two outer plates in space where the third plate is not present (i.e., at
(C)
a point above point 1.) is .

(D)
The capacitance of the system across two outer plates is .

2) A parallel plate capacitor has its two plates connected to an ideal spring of force constant K.
Relaxed length of spring is L and it is made of non-conducting material. The area of each plate is A.
The capacitor has a charge q0 on it. To discharge the capacitor through the resistance R, switch S is
closed. Assume that there is no friction and the plates always remains parallel to each other.
 If the time constant of the circuit is very large and discharge process is very slow, heat
(A)
dissipated in the resistance is
If the time constant of the circuit is very large and discharge process is very slow, heat
(B)
dissipated in the resistance
If the time constant of the circuit is very small and discharge process is almost instantaneous,
(C)
heat dissipated in the resistance is
If the time constant of the circuit is very small and discharge process is almost instantaneous,
(D)
heat dissipated in the resistance is

3) A smooth hemisphere of mass m and radius R is at rest. A smooth solid sphere of mass 2m and
radius R is moving with a velocity v0 between two horizontal smooth surfaces separated by a
distance slightly greater than 2R as shown in figure. Solid sphere collides with the hemisphere. If

the coefficient of restitution is , then :

(A) The speed of hemisphere after collision is v0.

(B)
The speed of solid sphere after collision is

(C)
The loss in kinetic energy of the system is

(D)
The final kinetic energy of hemisphere is of the initial kinetic energy of sphere.

4) 1 kg ball is released from rest as shown. It's collision with horizontal surface is perfectly inelastic,

then (all surfaces are smooth) :-

(A) After collision speed of ball is 8 m/s.

(B) After collision speed of ball is 6 m/s.
(C) Impulse on ball due to collision is 6 Ns
(D) Impulse on ball due to collision is 8 Ns

5) The given diagram shows a modified meter bridge. The wire AB has uniform resistance used for
measuring two unknown resistances. When the first galvanometer is used for obtaining the balance
point, it is found at point C. Now the first galvanometer is removed and the second galvanometer is
used, which gives balance point at D. Using the details given in the diagram, find out the value of R1
and R2. (Here AB = L ; AC = L/4 and AD = 2L/3)

(A) R1 = R/3
(B) R2 = 8R/3
(C) R1 = 5R/3
(D) R2 = 4R/3

6) Three ammeter A, B and C of resistance RA, RB and RC respectively are joined as shown. When
same potential difference is applied across the terminal T1 and T2, their readings are IA, IB and

IC respectively, then :-

(A) IA = IB
(B) IARA + IBRB = ICRC

(C)

(D)

SECTION-II

1) The network shown consists of an infinitely large number of identical sections. Resistance of each
branch is . If equivalent resistance of the whole network between A and B is nΩ, find n.
2) A galvanometer (coil resistance 99 Ω) is converted into an ammeter using a shunt of 1Ω and
connected as shown in figure-1. The ammeter reads 3A. The same galvanometer is converted into a
voltmeter by connecting a resistance of 101Ω in series. This voltmeter is connected as shown in
figure-2. Its reading is found to be 4/5 of the full scale reading. Range of the voltmeter (in nearest

integer) (in Volt) is :

3) A very large non-conducting plane carrying charge Q uniformly distributed over it is placed in a
medium with resistively ρ and primitively ∈. The plane leaks charge through the surrounding

medium and the charge becomes times the initial value after a time t = 8ρ∈ n2 elapses. Find the
integer value n. (Neglect the end effects and assume that resistive medium is present only in one

side of plane & other side has vacuum).

4) Plates of a charged parallel plate capacitor is connected with conducting wire as shown in figure.
A conducting thin plate was placed in the middle of the capacitor. Charge on the middle plate is 9μC.
Now the plate is moved parallel to itself by a distance 2 mm. What is the charge (in μC) flown
through the conducting wire, if distance between its plates is equal to 6 mm?

5) There are six parallel plates of equal area A are arranged as shown in figure (d<<A). The

equivalent capacitance between points 2 and 5, is . Then find the value of α.

6) A uniform chain A' B' of length 2ℓ having mass λ per unit length is hanging from ceiling of an
elevator by two light, inextensible threads AA' and BB' of equal length as shown in figure. Distance
AB is very small. At a certain instant, elevator starts ascending with constant acceleration a(<g) .
Two seconds after the beginning of motion, thread BB' is burnt. Assuming that instant to be t = 0.
Consider the motion before string becomes vertical. The tension in thread AA' at time t is

. The value of x is :

7)

A solid horizontal surface is covered with a thin layer of oil. A rectangular block of mass m = 0.4kg is
at rest on this surface. An impulse of 1.0 N s is applied to the block at time to t = 0 so that it starts
moving along the x-axis with a velocity v(t) = , where is a constant and . The
displacement of the block, in metres, at t = is ...... Take e–1 = 0.37 ?

[JEE-Advanced 2018]

8) A ball of 0.01 kg is suspended from a fixed point O by means of a light and inextensible string of
length 10 m. Initially string is released (rest) from horizontal position as shown in figure. At the
lowermost point of its path, it hits a stationary small block of mass 1.205 kg lying on a rough
horizontal surface. After striking the block, the ball rebounds and comes to rest when the string
makes an angle 30° with the horizontal. Due to impact the block moves through a distance of 0.5 m
on the horizontal surface. If the coefficient of friction between the block and the surface is k, find

value of 10k. (Take : g = 10 m/s2)

PART-3 : CHEMISTRY

SECTION-I(i)

1) Find out the total number of allylic mono-bromo substituted products (including stereo) in the
given reaction :

​ Products.

(A) 5
(B) 9
(C) 10
(D) 11

2) Photoelectric emission is observed from a surface when lights of frequency n1 and n2 incident. If
the ratio of maximum kinetic energy in two cases is K : 1 then (Assume n1 > n2) threshold frequency
is

(A) (K – 1) × (Kn2 – n1)

(B)

(C)

(D)

3)
At total pressure P1 atm and P2 atm, N2O4 is dissociated to an extent of 33.33% and 50.00%,
respectively. The ratio of pressures P1 and P2 is :
(A) 3:8
(B) 2:1
(C) 8:3
(D) 1:2

4) Which of the following statement(s) is/are not correct for Quartz?

(A) It is sheet silicate

(B) 4-corner oxygen atom shared per tetrahedral unit
(C) 3D network structure having tetrahedral unit
(D) Each Si form four covalent bond

SECTION-I(ii)

1) Which of the following compounds can be converted into alcohol on reaction with grignard
reagent in excess amount followed by acidification ?

(A) Aldehyde
(B) Ester
(C) CO2
(D) Epoxide

2) In the given reaction:

[X] will be :

(A)

(B)
(C)
(D)

3) Which of the following is correct when an ideal gas having initial pressure P, volume V and
temperature T is allowed to expand adiabatically until its volume becomes 5.66 V while its
temperature falls to half ? (Given : 100.75 = 5.66, log 2 = 0.30)

(A) The gas is diatomic

(B) The gas is monoatomic
(C) The work done by the gas is 1.25 PV
(D) All are correct

4) An ideal gas from same initial state is participated in two different thermodynamic processes (AC
- Reversible, AB - Irrversible) as shown in figure. If the entropy of surrounding remains constant in
these processes, then which of thefollowing are correct :-

(A) (ΔSgas)AB > (ΔSgas)AC

(B) |(ΔHgas)AB| < |(ΔHgas)AC|
(C) |(ΔUgas)AB| < |(ΔUgas)AC|
(D) (ΔSgas)AC > (ΔSgas)AB

5) Which of the following statement is/are CORRECT for A, B,

C, D, E ?

(A) E is Cu(BO2)2 and 'A' is Na2B4O7 . 10H2O

(B) 'B' is NaBO2 and 'C' is B2O3
(C) 'D' is Fe(BO2)2 and 'E' is CuBO2
(D) 'A' is borax and has two sp2 and two sp3 hybridised boron atoms

6) Consider following reaction/s & select correct statement.

(A) Black ppt (A) soluble in dil. HCl

(B) Black ppt (A) soluble in dil. CH3COOH
(C) Compound (D) has four Metal–Nitrogen bonds and it is paramagnetic
(D) Green solution give violet color solution when react with ethylenediamine

SECTION-II

1) How many moles of Grignard reagent will be consumed per mole of given compound during the
following reaction?

2) How many these reactions will give 1º alcohol as major product :

(1)

(2)

(3)

(4)

(5)

(6)

(7)

(8)

(9)

3) How many reactions give us Hoffmann elimination product?

(I)

(II)
(III)

(IV)

4) Assuming that bond enthalpy of axial P–Cl bond is different from bond enthalpy of equatorial P –
Cl bond, bond enthalpy of axial P – Cl bond in PCl5 will be (in KJ/mol) :
(given: )

and assume that the bond enthalpy of P–Cl bonds of PCl3 are same as equatorial bonds of PCl5

5) Calculate the pH of a 2.0 M solution of NH4Cl.

[Kb (NH3) = 2 × 10–5]

6) For how many of the following the colour is correctly matched with the compound?
A. K2Cr2O7 - Orange
B. PbCrO4 – Red
C. CrO5 - Yellow
D. Cu2+ (Borax bead test, oxidizing flame) - Blue
E. Cu2[Fe(CN)6] - Chocolate brown
F. Fe4[Fe(CN)6]3 Prussian blue
G. K2MnO4 - Dark Green

7) How many ions when react with NaOH (excess), precipitate is formed which is insoluble in excess
NaOH.
Bi3+, Cd2+, Zn2+, Al3+, Pb2+,
Sn2+, Mn2+, Co2+, Cu2+

8) Find the number of chemcial species which does not exist.

NCl5, SI6, TℓI3, FeI3, CuI2, PbI4, BiI5, NOF3
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I(i)

Q. 1 2 3 4
A. B A D A

SECTION-I(ii)

Q. 5 6 7 8 9 10
A. A,B B,C A,B,C,D A,B A,B,C A,C

SECTION-II

Q. 11 12 13 14 15 16 17 18
A. 2.00 1.00 1.00 1.00 10.00 11.00 2.00 19.00

PART-2 : PHYSICS

SECTION-I(i)

Q. 19 20 21 22
A. C B C B

SECTION-I(ii)

Q. 23 24 25 26 27 28
A. A,B,C,D B,C A,B,C A,C C,D A,B,D

SECTION-II

Q. 29 30 31 32 33 34 35 36
A. 1.00 10.00 16.00 3.00 1.00 0.75 6.3 0.04

PART-3 : CHEMISTRY

SECTION-I(i)

Q. 37 38 39 40
A. B D C A

SECTION-I(ii)

Q. 41 42 43 44 45 46
A. A,B,D A,B A,C A,B,C A,B,D D
 SECTION-II

Q. 47 48 49 50 51 52 53 54
A. 6.00 5.00 3.00 160.00 4.50 5.00 5.00 6.00
 SOLUTIONS

PART-1 : MATHEMATICS

1)

Put

2) Let ƒ(x) = a(x – x1)(x – x2).....(x – x10)

ℓnƒ(x) = ℓna + ℓn(x – x1) + ℓn(x – x2) +.....+ ℓn(x – x10)

3) p(x) has 2024 zeroes in (–∞, 1) ∴ Using Rolle's theorem p ′ (x) also has all zeros in (–∞, 1)
Now, f ′ (x) = p(ex)
f ″ (x) = p ′ (ex) ex
But ex > 1 ∀ x > 0
So, f ′ (x) and f ″ (x) have no zeroes in (0, ∞)

4) d2 = (x1 – x2)2 + (y1 – y2)2

x2y2 = 9, x12 + y12 = 2
xy = 9 x2 + y2 = 2

Let point on

equation of normal at p

it passes through centre (0, 0) of circle

x2 + y2 = 2
t4 = 81
t=3
point p(3, 3)
minimum distance = cp – r

5)

∴ P = 2,

6)

Let h(x) = f(x)ex

So, h(0) = h(1) = h(2) = h(3) = 0
⇒ h'(x) = 0 has atleast three solution in (0,1) ∪ (1,2) ∪ (2,3)
⇒ f'(x) + f(x) = 0 has atleast three solution in (0,1) ∪ (1,2) ∪ (2,3)
Hence, h'(x) = 0 has exactly one root in any one of such interval.
7)
for x < 0, f(x) is continuous

and and
Hence, Range of f(x) in (–∞,0)
f'(x) = 7(x + 1) – 2x2 which changes sign in (–∞,0)
6

⇒ f(x) is non-monotonic in (–∞,0)

For x > 3, f(x) is again continuous and and

Range of f(x) in [3,∞)

Hence f' has a local maximum at x = 1 and f' is NOT

differentiable at x = 1

8) Let circle (x – h)2 + (y – k)2 = r2

⇒ a2(h2 – r2) + b2(k2 – r2) + 2abhk + 2ah + 2bk + 1 = 0

comparing, we get centre (3, 0), r =

9)

Question Explanation: Finding line properties for two intersecting circles where PS = PR.

Concept: Geometry of Intersecting Circles and Chords.

Solution:

A. Circle Center , Radius .

 B. Circle Center , Radius .

C. Intersection P: Subtracting equations: .

Substitute x to find y:

D. Let be perpendicular distances from to the line RS.

and . Given PR = PS:

.

E. Using the midpoint property and coordinate geometry, solving for the lengths:

Final Answer: Options (1), (2), and (3) are correct.

10)

11)

cos–1cos4 = 2π – 4 = aπ + b
∴ a = 2; b = –4
(3a + b) = 2

12)
 ,

13)

÷ x2 ⇒

let

= tan–1t + C = tan–1 +C
⇒ f(x) = x
⇒ f(2) – f(1) = 1

14)
Let g(x) = x3 + x2 + 3x + sinx
g'(x) = 3x2 + 2x + 3 + cosx

g(x) is increasing function

∴
hence min. value of ƒ(x) is 0 at x = 0

15) g(x) = 0
⇒ x = 2, x = 4, x = β (7th degree poly)
(β < 0)
g(2) = g(4) = g(β) = 0
g'(r1) = 0 for r ∈ (2, 4)
g'(r2) = 0 for r ∈ (β, 2)
also g'(2) = g'(4) = 0
so g'(x) = 0 at x = 2, 4, r1, r2
⇒ g''(x) = 0 at atleast three points.
 16)
f ′ (x) = f ′ (x) (f(x))2
⇒ f ′ (x) = 0, f(x) = 1, f(x) = –1
f ′ (x) = 0 for alteast 4 points
f(x) = 1 for atleast 5 points
f(x) = –1 for atleast 2 point
so f ′ (x) = f ′ (x) (f(x))2 for atleast 11 points.

17)
Let the radius of circle C1 (smallest) be r, then from a behave fig., we have
AC = AB + BC ....(1)
Now, = AB2 + C2D2
⇒ (r + 1) = AB2 + (r – 1)2
2

⇒ AB2 = 4r ⇒ AB
Similarly, AB2 = (r + 4)2 – (4 – r)2 = 16r
and AC2 = 16 ⇒ AC = 4
Now, From eqn (1)

18) Centre of circle (0, 6) radius = 1

Line through centre and perpendicular to 2x + y + 4 = 0 is y – 6 = (x – 0)

∴ x – 2y + 12 = 0
Point of intersection of x – 2y + 12 = 0 and 2x + y + 4 = 0 is (–4, 4)
Length of tangent
=
Area of quadrilateral
k = RL =
∴ k2 = 19

PART-2 : PHYSICS
19)

0 = 3x – (R + r) sin 30°

20) Explain question: Find the value of V in terms of i and R.

Concept: Ohm's law.

Solution:

⇒ R2 – 4rR – 4r2 = 0

⇒
Resistance can not be negative, so

Final answer: option 2 is correct

21) Question Explanation:

A circuit contains a capacitor where one plate is fixed and the other is attached to an elastic
string (natural length , Young's modulus Y, area A). The EMF is slowly increased from zero
to E0. We need to identify the correct statement regarding the physical changes in the system.
Concept:
As voltage increases, electrostatic attraction pulls plates closer, stretching the string.
Solution:
Capacitance Change: As the EMF increases, the charges +Q and -Q on the plates increase,

creating an attractive force .

This force pulls the movable plate toward the fixed plate, decreasing the separation d.

Since , a decrease in d leads to an increase in capacitance C. Statement 1 is incorrect.

Energy Comparison: Because the plates move closer together, the work done by the
electrostatic force is stored as potential energy in the string and leads to a higher capacitance
compared to a fixed-plate scenario. This results in more energy being stored in the capacitor
for the same final voltage E0. Statement 3 is correct.
Linearity of Extension: The electrostatic force is proportional to the square of the charge (and
thus the square of the voltage), while the restoring force of the string is linear .
Therefore, the extension does not increase linearly with the EMF. Statement 4 is incorrect.
Final answer: Option (3)

22) , q = CV, q ∝ C

23)

24)

Refer class notes

25)
2mv0 = 2mv1 + mv2

e=

26)

Velocity of ball at bottom will be = 10 m/s

After perfectly inelastic collision the velocity perpendicular to the surface becomes zero.
Impulse =

= 6 N-s

27)

Refer class notes

28)
IA = IB
T1 – T2 = IARA + IBRB = ICRC
IB(RA + RB) = ICRC

29) Using mirror symmetry drawing in two D plane.

30) For ammeter

99 Ig = (I – Ig) 1 or I = 100 Ig ....(1)
Ig is the full scale deflection current of the galvanometer and I is the range of ammeter.

For the circuit in figure-1

31)

At q = q0/16

32)

Now after shifting

33)
This is balance bridge

α=1

34) Since, thread BB’ is burnt two second after the beginning of motion of elevator, therefore,
at that instant t = 0 velocity of elevator is v0 = 2a(upwards). When thread is burnt, end B’ of
chain starts moving under gravity while A’ continues to move upwards with the elevator.
Hence, length of left vertical part of chain increases. Tension in thread AA’ is due to two

factors:
(i) due to apparent weight of left vertical part of chain and
(ii) due to rate of change of momentum of the chain when its links transfer from right to left
part.
Considering downward motion of end B’ (relative to the elevator) as shown in fig.
Initial relative velocity, u = 0
Relative acceleration,
a’ = g – (–a) = (g + a)
∴ Relative displacement of end B’ in time t is

or
Mass of left vertical part of chain

∴ Rate of increase of mass in left part,

or
 Change in velocity of a link when it transfers from right to left vertical part,

∴ Rate of change of momentum,

Apparent weight of left vertical part

= M (g + a)
∴ Required tension

35)

Final Answer : 6.3

36)

from momentum conservation

0.01 v1 = – 0.01 v2 + 1.205 v
 c = 0.01 (v1 + v2) =
for block "1.205 kg"
0 = v2 – 2(µg)s

(0.20)2 = 2 µ 10 ×
µ = 0.004

PART-3 : CHEMISTRY

38) Question Explanation: Relation between incident frequency, threshold frequency, and
Kmax. Concept: Photoelectric Effect Equation
Solution: According to Einstein's photoelectric equation, the maximum kinetic energy is the
difference between the energy of the incident photon and the work function of the metal
. Let 0 be the threshold frequency.
For frequency
For frequency

Given we have:

Final Answer: Option (4)

39)

Explain the question:

Question asks to find the ratio of pressures at which N2O4 shows different degrees of
dissociation.

Concept:
Equilibrium Constant, Degree of Dissociation, Kp Expression.

Solution:

Given:
- At
- At

starting with 1 mole:

N2O4 ⇌ 2NO2
t=0 1 0
 N2O4 ⇌ 2NO2
At eq.

Total moles
Kp expression:

Since temperature is same, Kp is constant:

Substituting values:

Final Answer: Option (3)

40)

Refer class notes

41) CO2 gives carboxylic acid with RMgX.

42)

Explanation Question: Question is asking about product of given reaction.

Concept: This question is based on SN NGP
Solution:

The correct options are (1, 2)

43) (A) is correct because

 T1 = T,
V1 = V and V2 = 5.66 V

2 = (5.66)γ – 1
γ = 1.4

So the gas is diatomic.

(C) is correct because work done

44)

Question Explanation: Compare gas entropy and state changes in reversible vs irreversible
processes.

Concept: Thermodynamic Processes and Entropy.

Solution:
ΔSsurr = 0 for both processes.
For reversible process AC: ΔStotal = ΔSgas,AC + ΔSsurr = 0 ⇒ ΔSgas,AC = 0.
For irreversible process AB: ΔStotal = ΔSgas,AB + ΔSsurr > 0 ⇒ ΔSgas,AB > 0.
Therefore, (ΔSgas)AB > (ΔSgas)AC (Option 1 is correct).
In adiabatic expansion to the same final volume, Tfinal,irr > Tfinal,rev, so TB > TC.
Temperature drop is less in irreversible process: (TA – TB) < (TA – TC).
|ΔUgas| = nCv(TA – Tfinal), so |(ΔUgas)AB| < |(ΔUgas)AC| (Option 3 is correct).
|ΔHgas| = nCp(TA – Tfinal), so |(ΔHgas)AB| < |(ΔHgas)AC| (Option 2 is correct).

Final Answer: Option (1), (2) & (3)

45)

Question Explanation : Identify correct facts about Borax.

Concept: Borax bead test and structure.
Solution :
This reaction sequence describes the classic Borax Bead Test:

A. Identification of A : Compound A is . When heated, it first loses water

of crystallization and swells into a porous mass.
B. Formation of B and C: On further heating, it melts to form a clear, transparent glassy bead
consisting of Sodium metaborate ( ) and Boric anhydride ( ).
C. Borax Structure: In its anionic form , Borax contains two sp2 and two
sp3 hybridized boron atoms arranged in a cyclic structure.
D. Formation of D and E (Bead Test): The reacts with metal oxides to form colored metal
metaborates:
E. E: Reaction with CuO gives Copper(II) metaborate , which is blue.
F. D: Reaction with gives Iron(III) metaborate ), which is yellow in an oxidizing
flame. Note: Statement 3 is incorrect because it suggests .

Final Answer: Option (1), (2), and (4)

46)

Question Explanation: Identify correct statement using reactions of Ni compounds and

ligand tests.
Concept: Transition metal complex formation
Solution:
Black ppt (A) + aqua regia → green solution
Black ppt releasing S and NO with aqua regia indicates NiS.
(B) is green Ni2+ solution.
With DMG → rosy red ppt (D) = Ni(DMG)2 complex
This complex is square planar and diamagnetic, not paramagnetic → (3) false
NiS is insoluble in dilute HCl and dilute (1) and (2) false
ethylenediamine forms , which is violet → (4) true
Final Answer: Option (4)

47) Explanation: Question is asking about the moles of Grignard reagent will be - consumed
per mole of given compound during the following reaction.
Concept: Reaction of Grignard reagent
Solution:
(1) Number of acidic hydrogen in given compound is 4 (one triple bond hydrogen + 2 alcoholic
hydrogen + one acidic hydrogen of 2°amine) → 4 mole of Grignard reagent are used.
(2) No. of carbonyl group is 2(one aldehyde + one ketone)
One carbonyl group react with one mole of Grignard reagent so 2 mole of Grignard reagent
and used
Total moles of Grignard reagent used = 6
Final Answer: 6

48) (1), (2),(3),(7), (8) give primary alcohol as a product.

49)
(3) Can not undergo elimination since F– not stable
Ans = 3

50)

∴ 3EP–Cl = 995 ; BEP – Cl = 331.66

51) Question Explanation: Calculate the pH of an acidic salt solution (NH4​Cl).

Concept: pH of Salt of Strong Acid/Weak Base
Solution:

pH = 7 – (Salt of S, A & W.B.)

=
Final Answer: 4.5

52)

Explanation Question:
How many of compounds are correctly match with their colour
Concept:
This question is based on Colour of compounds (salt)
Solution:
A. K2Cr2O7 – Orange: Correct.
B. PbCrO4 – Red: Incorrect. Lead chromate (PbCrO4) is yellow, not red.
C. CrO5 – Yellow: Incorrect. CrO5 is typically blue or violet.
D. Cu2+ (Borax bead test, oxidizing flame) – Blue : Incorrect.
E. Cu2P[Fe(CN)] – Chocolate brown: Correct.
F. Fe4[Fe(CN)6]3 Prussian blue: Correct. This is the formula for Prussian blue.
G. K2MnO4 – Dark Green : Correct.
Final Answer: (4)

53) Solution :
1. (Bismuth): Forms a white precipitate ) which is insoluble in excess NaOH .
2. (Cadmium): Forms a white precipitate which is insoluble in excess NaOH .
3. (Zinc): Forms a white precipitate ) which dissolves in excess NaOH to form a
colorless solution (soluble).
4. (Aluminum): Forms a white gelatinous precipitate Al(OH)3 ) which dissolves in
excess NaOH (soluble).
5. , (Lead): Forms a white precipitate Pb(OH)2 ) which dissolves in excess NaOH
(soluble).
6. (Tin II): Forms a white precipitate Sn(OH)2 ) which dissolves in excess NaOH (soluble).
7. (Manganese): Forms a white/flesh-colored precipitate Mn(OH)2 ) which is insoluble in
excess NaOH.
8. (Cobalt): Forms a blue precipitate which is insoluble in excess NaOH .
9. (Copper): Forms a light blue precipitate which is insoluble in excess NaOH.
Chemistry LibreTexts +5
The ions that form a precipitate that is insoluble in excess NaOH are: , Co2+ ,
and .
Therefore, there are 5 such ions.
Final Answer : 5

54)

Refer class notes