12-07-2026
1701CJA101361260023 JA
PART-1 : MATHEMATICS
SECTION-I(i)
1) Let ƒ (x) be a differentiable function. Let h(x) = . Which one of the
following is correct ?
(A) h(x) increases as ƒ (x) increases
(B) h(x) always increases whether ƒ (x) increases or decreases
(C) h(x) increases as ƒ (x) decreases
(D) nothing can be said
2) Given : f (x) = g(x) =
h(x) = {x} k(x) =
then in [0, 1], Lagranges Mean Value Theorem is NOT applicable to
where [x] and {x} denotes the greatest integer and fractional part function.
(A) f, g, h
(B) h, k
(C) f, g
(D) g, h, k
3) If , then f(x) is :
(A) Differentiable at x = 0
(B) Not differentiable at x = 0
(C) Differentiable & Continuous ∀ x ∈ R
(D) None of these
4) If ƒ(x) ƒ(y) + 2 = ƒ(x) + ƒ(y) + ƒ(xy) and ƒ(1) = 2, ƒ'(1) = 2 then sgn ƒ(x) is equal to
(where sgn denotes signum function) -
(A) 0
(B) 1
(C) –1
(D) 4
SECTION-I(ii)
1)
Let ƒ,g : [–2,3] → R be continuous function which are twice differentiable on the interval (–2,3). Let
the values of ƒ and g at the points –2,0,1 and 3 be as given in the following table :
In each of the intervals (–2,0), (0,1) and (1,3) the function (ƒ – 5g)" never vanishes. Then the correct
statement(s) is (are)
(A) ƒ'(x) – 5g'(x) = 0 has exactly three solutions in (–2,0) ∪ (0,1) ∪ (1,3)
(B) ƒ'(x) – 5g'(x) = 0 has exactly one solutions in (0,1)
(C) ƒ'(x) – 5g'(x) = 0 has at least one solution in (1,3)
(D) ƒ'(x) – 5g'(x) = 0 has at least two solution in (–2,0)
2)
If , then
(A)
range of ƒ(x) is
(B) ƒ(x) is increasing for all x > –1
(C) ƒ(x) is decreasing for all x > –1
(D) least value of ƒ(ƒ(x)) is 0.
3) Let if
(A)
(B)
(C)
(D)
4) For the equation ; which of the following statement(s) is/are correct ?
(A) If a ∈ (0,∞), then equation has 2 real and distinct roots
(B) If a ∈ (–∞,–e2), then equation has 2 real & distinct roots.
(C) If a ∈ (0,∞), then equation has 1 real root
(D) If a ∈ (–e,0), then equation has no real root.
5)
Two adjacent sides of a rhombus are 2x + 3y = a – 5 and 3x + 2y = 4 – 2a and its diagonals intersect
at the point (1,2), then a can be -
(A) –16
(B) 16
(C)
(D)
6) If ƒ : R → R be a derivable function such that ƒ'(0) = ℓn2 and ƒ(x + y) = 2xƒ(y) + 22yƒ(x) ∀ x, y ∈ R,
then
(A) ƒ(x) is a one-one function
(B) ƒ(x) is a many one function
(C) equation ƒ(x) = 2 has exactly two solutions
(D) equation ƒ(x) = 2 has exactly one solution
SECTION-II
1) If , then at x = 1.5 is
2) If then a is
3) Number of integral values of 'k' for which equation has real solutions, is
4) Let ƒ(x) be non-constant thrice differentiable function defined on (–∞, ∞) such that ƒ(x) = ƒ(6 – x)
and ƒ'(0) = 0 = ƒ'(2) = ƒ'(5). If 'n' is the minimum number of roots of (ƒ"(x))2 + ƒ'(x)ƒ"'(x) = 0 in the
interval x ∈ [0, 6] then sum of digits of n equals
5) Let ƒ(x) be a cubic polynomial with ƒ(2) = 18 and ƒ(1) = –1. Also ƒ(x) has local maxima at x = –1
and ƒ'(x) has local minima at x = 0, then
Distance between the tangents drawn at point of local maxima and local minima is
6) Number of non negative integers which satisfy the inequation f(f(f(x))) > f(f(–x)), where f(x) = 30 –
2x – x3 is -
7) If the equation of tangent drawn to curve y = f(x) at point P(3, 5) is 5x – 4y + 5 = 0 and
= 2(a 320 ℓn c)2 (where a and c are prime numbers),
then a + c is
8) Let D is point on line ℓ1 : x + y – 2 = 0 and A(3, 3) is fixed point. ℓ2 is the line perpendicular to DA
and passing through A. If M is another point on line ℓ1 (other than D) and locus of point of
intersection of ℓ2 and angle bisector of ∠MDA is x2 + y2 + 2hxy + 2gx + 2fy + c = 0, then h + g + f +
c is equal to
PART-2 : PHYSICS
SECTION-I(i)
1) A force is applied on the body of mass 2 kg which varies with displacement of body according to
the given graph. If initial speed is 2 m/s, find the final speed of the body :-
(A) 8 m/s
(B) 6 m/s
(C) 4 m/s
(D) 10 m/s
2) Figure shows graph of deviation δ versus angle of incidence for a light ray striking a prism. Angle
of prism is :-
(A) 30°
(B) 45°
(C) 60°
(D) 75°
3) A planet of mass m is in an elliptical orbit about the sun (m << Msun) with an orbital period T. If A
be the area of orbit, then its angular momentum would be :
(A)
(B) mAT
(C)
(D) 2mAT
4) In the circuit shown below, the cells have negligible internal resistance. If the galvanometer G
reads zero, the value of the resistor R is
(A) 100 Ω
(B) 200 Ω
(C) 1000 Ω
(D) 500 Ω
SECTION-I(ii)
1)
Equivalent resistance between :-
(A) A and B is 0.8 R
(B) A and D is 1.2 R
(C) B and D is 1.2 R
(D) B and D is 2R
2) The current through the 3Ω resistor (as shown in figure) is 2A. Then the value of VA–VB will be
(A) 30 V
(B) 6 V
(C) –6V
(D) –30 V
3) A projectile is thrown at angle 30° with surface of earth, with velocity v0 such that it attains a
maximum height equal to radius of earth, then :
(A)
Minimum velocity would be .
Minimum velocity would be
(B)
(C) At maximum height velocity will be zero.
(D) Trajectory would not be parabolic
4) A charged particle of mass m = 1kg & charge Q = 1C, is projected from (0, 10) with velocity .
Uniform electric field N/C exist in the region. Gravity act along negative y direction.
(Take : g = 10 m/s2) For
(A) Particle passes through origin at some time.
(B) Time spent by charged particle in I quadrant is 2 seconds.
(C) While crossing origin, the trajectory makes equal angle with both x and y axes.
(D) K.E. of particle at (0, 10) will be half the K.E. at origin.
5) Three concentric conducting shells have radii 1m, 2m and 3m. They carry charges q, –4q, 9q
respectively.
(A) Charge on outer surface of middle shell is –3q.
(B) Potential of shell 1 is equal to potential of shell 2.
(C) If 1 and 3 are connected by a conducting wire, charge will flow from 1 to 3.
(D) If 1 and 3 are connected by a conducting wire, no charge will flow.
6)
In the network shown in the figure. Choose the correct statement(s).
(A) Magnitude of potential difference between points H and B is 5V
(B) Magnitude of potential difference between points D and B is 1V
(C) Magnitude of potential difference between points D and E is 0.5V
(D) Magnitude of potential difference between points D and G is 2V
SECTION-II
1) A mass of 2 kg slides down circular track of radius 1 m. If the speed of mass at the bottom is 4
ms–1, work done by the frictional force is (–α) joule. Find the value of α. [g = 10 m/s2]
2) The potential energy (in joules) function of a particle in a region of space is given as : U = (2x2 +
3y3 + 2z) Here x, y and z are in metres. Find the magnitude of x component of force (in newton)
acting on the particle at point P (1m, 2m, 3m).
3) Figure shows an equiconvex lens of µ = 1.50, in contact with a liquid layer on the top of a plane
mirror. When a point object is placed at 45 cm from lens, it is found that image coincides with
object. When liquid is removed and experiment is repeated, the new distance for object and image to
coincide is found to be 30 cm. Then refractive index of liquid would be . Find the value of n.
4) Three large thick conducting sheets are placed parallel to each other as shown, charge on plates
are 20 µC, –5 µC and – 15 µC and seperation between them is 1 cm and 2 cm respectively. Find the
ratio of electric field at B to that of electric field at A :-
5) Find the magnitude of electric field (in N/C) due to a line charge of λ = nC/m at a point P as
shown.
6) A particle of mass m is moving in circular motion of radius r with constant speed v in influence of
two fixed particles of mass M. Plane of circular motion is perpendicular to line joining fixed particles
as shown. Speed of particle is given as , find value of n (a = r )
7) In the shown potentiometer arrangement the wire PQ has a resistance of 5Ω and the driver cell
has an emf of 2V. If a balance point is obtained at 0.6m along PQ, what is the value of resistance R
(in Ω) ? (Length PQ = 1 m)
8) Resistance are connected in a meter bridge circuit as shown in the figure. The balancing length ℓ1
is 40cm. Now an unknown resistance x is connected in series with P and new balancing length is
found to be 80cm measured from the same end. Then the value of x will be _____ Ω
PART-3 : CHEMISTRY
SECTION-I(i)
1) Match the suitable mechanism given in list-II for the reaction given in list-I, in order to form major
product
List-I List-II
(P) (1) SN2
(Q) (2) SN1
(R) (3) E2 elimination
(S) (4) E1 elimination
(A) P → 1, Q→ 2, R → 3, S → 4
(B) P → 4, Q→ 3, R → 2, S → 1
(C) P → 3, Q→ 1, R → 4, S → 2
(D) P → 2, Q→ 4, R → 3, S → 1
2) + → H2O ; ΔH = – 57 kJ/mol
2HA(aq.) + Ba(OH)2(aq.) → BaA2 (aq.) + 2H2O; ΔH = –105 kJ/mol
Ionisation enthalpy of weak acid HA(aq.) will be -
(A) 9 kJ/mol
(B) 48 kJ/mol
(C) 4.5 kJ/mol
(D) 24 kJ/mol
3) The crystal field theory is now much more widely accepted than the valence bond theory. It
assumes that the attraction between the central metal atom and the ligands in a complex is purely
electrostatic. -
Which of the following complex is inner orbital as well as low spin complex -
3+
(A) [Cr(H2O)6]
3–
(B) [Fe(CN)6]
3–
(C) [Cu(CN)4]
2+
(D) [Mn(NH3)6]
4) Half life of a first order reaction :
A(aq.) → 2B(aq.) is 40 min at 27°C and 20 min at 37°C. The activation energy of reaction is
(ln2 = 0.7, R = 2.0 cal mol–1K–1)
(A) 19530 cal/ mol
(B) 13020 cal/ mol
(C) 26040 cal/ mol
(D) 6510 cal/ mol
SECTION-I(ii)
1)
Products which can be obtained during the reaction in good yield :
(A)
(B)
(C)
(D)
2) The product(s) obtained during reaction is/are
(A)
(B)
(C)
(D)
3) An ideal gas having 2 moles (fixed) is subjected to the changes as shown is (P–V) diagram. Select
the correct option(s) from the following diagram.
(A)
Temperature at "A" ; Pressure at "C" (60 R)
(B)
Temperature at "D" ; Pressure at "B" (75 R)
(C)
Temperature at "A" ; Pressure at "B" (75 R)
(D)
Temperature at "D" ; Pressure at "C" (60 R)
4) Which of the following salts of anion produce colourless vapours with conc. H2SO4.
(A) NaCl
(B) Na2S
(C) Na2S2O3
(D) NaI
5) Which of following give redox reaction on heating ?
(A) NH4NO2
(B) KMnO4
(C) HNO3
(D) NH4NO3
6) Which of the following are true for isothermal expansion of an ideal gas :
(A) Internal energy remains unaffected
(B) Temperature remains constant
(C) The enthalpy remains unaffected
(D) Enthalpy increases
SECTION-II
1) How many ether will give two different alkyl iodides on reaction with excess amount of HI.
(i) MeOEt (ii) Ph-OMe (iii) (iv)
(v) (vi) (vii) (viii)
2)
Number of α-Hydrogen atoms in Hydrocarbon formed as major product.
3) How many reactions giving alkyl halide as one of the final product ?
(a) C2H5OH + SOCl2
(b) R—I + AgF
(c) EtOH + NaI + H2SO4
(d) EtOH + NaI + H3PO4
(e) CH3–CH=CH2
(f) CH3–CH2–Cl
(g)
(h) CH3–O–C2H5
4) The entropy change of system involving the heating of one mole of helium gas, assuming ideal
behaviour, from a temperature of 250 K to a temperature of 1000 K at constant pressure, in cal K–1
mole–1 , is
(ℓn10 = 2.3, log2 = 0.3) (R = 2 Cal mol–1K–1)
5) Find the number of complexes, which shows cis and trans isomerism as well as optical isomerism.
[Pt(NH3)2Cl2], [Co(NH3)2(H2O)2Cl2]Cl, [Co(NH3)3F3], [Ni(NH3)4Cl2], [Co(gly)3]
[Co(en)2Cl2]Cl
6) SO32– ?
(Sol.)
SO32– ?
(Sol.)
What is the difference between oxidation number of sulphur in product of both reactions ?
7) The number of compound among the following which give diprotic acid on hydrolysis is X. Then
value of X/2 is
8) 100 gm water is heated from 27 ºC to 77ºC at constant pressure. The value of ΔStotal
(i.e., ΔSsystem + ΔSsurrounding), in J K–1, if the process is performed irreversibly.
(Given: Specific heat capacity of water = 4.2 J K–1 gm–1; ln 7 = 1.95; ln 6 = 1.80)
ANSWER KEYS
PART-1 : MATHEMATICS
SECTION-I(i)
Q. 1 2 3 4
A. A A B B
SECTION-I(ii)
Q. 5 6 7 8 9 10
A. A,B,C A,D A,C,D B,C,D A,D B,D
SECTION-II
Q. 11 12 13 14 15 16 17 18
A. 0.50 1.25 2.00 3.00 19.00 3.00 8.00 23.00
PART-2 : PHYSICS
SECTION-I(i)
Q. 19 20 21 22
A. A B A C
SECTION-I(ii)
Q. 23 24 25 26 27 28
A. A,B,C B,D B,D A,B,C,D A,D A,B,C,D
SECTION-II
Q. 29 30 31 32 33 34 35 36
A. 4.00 4.00 4.00 0.00 3.00 4.00 995.00 20.00
PART-3 : CHEMISTRY
SECTION-I(i)
Q. 37 38 39 40
A. D C B B
SECTION-I(ii)
Q. 41 42 43 44 45 46
A. A,B B,C B,C A,B,C A,B,C,D A,B,C
SECTION-II
Q. 47 48 49 50 51 52 53 54
A. 4.00 3.00 6.00 6.90 3.00 8.00 2.50 3.00
SOLUTIONS
PART-1 : MATHEMATICS
1) h'(x) = {(ƒ (x))2 + 2ƒ (x) + 1} ƒ '(x)
h'(x) = (ƒ (x) + 1)2 . ƒ '(x)
If ƒ '(x) ≥ 0 ⇒ h'(x) ≥ 0
Hence if ƒ(x) increases, h(x) also increases.
2)
Question Explanation: Determine applicability of LMVT based on continuity and
differentiability.
Concept: Lagrange's Mean Value Theorem (LMVT) conditions.
Solution:
For f(x): . At x = 1/2, the derivative is undefined (infinite). Thus, it's
non-differentiable in (0, 1). (Not Applicable)
For g(x): As , so tan[x] = 0, making g(x) = 0. Since g(0) = 1, the function is
discontinuous at x = 0. (Not Applicable)
For h(x): x is discontinuous at integers. At x = 1, the left-hand limit is 1 but h(1) = 0. It is
discontinuous in [0, 1]. (Not Applicable)
For k(x): is a continuous and differentiable as exponential/logarithmic composition
for all x ∈ [0, 1]. (Applicable)
Final Answer: Option (1)
3) LHD =
RHD =
4) Put y =
f(x)
⇒ f(x) =
⇒ f(x) = 1 ± xn
f(1) = 2, f'(1) = 2
⇒ f(x) = 1 + x2
sgn(f(x)) = sgn(1 + x2) = 1
5) Let h(x) = ƒ(x) – 5g(x)
h(x) is continuous, differentiable & ƒ'(x) is also continuous, differentiable
h(–2) = 6 = h(0) = h(1) = h(3) & (ƒ – 5g)"
never vanishes
⇒ exactly one root in (–2, 0), (0, 1) & (1, 3)
6)
for x ∈ (–1, 0), g(x) is decreasing
⇒ g(x) ∈ (1, ∞)
for x Î (0, ∞), g(x) is increasing
⇒ g(x) ∈ (1, ∞)
Now ƒ(x) = 2tan–1g(x)
7)
At
For
∴ must be odd
⇒ is even
8) Question Explanation: Determining the number of roots by analyzing function range.
Concept: Function Extremas and Range.
we part of the graph of f(x)
Let . We find its local extrema using . By sketching the behavior of g(x) as
and ,
we can see how many times the horizontal line y = a intersects the curve.
Critical point at . As . As .
Range for is (one root for a>0). Range for x< -1 is (two roots for
).
Final Answer: option (2) , (3) , and (4) are correct.
9)
We know diagonals are angle bisectors of a rhombus
10) ƒ(x + y) = 2xƒ(y) + 4yƒ(x) ...... (i)
Replace x by y and y by x :
ƒ(x + y) = 2yƒ(x) + 4x.ƒ(y) ...... (ii)
By (i) and (ii)
2xƒ(y) + 4yƒ(x) = 2yƒ(x) + 4xƒ(y)
⇒
⇒ ƒ(x) = k.(4x – 2x)
∴ ƒ'(x) = k(4xℓn4 – 2xℓn2)
∵ ƒ'(0) = ℓn2 ⇒ k = 1
∴ ƒ(x) = 4x – 2x
Many one function.
ƒ(x) = 2 ⇒ (2x)2 – 2x = 2 ⇒ x = 1 only
11)
at x = 1.5
12)
13) Let
ƒ'(x) = (–2x – x(1 – x2)) = × (x2 – 3)
⇒ k = 0, 1
14) ƒ(x) = ƒ(6 – x)
⇒ ƒ'(x) = –ƒ'(6 – x) .... (1)
put x = 0, 2, 5
ƒ'(0) = ƒ'(6) = ƒ'(2) = ƒ'(4) = ƒ'(5) = ƒ'(1) = 0
and from equation (1) we get ƒ'(3) = –ƒ'(3)
⇒ ƒ'(3) = 0
So ƒ'(x) = 0 has minimum 7 roots in
x ∈ [0, 6] ⇒ ƒ"(x) has min 6 roots in x ∈ [0,6]
h(x) = ƒ'(x).ƒ"(x)
h'(x) = (ƒ"(x))2 + ƒ'(x) ƒ"'(x)
h(x) = 0 has 13 roots in x ∈ [0, 6]
h'(x) = 0 has 12 roots in x ∈ [0, 6]
15)
Question Explanation: Finding distance between horizontal tangents at extremum points.
Concept: Maxima and Minima of Polynomials
Solution:
ƒ(x) = ax3 + bx2 + cx + d
ƒ(1) = –1 ∴ a + b + c + d = –1 .... (i)
ƒ(2) = 18 ∴ 8a + 4b + 2c + d = 18 .... (ii)
ƒ"(0) = 0 ∴ b = 0 .... (iii)
ƒ'(–1) = 0 ⇒ 3a – 2b + c = 0 .... (iv)
Solving (i), (ii), (iii) and (iv)
a= , b = 0, c = ,d=
ƒ(x) = (19x3 – 57x + 34)
ƒ'(x) = [57x2 – 57] = 0
x = 1, x = –1
point of maxima ≡ (–1, 18)
point of minima = (1, –1)
Distance between the tangents is = 19 units
Also number of solutions of |ƒ(x)| – 18 = 0
Three solutions.
Final Answer: 19.00
16) ∵ f′(x) = –3x2 – 2
∴ f(x) is decreasing
⇒ f(f(x)) < f(–x)
⇒ f(x) > –x ⇒ 30 – 2x – x3 > –x
⇒ x3 + x – 30 < 0
⇒ (x – 3)(x2 + 3x + 10) < 0 ⇒ x < 3
∴ Non negative x = 0, 1, 2
17) f(3) = 5 & f ′(3) =
= 2 × 340 (ℓn 3)2 × 25
18)
In ΔFDP & ΔADP
∠F = ∠A = 90°, ∠FDP = ∠ADP = θ & PD is common
⇒ ΔFDP & ΔADP are congurent ⇒ PF = PA
⇒ (h – 3)2 + (k – 3)2 =
⇒ x2 + y2 – 2xy – 8x – 8y + 32 = 0
PART-2 : PHYSICS
19) Explain Question : A force is applied on a body of mass 2 kg which varies with
displacement of body according to given F-s graph. If initial speed is 2 m/s and we need to find
the final speed of the body.
Concept : This question is based on work-energy theorem, force-displacement graph.
Solution : Let apply W.E.T
W = KEf – KEi
× 10 (10 + 2) = ×2×
60 = –4
= 64
Vf = 8
object is finally move at 8 m/s
Final Answer: Option (1)
20) δ = i + e – A ⇒ A = 45° (i = 15°; e = 60°)
21)
Question Explanation:
Find the angular momentum of a planet moving in an elliptical orbit.
Concept:
Kepler's Second Law (constant areal velocity).
Solution:
Area swept in one revolution = A, time = T
Final Answer:
22) As G reads zero, the p.d. across R is 6V
Hence
3000 + 6R = 9R
R = 1000 Ω
23)
Req between A and B is
Req between A, D
Req between B, D
24)
(B) 6 V
(D) –30 V
25)
Angular momentum remains conserved about centre of earth.
mv0 cos30°R = mv2R
Path will not be parabolic because acceleration due to gravity does not remain constant.
26)
for y = 0,
0 = 10 t – × 10 t2 = 0
t = 0, t = 2
at t = 0, x = 0, & at t = 2,
x = 0 + (5) (2)2 = 10
∴ it passes through origin.
at origin, vx =
vnet =
27)
VA = VB
q1 = q [Hence no charge will flow] 1 to 3
28)
(A) Magnitude of potential difference between points H and B is 5V
(B) Magnitude of potential difference between points D and B is 1V
(C) Magnitude of potential difference between points D and E is 0.5V
(D) Magnitude of potential difference between points D and G is 2V
29) Using KE= mv2 when
We get KE= m2gr = 2 × 10 × 1 = 20 J
But KE = × 2 × 42 = 16 J
Frictional work = 16–20 = – 4 J = – αJ
⇒ α=4
30)
31)
Focal length of convex lens
f=R
focal length of lens made of liquid
f' =
case-2
= –2R [∵ fm → ∞]
⇒ f'eq = = –2R ⇒ R = 7.5
case-1
⇒ = (µ – 2) ⇒ µ =
⇒µ=
32)
33)
34) Question Explanation:
Finding a constant in the speed formula for a particle in circular motion.
Concept:
Uniform Circular Motion & Newton's Law of Gravitation.
Solution:
The net gravitational force on mass 'm' from the two fixed masses 'M' provides the required
centripetal force for its circular motion. By resolving the gravitational forces into components,
we can find the net force towards the center of the circle and equate it to the centripetal force
expression.
The distance (d) from the orbiting mass 'm' to each fixed mass ' M ' is
Given
.
The net force towards the center is the sum of the horizontal components of the two
gravitational forces:
Here,
This net force provides the centripetal force:
Comparing this with the given expression
, we find that n = 4.
Final Answer:
Correct answer is 4.
35)
Using basics concept of potentiometer.
36) Initially, …(1)
Finally, …(2)
Divide (2) by (1)
⇒
∴ x = 5P = 5 × 4 = 20 Ω
PART-3 : CHEMISTRY
37)
Question Explanation: Matching reactions with suitable mechanisms.
Concept: SN1, SN2, E1, E2 reaction conditions.
Solution:
P: A tertiary alkyl halide with a weak nucleophile/solvent (CH3OH) and no heat. This favors an
SN1 reaction.
Q: A tertiary alkyl halide with a weak nucleophile/solvent (CH3OH) and heat. Heat favors
elimination, so this is an E1 elimination.
R: A primary alkyl halide with a strong base (CH3CH2O−). This favors an E2 elimination.
S: A primary alkyl halide with a strong nucleophile (KCN) and a polar aprotic solvent (DMF).
This is a classic SN2 reaction. Calculation: Not applicable.
Final Answer: P→2,Q→4,R→3,S→1.
38) Question Explanation: Calculating enthalpy of ionization for a weak acid.
Concept: Enthalpy of Neutralization.
Solution: The enthalpy of neutralization for a strong acid and strong base is -57 kJ/mol . If a
weak acid is used, some energy is absorbed to dissociate (ionize) the weak acid. The observed
enthalpy change is the sum of the enthalpy of neutralization and the enthalpy of ionization.
Calculation:
For 2 moles of
Final Answer: 4.5 kJ/mol
39)
[Fe(CN)6]3–
40)
Rate constant
Rate constant
Ea = (ln 2 × 2 × 310 × 30) cal/mol
= 13020 cal/mol
41)
42)
(B)
(C)
43) By PV = nRT
At “A”
2 × 8 = 2 × R × TA
TA =
Between A & B , V is constant
PB = 75 R
Between A & D ,P is constant
TD =
44)
Correct options are (A), (B) & (C)
45)
Correct options are (A), (B), (C) & (D)
46) Fact
47) i, iii, vi, vii will give two iodides.
48)
Refer notes.
49)
Explaining the Question :-
Question is asking about the reaction which give alky halide.
Concept:-
This question is based on preparation of R-X.
Solution :-
(a) C2H5OH + SOCl2 → C2H5 – Cl + SO2 + HCl
(b) R – I + AgF → R – F + Ag I
(C) EtOH + Nal + H2SO4 → C2H5OH + I2 + other product
(d) EtOH + Nal + H3PO4 → Et – I
(e)
(f)
(g)
(h)
Except (c) and (g) al reactions give alkyle halides.
Final Answer :- (6)
50) The expression for change in entropy ΔS with change in temperature is given by the
expression at constant pressure as under :
for one mole = 2.303 CP
[CP for monoatomic gas = ]
51)
Refer notes.
52)
Refer notes.
53)
54) ΔSsystem = m . s . ln = 100 × 4.2 × ln = 63 J K–1
ΔSsurrounding = =
= = – 60 J K–1
∴ ΔStotal = ΔSsys + ΔSsurr = 63 + (– 60) = 3 J K–1