SRI SAIRAM PU COLLEGE
CHEMISTRY (34)
SOLUTIONS
I . Select the correct option from the given choice (1mark)
1. The concentration of a solution expressed in terms of moles of solute
per kilogram of solvent is called:
A) Molarity B) Molality C) Mole fraction D) Mass percentage
2. Which of the following concentration terms is independent of temperature?
A) Molarity B) Molality C) Normality D) Volume percentage
3. According to Henry's law, the solubility of a gas in a liquid is:
A) Directly proportional to the partial pressure of the gas
B) Inversely proportional to the partial pressure of the gas
C) Independent of pressure
D) Directly proportional to temperature
4. The value of Henry's law constant Kₕ for a gas is higher at higher temperature.
This indicates that the solubility of the gas:
A) Increases with increase in temperature
B) Decreases with increase in temperature
C) Remains constant
D) First increases and then decreases
5. Which of the following is an example of a solution containing gas in liquid?
A) Air B) Soda water C) Brass D) Sugar solution
6. For an ideal solution, the enthalpy of mixing (ΔH ₘᵢₓ) is:
A) Positive B) Negative C) Zero D) Infinite
7. For an ideal solution, the volume of mixing (ΔV ₘᵢₓ) is:
A) Positive B) Negative C) Zero D) Temperature dependent
8. A solution of ethanol and acetone shows positive deviation from Raoult's law
because:
A) A–B interactions are stronger B) A–B interactions are weaker
C) A–B interactions are equal to A–A interactions D) Both liquids form an azeotrope
always
9. Which of the following shows negative deviation from Raoult's law?
A) Ethanol + Acetone B) Chloroform + Acetone
C) Benzene + Toluene D) n-Hexane + Ethanol
10. The vapour pressure of a solution containing a non-volatile solute is:
A) Greater than that of pure solvent
B) Equal to that of pure solvent
C) Less than that of pure solvent
D) Independent of the amount of solute
11. The relative lowering of vapour pressure of a dilute solution is equal to:
A) Mole fraction of solvent B) Mole fraction of solute
C) Molality of solvent D) Molarity of solute
12. Which of the following is not a colligative property?
A) Relative lowering of vapour pressure B) Elevation in boiling point
C) Depression in freezing point D) Viscosity
13. When a non-volatile solute is added to a solvent, the boiling point of the
solution:
A) Decreases B) Increases C) Remains unchanged D) Becomes zero
14. The elevation in boiling point of a solution is given by:
A) ΔTᵦ = Kᵦm B) ΔTᵦ = Kᶠm C) ΔTᵦ = Kᵦ/m D) ΔTᵦ = m/Kᵦ
15. A solution containing 1 mole of solute and 9 moles of solvent has the mole
fraction of solute equal to:
A) 0.01 B) 0.1 C) 0.9 D) 1.0
16. The osmotic pressure of a solution is represented by:
A) π = CRT B) π = C/RT C) π = RT/C D) π = C + RT
17. Reverse osmosis is used for:
A) Increasing the concentration of salt in seawater
B) Desalination of seawater
C) Increasing boiling point
D) Separating gases
18. The van't Hoff factor for K₂SO₄, assuming complete dissociation, is:
A) 1 B) 2 C) 3 D) 4
19. If a solute undergoes association in solution, the experimentally determined
molar mass will be:
A) Lower than the normal molar mass
B) Higher than the normal molar mass
C) Equal to the normal molar mass
D) Zero
20. A solution containing 0.5 mol of a non-volatile solute in 1 kg of water has Kᵦ =
0.52 K kg mol⁻¹. The elevation in boiling point is:
A) 0.26 B) 0.52 K C) 1.04 K D) 2.60 K
[Link] mass percentage (W/W) of glucose in water is 10% means.
a) 10g of glucose dissolved in 100 g of water
b) 10g of glucose dissolved in 90 mL of water
c) 10g of glucose dissolved in 100 mL of water
d) 10g of glucose dissolved in 90 g of water
22) Statement-1: If on mixing the two liquids, the solution becomes hot, it
implies that it shows negative deviation from Raoult's law.
Statement-2: Solutions which show negative deviation are accompanied by
decrease in volume.
a) Both Statement-1 and Statement-2 are true.
b) Statement-1 is true but Statement-2 is false;
c) Both Statement-1 and Statement-2 are false.
d) Statement-1 is false but Statement-2 is true.
23) The mixture which shows positive deviation from Raoult's Law is
a) n-hexane and n-heptane b) Bromoethane and chloroethane
c) Ethanol and Acetone d) Chloroform and Acetone
24) A student took two glasses of pure water from a water filter. He cools
glass-A in a fridge and warms the other glass-B on a stove. On comparing the
solubility of oxygen in H2O in glass-A and glass-B, he state that glass-'A'
contains
a) more oxygen than glass-B.
b) less oxygen than glass-B.
c) same amount of oxygen as in glass-B.
d) zero concentration of oxygen.
25) 10 mL of liquid 'A' and 20 ml. of liquid 'B' are mixed at 25 ° C The volume of
the solution was measured to be 30.1 mL. then,
a) ∆ Hmix>0 Solution shows negative deviation from Raoult's low.
b) ∆Hmix< 0 Solution shows negative deviation from Raoult's low.
C)∆Hmix >0 Solution shows positive deviation from Raoult's low.
d) ∆Hmix <0 Solution shows positive deviation from Raoult's low.
26) A binary solution has two components 'A' and 'B'. The mole fraction of
component 'A' is 0.5, then the number of moles of components 'A and 'B' in the
solution is
a) nA > nB b) nA < nB C)nA= nB d) All of these
[Link] cells retain their normal shape in solution which are
a) hypotonic to blood b) hypertonic to blood
c) isotonic to blood sd) not equimolar to blood.
[Link] the items given in Column I with the type of solutions given In
Column II.
Column I Column II
i) Soda water. A) A solution of liquid in solid
ii)Sugar solution. B) A solution of gas in gas
iii)German silver. C) A solution of solid in liquid
iv)Air. D) A solution of solid in soild
v)solid in solid E) A solution of gas in liquid
a) (i) - B;(ii)- C;(iii)-D; (iv)-E
b) (i) - E (ii) - C;(iii) -D;(iv)-B;
c) (i) - B;(ii) -E; (iii)-D; (iv)B;-
d) (i) - E;(ii) - C; (iii)–B;(iv)-D;
[Link] one mole of a substance is present in one kg of solvent, then
a) It shows molar concentration
b) It shows molal concentration
c) It shows normality
d) It shows strength g/g
[Link] of the following is dependent on temperature?
a) Molarity b) Mole fraction c) Weight percentage d) Molality
[Link] in the blanks which using the appropriate words from those use in
the brackets. (1mark)
SET-1
[Less, More, Solid, Nitrogen, one, Isotonic]
31) Van't Hoff factor for KCl solution assuming the complete dissociation is __
32) Solutions having the same osmotic pressure are called____
33) At the same temperature nitrogen gas is____soluble in water than oxygen.
34) In deep sea diving the disease called Bends is caused due to the dissolution
of___in the blood.
35) 22 carat gold is an example of solid in____solution.
SET-2
[Solvent, Pressure, Osmotic, Molarity , Mole Molality]
[Link] component present in larger quantity in a solution is called the ____.
[Link] concentration of a solution expressed as the number of moles of solute
present in one litre of solution is called ____.
[Link] solubility of a gas in a liquid increases with increase in ____.
[Link] to Raoult's law, the partial vapour pressure of a volatile component is
proportional to its ____ fraction.
[Link] colligative property used to determine the molar mass of a solute is ____
pressure.
III. Answer the following question. Each question carry three marks.
41. Define molarity. How does it very along the temperature. mention its SI unit .
42. What is molality. How does it very along the temperature .mention it SI unit.
43. State Henry's. mention its application
44. Give the difference between ideal and non- ideal solution.
45. Give the difference between positive and negative deviation
46. What are azeotropic mixture. give example for minimum and maximum boiling
azeotrophes.
47. State raoult' s law and raoult 's law of RLVP? Mention its mathematical form.
48. What are isotonic solution. Explain the types of isotonic solution
49. Define reverse osmosis explain desalination of sea-water.
50. Define colligative property mention it types
51. What are binary solution? give example.
52. Define vant' factor. mention its significance
53. Give the graph for elevation in boiling point and depression and freezing point.
54. Calculate the vant's hoff factor for Kcl, Na2So4, Alcl3, Cr2(So4)3, Bacl2 ethanoic acid in
benzene.
[Link] happens to the solubility of gas in liquid with increase in temperature? Give
reason
56. Explain the factors on solubility in solid in liquid and gas in liquid based on pressure
and temperature.