19-03-2023

1001CJA102122058 JA

PART-1 : PHYSICS

SECTION-I (i)

1) The smallest division on the main scale of a Vernier calipers is 0.1 cm. Ten divisions of the Vernier
scale correspond to nine divisions of the main scale. The figure below on the left shows the reading
of this calipers with no gap between its two jaws. The figure on the right shows the reading with a
solid sphere held between the jaws. The correct diameter of the sphere is

(A) 4.07 cm
(B) 4.11 cm
(C) 3.15 cm
(D) 4.16 cm

2) An ideal gas undergoes a four step cycle as shown in the P – V diagram below. During this cycle,

heat is released by the gas in

(A) steps 1 and 2

(B) steps 2 and 3
(C) steps 1 and 4
(D) steps 2 and 4

3) An extended object is placed at point O, 10 cm in front of a convex lens L1 and a concave lens L2 is
placed 20 cm behind it, as shown in the figure. The radii of curvature of all the curved surfaces in
both the lenses are 20 cm. The refractive index of both the lenses is 1.5. The total magnification of
this lens system is

(A) 1.5
(B) 0.8
(C) 1.3
(D) 0.67

4) A heavy nucleus Q of half-life 20 minutes undergoes alpha-decay with probability of 40% and beta-
decay with probability of 60%. Initially, the number of Q nuclei is 1000. The number of alpha-decays
of Q in the first one hour is

(A) 50
(B) 75
(C) 350
(D) 525

SECTION-I (ii)

1) A horizontal force F is applied at the center of mass of a cylindrical object of mass m and radius R,
perpendicular to its axis as shown in the figure. The coefficient of friction between the object and
the ground is μ. The center of mass of the object has an acceleration a. The acceleration due to
gravity is g. Given that the object rolls without slipping, which of the following statement(s) is(are)

correct ?

(A) For the same F, the value of a depends on whether the cylinder is solid or hollow
(B) For a thin-walled hollow cylinder, the maximum possible value of a is 2μg
(C) The magnitude of the frictional force on the object due to the ground is always μmg

(D)
For a thin-walled hollow cylinder,

2) A wide slab consisting of two media of refractive indices n1 and n2 is placed in air as shown in the
figure. A ray of light is incident from medium n1 to n2 at an angle θ, where sin θ is slightly larger
than 1/n1. Take refractive index of air as 1. Which of the following statement(s) is(are) correct ?

(A) The light ray does not enter air if n2 = n1

(B) The light ray is finally reflected back into the medium of refractive index n1 if n2 < n1
(C) The light ray is finally reflected back into the medium of refractive index n1 if n2 > n1
(D) The light ray is not reflected back into the medium of refractive index n1 if n2 = 1

3) A particle of mass M = 0.2 kg is initially at rest in the xy-plane at a point (x = – , y = –h), where
= 10 m and h = 1m. The particle is accelerated at time t = 0 with a constant acceleration a = 10
m/s2 along the positive x-direction. Its angular momentum and torque with respect to the origin, in
SI units, are represented by and , respectively. are unit vectors along the positive x, y
and z-directions, respectively. If then which of the following statement(s) is(are) correct ?

(A) at t = sec.
(B) when the particle passes through the point (x = , y = –h)
(C) when the particle passes through the point (x = , y = –h)
(D) when the particle passes through the point (x = 0, y = –h)

4) Which of the following statement(s) is(are) correct about the spectrum of hydrogen atom ?

(A) The ratio of the longest wavelength to the shortest wavelength in Balmer series is 9/5
(B) There is no overlap between the wavelength ranges of Balmer and Paschen series.

0
(C) The wavelengths of Lyman series are given by , where λ is the shortest wavelength of
Lyman series and m is an integer
(D) The wavelength ranges of Lyman and Balmer series do not overlap

5) A long straight wire carries a current, I = 1 ampere. A semi-circular conducting rod is placed
beside it on two conducting parallel rails of negligible resistance. Both the rails are parallel to the
wire. The wire, the rod and the rails lie in the same horizontal plane, as shown in the figure. Two
ends of the semi-circular rod are at distances 1cm and 4 cm from the wire. At time t = 0, the rod
starts moving on the rails with a speed v = 3.0 m/s (see the figure).
A resistor R = 1.4 Ω and a capacitor C0 = 5.0 µF are connected in series between the rails. At time t
= 0, C0 is uncharged. Which of the following statement(s) is(are) correct ?
 0

[μ = 4π × 10–7 SI units. Take ln 2 = 0.7]

(A) Maximum current through R is 1.2 × 10–6 ampere

(B) Maximum current through R is 6 × 10–7 ampere
–12
(C) Maximum charge on capacitor C0 is 8.4 × 10 coulomb
–12
(D) Maximum charge on capacitor C0 is 4.2 × 10 coulomb

6) A cylindrical tube, with its base as shown in the figure, is filled with water. It is moving down with
a constant acceleration a along a fixed inclined plane with angle θ = 30°. P1 and P2 are pressures at
points 1 and 2, respectively, located at the base of the tube. Let β = (P1 –P2)/(ρgd), where ρ is density
of water, d is the inner diameter of the tube and g is the acceleration due to gravity. Which of the

following statement(s) is(are) correct ?

(A)
β = 0 when a =

(B)
β > 0 when a =
(C) β = when a = g/2

(D)
β < 0 when a =

SECTION-II (i)

Common Content for Question No. 1 to 2

A projectile is thrown from a point O on the ground at an angle 45° from the vertical and with a
speed m/s. The projectile at the highest point of its trajectory splits into two equal parts. One
part falls vertically down to the ground, 0.3 s after the splitting. The other part, t seconds after the
splitting, falls to the ground at a distance x meters from the point O. The acceleration due to gravity
g =10 m/s2.

1) The value of t is ___ .

2) The value of x is ___ .

Common Content for Question No. 3 to 4

In the circuit shown below, the switch S is connected to position P for a long time so that the charge
on the capacitor becomes q1 μC. Then S is switched to position Q. After a long time, the charge on

the capacitor is q2 μC.

3) The magnitude of q1 is ___ .

4) The magnitude of q2 is ___ .

Common Content for Question No. 5 to 6

Two point charges –Q and +Q/2 are placed in the xy-plane at the origin (0, 0) and a point (2, 0),
respectively, as shown in the figure. This results in an equipotential circle of radius R and potential
V = 0 in the xy-plane with its center at (b, 0). All lengths are measured in meters.

5) The value of R is ___ meter.

6) The value of b is ___ meter.

SECTION-II (ii)

1) An α-particle (mass 4 amu) and a proton (mass 1 amu) are initially at rest. They are accelerated
through a potential V and then allowed to pass into a region of uniform magnetic field which is
normal to the velocities of the particles. Within this region, the α-particle and the proton move in

circular orbits of radii rα and rp, respectively. The value of is ______.

2) A thin rod of mass M and length a is free to rotate in horizontal plane about a fixed vertical axis
passing through point O. A thin circular disc of mass M and of radius a/4 is pivoted on this rod with
its center at a distance a/4 from the free end so that it can rotate freely about its vertical axis, as
shown in the figure. Assume that both the rod and the disc have uniform density and they remain
horizontal during the motion. An outside stationary observer finds the rod rotating with an angular
velocity Ω and the disc rotating about its vertical axis with angular velocity 8Ω. The total angular

momentum of the system about the point O is . The value of n is___.

3) A small object is placed at the center of a large evacuated hollow spherical container. Assume that
the container is maintained at 0 K. At time t = 0, the temperature of the object is 400 K. The
temperature of the object becomes 200 K at t = t1 and 50 K at t = t2. Assume the object and the
container to be ideal black bodies. The heat capacity of the object does not depend on temperature.
The ratio (t2/t1) is______ .

PART-2 : CHEMISTRY

SECTION-I (i)

1) The major product formed in the following reaction is

Q is

(A)

(B)
(C)

(D)

2) Among the following, the conformation that corresponds to the most stable conformation of (2S,
3S)-butane-2,3-diol is –

(A)

(B)

(C)

(D)

3) For the given close packed structure of a salt made of cation X (having atomic mass = 10) and
anion Y (having radius = 200 pm, atomic mass = 30) shown below (ions of only one face are shown

for clarity) , the density is

(A) 2.58
(B) 1.56
(C) 3.40
(D) 2.40

4) The calculated spin only magnetic moments of [CuF6]3– and [Cr(CN)6]3– in BM, respectively, are
(Atomic numbers of Cr and Cu are 24 and 29, respectively)
(A) 3.87 and 1.73
(B) 4.90 and 1.73
(C) 2.84 and 3.87
(D) 4.90 and 2.84

SECTION-I (ii)

1) Given

D-Glucose
The compound(s), which on reaction with HNO3 will give the product having degree of rotation, [α]D
= –52.7º is (are)

(A)

(B)

(C)

(D)

2) The reaction of Q with PhSNa yields an organic compound (major product) that gives positive
Carius test on treatment with Na2O2 followed by addition of BaCl2. The correct option(s) for Q is
(are).
(A)

(B)

(C)

(D)

3) The correct statement(s) related to colloids is(are)

(A) Haemoglobin is positive charged colloid and blood is negative charged colloid.
Colloidal solution freezes at higher temperature than the true solution at the
(B)
same concentration.
Surfactants form micelle below critical micelle concentration (CMC). CMC depends
(C)
on temperature
(D) Micelles are associated colloids.

4) An ideal gas undergoes a reversible isothermal expansion from state I to state II followed by a
reversible adiabatic expansion from state II to state III. The correct plot(s) representing the
changes from state I to state III is(are)
(p : pressure, V : volume, T : temperature, H : enthalpy, S : entropy)

(A)

(B)
(C)

(D)

5) The correct statement(s) related to the metal extraction processes is(are)

(A) A mixture of PbS and PbO undergoes self-reduction to produce Pb and SO2.
(B) In the extraction process of copper from copper pyrites, silica is added to produce iron silicate.
Partial oxidation of sulphide ore of copper by roasting, followed by self-reduction produces
(C)
blister copper.
(D) In cyanide process, zinc powder is utilized to precipitate silver from Na[Ag(CN)2]

6) A mixture of two salts is used to prepare a solution S, which gives the following results :

The correct option(s) for the salt mixture is(are)

(A) AgNO3 and Bi(NO3)3

(B) Pb(NO3)2 and Hg(NO3)2
(C) Pb(NO3)2 and Zn(NO3)2
(D) Pb(NO3)2 and Bi(NO3)3

SECTION-II (i)

Common Content for Question No. 1 to 2

For the following reaction scheme, percentage yields are given along the arrow :

x g and y g are mass of R and U, respectively.

(Use : Molar mass (in g mol–1) of H, C and O as 1, 12 and 16, respectively)

1) The value of x is_____.

2) The value of y is______.

Common Content for Question No. 3 to 4

For the reaction , the plot of ln versus is given below (in solid line),

where pz is the pressure (in bar) of the gas Z at temperature T and bar.

(Given, where the equilibrium constant,

K= and the gas constant, R = 8.314 J K–1 mol–1)

3) The value of standard enthalpy, (in kJ mol–1) for the reaction is_____ .

4) The value of (in J K–1 mol–1) for the given reaction, at 1000 K is______ .

Common Content for Question No. 5 to 6

The boiling point of water in a 0.1 molal aqueous barium chloride solution (solution A) is x ºC. To
this solution A, an equal volume of 0.2 molal aqueous silver nitrate solution is added to make a new
solution B. The difference in the boiling points of water in the two solutions A and B is y × 10–2 ºC.
(Assume : Densities of the solutions A and B are the same as that of water and the soluble salts
dissociate completely.)
Use: Molal elevation constant (Ebullioscopic Constant), Kb = 0.5 K kg mol–1; Boiling point of pure
water as 100ºC.)

5) The value of x is _______.

6) The value of |y| is _____ .

SECTION-II (ii)
1) The maximum number of possible isomers (including stereoisomers) which may be formed on
allylic mono-bromination of 1-methylcyclohex-1-ene using Br2 and UV light is ____

2) In the reaction given below, the total number of atoms having sp2 hybridization in the major

product P is ___ P

3) The total possible isomers for [Pt(NH3)4Cl2]Br2 is/are "x" and total possible isomers for
[Pt(en)2Cl2]Cl2 is/are "y".
Find (x + y) = ?

PART-3 : MATHEMATICS

SECTION-I (i)

1) Consider a triangle Δ whose two sides lie on y = x and 3y – x + 4 = 0. If the orthocenter of Δ is (1,
1), then the equation of circle passing through the vertices of the Δ is

(A) x2 + y2 – x + 5y = 0

(B)
x2 + y2 + + –4=0
(C) 2x2 + 2y2 – x + 5y – 8 = 0
(D) 2x2 + 2y2 – x – 5y – 28 = 0

2) The area of the region R1 ∩ R2 ∩ R3 where

,
,

(A) 10
(B) 6.5
(C) 5
(D) 4.5

3) Consider three sets E1 = {1, 3, 4}, F1 = {1, 4, 5} and G1 = {3, 4, 5, 6}. Two elements are chosen
at random, without replacement, from the set E1, and let S1 denote the set of these chosen elements.
Let E2 = E1 – S1 and F2 = F1 ∪ S1. Now two elements are chosen at random, without replacement,
from the set F2 and let S2 denote the set of these chosen elements.
Let G2 = G1 ∪ S2. Finally, two elements are chosen at random, without replacement, from the set G2
and let S3 denote the set of these chosen elements.
Let E3 = E2 ∪ S3. Given that E1 = E3, let p be the conditional probability of the event S1 = {1, 3}.
Then the value of p is
(A)

(B)

(C)

(D)

4) Let θ1, θ2, ..., θ100 be positive valued angles (in radian) such that . Define the complex
numbers and for k = 2, 3, ..., 100, where . Consider the
statements P and Q given below :
P : |z2 – z1| + |z3 – z2| + ... + |z100 – z99| + |z1 – z100| > 2101 – 2

Q:

(A) P is TRUE and Q is FALSE

(B) Q is TRUE and P is FALSE
(C) both P and Q are TRUE
(D) both P and Q are FALSE

SECTION-I (ii)

1) Correction : Old Ans B,D, New Ans. Bonus

For any 3 × 3 matrix M, let |M| denote the determinant of M. Let

and C = .

If D = is a matrix such that m ≥ 2, then which of the following statements is (are)

CORRECT ?

(A)

B = CAC and

(B)

B = CAC and
(C)

(D)

2) Let be defined by

.
Then which of the following options is (are) TRUE ?

(A) f(x) is onto function.

(B)
If A = then the set A ∩ N has at least 3 elements. (N
is set of natural numbers)

(C)
If B = then |B| ≥ 2.
(D) f(x) is decreasing in the interval (–∞, –1]

3) Let E,F and G be three events having probabilities

and , and let .

For any event H, if H denotes its complement, then which of the following statements is(are) TRUE
C

(A)

(B)

(C)

(D)

4) For any 3 × 3 matrix M, let |M| denote the determinant. Let I be the 3 × 3 identity matrix. Let A,
B and C be three 3 × 3 matrices such that (I + ABC) is invertible. If D = (ABC + I)–1, then which of
the following statements is (are) TRUE ?

(A) (ABCD)T = CTBTATDT

(B) |ABC| = |I + ABC| |ADBC|
(C) (I + CAB) (I + CDAB) = I
(D) (I + CAB) (I – CDAB) = I

5) For any positive integer n, define fn : (0, ∞) as

for any x ∈ (0, ∞), . Which of the following statement(s) is (are) TRUE ?

(A)

(B)

(C)
has exactly one solution in (0,∞)
(D) tan(fn(x)) > sinx, for all n ≥ 1 and x > 0

6) For any complex number w = c + id, let , where . If a complex numbers z

= x + iy satisfies , then (x, y) lies on the circle x2 + y2 – 2x + 2y – 8 = 0. Assume α

& β are real numbers. Then which of the following statements is (are) TRUE ?

(A) αβ = 8
(B) αβ = –4
(C) set of pairs of (α, β) is {(–2, 2), (–2, –4), (4, 2), (4, –4)}
(D) (α, β) ∈ {(–2, 2), (–2, –4), (4, 2), (4, –4)}

SECTION-II (i)

Common Content for Question No. 1 to 2

Three numbers are chosen at random one after another with replacement, from the set S = {1, 2, 3,
..., 100}. Let P1 be the probability that the minimum of chosen numbers is at most 60 and P2 be the
probability that the maximum of chosen numbers is at least 41 and at most 80.

1) The value of is _____

2) The value of is ______

Common Content for Question No. 3 to 4

Let a, b and c are real numbers such that the system of linear equations
x+y+z=a
x + 5y – z = b
x – y + 2z = c + 2 is consistent.

Let |M| represent the determinant of the matrix M = . Let 'P' be the plane containing all
those (a, b, c) for which above system of linear equations is consistent and 'D' be the square of
distance of the point (1, 1, 1) from the plane 'P'.
3) The value of is ______

4) The absolute value of |M| is ______

Common Content for Question No. 5 to 6

Consider the lines L1 and L2 defined by
and
For a fixed constant λ, let C be the locus of a point P such that the product of the distance of P from
L1 and the distance of P from L2 is λ2. The line y = 2x + 1 meets C at two points R and S, where the
distance between R and S is .
Let the perpendicular bisector of RS meet C at two distinct points R' and S'. Let D be the square of
the distance between R' and S'.

5) The value of λ2 is __________.

6) The value of is __________.

SECTION-II (ii)

1) If 2|x2 – 4| = x2 – 4x + a has exactly three distinct solutions then sum of all possible value of '3a' is
______

2) In ΔABC, let BC = , CA = & AB = . Then the value is

3) Let and be vectors in three-dimensional space, where , , , ,

. If the volume of the parallelopiped, whose adjacent sides are represented by the vectors

and , is , then the value of is _____

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. D B D C

SECTION-I (ii)

Q. 5 6 7 8 9 10
A. A,D A,B,C A,C,D A,B,C,D B,D D

SECTION-II (i)

Q. 11 12 13 14 15 16
A. 0.30 2.70 2.00 1.33 1.33 2.66 to 2.67

SECTION-II (ii)

Q. 17 18 19
A. 2 55 73

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 20 21 22 23
A. A D B C

SECTION-I (ii)

Q. 24 25 26 27 28 29
A. B,C,D A,C,D A,B,D A,C,D A,B,C,D C,D

SECTION-II (i)

Q. 30 31 32 33 34 35
A. 3.24 3.20 83.14 58.19 or 58.20 100.15 7.50

SECTION-II (ii)

Q. 36 37 38
A. 9 8 9

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 39 40 41 42
A. C D C A

SECTION-I (ii)

Q. 43 44 45 46 47 48
A. B,D C,D A,B,C,D A,B,D B,C,D A,D

SECTION-II (i)

Q. 49 50 51 52 53 54
A. 19.50 14.00 0.41 to 0.45 16.00 16.00 68.57

SECTION-II (ii)

Q. 55 56 57
A. 40 2 83
 SOLUTIONS

PART-1 : PHYSICS

1) Given 10 VSD = 9 MSD Here MSD → Main Scale division

1 VSD = MSD
VSD → Vernier Scale division
Least count = 1 MSD – 1 VSD

= MSD
= 0.1 MSD
= 0.1 × 0.1 cm
= 0.01 cm
As '0' of V.S. lie before '0' of M.S.
Zero error = –[10 – 6] L.C.
= – 4 × 0.01 cm
= –0.04 cm
Reading = 4.1 cm + 2 × LC
= 4.1 cm + 2 × 0.01 cm
= 4.12 cm
True diameter = Reading – Zero error
= 4.12 – (–0.04) cm = 4.16 cm

2) Process 1 P = constant, Volume increases and temperature also increases

⇒ W = positive , ΔU = positive
⇒ Heat is positive and supplied to gas
Process -2
V = constant, Pressure decrease
⇒ Temperature decreases

ΔT is negative and ΔU = nRΔT

⇒ ΔU in negative
ΔQ = ΔU + W
∴ ΔQ → Heat is negative and rejected by gas
Process 3
P = constant, Volume decreases
⇒ Temperature also decreases
W = PΔV = negative

ΔU = nRΔT = negative
ΔQ = W + ΔU = negative
Heat is negative and rejected by gas.
Process 4
V = constant, Pressure increases
W=
PV = nRT ⇒ Temperature increase

⇒ ΔU = is positive
ΔQ = ΔU + W
= positive

3) Focal length of convex lens (f1)

Focal length of concave lens (f2)

For lens 1

For lens 2

u = –40, f = –20,

Net magnification

m = m1m2 =

4) Out of 1000 nuclei of Q 40% may go α-decay

⇒ 400 nuclei may have a-decay

t = 1 hour = 60 minutes
Using

N=
So, No. of nuclei decayed

= 400 – = 350

5)

Thin walled hollow cylinder

6)
i.e.

If n1 = n2 then θ2 = θ1
n2sinθ2 = (1) sinθ3

This means ray cannot enter air

For n1 > n2 ;

for surface 2 – air interface

θ2 > 90°
It means ray is reflected back in medium-2

for surface 1 – surface 2 interface

for ray to enter medium-1

which is true
Hence ray enters medium-1
For n2 > n1

For surface 2 – air interface

n2 sin θ2 = sin θ3

sinθ2 =
θ2 > 90
It means ray is reflected back in medium - 2

n2 sin θ2 = n1 sin θ1

sin θ1 = sin θ2

→ critical angle
For ray to enter medium - 1
θ2 < θ2c
sin θ2 < sin θ2c

sinθ1 < 1
θ1 < 90°, which is true
Hence ray enters medium - 1
Let n2 = 1

n1 sin θ1 = n2 sin θ2
n2 = 1
n1 sin θ1 = sin θ2

sin θ2 > 1 ⇒ θ2 > 90°

ray is reflected back in medium -

7)
t= sec

At point A(0, –1)

8) For A
When the transition is from any level to n = 2, then photon emitted belong to Balmer series.
∴ For longest wavelength, transition occurs from n = 3 to n = 2.

∴ & for shortest wavelength transition occurs from n = 3 to n = 2

For (B)

of Balmer =

of Paschen =
Hence these wavelength don't overlap.
For (C)
For Lyman series,

Also

For (D)

,
Hence that wavelength don't overlap.

9) EMF developed across the emf of semi-circular rod =

Form given value,
imax =

10)

11)

Range R =

Time of flight T =
∵ Time of motion of one part falling vertically downwards is = 0.3 sec =

⇒ Time of motion of another part, t = = 0.3 sec

From momentum conservation ⇒
2m × 3 = m × v
v = 6 m/s

Displacement of other part in 0.3 sec in horizontal direction =

= 3 × 0.3 = 0.9 m = R

∴ Total distance of second part from point 'O' is,

x = 2.7 m

12)

Range R =

Time of flight T =
∵ Time of motion of one part falling vertically downwards is = 0.3 sec =

⇒ Time of motion of another part, t = = 0.3 sec

From momentum conservation ⇒
2m × 3 = m × v
v = 6 m/s

Displacement of other part in 0.3 sec in horizontal direction =

= 3 × 0.3 = 0.9 m = R

∴ Total distance of second part from point 'O' is,

x = 2.7 m

13)

When S is connected to position P

q1 = C Eeq = 2
When S is connected to position Q

P.d. across capacitor =

14)

When S is connected to position P

q1 = C Eeq = 2
When S is connected to position Q

P.d. across capacitor =

15)
4 (x – 2)2 + 4y2 = x2 + y2
4x2 + 16 – 16x + 4y2 = x2 + y2

16)
4 (x – 2)2 + 4y2 = x2 + y2
4x2 + 16 – 16x + 4y2 = x2 + y2

17)

18)
n = 55

19)
PART-2 : CHEMISTRY

20)

Alkyne is more reactive then alkene towards hydrogenation.

21)
(2S, 3S) butane –2,3,–diol
(D) is the answer

22)

= 1.56

23) [CuF6]3–
Cu3+ ⇒ [Ar]3d8
In presence of F– Ligand

Cu3+ ⇒ eg

t2g
Number of unpaired electrons = 2
B.M.
B.M.
⇒ 2.84 B.M

[Cr(CN)6]3–
Cr3+ ⇒ [Ar]3d3

In presence of CN ligand eg
 t2g
Number of unpaired electrons = 3
B.M.
B.M.
B.M.
⇒ 3.87 B.M.

24) The enantiomer of P has rotation –52.7° is as

follows

25) (A)

(C)
(D)

26) (A) Process of precipitating colloidal solution is called coagulation. Hence false.
(B) For colloidal solutions concentration is very small due to very large molar mass and hence
their colligative properties are very small as compared to true solutions
∴ ΔTf is lesser for colloidal solution. Hence true.
(C) At CMC surfactant form micelles. Hence true
(D) Micelles and macromolecular colloids are two different types of colloids. Hence false.

27) From state I to II (Reversible isothermal expansion)

⇒ P decreases, V increases, T constant
H constant & S increases.
From state II to III (Reversible adiabatic expansion)
⇒ P decreases, V increases, T decreases
H decreases, S constant
∴ Plots (A), (B), (D) are correct while (C) is wrong as from II to III, H is decreasing.

28) (A) PbS + 2PbO → 3Pb + SO2 (self reduction)

(B) Silica is added to remove impurity of Fe in the form of slag FeSiO3
(C) CuFeS2 ore is partially oxidized first by roasting and then self reduction of Cu takes place
to produce blister copper.

(D)

29)
30) Mg2C3 + 4H2O → 2Mg(OH)2 + CH3C ≡CH

The value of x = 162 × 0.02 = 3.24 gm

31) (3.20 OR 3.90 TO 3.91)

60 + 32 + 8 = 100
The value of Y = 0.032 × 100 = 3.2

32)

Slope =
⇒ ΔHo = 104 × R
= 83.14 kJ/mole
33) From the plot when,
⇒ T = 1000 K

Substituting in equation :

We get,

⇒ ΔSo = 7R
⇒ ΔSo = 7 × 8.314 J/K-mol
⇒ ΔSo = 58.19 or 58.20 J/K-mol

34) BaCl2(aq) → Ba+2(aq) + 2Cl–(aq)

0.1 m 2 × 0.1 m
ΔTb = 0.3 × 0.5
= 0.15°C = 0.15 K
Boiling point of solution = 100.15°C = X

35) AgNO3(aq) → Ag+(aq) +

0.1 m 0.1 m 0.1 m
BaCl2(aq) → Ba2+(aq) + 2Cl–(aq)
0.05 m 0.05 m 0.1 m
+ –
Ag and Cl combine to form AgCl precipitate
Ag+(aq) + Cl–(aq) → AgCl(s)
t=0 0.1 m 0.1 m
t=∞ 0 0
In final solution total concentration of all ions :
= 0.15 m
ΔTb = 0.5 × 0.15 = 0.075 °C
B.P. of solution ‘B’ = 100.075°C
B.P. of solution ‘A’ = 100.15°C
|y| = 100.15 – 100.075
= 0.075 = 7.5 × 10–2

36)
 Total 9 product

37)
Total 8 atoms are sp2 hybridised

PART-3 : MATHEMATICS

39) Correct Ans C

Since (1, 1) lies on y = x & it is orthocentre
⇒ D must be right angle at (1, 1)
so third side passing through (1, 1) ⊥r to y = x
is y + x – 2 = 0
Diameter of circle : (–2, –2)

& : point of intersection of x + y – 2 = 0 & 3y – x + 4 = 0

Circle : (x + 2) + (y + 2) =0
⇒ (x + 2) (2x – 5) + (y + 2) (2y + 1) = 0

40) For R1 : (y – x – 4) (y + x – 4) ≤ 0
R2 : (x + y – 4) (y – 2x + 2) ≥ 0
R3 : (2x – y – 2) (x + 2y – 11) ≥ 0

Area

= 4.5

41)
P(B) = P(B1,3) + P(B1,4) + P(B3,4)
↑ ↑ ↑
If 1,3 If 1,4 If 3,4
chosen chosen chosen
at start at start at start

42) Correct Ans. D

P : |z2 – z1| + |z3 – z2| + ... |z100 – z99| + |z1 – z100|
≥ ||z2|| – |z1|| + ||z3| – |z2|| + ... ||z100| – |z99|| + ||z100| – |z1||
= (2 – 1) + (22 – 21) + (23 – 22) + ... (2100 – 299) + (2100 – 1)
= 2100 – 1 + 2100 – 1 = 2101 – 2
Arc ≥ |2 98z2 – 2 99z1|
θ2 × OA ≥ |2 98z2 – 2 99z1|
Σ θ2 × 299 ≥ Σ |2 98z2 – 2 99z1|
⇒ 2π × 299 ≥ Σ |2 98z2 – 2 99z1|

43) C is permutation matrix

CAC = B & C3 = I, |A| = 0
|AD + C2BD–1| = |AD + C2CACD–1| = |AD + ACD–1| = A |D + CD–1| = 0
|AD| + |CBD–1| = |AD| + |C| × |CAC| |D–1|
=0

44) f'(x) =

⇒ f'(x) ≥ 0

Assymptotes of graphs are x = &y=1

For a > 0 & two solution
at (0, 1) ∪ (1, 3)
for b, for one solution : b = 1, b = 3
B = {1, 3}, |B| = 2

45) P(E) = ; P(F) = ; P(G) = ; P(E ∩ F ∩ G) =

(C) P(E ∪ F ∪ G) = P(E) + P(F) + P(G) – P(E ∩ F) – P(F ∩ G) – P(G ∩ E) + P(E ∩ F ∩ G)

⇒ P(E ∪ F ∪ G) ≤ [(C) is Correct]

(D) P(EC ∩ FC ∩ GC) = 1 – P(E ∪ F ∪ G) ≥ 1 –

⇒ P(EC ∩ FC ∩ GC) ≥ [(D) is Incorrect]

(A) P(E) = ≥ P(E ∩ F ∩ GC) + P (E ∩ F ∩ G)

[(A) is Correct]

(B) P(F) = ≥ P(EC ∩ F ∩ G) + P(E ∩ F ∩ G)

≥ P(EC ∩ F ∩ G)
⇒ ≥ P(EC ∩ F ∩ G) [(B) is Correct]

46) I + ABC and I commutes with D

⇒ (I + ABC) – I also commutes with D
⇒ ABCD = DABC
⇒ (ABCD)T = CT BT AT DT
|I + ABC| |ADBC| = |(I + ABC) × D| × |ABC|
= 1 × |ABC|
(I + CAB) (I – CDAB) = I + CAB – CDAB – C(ABCD) AB
= I + CAB – CDAB – C (I – D) AB
=I

47) Correct Ans B,C,D

fn(n) =

= tan–1 (2n + 1nx)

y = tan(fn(x)) = 2n + 1nx, slope > 1 for n ≥ 1

48) x = 0, y2 + 2y – 8 = 0 ⇒ y = 2 & –4
y = 0, x2 – 2x – 8 = 0 ⇒ x = –2 & 4
centre of circle (1, –1)

∠A'CB' =

∠A'CB' =
For : α = 4, β = 2

For 'P'
For α = –2, β = –4

For P,

49) P1 = 1 – prob(minimum of chosen numbers is at least 61)

50) Let A = {1, 2, ... 40, ... 80}

B = {1, 2, 3, ... 40}

P2 = P(A3) – P(B3)

51) P1 : x + y + z = a
P2 : x + 5y – z = b
P3 : x – y + 2z = c + 2
for consistent
P2 = 3P1 – 2P3 ⇒ b = 3a – 2c – 4
⇒ 3a – b – 2c – 4 = 0
so P : 3x – y – 2z – 4 = 0

= 3a – 2(c – 6) + b(–1)
= 3a – b – 2c + 12
= 4 + 12 = 16

52) P1 : x + y + z = a
P2 : x + 5y – z = b
P3 : x – y + 2z = c + 2
for consistent
P3 = 3P1 – 2P2 ⇒ b = 3a – 2c – 4
⇒ 3a – b – 2c – 4 = 0
so P : 3x – y – 2z – 4 = 0

= 3a – 2(c – 6) + b(–1)
= 3a – b – 2c + 12
= 4 + 12 = 16

53)

line y = 2x + 1, , R(x1,y1) and S(x2,y2)

y1 = 2x1 + 1 and y2 = 2x2 + 1 ⇒ (y1 – y2) = 2(x1 – x2)

solve curve C and line y = 2x + 1 we get

54) ⊥ bisector of RS

Here x1 + x2 = 0
T = (0,1)
Equation of

R'S' :
R'(a1,b1) S'(a2,b2)
D = (a1 – a2)2 + (b1 – b2)2 = 5(b1 – b2)2

solve and

55) Case 1 : when For '3' solution

y = x2 – 4x + a touches
y = 8 – 2x2 in [–2, 2]
⇒ x2 – 4x + a = 8 – 2x2
⇒ 3x2 – 4x + a – 8 = 0 has exactly one root
16 – 12(a – 8) = 0
⇒ 4 – 3a + 24 = 0 ⇒ 28 = 3a

⇒a=

(Note : L.R. of y = x2 – 4x + a > L.R. of y = 2x2 – 8)

Case- 2 :

when y = x2 – 4x + a passes through (2,0)

a=4

56)
57)

=1+2+9+2