Solutions - Complete Notes (Board Revision)
1. Solution
A homogeneous mixture of two or more substances.
2. Components
Solute: Present in smaller amount and gets dissolved.
Solvent: Present in larger amount and dissolves the solute.
3. Types of Solutions
Solid in Liquid: Salt in Water
Liquid in Liquid: Alcohol in Water
Gas in Liquid: CO■ in Cold Drink
Gas in Gas: Air
4. Saturated / Unsaturated / Supersaturated
Unsaturated: More solute can dissolve.
Saturated: No more solute dissolves.
Supersaturated: Contains more dissolved solute than a saturated solution; unstable.
5. Solubility
Maximum amount of solute that dissolves in a given amount of solvent at a given temperature.
6. Factors Affecting Solubility
Temperature: Solids generally ↑, Gases generally ↓.
Pressure: Mainly affects gases. Higher pressure → Higher gas solubility.
7. Concentration Terms
Mass % = (Mass of Solute / Mass of Solution) ×100
Volume % = (Volume of Solute / Volume of Solution) ×100
ppm = (Mass of Solute / Mass of Solution) ×10■
Molarity (M) = Moles of Solute / Volume of Solution (L)
Molality (m) = Moles of Solute / Mass of Solvent (kg)
Mole Fraction (χ) = Moles of Component / Total Moles
8. Henry's Law
At constant temperature, the solubility of a gas in a liquid is directly proportional to the pressure of
the gas above the liquid.
Application: Cold drinks, scuba diving.
9. Raoult's Law
For an ideal solution, the vapour pressure of the solvent is directly proportional to its mole fraction.
P = X(solvent) × P°
10. Ideal & Non-Ideal Solutions
Ideal: Obey Raoult's law, no heat or volume change on mixing.
Non-Ideal: Deviate from Raoult's law.
11. Colligative Properties
Depend only on the number of solute particles.
• Relative lowering of vapour pressure
• Elevation in boiling point
• Depression in freezing point
• Osmotic pressure
12. Osmosis
Movement of solvent through a semipermeable membrane from lower concentration to higher
concentration.
13. Reverse Osmosis
Applied pressure reverses osmosis. Used in RO water purifiers.
14. Quick Revision
• Solute = Smaller amount
• Solvent = Larger amount
• Molarity → Litre of Solution
• Molality → kg of Solvent
• Henry: Pressure ↑ ⇒ Gas solubility ↑
• Raoult: Vapour pressure ∝ Mole fraction
• PV=nRT is Ideal Gas Equation (not Solution chapter, but often confused)