ARAVALI HILLS PUBLIC SCHOOL,TANKRI (REWARI)

Subjects : Chemistry IIT JEE

Total Marks : 380

Chemistry - Section A ( MCQ )

1. Ratio of of 10 g AB2 and 14 g A2B per 100 g of solvent in their respective, solution (AB2 and A2B both
ΔT b

Kb

are non-electroytes) is 1 mol/kg in both cases. Hence, atomic wt. of A and B are respectively :
A) 100, 40 B) 60, 20 C) 20, 60 D) None of these
2. The amount (in grams) of sucrose (mol wt. = 342 g) that should be dissolved in 100 g water in order to
produce a solution with a 105. 0 C difference between the freezing point and boiling point is
o

(Given that K = 1.86 K kg mol and K = 0.51 K kg mol for water)

f
−1
b
−1

A) 34. 2 g B) 72. 2 g C) 342 g D) 460 g

3. A 0.10 M solution of a monoprotic acid (d = 1.01 g/cm3) is 5% ionized. What is the freezing point of the
solution ? The molecular weight of the acid is 300 g/mol and Kf(H2O) = 1.86o C/m.

A) -0.189oC B) -0.194oC C) -0.199oC D) None of these

4. Benzene and napthalene form ideal solution over the entire range of composition. The vapour pressure of
pure benzene and naphthalene at 300 K are 50.71 mm of Hg and 32.06 mm of Hg respectively. What will
be the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of naphthalene?
A) 0.0675 B) 0.675 C) 0.35 D) 0.5
5. Urea (NH − CO − NH ) needs to be dissolved in 100g of water, in order to decrease the vapour pressure
2 2

of water by 25%? What will be the molality of the solution?

A) 18.52 B) 62.45 C) 28.52 D) 35.64
6. A 5.25% solution of a substance is isotonic with a 1.5% solution of urea ( molar mass = 60 g mol-1) in the
same solvent. If the densities of both the solutions are assumed to be equal to 1.0 g cm-3, molar mass of
the substance will be
A) 210 g mol-1 B) 90.0 g mol-1 C) 115.0 g mol -1 D) 105.0 g mol -1

7. The solubility of N in water at

2 300 K and 500 torr partial pressure 0.01 g L
−1
. The solubility (in g L
−1
) at
750 torr partial pressure is:

A) 0.0075 B) 0.005 C) 0.02 D) 0.015

8. 2.0 molal aqueous solution of an electrolyte X 2 Y3 is 75% ionised. The boiling point of the solution a 1 atm is
−1
(K b(H 2 O) = 0.52 K kg mol )

A) 274.76 K B) 377 K C) 376.4 K D) 377.16 K

9. pH of 0.1 M aqueous solution of weak monoprotic acid HA is 2. Calculate osmotic pressure of this solution
at 27 C. Take solution constant R = 0.082 L atm/K-mol
o

A) 2.46 atm B) 3.5 atm C) 3.05 atm D) 2.7 atm

10. The vapour pressure of pure liquid A is 10 torr and at the same temperature when 9 g of B solid dissolved
in 20 g of A, its Vapour pressure is reduced to 5 torr. If the molecular mass of A is 200 amu, then the
molecular mass of B is
A) 100 amu B) 90 amu C) 75 amu D) 120 amu

1
11. K 2 HgI 4 is 55% ionized in aqueous solution. The value of Van't Hoff factor is
A) 2.1 B) 4.3 C) 1.9 D) 3.7
12. 3.0 molal aqueous solution of an electrolyte A 2 B3 is 50 % ionised. The boiling point of the solution at 1 atm
is: [K (H O) = 0.52 Kkgmol ]
b 2
−1

A) 274.76 K B) 377.68 K C) 374.68 K D) 104.68 K

13. The concentration in g/L of a solution of cane sugar (Molecular weight = 342) which is isotonic with a
solution containing 6 g of urea (Molecular weight= 60) per litre is
A) 3.42 B) 34.2 C) 5.7 D) 19
14. At a constant temperature, which of the following aqueous solutions will have the maximum vapour
pressure?
−1
(Mol. wt. NaCl = 58.5, H 2 SO 4 = 98.0 g mol )

A) 1 molal NaCl (aq)

B) 1 molar NaCl (aq)

C) 1 molal H 2 SO 4 (aq)

D) 1 molar H 2 SO 4 (aq)

15. The amount (in grams) of sucrose ([Link]. = 342 g) that should be dissolved in 100 g water in order to
produce a solution with a 105.0 C difference between the boiling point and freezing point is
o

(Given that kƒ = 1.86 Kkgmol and k = 0.52 Kkgmol for water)

–1
b
–1

Report your answer by rounding it up to the nearest whole number.

A) 75.55 g B) 72.2 g C) 74.30 g D) 80.55 g
16. For a mixture of two volatile,completely miscible liquids A and B, with P = 500 torr and P ∘

A
∘

B
,
= 800 torr

What is the composition of last droplet of liquid remaining in equilibrium with vapour?
Provided the initial ideal solution has a composition of x = 0.6 and x = 0.4 A B

A) x A = 0.6 ; x
B
= 0.4 B) x A = 0.5 ; x
B
= 0.5 C) x A = 0.7 ; x
B
= 0.3 D) x A = 0.3 ; x
B
= 0.7

17. The vapor pressure of benzene is 53.3 kP at 603 C, but it falls to 51.5 kP when 19 g of a non-volatile
a
o
a

organic compound is dissolved in 500 g benzene. The molar mass of the non-volatile compound is
A) 82 B) 85 C) 88 D) 92
18. Which of the following is correct?
A) a liquid with low vapour pressure will have a low surface tension and high boiling point
B) a liquid with high vapour pressure will have high intermolecular forces and high boiling point
C) a liquid with low vapour pressure will have high surface tension and high boiling point
D) a liquid with low vapour pressure will have low surface tension and low boiling point
19. Identify the correct statement:
A) 0.1 M NaCl and 0.1 M glucose solution are isotonic.
B) 0.1 M NaCl and 0.3 M glucose solution are isotonic.
C) The boiling point of 0.1 m aqueous urea solution is less than 0.1 m aqueous KCl solution.
D) The freezing point of 0.1 m glucose solution is less than 0.1 m KCl solution.
20. Which one of the following statements regarding Henry's law is not correct?

2
 A) The value of K changes with the nature of the gas.
H

B) Higher the value of K at a given pressure, higher is the solubility of the gas in the liquids
H

C) The partial pressure of the gas in vapour phase is proportional to the mole fraction of the gas in the
solution.
D) Different gases have different K (Henry's law constant) value at the same temperature.
H

21. 100 g of liquid A (molar mass 140 g mol ) was dissolved in 1000 g of liquid B (molar mass 180 g mol ). The
−1 −1

vapour pressure of pure liquid B was found to be 500 torr. Calculate vapour pressure of A (in torr) the
solution if the total vapour pressure of the solution is 475 torr.
A) 25torr B) 32torr C) 30torr D) 29torr
22. A solution containing 10 g of a non-volatile, higher nonelectrolyte and 400 g of water boils at 100.256 o
C at
1 atm. The molecular weight of the solute (in g/mol) is

Given: (K for water 0.512 οC/m)

b

A) 50 g/mol B) 60 g/mol C) 70 g/mol D) 80 g/mol

23. The osmotic pressure of equimolar solutions of urea, BaCl and AlCl will be in the order of
2 3

A) AlCl 3 > Urea > BaCl 2

B) Urea > BaCl 2 > AlCl 3

C) AlCl 3 > BaCl 2 > U rea

D) BaCl 2 > AlCl 3 > Urea

24. Which of the following represents correctly the changes in thermodynamic properties during the
formation of an ideal binary solution:
A) B) C) D)

25. Which of the following statements is true for all the alkali metals?
A) Their nitrates decomposes on heating to give the corresponding nitrites and oxygen
B) Their chlorides are deliquescent and crystallize as hydrates.
C) They react with water to form hydroxide and hydrogen.
D) They react with halogens to form only ionic halides M +
X
−
.
26. A complex is represented as CoCl . xH O. Its 0.1 m solution in aqueous medium shows ΔT = 0.558 K. K
3 2 f f

for water is 1.86 kg mol K and assuming 100% ionisation of the complex having coordination number 6.
–1

The formula of the complex is

A) [Co(H 2 O) Cl]Cl 2
4
B) [Co(H 2 O) Cl 2 ]Cl
4
C) [Co(H 2 O) ]Cl 3
6
D) [Co(H 2 O) Cl]Cl 2
5

27. 0.15 gof a substance dissolved in 15 g of solvent boiled at a temperature higher by 0.216 C than that of the
o

pure solvent. The molecular weight of the substance is [Given: Molal elevation constant for the solvent is
2.16 Kkg mol ]
−1

3
 A) 50 g/mol B) 80 g/mol C) 100 g/mol D) 90 g/mol
28. Osmotic pressure of a sugar solution at o
24 C is 2.5 atmospheres. Determine the concentration of the
solution in mole per litre.
A) 0.0821 moles/litre B) 1.082 moles/litre C) 0.1025 moles/litre D) 0.0827 moles/litre
29. Mixture of voltaic component A and B has total vapure pressure (in torr)

P = 254 − 119X A .

Where X is mole fraction of A in the mixture. Hence, P & P (in torr) are:
A
0

A
0
B

A) 254, 199 B) 119, 254 C) 135, 254 D) 119, 373

30. If latent heat of fusion of ice is 80 cals per g at 0 o

C , calculate molal depression constant for water.
A) 18.63 B) 186.3 C) 1.863 D) 0.1863
31. 1 g of non-volatile non-electrolyte solute is dissolved in 100 g of two different solvents A and B whose
ebullioscopic constants are in the ratio of 1:5. The ratio of the elevation in their boiling point, , is
ΔT b (A)

ΔT b (B)

A) 5 : 1 B) 10 : 1 C) 1 : 5 D) 1 : 3
32. A current of dry air was passed first through a series of bulbs containing a solution of C H –NO in 6 5 2

ethanol of molality 0.725 and then through a series of bulbs containing pure ethanol. (T = 284 K) loss in
weight of the solvent bulbs was 0.0685 g. Calculate the loss in weight of the solution bulbs.
A) 4.60 g B) 5.20 g C) 2.50 g D) 2.05 g
33. The freezing point of equimolal aqueous solution will be highest for
A) C6 H5 N
+
H 3 Cl
−
B) Ca(NO 3 )
2
C) La(NO 3 )
3
D) C 6 H 12 O 6 (Glucose)
(aniline
hydrochloride)
34. A liquid is immiscible in water was steam distilled at 95.2oC at a pressure of 0.983 atm. What is the mass
of the liquid present per gram of water in the distillate. Molar mass of the liquid is 134.3 g/mol and the
vapour pressure of water is 0.84 atm. Also, Vapour pressure of pure liquid is 0.143 atm.
A) 1 g B) 1.27 g C) 0.787 g D) 13.43 g
35. At 48°C the vapour pressure of pure CS is 850 torr. A solution of 2.0 g of sulphur in 100 g of
2 CS 2 has a
vapour pressure 844.9 torr. Determine the atomicity of sulphur molecule :
A) 1 B) 2 C) 4 D) 8
36. The weight of glucose dissolved in 100 gm of water produce same lowering of vapor pressure as 1 gm
urea dissolved in 50gm of water at same temperature is
A) 8 of glucose B) 10 of glucose C) 6 of glucose D) 11 of glucose
37. 18 glucose (C H O ) is added to 178.2 g water. The vapour pressure of water (in torr) for this aqueous
6 12 6

solution at 273 K is
A) 759 B) 739.6 C) 746 D) 752.4
38. Pure water freezes at 273 K and 1 bar. The addition of 34.5 g of ethanol to 500 g of water changes the
freezing point of the solution. Use the freezing point depression constant of water as 2 K kg mol . The −1

figures shown below represent plots of vapour pressure (V.P.) versus temperature (T). [molecular weight of
ethanol is 46 g mol ] −1

Among the following, the option representing change in the freezing point is

4
 A) B) C) D)

39. Two beaker A and B present in a closed vessel. Beaker A contains 152 .4 g aqueous solution of urea,
containing 12 g of urea. Beaker B contains 196.2 g glucose solution, containing 18 g of glucose. Both
solutions allowed to attain the equilibrium. Determine wt. % of glucose in it's solution at equilibrium:
A) 6.71 B) 14.49 C) 16.94 D) 20
40. How much amount of NaCl should be added to 600 g of water ( ρ = 1.00 g/mL ) to decrease the freezing
point of water to –0.2 C ? o

(The freezing point depression constant for water = 2 K kg mol −1

)
A) 2.14 g B) 0.88 g C) 1.96 g D) 1.76 g
41. For which of the following van't Hoff factor cannot be greater than unity?
A) K 4 [Fe(CN) ]
6
B) AlCl 3 C) NH 2 CONH 2 D) KNO 3

42. In a galvanic cell, after running the cell for sometime, the concentration of the electrolyte is automatically
raised to 3 m HCl. Molar conductivity of the 3 m HCl is about 240 S cm mol and limiting molar 2 −1

conductivity of HCl is about 420 S cm mol . If K of water is 0.52 K kg mol , calculate the boiling point
2 −1
b
−1

of the electrolyte at the end of the experiment.

A) 375.6 K B) 376.3 K C) 378.1 K D) 380.3 K
43. If x and x represent the mole fractions of a component A in the vapour phase and liquid mixture
1 2

respectively and p and p represent vapour pressure of pure A and B, then total vapour pressure of
o

A
o
B

liquid mixture is
A) B) C) D)
o o o o
p x1 p x2 p x1 p x2
A A B B

x2 x1 x2 x1

44. 1.22 g C6H5COOH is added into the 100 g solvent CH3COCH3 where data of Δ Tb and Kb are given as:
ΔTb = 0.17, solute by Kb = 1.7 K kg/mol
Find out the molecular weight (g/mol) of the solute in the solution by interpreting the result.
A) 122 g/mole B) 120 g/mole C) 110 g/mole D) 125 g/mole
45. An ideal mixture of two liquids A and B is put in a cylinder containing piston. Piston is pulled out
isothermally so that the volume of liquid decreases but that of vapours increases. Negligibly small amount
of liquid was left and mole-fraction of A in vapour is 0.4. If P = 0.4 and P = 1.2 atm at the experimental
∘

A
∘

temperature, which of the following is the total pressure at which the liquid is almost evaporated?
A) 0.22 atm B) 0.431 atm C) 0.667 atm D) 1 atm
46. Intramolecular forces between n-hexane and n-heptane are nearly same as between hexane and heptane
individually. When these two are mixed, which of the following is not true about the solution formed?
A) It obeys Raoult's law, i.e. p A = xA p
o

A
and B) ΔH mixing is zero
o
pB = xB p
B

C) ΔV mixing is zero D) Its forms minimum boiling azeotrope

47. The freezing point of 1 molal NaCl solution assuming NaCl to be 100% dissociated in water is -
0 −1
(K f f or H 2 O = 1.86 C m )

5
 A) −1.86 C
0
B) −3.72 C
0
C) +1.86 C
0
D) +3.72 C
0

48. Which of the following azeotropes is not correctly matched?

A) HNO 3 (68%) +H 2O (32%): Maximum boiling azeotrope, boiling point = 393.5 K
B) H2 O (43%) + HI (57%): Minimum boiling azeotrope, boiling point = 290 K
C) C 2 H 5 OH (95.5%) +H 2O (4.5%): Minimum boiling azeotrope, boiling point = 351.15 K
D) Chloroform (93.2%) +C 2 H 5 OH (6.8%): Minimum boiling azeotrope, boiling point = 332.3 K
49. Sea water is 3.5% by mass of common salt and has a density 1.04 g cm at 293 K. Assuming the salt to be −3

sodium chloride, then osmotic pressure of sea water will be (assume complete ionisation of the salt)
A) 25.45 atm B) 11.56 atm C) 29.98 atm D) 30.20 atm
50. The relative lowering of the vapour pressure of an aqueous solution containing a nonvolatile solute is
0.0125. The molality of the solution is
A) 0.70 m B) 0.50 m C) 0.80 m D) 0.40 m
51. 1 g of a monobasic acid (HA) in 100 g water lowers the freezing point by 0.1 K. If 0.75 g of same acid
requires 15 ml of N NaOH solution for complete neutralization, then % degree of ionization of acid in
1

water is (K of H O = 1 .86 K kg mol )

f 2
−1

A) 0.22 B) 0.25 C) 0.34 D) 0.5

52. What is the correct sequence of the increasing order of freezing points at one atmosphere of the following
1.0 M aqueous solution?
1. Urea, 2. Sodium chloride, 3. Sodium sulphate, 4. Sodium phosphate.

Select the correct answer using the codes given below

A) 4, 3, 1, 2 B) 3, 4, 2, 1 C) 3, 4, 1, 2 D) 4, 3, 2, 1
53. The elements X and Y form compound having molecular formula XY and XY (both are non- 2 4

electrolyses). When dissolved in 20 g benzene, 1 g XY lowers the freezing point by 2.3 C whereas 1 g of
2
o

XY lowers the freezing point by 1.3 C. Molal depression constant for benzene is 5.1. Thus atomic masses
o
4

of X and Y respectively are

A) 42.64, 21.10 B) 21.10, 42.64 C) 25.59, 42.64 D) 42.64, 25.69
54. The vapour pressure of pure benzene and toluene are 160 and 60 torr respectively. The mole fraction of
toluene in vapour phase in cotanct with equimolar solution of benzene and toluene is
A) 0.5 B) 0.6 C) 0.27 D) 0.73
55. 30 mLof 0. 1 M KI(aq) and 10 mL of 0. 2 M AgNO are mixed. The solution is then filtered out. Assuming no
3

change in total volume, depression in freezing point of the resulting solution will be : (Given : K for f

H O = 1. 86 K kg mol
2 , assume molarity = molality)
−1

A) ∘
0.18 C B) 0.20 C
∘
C) ∘
0.24 C D) ∘
0.28 C

56. The vapour pressure of a pure liquid A is 70 torr at 27°C . It forms an ideal solution with another liquid B.
The mole fraction of B is 0.2 and total vapour pressure of the solution in 84 torr at 27°C . The vapour
pressure of pure liquid B at 27°C is
A) 140 torr B) 56 torr C) 14 torr D) 70 torr
57. A solution containing 1.8 g of a compound (empirical formula CH 2 ) in 40 g of water is observed to freeze
O

at −0 .465 C. The molecular formula of the compound is-

∘

(K of water = 1 .86 kg K mol )

f
−1

A) C2 H4 O2 B) C3 H6 O3 C) C 5 H 10 O 5 D) C 6 H 12 O 6

6
58. The aqueous 0.01 M of [Cr(NH ) ] [Co(NH 3 6 2 3 )(NO 2 ) 5 ] 3 is expected to have ΔT equal to f

Given: K of H O is 1.86 K kg mol .

f 2
−1

A) 0.0186 B) 0.0372 C) 0.0558 D) 0.093

59. The freezing point of a 3% aqueous solution of 'A' is equal to the freezing point of 9% aqueous solution 'B'.
If the molecular weight of 'A' is 60, then the molecular weight of 'B' will be
A) 191.9 B) 90 C) 45 D) 20
60. The freezing point of a 0.08 molal aqueous solution of NaHSO is −0.372°C . The dissociation constant for 4

the following reaction is ( K for H O = 1.86 K kg mol ) f 2

−1

− + 2−
HSO ⇌ H + SO
4 4

A) 0.04 B) 0.02 C) 0.01 D) 0.2

61. The plot of Vs ( on y-axis) where A and B form a ideal solution. Y is mole fraction in vapour phase
YA
1

XA
1

YA
1

and X is mole fraction in liquid phase, is linear with slope and intercept respectively
A) and B) and C) and D) and
0 0 0 0 0 0 0 0 0 0 0 0
p p −p p p −p p p −p p p −p
A A B A B A B A B B B A

0 0 0 0 0 0 0 0
p p p p p p p p
B B B B A A A B

62. What is the freezing point of a solution containing 8.1 g HBr in 100 g water, assuming that the acid to be
90% ionized [K (H O)] = 1.86 Kkgmol . f 2
−1

A) 0.85°C B) +3.53°C C) 0°C D) −3.5°C

63. The vapour pressure of water at T (K) is 20 mm Hg. The following solutions are prepared at T (K)
I. 6 g of urea (molecular weight = 60) is dissolved in 178.2 g of water.
II. 0.01 mol of glucose is dissolved in 179.82 g of water.
III. 5.3 g of Na CO (molecular weight = 106) is dissolved in 179.1 g of water.
2 3

Identify the correct order in which the vapour pressure of solutions increases
A) III < I < II B) II < III < I C) I < II < III D) I < III < II
64. Compound PdCl . 6H O is a hydrated complex; 1 molal aqueous solution of it has freezing point 269.28 K.
4 2

Assuming 100% ionization of complex, calculate the molecular formula of the complex
( K for water = 1.86 K kg mol )
f
−1

A) [Pd(H 2 O) ]Cl 4
6
B) [Pd(H 2 O) Cl 2 ]Cl 2 . 2H 2 O
4
C) [Pd(H 2 O) Cl 3 ]Cl. 3H 2 O
3
D) [Pd(H 2 O) Cl 4 ]. 4H 2 O
2

65. A solution is prepared containing a 2:1 mol ratio of dibromo ethane (C H Br ) and dibromo propane 2 4 2

(C H Br ) what is the total vapour pressure over the solution assuming ideal behaviour?
3 6 2

Vapour pressure (mm Hg)

C 2 H 4 Br 2 173

C 3 H 6 Br 2 127

A) 300 mm Hg B) 158 mm Hg C) 150 mm Hg D) 142 mm Hg

66. The mass (in grams) of glucose that should be dissolved in 100 g of water in order to produce same
lowering of vapour pressure as is produced by dissolving 1 g of urea (molecular mass = 60) in 50 g of
water is
A) 6 g B) 10 g C) 15 g D) 9 g
67. If P and P are the vapour pressures of the solvent and solution respectively,
0
S n1 and n2 are the mole
fractions of the solvent and solute respectively, then
7
 A) 0
PS = P n1 B) PS = P n2
0
C) P
0
= PS n2 D) PS = P (
0 n1

n2
)

68. Mole fraction of the toluene in the vapour phase which is in equilibrium with a solution of benzene
(p = 120 Torr) and toluene (p = 80 Torr) having 2.0 moles of each, is
o o

A) 0.5 B) 0.25 C) 0.6 D) 0.4

69. Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of
molar mass 185000 in 450 mL of water at 37o C.
A) 29.05 Pa B) 28.95 Pa C) 32.45 Pa D) 30.95 Pa
70. At solution containing 12.5 g of non-electrolyte substance in 175 g of water gave boiling point elevation of
0.70 K. Calculate the molar mass of the substance. Molal elevation constant (K ) for water 0.52 K kg mol
b
−1

?
A) 53 B) 65 C) 84 D) 79
71. What is the amount of CaCl2 in grams (i = 2.47) dissolved in 2.5 L of water such that its osmotic pressure is
0.75 atm at 27oC.?
Report your answer up to one decimal place.
A) 3.42 g B) 3.30 g C) 4.25 g D) 5.56 g
72. Role of ethylene glycol in the radiator of vehicles is to
A) Decrease the freezing point of water in the winter and increase the boiling point of water in the summer
B) Only decrease the freezing point of water
C) Only increase the boiling point of water
D) Prevent corrosion of automobile parts
73. The elevation in boiling point of a solution of a solution dT is related with molality of solution (m) by the
b

relation
], where M is molar mass of solvent and ΔH is heat of vaporization of solvent. For
2
RT M1
b
dT = [
b ][ 1 vap
ΔH vap 1+mM 1

a dilute solution, the relation ( ∂T b

∂m
) gives:
m→0

A) Molal ebullioscopic constant

B) Elevation in boiling point
C) Boiling point of solvent
D) Elevation in boiling point (ΔT ) becomes more predominant
b

74. Which is the correct order of decreasing boiling point of azeotropic mixtures X − H 2O ?
A) HI > HBr > HF > HCl B) HI > HCl > HBr > HF

C) HF > HCl > HBr > HI D) HCI > HF > HBr > HI

75. Assertion: Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling points
either greater than both the components or less than both the components.
Reason: The composition of the vapour phase is same as that of the liquid phase of an azeotropic mixutre.
A) If both assertion and reason are true and the reason is the correct explanation of the assertion.
B) If both assertion and reason are true but reason is not the correct explanation of the assertion.
C) If assertion is true but reason is false.

8
 D) If assertion is false but reason is true.
76. pH of a 0.1 M monobasic acid (HA) is measured to be 2. Its osmotic pressure at temperature T K is
A) 0.1 RT B) 0.11 RT C) 1.1 RT D) 0.01 RT
77. If a 0.004 M solution of Na SO is isotonic with a 0.010 M solution of glucose at same temperature. Then
2 4

what is the apparent degree of disociation of Na SO is 2 4

A) 25% B) 50% C) 75% D) 85%

78. Vapour pressure of a solution of 5g of non- electrolyte in 100g of water at a particular temperature is
2985N/m . The vapour pressure of pure water is 3000N/m . The molecular weight of the solute is
2 2

A) 60 B) 120 C) 180 D) 380

79. on reaction with K [Fe(CN) ] in aqueous solution gives blue colour. These are separated by a
FeCl 3 4 6

semipermeable membrane AB as shown. Due to osmosis there is

A) blue colour formation in side X B) blue colour formation in side Y

C) blue colour formation in both of the side X D) no blue colour formation
and Y
80. The boiling point of an azeotropic mixture of water and ethyl alcohol is less than that of theoretical value
of water and alcohol mixture. Hence, the mixture shows
A) that solution is highly saturated B) positive deviation from Raoult's law
C) negative deviation from Raoult's law D) nothing can be said
81. Which of the following can show positive deviation from Raoult's law?
A) Water- B) Water-nitric acid C) Benzene- D) Acetone-
hydrochloric acid methanol chloroform
82. If the density of some lake water is 1.25 g mL-1 and contains 92 g of Na+ ions per kg of water, calculate the
molality of Na+ ions in the lake.
A) 4 mol kg
−1
B) 3 mol kg
−1
C) 2 mol kg
−1
D) 5 mol kg
−1

83. At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the
osmotic pressure of the solution is 1.52 bar at the same temperature, what would be its concentration?
[Report your answer upto two decimal places.]
A) 0.0610 mol L
−1
B) 0.0500 mol L
−1
C) 0.0440 mol L
−1
D) 0.0300 mol L
−1

84. 5 g sulphur is present in 100 g of CS 2 . ΔT b of solution 0.954 and Kb is 4.88. The molecular formula of
sulphur is
A) S2 B) S4 C) S3 D) S8

9
85. Equal volumes of 0.1 M NaCl and 0.06 M CaCl solutions are separated by a semi- permeable membrane
2

in container. For this system, choose the correct answer

A) Water flows from NaCl solution towards CaCl solution 2

B) There is no movement of any solution across the membrane

C) Osmotic pressure of 0.1 M NaCl is lower than the osmotic pressure of CaCl (Assume complete 2

dissociation)
D) Water flows form CaCl solution towards NaCl solution
2

Chemistry - Section B ( Numeric )

86. Depression in freezing point of 0.01 molal aqueous HCOOH solution is 0.02046°C. 1 molal aqueous urea
solution freezes at –1.86°C. Assuming molality equal to molarity, calculate the pH of HCOOH solution.

87. The molarity (in mol/liter) of a 13% solution (by weight) of sulphuric acid with a density of 1.02 g/mL is
(Note: Report your answer in the required format by relevant rounding up.)

88. 0.002molal aqueous solution of an ionic compound with moleciular formula Co(NH ) (NO )Cl freezes at 3 5 2

−0.00744 C . How many moles of ions does 3 moles of the salt produce on being dissolved in water?
∘

[Given: K of water = 1.86 K kg mol ]

f
−1

89. Depression in freezing point of 0.01 molal aqueous solution of HA is 0.01924 K. The pK value of HA is a

[Given = molarity = molality, [K (H O) = 1.85 Kkg mol , log 2 = 0.3]

f 2
−1

90. The vapour pressure of pure water at 26 C is 25.5 torr.. The vapour pressure of a solution which contains
o

20.0 glucose, (C H O ), in 100 g water (in torr) is?

12 6
6

91. When 10.6 g of a non volatile substance is dissolved in 750 g of ether, its boiling point is raised 0.266 C. The o

molecular weight of the substance is

(Given: Molal boiling point constant for ether is 2.0 C kg/mol) o

Report your answer by rounding it up to nearest whole number.

92. When a gas is bubbled through water at 298 K, a very dilute solution of gas is obtained. Henry's law
constant for the gas is 100 kbar. If gas exerts a pressure of 1 bar, the number of moles of gas dissolved in
1 litre of water is x × 10 . Find the value of x here?
−5

Report your answer upto two decimal places.

93. The Henry’s law constant for the solubility of N gas in water at 298 K is 1 × 10 atm. The mole fraction of
2
−5

N 2 in air is 0.8 . If the number of moles of N of air dissolved in 10 moles of water at 298 K and 5 atm is
2

. Find the value of x.

−4
x ⋅ 10

94. For a liquid the vapour pressure is given by

−400
log P = + 10
10 T

Vapour pressure of the liquid is 10 x

mm Hg at 400 K. The value of x will be?

95. If the freezing point of a 0. 01 molal aqueous solution of a cobalt (III) bromide-ammonia complex (which
behaves as a strong electrolyte) is −0. 0557°C , the number of bromide(s) in the coordination sphere of
the complex is [ K for water = 1 .86 K kg mol ]
f
−1

10