Note
Note
4 Wave Motion 23
4.1 Equation of a Simple Harmonic Traveling Wave . . . . . . . . . . . . . . . 23
4.2 Differential Equation of a Traveling Wave . . . . . . . . . . . . . . . . . . . 24
4.3 Phase Velocity and Group Velocity . . . . . . . . . . . . . . . . . . . . . . . 24
4.4 Superposition: Standing Waves and Beats . . . . . . . . . . . . . . . . . . 25
4.4.1 Standing Waves . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
4.4.2 Beats . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
iii
iv Contents
5 Fourier Series 27
5.1 Fourier Coefficients . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
5.2 Example: Square Wave . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
6 Practice Problems 29
Chapter 1
If an object A is hotter than object B, and we place them in contact for a sufficient
time, they become equally hot. The two objects are then said to be in thermal
equilibrium.
Heat Flow
A (Hotter) B (Colder)
A B
A C
B C
1
2 Chapter 1. Heat and Thermodynamics
A B C
There are measurable physical properties, such as the volume of a mercury column or
the electrical resistance of a metal wire, that vary linearly and continuously with a rise
in temperature. Thus, we have thermometric substances and thermometric properties.
Any of these properties can be used to construct a thermometer.
X l
=
R 100 − l
X R
G
100 − l l
• Electrical Resistance
• Volume of a gas
1.3. First Law of Thermodynamics 3
Mathematically:
dQ = dU + dW
dU = dQ − dW
Where:
∆W = F · ∆L
= (P A) · ∆L
= P (A · ∆L)
= P ∆V
Here,
• W = Work done
4 Chapter 1. Heat and Thermodynamics
Handle
Piston
∆L
P ,V , T
Ideal Monoatomic Gas
Heat Reservoir at T K
Figure 1.2: Cylinder with movable piston containing an ideal monoatomic gas.
∫ ∫ Vf
W = dW = P dV
Vi
Graphically, this represents the area under the curve on a P-V diagram:
P
A(Vi , Pi )
B(Vf , Pf )
V
Vi Vf
1.5. State Functions and Parameters 5
State Function
A state function in thermodynamics is a property of a system that depends only
on the current equilibrium state of the system, not depending on the path taken
to reach that state.
State functions are essential because they are defined purely by the current equilib-
rium state regardless of the process used to get from one state to another. Examples:
Internal energy (U ), enthalpy (H ), entropy (S ), Gibbs free energy (G ), etc.
Characteristics of a State Function:
1. Path independent.
2. Depends only on the initial and final states.
Heat (Q ) and work (W ) are path-dependent functions, so they are not state functions.
A
C
B
D
However, the quantity Q −W does not depend on the path followed. Q −W depends
only on the initial and final states. We denote Q −W by ∆U (change in internal energy).
Thus:
∆U = Q − W =⇒ Q = W + ∆U
∆U = ∆Q − ∆W =⇒ ∆U = 0
Hence, the internal energy U of an ideal gas is a function solely of its temperature.
Isothermal Process
The thermodynamic process in which the pressure and volume of a system are
changed but the temperature remains constant throughout the process is called
an Isothermal Process.
In this process, the system is perfectly conducting to the surroundings. The system
can absorb heat from or give heat to the surroundings to maintain a constant tem-
perature. The equation for an isothermal process is PV = constant. Thus, it obeys
Boyle’s law.
1.7. Isothermal Process 7
Pressure (P )
6
2
T1
0
0 2 4 6 8 10
Volume (V )
A(Vi , Pi )
Pressure (P )
B(Vf , Pf )
T = constant
Vi Volume (V ) Vf
Vf
W = nRT ln
Vi
8 Chapter 1. Heat and Thermodynamics
2. These atoms or molecules are in constant random motion and obey New-
ton’s laws of motion.
We consider a particle of mass m and velocity v̄ = vx iˆ+ v y jˆ+ v z k̂ in a cubic box of side
L. When the particle collides with face 1, it rebounds with a velocity −vx . The change
of momentum is:
vx mvx2
F = 2mvx · =
2L L
1.8. Microscopic Theory of an Ideal Gas 9
Face 2
Face 1
= ρvx2
1 1
P = ρv 2 = ρvr2ms
3 3
c(Pf ,Vi , Ti + ∆T )
CV
Consider a monoatomic ideal gas at state a(Pi ,Vi , Ti ). Let us raise the temperature
to Ti + ∆T without changing the volume V (isochoric process), so the system reaches
state c(Pf ,Vi , Ti + ∆T ). The First Law gives:
∆Q = ∆U + ∆W =⇒ nCV ∆T = ∆U + 0
Because ∆W = P ∆V = P (0) = 0. Thus:
∆U = nCV ∆T (1.1)
Now, let us take the system from a to b (isobaric process). We raise the temperature
by ∆T while keeping the pressure P constant. The First Law gives:
nC P ∆T = ∆U + P ∆V (1.2)
For an ideal gas, the internal energy U depends only on temperature T . Since the
temperature change ∆T is the same for both paths, ∆U is the same. Substituting (1.1)
into (1.2):
nC P ∆T = nCV ∆T + P ∆V (1.3)
For the constant pressure path (a to b), the ideal gas law PV = nRT yields:
P ∆V + V ∆P = nR ∆T =⇒ P ∆V = nR ∆T (since ∆P = 0)
Substituting this into (1.3):
nC P ∆T = nCV ∆T + nR ∆T
=⇒ C P = CV + R
1.10. Adiabatic Process 11
Mayer’s Relation
C P − CV = R
Adiabatic Process
A thermodynamic process in which the pressure and volume of a system change,
but the system neither absorbs heat from the surroundings nor releases heat to
the surroundings (∆Q = 0), is called an adiabatic process.
The system is completely thermally isolated. Throughout the process, the rela-
tionship PV γ = constant holds true, where γ = C P /CV . It does not obey Boyle’s
law.
The adiabatic curve is steeper than the isothermal curve. We can derive PV γ =
const: From the First Law (∆Q = 0):
0 = ∆U + ∆W =⇒ ∆W = −∆U
−P dV
nCV dT + P dV = 0 =⇒ dT = (1.4)
nCV
P dV + V dP = nR dT (1.5)
12 Chapter 1. Heat and Thermodynamics
PV γ = constant
nR nR
W = (Tf − Ti ) = (Ti − Tf )
1−γ γ−1
Homework
1. What is a Carnot engine?
3. Show that the efficiency of a machine that works as a Carnot engine is:
W Q1 − Q2 Q2
η= = =1− <1
Q1 Q1 Q1
14 Chapter 1. Heat and Thermodynamics
Chapter 2
Black Body
T4
T3
Emissive Power (E )
T2
T1
Wavelength (λ)
15
16 Chapter 2. Black Body Radiation
3. λ m · T = constant.
Em
4. T5
= constant, where E m is the maximum energy density.
Stefan-Boltzmann Law
The total radiant energy emitted by a perfectly black body per unit area per
second is directly proportional to the fourth power of its absolute temperature.
Let E be the emitted energy per unit area per second. Then:
E ∝ T 4 =⇒ E = σT 4
8πhν 3 1
U (ν) = 3
· hν
c e kT − 1
Where U is the energy density and hν is the quantum of energy.
2.3. Important Laws of Radiation 17
Eλ
Rayleigh-Jeans Law
Planck’s Law
Wien’s Law
Notice that at low λ, Wien’s law approximates Planck’s law well, but at high λ, they
diverge. Conversely, the Rayleigh-Jeans law works well at high λ but fails spectacularly
at low λ (the ”ultraviolet catastrophe”).
Thus, e x − 1 ≈ e x .
8πhc 1 8πhc − hc
U (λ) ≈ 5
· hc = e λkT
λ e λkT λ5
This is the mathematical form of Wien’s Radiation Law.
To find the peak wavelength λ m , we differentiate Planck’s law with respect to λ and
set it to zero:
dU
=0
dλ
Let U (λ) = u. Taking the natural logarithm:
hc
ln u = ln(8πhc) − 5 ln λ − ln e λkT − 1
hc
λ mT = = constant
4.9651k
This successfully derives Wien’s Displacement Law. (Planck’s constant, h = 6.626 ×
10−34 J · s).
Chapter 3
θ Equilibrium
y
m
y
F ∝ −y and a ∝ −y
F def = F rest
ma = −k y [using Newton’s 2nd law and Hooke’s law]
d2 y
m = −k y
dt 2
d2 y k
=− y
dt 2 m
Letting ω 2 = m:
k
d2 y
+ ω2 y = 0
dt 2
19
20 Chapter 3. Simple Harmonic Motion and Waves
y (t ) = a sin(ωt + φ)
K1
+
K2
i
C L
V
−
If Q is the charge on the capacitor at any instant t , then the voltage across the
capacitor equals the induced EMF across the inductor (ignoring resistance):
VC = VL
Q di
= −L
C dt
dQ
Since current is the rate of flow of charge, i = dt :
Q d2 Q
= −L 2
C dt
d2 Q Q
L 2 + =0
dt C
d2 Q 1
+ Q =0
dt 2 LC
ma = −k y − bv
d2 y dy
m +b +ky = 0
dt 2 dt
Dividing by m and letting b
m = 2λ (where λ is the damping factor) and k
m = ω2:
d2 y dy
+ 2λ + ω2 y = 0
dt 2 dt
3. Overdamped (λ > ω): The system slowly returns to equilibrium without oscillat-
ing.
y (t )
a 0 e −λt
t
d2 y
Homework Proof: Prove that y = a 0 e −λt sin(νt ) is a solution to dt 2
+2λ dy 2
dt +ω y = 0.
d2 y dy
m = −k y − b + F 0 sin(pt )
dt 2 dt
Dividing by m and rearranging:
d2 y dy
+ 2λ + ω 2 y = f0 sin(pt )
dt 2 dt
22 Chapter 3. Simple Harmonic Motion and Waves
Where f0 = Fm0 .
The complete solution consists of a complementary function (the transient solution,
identical to DHM) and a particular integral (the steady-state solution).
y = y comp + y part
Wave Motion
Wave Motion
Wave motion is the propagation of disturbances (oscillations) through a medium
or vacuum that transfers energy or momentum from one point to another without
the permanent transfer of matter.
Waves
Mechanical Non-mechanical
Waves (Electromagnetic)
h x i
y = a sin ω t −
v
ω
y = a sin ωt − x
v
23
24 Chapter 4. Wave Motion
∂y
= ωa cos(ωt − k x )
∂t
∂2y
= −ω 2 a sin(ωt − k x ) . . . (1)
∂t 2
Now differentiate with respect to x :
∂y
= −k a cos(ωt − k x )
∂x
∂2y
= −k 2 a sin(ωt − k x ) . . . (2)
∂x 2
Dividing (1) by (2):
∂2y 2π 2
2
∂t 2 ω2 T λ
= 2 = = = v2
∂2y k 2π 2 T
∂x 2 λ
Wave Equation
∂2y 1 ∂2y
=
∂x 2 v 2 ∂t 2
The velocity at which a specific phase of the wave (like a crest or trough) propa-
gates through the medium. For a wave y = a sin(ωt − k x ), the phase is constant
when ωt − k x = constant. Differentiating with respect to t : ω − k dx dt = 0 =⇒
vp = ωk .
The speed at which the overall envelope or shape of a wave packet (a group of
waves) propagates. It is the velocity at which energy or information travels.
4.4. Superposition: Standing Waves and Beats 25
Suppose two waves with slightly different frequencies and wave numbers interfere:
y 1 = a sin(ω1 t − k 1 x )
y 2 = a sin(ω2 t − k 2 x )
∆ω limit dω
vg = −−−→
∆k dk
d dvp
vg = (k vp ) = vp + k
dk dk
Also, since k = λ :
2π
dk = − 2π
λ2
dλ:
dvp
vg = vp − λ
dλ
y = y 1 + y 2 = a[sin(ωt − k x ) + sin(ωt + k x )]
This represents a standing wave. The amplitude A(x ) = 2a cos(k x ) depends on posi-
tion.
The separation between adjacent nodes (or adjacent antinodes) is λ/2. The distance
between a node and an adjacent antinode is λ/4.
26 Chapter 4. Wave Motion
4.4.2 Beats
When two waves of slightly different frequencies n 1 and n 2 traveling in the same
direction superimpose at a point:
y 1 = a sin(2πn 1 t )
y 2 = a sin(2πn 2 t )
Assuming equal amplitude a, their sum produces a wave whose amplitude fluctuates
over time. The time between two consecutive maxima (beats) is |n 1 −n
1
2|
. The number
of beats per unit time (beat frequency) is:
fbeat = |n 1 − n 2 |
Chapter 5
Fourier Series
Fourier Series
Any well-behaved periodic function f (t ) with period T can be expressed as an
infinite sum of sine and cosine functions:
∞ Õ ∞
2nπ 2nπ
a n cos b n sin
Õ
f (t ) = a 0 + t + t
n=1
T n=1
T
Solution: First, notice that f (−x ) = −f (x ), which means the function is odd. For
an odd function, the average value a 0 = 0, and all cosine coefficients a n = 0. We only
need to calculate the sine coefficients b n .
The formula for b n on the interval [−π, π] is:
∫ π
1
bn = f (x ) sin(nx ) dx
π −π
27
28 Chapter 5. Fourier Series
Since f (x ) sin(nx ) is the product of two odd functions, it is an even function. We can
simplify the integral by evaluating from 0 to π and doubling it:
∫ π
2
bn = (1) sin(nx ) dx
π 0
cos(nx ) π
2
= −
π n 0
2
= [1 − cos(nπ)]
nπ
Evaluating for different values of n:
• If n is even: cos(nπ) = 1, so b n = 2
nπ (1 − 1) = 0.
4 1 1
f (x ) = sin(x ) + sin(3x ) + sin(5x ) + . . .
π 3 5
∞
4
sin(nx )
Õ
=
n=1,3,5...
nπ
Chapter 6
Practice Problems
1. (a) Explain how mass is defined. State and explain Newton’s second law
of motion in two alternate formats.
(b) Find the final speeds of two particles of mass m 1 and m 2 when the
particle m 1 hits the stationary target m 2 (elastic collision).
29
30 Chapter 6. Practice Problems