22-03-2026

0999DJM262101250013 JM

PART-1 : PHYSICS

SECTION-I

1) Two uniform steel rods P and Q of length ℓ and 2ℓ and radii 2r and r respectively are heated to
the same temperature. The ratio of the increase in lengths of P to that of Q is :-

(A) 1 : 1
(B) 1 : 2
(C) 2 : 1
(D) 1 : 4

2) A gas is filled in the cylinder shown in the figure. The two pistons are joined by a string. If the gas

is heated, the pistons will :-

(A) Move towards left

(B) Move towards right
(C) Remain stationary
(D) None of these

3) 28 gm of N2 gas is contained in a flask at a pressure of 10 atm and at a temperature of 57°C. It is

found that due to leakage in the flask, the pressure is reduced to half and the temperature reduced
to 27°C. The quantity of N2 gas that leaked out is

(A) 11/20 gm
(B) 20/11 gm
(C) 5/63 gm
(D) 63/5 gm

4) Five molecules of a gas are having speeds 1, 2, 4, 8 and 16 m/s at some instant. The root mean
square velocity of the gas molecules is :-

(A) 6.2 m/s

(B) 8.2 m/s
(C) 9.2 m/s
(D) 68 m/s
5) The mixture of two non-reacting gases A and B is in a container at a constant temperature. Gas A
is diatomic and B is monoatomic. The ratio of molecular masses of A and B is 4, their ratio of the rms
speeds is :-

(A) 1 : 1
(B) 1 : 2
(C)
(D)

6) An ideal gas is taken through the cycle A → B → C → A, as shown in figure. If the net heat supplied
to the gas in the cycle is 5 J, the work done by the gas in the process C → A is :-

(A) –5 J
(B) –10 J
(C) –15 J
(D) –20 J

7) A copper rod 2m long has a circular cross-section of radius 1 cm. One end is kept at 100ºC and
the other at 0ºC and the surface is covered by non-conducting material to check the heat losses
through the surface. The thermal resistance of the bar in degree kelvin per watt is (Take thermal
conductivity K = 401 W/m-K of copper):-

(A) 12.9
(B) 13.9
(C) 14.9
(D) 15.9

8) A 5g piece of ice at –20°C is put into 10g of water at 30°C. Assuming that heat is exchanged only
between the ice and the water, find the final temperature of the mixture :

(A) 0°C
(B) 30°C
(C) –20°C
(D) 10°C

9) If tan θ = and θ lies in the first quadrant, the value of cos θ is :

(A)
(B)
–

(C)

(D)
–

10) Which is dimensionless :-

(A)

(B)

(C)

(D)

11) V = at + , V = velocity, t = time, a, b, c are constants. The dimensions of a, b and c are

(A) LT–2, L and T

(B) L2, T and LT2
(C) LT2, LT and L
(D) L, LT and T2

12) Which of the following is correct regarding these four vectors?

(A)
(B)
(C)
(D)

13)

A particle moving in a straight line covers half the distance with speed of 3m/s. The other half of the
distance is covered in two equal time intervals with speed of 4.5 m/s and 7.5 m/s respectively. The
average speed of the particle during this motion is :-

(A) 4.0 m/s

(B) 5.0 m/s
(C) 5.5 m/s
(D) 4.8 m/s

14) Three balls are projected with equal speed at angle 15°, 45°, 75° and their ranges are
respectively R1, R2 and R3 then :-

(A) R2 > R1 > R3

(B) R1 > R2 > R3
(C) R1 = R2 = R3
(D) R1 = R3 < R2

15) If two ends of an ideal rope are pulled with forces of equal magnitude of 100 N in opposite
direction, the tension at the center of the rope must be

(A) 200 N
(B) 100 N
(C) 50 N
(D) 0 N

16) A box is lying on an inclined plane what is the coefficient of static friction if the box starts sliding
when an angle of inclination is 60° :-

(A) 1.173
(B) 1.732
(C) 2.732
(D) 1.677

17) The kinetic energy acquired by a body of mass m in travelling some distance s, starting from rest
under the action of a constant force, is directly proportional to

(A) m°
(B) m
(C) m2
(D)

18) One projectile moving with velocity v in space, gets burst into 2 parts of masses in the ratio 1 : 3.
The smaller part becomes stationary. What is the velocity of the other part ?

(A) 4v
(B) v

(C)

(D)

19) A uniform square plate abcd has a mass of 1 kg. If two point masses each of 20 g are placed at
the corners b and c as shown, then the centre of mass shifts on the line :-

(A) OW
(B) OX
(C) OY
(D) OZ

20) Two discs having masses in the ratio 1 : 2 and radii in the ratio 1 : 8 roll down without slipping
one by one from an inclined plane of height h. The ratio of their linear velocities on reaching the
ground is:-

(A) 1 : 16
(B) 1 : 128
1:8
(C)

(D) 1 : 1

SECTION-II

1) A block of aluminium of mass 1 kg and volume 3.6 × 10–4 m3 is suspended from a string and then
completely immersed in a container of water. The decrease in the tension in the string [Round off to
nearest integer] (in N) after immersion is :-

2) A particle moves such that acceleration is given by a = – 4x. The period of oscillation is xπ. Find x.

3) If 100 N force is applied on the block then frictional force acting on the block will be :

4) A body of mass 3 kg is under a force, which causes a displacement in it given by S = (in m).
Find the work done by the force in first 2 seconds.

5) A body of mass 10 kg and radius of gyration 50 cm, is being acted on by a torque of 108 dyne-cm.
The angular acceleration produced in the body is
(in rad/s2) :-
 PART-2 : CHEMISTRY

SECTION-I

1) IUPAC name of the compound is

(A) 2-Chlorocarbonyl ethylbenzenecarboxylate

(B) 2-Carboxyethylbenzoyl chloride
(C) Ethyl 2-(chlorocarbonyl) benzenecarboxylate
(D) Ethyl 1-(chlorocarbonyl) benzenecarboxylate

2) Select the pair of chain isomer ?

(A)
and

(B)
and

(C)
and

(D)
and

3) Appearance of blood red colour, on treatment of the sodium fusion extract of an organic
compound with FeSO4 in presence of concentrated H2SO4 indicates the presence of element/s

(A) Br
(B) N
(C) N and S
(D) S

4) Which of the following is correct order of stability :-

(A) I > III > II > IV

(B) I > II > III > IV
(C) III > I > II > IV
(D) I > IV > III > II
5) Correct order of Acidic strength :

(A) C2H5OH < CH3COOH < C6H5OH

(B) C6H5OH < CH3COOH < C2H5OH
(C) CH3COOH < C6H5OH < C2H5OH
(D) C2H5OH < C6H5OH < CH3COOH

6) In which of the following compound least stable :-

(A)

(B)

(C)

(D)

7) The orbital angular momentum of a p-electron is given as :-

(A)

(B)

(C)

(D)

8) Consider the reaction whose KC = 36,

if 0.1 mole each of SO2 and NO2 are placed initially in 1 litre container then; What is the
concentration of SO2 at equilibrium ?

(A) 0.003 M
(B) 0.015 M
(C) 0.085 M
(D) 0.097 M

9) In which of the following equilibrium, KC and KP are unequal ?

(A) 2C(s) + O2(g) ⇌ 2CO2(g)

(B) 2NO(g) ⇌ N2(g) + O2(g)
(C) SO2(g) + NO2(g) ⇌ SO3(g) + NO(g)
(D) H2(g) + I2(g) ⇌ 2HI(g)
10) In a compound of X and Y, X is 40% by mass of compound and atomic weight of X is 60% of Y.
Empirical formula is :-

(A) X9Y8
(B) X10Y9
(C) X9Y10
(D) X8Y9

11) 0.01 mole of iodoform (CHI3) reacts with Ag to produce a gas whose volume at NTP is
2CHI3 + 6Ag → 6AgI(s) + C2H2(g)

(A) 224 mL
(B) 112 mL
(C) 336 mL
(D) None of these

12) Which of the following groups of molecules act both as oxidising agent as well as reducing
agent?

(A) KMnO4, O3, SO3

(B) HClO4, HNO2, H2O2
(C) HNO2, SO2, H2O2
(D) HNO3, SO2, H2SO4

13)

The total no. of proton, electrons and neutrons in 12 g of 6C12 is :-

(A) 1.084 × 1025

(B) 6.022 × 1023
(C) 6.022 × 1022
(D) 18

14) The molecule having only one lone pair is

(A) ClF3
(B) NH3
(C) H2O
(D) PCl3

15) Which of the following molecule does not show back-bonding :-

(A) N(SiH3)3
(B) BCl3
(C) AlF3
(D) : CF2

16) Which of the following molecule have only pπ – dπ type of pie (π) bonds :-

(A) SO3
(B) XeO4
(C) XeO2F2
(D) Both (B) and (C)

17) Which of the following is transuranic element :

(A) Ce
(B) Th
(C) Cd
(D) Cf

18) The correct order of the atomic radii of C, Cs, Al and S is :

(A) S < C < Al < Cs

(B) S < C < Cs < Al
(C) C < S < Cs < Al
(D) C < S < Al < Cs

19) Arrange the following in increasing order of energy :-

(i) n = 4, ℓ = 2, m = –1, s = +½
(ii) n = 3, ℓ = 2, m = –1, s = –½
(iii) n = 4, ℓ = 0, m = 0, s = +½
(iv) n = 5, ℓ = 0, m = 0, s = –½

(A) (i) < (ii) < (iii) < (iv)

(B) (iii) < (ii) < (iv) < (i)
(C) (iii) < (iv) < (ii) < (i)
(D) (ii) < (iii) < (i) < (iv)

20) Which electronic configuration represents a violation of Hund’s rule rule and Pauli’s rule
both for an atom in its ground state ?

(A)

(B)

(C)
(D)

SECTION-II

1)

The IUPAC name of is p-ethyl-q, r-dimethyl heptane; then the value of (p + q - r) is

equal to

2) The number of possible alkynes with molecular formula C5H8 is

3) The number of atomic orbitals from the following having 5 radial nodes is ________.
7s, 7p, 6s, 8p, 8d

4) In the following reaction the value of X is

H2O + SO3–2 → SO4–2 + 2H+ + X e–

5) Ions having, radius greater than Mg+2

Na+, N3–, Be+2, O2–, S2–, Al3+

PART-3 : MATHEMATICS

SECTION-I

1) If , then a =

(A) –5
(B) –6
(C) –4
(D) –2

2) If , then –

(A) x2 = y
(B) x = y
(C) x = y2
(D) x3 = y
3) If roots of equation 3x2 + x + 4 = 0 are in 3 : 2 then p =

(A)
(B)
(C) 50
(D) 100

4) Sum of an infinite G.P. is times the sum of all the odd terms. The common ratio of the G.P. is :-

(A)

(B) 4

(C)

(D) None of these

5)

The total number of words can be made by using all letters of word 'ALLEN' If all vowels occurs in
alphabatical order :-

(A) 120
(B) 60
(C) 30
(D) 12

6) Imaginary part of conjugate of complex number

z= is :-

(A)

(B)
–
(C) – 4
(D) 4

7) The number of integral values of 'c' for which the circle x2 + y2 – 4x – 6y + c = 0 does not touch or
intersect the coordinate axes and point (2, 2) lies inside the circle is

(A) 2
(B) 3
(C) 4
(D) 5

8) The length of the latus rectum of the ellipse

9x2 + 5y2 – 30y = 0 is -

(A)

(B)

(C)

(D)

9) If the eccentricities of the ellipse =1

and the hyperbola = 1 are reciprocals of each other, then b2 =

(A) 192
(B) 64
(C) 16
(D) 32

10) If the focus of a parabola is (–2, 1) and the directrix has the equation x + y = 3 then the vertex is
-

(A) (0, 3)

(B)

(C) (–1, 2)
(D) (2, –1)

11) If the slope of a line passing through the point A(3, 2) is , then the points on this line which are
5 units away from A, are :-

(A) (5, 5) and (–1,–1)

(B) (7, 5) and (–1, –1)
(C) (5, 7) and (1, 1)
(D) (7, 5) and (1, 1)

12) A line L passes through (1, 1) and (0, 2) and another line M passes through and
perpendicular to L. The Area of triangle forming these lines with y-axis is :-

(A)

(B)
(C)

(D)

13) The value of

is

(A)

(B)

(C)

(D)

14) If tanA + cotA = 4; then tan4A + cot4A equals :-

(A) 156
(B) 175
(C) 135
(D) 194

15) The line x + y + 4 = 0 divides the line joining the points (–1,1) and (5,7) in the ratio :-

(A) 4 : 1
(B) 1 : 4
(C) 1 : 4 externally
(D) None of these

16) The value of is :

(A)
(B)
(C)
(D)

17) If f(x) = sin , x ∈ R, then domain of f(x) are given by –

(A) (–2, 1)
(B) (–∞, –2) ∪ (1, ∞)
(C) (0, 1)
(D) None of these
18) The value of is :-

(A)

(B)

(C) 0
(D) None

19)

If , then is equal to

(A) 2 ln x
(B) 2 ln x + 1
(C)

(D)

20) Let x1, x2, ...., xn be n observations such that and . Then a possible value
of n among the following is

(A) 15
(B) 18
(C) 9
(D) 12

SECTION-II

1) If are in AP and ;
then the sum of 24 terms of this AP is-

2) If the coefficients of rth and (r + 1)th terms in the expansion of (3 + 7x)29 are equal, then r equals:

3) y + x = 0 & y – x = 0 are tangents at the vertex & axis of a parabola respectively and y = 2x + 3 is
a tangent to the same parabola, the coordinate of whose focus is (a, b), then 6(a + b) is equal to

4) The value of is

5) From a pack of 52 cards a card is drawn at random then probability of getting ace or card of

spade is .
(where a, b are co-prime) then b – a =
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B D B B A D A A D A B A D B B A C C D

SECTION-II

Q. 21 22 23 24 25
A. 4 1 100 24 4

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C D C A D A C B A B B C A B C D D D B B

SECTION-II

Q. 46 47 48 49 50
A. 3 3 3 2 4

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C C C A C A A C A C B B B D C B A A D B

SECTION-II

Q. 71 72 73 74 75
A. 900 21 4 1 9
 SOLUTIONS

PART-1 : PHYSICS

1) ΔL = Lα.Δt
∴ ΔL ∝ L

2) When temperature of gas increases, it expands. As the cross-sectional area of right piston is
more, therefore greater force will work on it (because F = PA). So piston will move towards
right.

3)
P α m.T

Leaked mass =

4)

5)

6) From A to B WAB = P(VB – VA) = 10 (2–1)

= 10 J
From B to C, volume is constant, hence WBC = 0
Given Q = 5 J for the closed cycle ABCA
Thus, work done during the closed cycle is also 5 J
Now Wtotal = WAB + WBC + WCA = 5 J
10 + 0 + WCA = 5J
WCA = –5J

7)

Thermal resistance,

R=
= = 15.9 kelvin/watt

8) Given : 5gm ice at –20°C

on mixing
0°C ice = 50 cal

0°C water
10 gm water at 30°C

0°C water
so all heat of water will be taken by ice & mixture will be at 0°C

9)

10) = [1]

11) C = [T]
a[T] = [LT–1]
a= [LT–2]

[LT–1] =
b = [L]
12) (according to pollygon law)

13)
x1 = 4.5t2, x2 = 7.5t2

Also x1 + x2 =

That is

t = t1 + 2t2 =

v=

14) R1 = R3 < R2

15) TC = 100 N

16) µ = tan(Angle of repose) = tan60° = 1.732

17) K.E. acquired by the body = work done on the body K.E. mv2 = Fs i.e. it does not depends
upon the mass of the body although velocity depends upon the mass

v2 ∝ [If F and s are constant]

18) Pi = Pf

m(V) = (O) + (V1)

⇒ V1 = 4V/3

19) C.O.M shifts towards OY as mass shift towards there.

20)

21) Here, mass of block, m = 1 kg

volume of a block, V = 3.6 × 10–4 m3
Tension in the string, T = mg, T' = mg –
∴ Decrease in the tension of string T – T'
= mg – [mg – Vρwaterg] = Vρwater g
= (3.6 × 10–4 m3) × (103 kgm–3) ×(10ms–2) = 3.6 N
 22)

∵ a = – ω2x
given a = – 4x ⇒ ω2 = 4
ω=2

∴T= = =π×l

23) 100 N

24)

S=
∴ dS = t2dt

⇒a= =
Now work done by the force

W=

25)

τ = Iα
I = MK2

PART-2 : CHEMISTRY

26)

27) Difference in length of parent carbon chain or side chain.

28)
Appearance of blood red colour indicates presence of both nitrogen and sulphur.

29) Stability of carbocation ∝ + m1 + I1 + h ∝

30)

31) Anti-Aromatic least stable.

32) Oribital angular moment =

for p orbital ℓ = 1

33) t = 0 0.1 mole 0.1 mole 0 0

t = teq (0.1 – x) (0.1 –x) x x

∴ [SO2] = 0.1 – 0.085 = 0.015 M

34) In (A), and hence KC ≠ KP. However, in all the other cases, .

35)

X : Y

:
10 : 9
X10Y9

36) 2 mole CHI3 ® 1 mole C2H2

1 mole → mole C2H2

.01 mole → × .01 mole

Volume = × .01 × 22.4

= .112 1tr
 = 112 m1

37) Compounds where oxidation state of central atom ⇒ O.S. between min. & max.
⇓
Act as both
Oxidant, Reductant

38)

total (P + e– + n) ⇒ 6 + 6 + 6 ⇒ 18 mol
⇒ 18 × 6.023 × 1023 ⇒ 1.084 × 1025

39)

40) Question Explanation: Identify the molecule that does not show back-bonding.
Concept: Back-Bonding.
Solution: Back-bonding requires a vacant orbital on one atom and a lone pair on an adjacent
atom.

A. N(SiH3​)3​: pπ−dπ back-bonding.

B. BCl3​: pπ−pπ back-bonding.
C. AlF3​: Predominantly ionic. AlF3​ in the solid state is ionic/polymeric and does not show typical
molecular back-bonding.

Final Answer: Option (C)

41)

The Correct Answer is (D)

42) Question Explanation: Identify the transuranic element from the list.
Concept: Transuranic Elements.
Solution: Transuranic elements are chemical elements with atomic numbers greater than 92
(the atomic number of Uranium). Californium (Cf) has an atomic number of 98, making it a
transuranic element.
Final Answer: Option (D)

43) Question Explanation: Correct order of atomic radii.

Concept: Atomic radii trends.

Solution:
Atomic radius increases down a group and decreases across a period. Cs is in a different
period and group from C, S, and Al. S and Al are in the same period, with Al having a larger
radius than S. C is in a different period. The correct order from smallest to largest is C, S, Al,
and Cs.

Atomic radii order : C < S < Al < Cs

Atomic radius of C : 170 pm
Atomic radius of S : 180 pm
Atomic radius of Al : 184 pm
Atomic radius of Cs : 300 pm
Final Answer: Option (D)

44) From (n + ℓ) Rule

45) Theory based.

46)

p=3
q=4
r=4

47) C5H8 :
(a) HC≡C–CH2–CH2–CH3
(b) CH3–C≡C–CH2–CH3

48) Radial node = n – ℓ –1

7s ⇒ R.N = 7 – 0 – 1 = 6
7p ⇒ R.N = 7 – 1 – 1 = 5
6s ⇒ R.N = 6 – 0 – 1 = 5
8p ⇒ R.N = 8 – 1 – 1 = 6
8d ⇒ R.N = 8 – 2 – 1 = 5
So, Answer is 3

49)
ΔO.N. = 6 – 4 = 2

50)
 Ions having radius greter then Mg+2. in following ions Na+, N–3, O–2, S–2 has more radius then
Mg+2.
S–2 has large radius due to more [Link] e–[18e–] Na+ has less attraction from neuclesus the Mg+2,
N–3 & O–2 has 3 & 2 extra e– So attraction from neuclesus decreses.
hence total 4 ione Na+, N–3, O–2 & S–2

PART-3 : MATHEMATICS

51) squaring both sides,

=8+5+2 ⇒ a=–4

52) log2 y =

⇒ log2 y = logx 4 =
⇒ 2 log2 y = log2 x ⇒ y2 = x

53) =

p=
p = 50

54) Let the G.P. be a + ar + ar2 + ar3 + .... to ∞,

then a + ar + ar2 + .... =

(a + ar2 + ar4 +.... to ∞)

⇒ = 1+r=

55)

No. of words = = 30

56) z =
conjugate

imaginary part of

57)

So, 2 values of (c)

58) 9x2 + 5(y2 – 6y) = 0

⇒ 9x2 + 5(y2 – 6y + 9) = 45

∴ =

59) Eccentricity of given ellipse is

⇒e=
∴ Eccentricity of hyperbola is 2
∴ Using b2 = a2 (e2 – 1)
b2 = 64 (4 – 1)
= 64 (3) = 192

60) The vertex is the middle point of the perpendicular dropped from the focus to the directrix.

61) Here tanθ = ⇒ sinθ = and cosθ =

Hence

62) Equation of line L is y = – x +2

Equation of line M is y = x –

If these lines meet y-axis at P and Q then PQ =

Intersection point of these line

so area =

63)
 E= (1 + cos20°)(1 + cos100°)(1 + cos140°)

= (2cos210°)(2cos250°)(2cos270°)

64) Given tanA + cotA = 4

on squaring, tan2A + cot2A + 2 = 16
Again squaring, tan4A + cot4A = 194.

65)

Ratio

66)

The Correct Answer is (B)

67) ∴ loge a is defined for a > 0.

∴ log is defined for

. ....(1)
Now is real
if –2 ≤ x ≤ 2.
∴ (1) holds if –2 < x < 2 and 1 – x > 0

∵ = 0 when x = ± 2
⇒ –2 < x < 2 and x < 1 ⇒ –2 < x < 1.
Thus, the domain of f(x) is (–2, +1).

68)

Again rationalizing

69)

The Correct Answer is (D)

70)

The Correct Answer is (B)

71) a1 + a2 + a3 + ..... + a23 + a24 → A.P.

So, a1 + a24 = a2 + a23 = a5 + a20 = a10 + a15
= x(Let)
Now, a1 + a5 + a10 + a15 + a20 + a24 = 225
(a1 + a24) + (a5 + a20) + (a10 + a15) = 225
x + x + x = 225
3x = 225
x = 75 .....(1)

Sum of series = = 12 × 75 = 900

72) From given condition;

73) Intersection point of tangent at vertex & give tangent is (–1, 1).
perpendicular from focus on given tangent meets it at tangent at vertex.

⇒ focus is the intersection point of y = x &

⇒ coordinate of focus is

⇒ 6(a + b) = .

74)

75)

P(Ace ∪ spade) = P(A) + P(S) – P(A ∩ S)

=
b – a = 13 – 4 = 9