12-07-2026

2331CJA101001260001 JM

PHYSICS

SECTION-I

1) If energy (E), velocity (V) and time (T) are chosen as the fundamental quantities, then the
dimensions of surface tension will be. (Surface tension = force/length)

(A) E V–2 T–1

(B) E V–1 T–2
(C) E–2 V–1 T–3
(D) E V–2 T–2

2) Consider three vectors , , and . A vector of the form

(α and β are numbers) is perpendicular to . The ratio of α and β is

(A) 1 : 1
(B) 2 : 1
(C) –1 : 1
(D) 3 : 1

3) The time period of a simple pendulum is given by . The measured value of the length
of pendulum is 10 cm known to a 1mm accuracy. The time for 200 oscillations of the pendulum is
found to be 100 second using a clock of 1s resolution. The percentage accuracy in the determination
of 'g' using this pendulum is 'x'. The value of 'x' to the nearest integer is :-

(A) 2%
(B) 3%
(C) 5%
(D) 4%

4) Given : and . The unit vector of is :

(A)

(B)

(C)
(D)

5) A particle is moving with speed along positive x-axis. Calculate the speed of the particle
at time t = (assume that the particle is at origin at t = 0).

(A)

(B)

(C) b2 τ

(D)

6) A car starts from P and follows the path as shown in figure. Finally, car stops at R. Find the

distance travelled and displacement of the car if a = 7 m, b = 8 m and r = m. [Take ]

(A) 48m, 36m

(B) 36m, 48m
(C) 81m, 36m
(D) 48m, 48m

7) A particle is projected from the ground with velocity u at angle θ with horizontal. The horizontal
range, maximum height and time of flight are R, H and T respectively. They are given by

; and . Now keeping u fixed, θ is varied from 30° to 60°, then

:-

(A) R will first increase then decrease, H will increase and T will decrease.
(B) R will first increase then decrease while H and T both will increase.
(C) R will decrease while H and T both will increase.
(D) R will increase while H and T both will also increase.

8) Two cars C1 and C2 are moving in the same direction on a straight single lane road with constant
velocities 12 m/s and 10 m/s respectively. When the separation between the two was 200 m, C2
started accelerating to avoid collision. The minimum acceleration of car C2 so that they don’t collide,

is:

(A) 1 cm/s2
(B) 2 cm/s2
(C) 3 cm/s2
(D) 4 cm/s2

9) A particle moves from the point m, at t = 0, with an initial velocity ms–1. It

is acted upon by a constant force which produces a constant acceleration ms–2.

What is the distance of the particle from the origin at time 2s?

(A)
(B)
(C) 5 m
(D) 15 m

10) A particle is projected from a horizontal plane (x–z plane) such that its velocity vector at time t is
given by . Its range on the horizontal plane is given by :

(A)

(B)

(C)

(D) None

11) In the given figure, block are at rest and in equillibrium. Acceleration of block A is a and B is b

just after spring (2) is cut, then.

(A) a = g↓, b = g
(B)
a = g↓, b =
(C) a = 0, b = g

(D) a = 0, b =

12) See the arrangement shown in figure. If the acceleration of block B is a, then the acceleration of

block A in magnitude will be :

(A) a
(B) 2a
(C) 3a
(D) 4a

13) Figure shows three blocks that are being pulled along a smooth horizontal surface. The masses
of the blocks are shown in figure and tension force in cord connecting A and B = 120 N. The pulling

force F is :

(A) 50 N
(B) 100 N
(C) 125 N
(D) 200 N

14) Consider the ratio to be determined by measuring a dimensionless quantity a. If the

error in the measurment of a is Δa(Δa/a<<1), then what is the error Δr in determining r ?

(A)

(B)

(C)
(D)

15) Which one of the following is not the name of a physical quantity?

(A) Density
(B) impulse
(C) Energy
(D) Kilogram

16) If and are two non collinear unit vectors and if then the value of
is:

(A) 2

(B)

(C)

(D) 1

17) The acceleration versus time graph of a particle is shown in figure then respectively v–t graph is

:-

(A)

(B)

(C)

(D)
18) Three blocks of masses m1 = 4 kg, m2 = 2 kg, m3 = 4 kg are connected with ideal strings passing
over a smooth, massless pulley as shown in figure. The acceleration of blocks will be (g = 10 m/s2) :-

(A) 2 m/s2
(B) 4 m/s2
(C) 3 m/s2
(D) 5 m/s2

19) A string of negligible mass going over a clamped pulley of mass m supports a block of mass M as

shown in the figure, The force on the pulley by the clamp is given by:

(A) Mg
(B) mg

(C)

(D)

20) A particle is projected from the ground with an initial speed of ν at an angle θ with horizontal.
The magnitude of average velocity of the particle between its point of projection and highest point of
trajectory is :-

(A)

(B)

(C)

(D) ν cos θ

SECTION-II
1) A body travelling along a straight line traversed one third of the total distance with a velocity 4
m/s. The remaining part of the distance was covered with a velocity 2 m/s for half the time and with
velocity 6 m/s for the other half of time. Find the mean velocity averaged over the whole time of
motion.

2) A particle is projected at t = 0 with a velocity 120 ms–1 at an angle 60° to the horizontal. (Take
acceleration due to gravity is 10 ms–2). The change in velocity of the particle in ms–1 in a time interval
from t = 0.28 sec to 0.31 sec. is x/10. What is the value of x?

3) An inclined plane is bent in such a way that the vertical cross section is given by where y
is in vertical and x is in horizontal direction. If the upper surface of this curved plane is rough with
coefficient of friction μ = 0.5, then the maximum height in cm at which a stationary block will not
slip downward is ____ cm.

4) After one second of releasing block string is cut. Find the time taken by lighter block to reach the

ground ( g =10m / sec2, )

5) If three forces , and acting

simultaneously on a body keep it in translational equilibrium (Net force = 0), determine numerical
value of 0.5 (a + b).

CHEMISTRY

SECTION-I

1)

The greater the energy of a photon, the :-

(A) longer the wavelength and the higher the frequency.

(B) longer the wavelength and the lower the frequency.
(C) shorter the wavelength and the higher the frequency.
(D) shorter the wavelength and the lower the frequency.
2) Rydberg given the equation for all visible radiation in the hydrogen spectrum as . The
value of k in terms of Rydberg constant is

(A) 4R

(B)

(C)

(D) R

3) In hydrogen atom, two electrons move around the nucleus in circular orbits of radii R and 4R.
Find the ratio of the time taken by them to complete one revolution ? (Considering Bohr's atomic
theory is applicable)

(A) 1 : 4
(B) 4 : 1
(C) 1 : 8
(D) 8 : 1

4) An excited hydrogen atom returns to the ground state. The wavelength of emitted photon is λ. The
principal quantum number of the excited state will be -

(A)

(B) [λR(λR +1)]1/2

(C)

(D)

5) The velocity of electron in the 2nd orbit of H–atom is v cm/sec. Its velocity in 5th Bohr's orbit would
be :-

(A) 5 × v cm/sec

(B)
cm/sec

(C)
cm/sec
(D) none

6) Match the following

Column I Column II

2s, 3s, 4s, 4d

(i) (order of increasing (a) Bohr
energy )
 Quantum numbers
of 2s2 electrons

(ii) (b) Hund’s Rule

2p3 is
Pauli’s
(iii) (c)
exclusion
and not

Principal Aufbau
(iv) (d)
quantum number “n” principle

(e) Size of orbit

(A) (i) c ; (ii) d ; (iii) b ; (iv) e
(B) (i) d ; (ii) c ; (iii) b ; (iv) a,e
(C) (i) e ; (ii) b ; (iii) d ; (iv) c,e
(D) (i) e,c ; (ii) d ; (iii) a ; (iv) b

7) The kinetic energy of the electron present in the ground state of Li2+ ion is represented by :

(A)

(B)

(C)

(D)

8) Statement-1 : For n = 2 the values of ℓ may be 0, 1 and m may be 0, ±1.

Statement-2 : For each value of n, there are 0 to (n – 1) possible values of ℓ, for each value of ℓ
there are 0 to ± ℓ values of m.

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
(B)
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

9) For hydrogen atom, the orbital/s with lowest energy is/are :

(A) 4s (B) 3px (C) (D) (E)
Choose the correct answer from the options given below :

(A) (A) and (E) only

(B) (B) only
(C) (A) only
(D) (B), (C) and (D) only

10) Which of the following is/are not correct with respect to energy of atomic orbitals of hydrogen
atom?
(A) 1s < 2p < 3d < 4s
(B) 1s < 2s = 2p < 3s = 3p
(C) 1s < 2s < 2p < 3s < 3p
(D) 1s < 2s < 4s < 3d
Choose the correct answer from the options given below :

(A) (B) and (D) only

(B) (A) and (C) only
(C) (C) and (D) only
(D) (A) and (B) only

11) Which of the following pair of elements have same value of azimuthal quantum number for outer
most unpaired electron.

(A) Na, Cl
(B) O, Sc
(C) Cu, Li
(D) All of these

12) Molality of pure liquid benzene if it's density is 1.23 gm/ml is -

(Molar Mass of benzene = 78 gm)

(A) 15.77 m
(B) 5 m
(C) 1.577 m
(D) 12.8 m

13) A solution is made by dissolving CaBr2 in water (solvent) such that mass fraction of solute and
solvent is same in the solution. The molality of solution is [Atomic mass of Br = 80,Ca = 40]

(A) 2.5 m
(B) 55.55 m
(C) 2 m
(D) 5 m

14)

If 6 moles of KClO3 are decomposed according to following reactions calculate the moles
of produced if moles of O2 produced is 1.

(A) 2 mole
(B) 4 mole
(C) 3 mole
(D) 5 mole

15) Match the list:

List-I List-II

(P) No. of electrons in nucleus of (1) 146

(Q) No. of protons in nucleus of (2) 238

(R) No. of neutrons in nucleus of (3) 92

(S) No. of nucleons in nucleus of (4) Zero

(5) 54
(A) P-1, Q-2,R-3, S-4
(B) P-4, Q-3,R-1, S-2
(C) P-3, Q-2,R-4, S-1
(D) P-2, Q-1,R-4, S-3

16) The Difference in wavelength of first and last line of lyman series in emission spectrum of He+
would be :

(A)

(B)

(C)

(D)

17) 2NH3(g) N2(g) + 3H2(g)

if degree of dissociation of ammonia at equilibrium is 0.7 then observed molecular weight of reaction
mixture at equilibrium -

(A) 12
(B) 10
(C) 15
(D) 17

18) An unknown amino acid has 0.032% by wt. sulphur. If each molecule has one S atom only, then 1
gm of amino acid has ______ molecules :-

(A) 6.02×1018
(B) 6.02 × 1019
(C) 6.02×1024
(D) 6.02×1023

19) Two oxides of a metal contain 22.22% and 30% oxygen by mass respectively. If the formula of
the first oxide is MO, then the formula of the second oxide is :-

(A) MO2
(B) M2O3
(C) M2O
(D) M2O5

20)
If longest wavelength of Balmer series of hydrogen atom is x nm, then :
Match the list -

List-I List-II

(P) Approximate energy difference of 3rd and Ist orbit of H-atom (1)

(Q) Wavelength of first line of Paschen series of H-atom (2)

(R) Approximate energy difference of 4th and 2nd orbit of H-atom (3)

(S) Wavelength of series limit of Lyman series of H-atom (4)

(A) P-2, Q-1, R-4, S-3

(B) P-3, Q-4, R-2, S-1
(C) P-3, Q-1, R-4, S-2
(D) P-2, Q-3, R-4, S-1

SECTION-II

1) The work function of some metals is listed below. The number of metals which will show
photoelectric effect when light of 500 nm wavelength falls on the metal is :

2) Number of unpaired electrons present in Mn+2 is x and Zn+2 is y. Sum of x + y is _____.

3)

The molarity of HNO3 in a sample which has density 1.4 g/mL and mass percentage of 63% is _____.
(Molecular Weight of HNO3 = 63)
4) 27 gm of Al react with excess of oxygen to give 4.59 gm of Al2O3. Calculate percentage yield of
reaction.

5) Debroglie wavelength 'l' of ideal gas molecule at any given temperature is given as λ ∝ m–x × T–y.
Where m = mass of one gas molecule.
T = temperature (K)
Give x + y = ?

MATHEMATICS

SECTION-I

1) Let x, y, z are distinct such that (logyx)3 + (logzy)3 + (logxz)3 = 3, then (logyx)(logzx) + (logzy)(logzx)
is -

(A) 1
(B) 0
(C) 3
(D) –1

2) is -

(A) 96
(B) 8
(C) 102
(D) 7

3)

Number of natural number 'n' for which is a natural number, is

(A) 2
(B) 3
(C) 4
(D) 6

4) The sum of the product of the 2n numbers ±1, ±2, ±3, ........, ±n taken two at a time is :-

(A)

(B)

(C)
(D)

5) Number of positive integers satisfying is

(A) 0
(B) 1
(C) 2
(D) 3

6) If x = then value of (1 + x)48 is :-

(A) 5
(B) 25
(C) 125
(D) 625

7) . Then the number of real solutions for the given equation is

(A) 3
(B) 2
(C) 1
(D) 0

8) If a, a1, a2, a3, ...., a2n, b are in A.P. and a, g1, g2, g3, .... g2n, b are in G.P. then

+ +

+ .... + =

(A)

(B)

(C)

(D)

9)

(A)
(B)

(C)

(D)

10)

(A)

(B)

(C)

(D)

11) If α and β are the roots of the equation x2 + px + 2 = 0 and and are the roots of the equation

2x2 + 2qx + 1 = 0, then is equal to

(A)

(B)

(C)

(D)

12) If α and β are the roots of equation x2–2x–20 = 0 and an = αn+ βn ; n ≠ 0 then the value of

is

(A) 1
(B) 2
(C) 3
(D) 4

13) If α, β are real numbers such than β > α and then the equation
has

(A) both roots in

(B) No real roots
(C) both roots in
(D) both roots in

14)

If graph of expression x2 + bx + d is following

Now Δ OBC is right angled isosceles triangle and A is mid point of OB then roots of equation
x2 + bx + d = 0 is :-

(A) 2, 4
(B) 0, 0
(C) 1, 2
(D) 4, 8

15)

If x2 – 3x + 2 is factor of x4 – px2 + q then p, q respectively :-

(A) 5, 4
(B) 4, 5
(C) –3, 2
(D) 2, 3

16)

The A.M. and H.M. of two positive numbers are 16 and 12 respectively, then there G.M. is :-

(A) 8
(B)
(C) 14
(D) None

17) If a + b + c = 3 and a > 0, b > 0, c > 0 then the greatest value of a2b2c2 is :-
(A)

(B) 1

(C)

(D) None of these

18) 32 + x, 41, 32–x are in A.P. then which is wrong :-

(A) x2 – 4 = 0
(B) x + 2 = 0
(C) x – 2 = 0
(D) None of these

19) If 'n' arithmetic means A1, A2, A3 ...... An are inserted between 7 and 49 such that sum of these

means is 364. If the G.M. of A3 and A6 is K then is equal to

(A) 25
(B) 20
(C) 5
(D) 15

20) The sum of 'n' terms of series 1·4·7 + 4·7·10 + 7·10·13 + ........... is :-

(A)
(27n4 – 90n3 + 45n2 – 50n)

(B)
(27n4 + 90n3 + 45n2 + 50n)

(C)
(27n4 + 90n3 + 45n2 – 50n)
(D) None

SECTION-II

1) If then x + y + z is equal to

2) If , then is equal to

3) Number of solutions of the equation is _______

4) The smallest possible natural number n, for which the equation x2 – nx + 2014 = 0, has integral
roots is_____.
5) Between 1 and 31, m numbers have been inserted in such a way that the resulting sequence is
an A. P. and the ratio of 7th and (m – 1)th numbers is 5 : 9. Find the value of m.
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D A B A B A B A A B B C D B D C A A D C

SECTION-II

Q. 21 22 23 24 25
A. 4 3 25 2 6

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C C C C B B A A D C C D D B B A B A B A

SECTION-II

Q. 46 47 48 49 50
A. 3 5 14 9 1

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D B D C B C C C C A D B B C A B B D C C

SECTION-II

Q. 71 72 73 74 75
A. 6 4 0 91 14
 SOLUTIONS

PHYSICS

1) Question Explanation: Find the dimensional formula for Surface Tension (S) when Energy
(E), Velocity (V), and Time (T) are fundamental quantities.
Concept: This question is based on method of dimensions
Solution:
0
[surface tension] = [force/length] = M1 L T–2
suppose [surface tension] = Ea Vb Tc
0
∴ M1 L T–2 = [M1 L2 T–2]a [L1 T–1]b [T]c
Matching dimensions of M ⇒ a = 1
Matching dimensions of L ⇒ 2a + b = 0 ⇒ b = –2
Matching dimensions of T ⇒ –2a – b + c = –2 ⇒ c = –2
∴ [surface tension] = EV–2 T–2
Final Answer The correct option is (4)

2) Question Explanation: The question asks to find the ratio of coefficients for a
perpendicular vector combination.
Concept: Vector Perpendicularity and Dot Product (Scalar Product).
Solution:

The dot product condition is :

Final Answer: Option (1)

3)

4)
5) ν =

a=

a=

ν= t

6) Explain the question : A particle moves in the given path as shown in the diagram we
have to find the distance and displacement of the particle.
Concept : This question is based on distance and displacement.
Solution :
Distance = a + πr + b + 2πr
= a + b + 3πr

= 7 + 8 + 3π ×
= 48 m
Displacement = a + 2r + b + 4r

=7+8+6×
= 15 + 21 = 36 m
Final answer : 1

7)

Range is maximum at 45°.

∴ Range increases from 30° to 45° and decreases from 45° to 60°.
Time of flight and maximum height depends on sinθ which increases with increase in θ.
∴ Both increases.

8) Explanation:
Two cars move on the same straight road, with the back car moving faster. The front car starts
accelerating when they are 200 m apart. We have to find the minimum acceleration needed to
just avoid collision.

Concept:
This question is based on relative motion in a straight line.

Solution:
Velocity of C1 = 12 m/s
Velocity of C2 = 10 m/s
Relative velocity of C1 w.r.t. C2,
u = 12 − 10 = 2 m/s
Initial separation, s = 200 m
For minimum acceleration, relative velocity becomes zero just at collision point, v = 0
Using relative motion equation,
v² = u² − 2as
0 = (2)² − 2 · a · 200
0 = 4 − 400a
a = 4 / 400
a = 0.01 m/s²
a = 1 cm/s²

Final Answer: Option (1)

9) Solution:

Final Answer: The correct option is (1).

10)

At top point velocity along y-axis is zero.

Vy = 0 = b – ct = 0

Time of flight =

Range =

11) Question Explanation:

The problem asks for the accelerations of blocks A and B immediately after the spring
connecting them is cut from an equilibrium state.
Concept:
Spring force non-impulsive nature.

Solution:

For equilibrium after cutting

(ii) mg = ma k1x – 2mg = 2mb

a = g↓ 3mg – 2mg = 2mb ⇒

Final Answer: Option(2)

12) Question Explanation:

The problem asks for the magnitude of acceleration of block A, given that the acceleration of
block B is a.

Concept:
Principle of virtual work (power method).

Solution:

Final Answer: Option(3)

13) Question Explanation: The question asks to find the total pulling force F acting on a
three-block system.
Concept: Newton's Second Law of Motion and System Acceleration.
Solution:

Final Answer: Option (4)

14)
15) Answer: Kilogram

16)

a1 = a2 1 and

17)

Slope of v-t graph represent acceleration.

18)

Question Explanation:
The ques asks to find the acceleration of a three-block pulley system with the given masses.
Concept:
For connected blocks over a pulley, acceleration is calculated using Newton’s Second Law:
acceleration = net unbalanced force ÷ total mass of the system.
Solution:

Left side: Block m3 = 4 kg → weight WL = 4 × 10 = 40 N

Right side: Blocks m1 = 4 kg and m2 = 2 kg → total weight WR = 6 × 10 = 60 N
Net force: Fnet = WR − WL = 60 − 40 = 20 N
Total mass: Mtotal = 4 + 2 + 4 = 10 kg
Acceleration: a = Fnet / Mtotal = 20 / 10 = 2 m/s2
Final Answer:
Option (1)
19)
T = Mg

R=

= g

20) Initial velocity =

Final velocity =

21) Let total distance = s

Let the time take to cover first one third distance = t1, then

Now let t2 be the time for the rest two journeys. Then

22)

23) At maximum ht. block will experience maximum friction force. Therefore if at this height
slope of the tangent is tan θ, then θ = Angle of repose.

x=1
24)

25)
 6a – 8b = – 26...(i)
– 8a + 3b = – 19 ...(ii)
From equation (ii) a = 5 and b = 7
0.5 (a + b) = 6

CHEMISTRY

26)

Explanation Question: Question is asking about energy of photon.

Concept: This question is based on Planck's quantum theory.
Solution:

The correct option is (3)

27)

28)

Question Explanation: Find the ratio of time.

Concept : This question is based on Bohr Model
Solution:

Time period of Revolution =

z=1

Final Answer:
option (3)

29) ,n=

30)

31)

Explanation: select correct matching

Concept: This question is based on rules to fill electronic configuration.

Solution:
(i) → (d) (n + 1) rule or Aufbau principle
(ii) → (c) two electron must have opposite spin Pauli's exclusion principle
(iii) → (b) electron must be spin singly occupied Hund's Rule
(iv) → (a, e) It was used by Bohr's and it represents the size of orbit .

Final answer : Option (2)

32)

Question Explanation: Find kinetic energy of the electron present in the ground state of
Li2+ ion

Concept: This question is based on Bohr's atomic model.

Solution:
For a hydrogen-like atom with atomic number Z :

Centripetal force = Electrostatic force ⇒

Kinetic Energy (K) =

For Li2+, atomic number Z = 3.

Substituting Z = 3 : K =

Final Answer:
The correct option is (1)

33) (1) for n = 2, the value of l = 0 to (n – 1)

then l = 0, 1
then me = 0 (when l = 0)
me = –1, 0, +1 (when l = 1)
Here value of “me” is depend upon the value of ‘l’, which gives orientation of orbitals of
subshell

34) In hydrogen atom the orbitals in a shell are degenerate means energy depends only on ‘n’
∴

35)

Explain the question: Identify the incorrect energy order(s) for hydrogen atom orbitals.

Concept: Degeneracy in single-electron systems.

Solution:
In a single-electron system like the hydrogen atom, there is no electron-electron repulsion.
Consequently, the energy of an atomic orbital is determined entirely by the principal quantum
number (n). Orbitals belonging to the same shell (same n) are degenerate, meaning they have
the exact same energy regardless of their azimuthal quantum number (l).
The correct energy sequence for hydrogen is 1s < 2s = 2p < 3s = 3p = 3d < 4s = 4p = 4d =
4f.
Based on this:
Statement (A) is correct (1 < 2 < 3 < 4).
Statement (B) is the correct complete representation.
Statement (C) is incorrect because it implies 2s ≠ 2p and 3s ≠ 3p, which applies only to multi-
electron atoms.
Statement (D) is incorrect as it follows the Aufbau principle for multi-electron atoms where 4s
< 3d, whereas for hydrogen, 3d < 4s because n = 3 is lower energy than n = 4.
Thus, (C) and (D) are not correct.

Final Answer: Option (3)

36) Explanation of Question: The pair of elements have same value of azimuthal
quantum number outermost e–.
Concept: This question is based on the quantum numbers.
Solution:

Final Answer: Option (3)

37) Question Explanation: Calculate the molality of pure liquid benzene.

Concept: Molality of Pure Liquids.

Solution: Molality is defined as moles of solute per kilogram of solvent.

For a pure liquid, the substance acts as both. We assume 1 liter of liquid and calculate the
mass of 1 kg of solvent relative to the moles present in that volume.
Assume: 1 L(1000 ml) of Benzene.
Mass of 1 L: .

Moles in moles.
Mass of Solvent: 1230 g = 1.23 kg.

Molality (m):

Final Answer: Option (4)

38)

39) Answer is (B) 4 mole

40) Explain Question: Find the correct match

Concept: Subatomic particle.
Solution:

No. of electrons : 92
No. of electrons in Nucleus : O
No. Of protons : 92
No. of Neutrons : 146
No. of Nucleons : (n + p)
⇒ 146 + 92 = 238
Final Answer: (B)

41) Explanation Question: Question is asking about difference in wavelength of first and last
line of Lyman series for H+.
Concept: This question is based on atomic line spectrum.

Solution: Wave length =

Wave number for a line in spectrum

Z = 2 Lyman series n1 = 1
First line n2 = 2, last line n2 = ∞

⇒
 ⇒

So,

= Final Answer: Option (1).

42) Question Explanation:

Calculate observed molecular weight of the reaction mixture.

Concept:

Observed molecular weight

Solution:
Molar mass of ammonia is 17. With α = 0.7 and n=2 (since 2 moles reactant form 4 moles
product), calculate

2NH3(g) N2(g) + 3H2(g)

1 + (2 – 1) (0.7) =
Mobs = 10

Final Answer: Option:(2)

43) Molar mass of amino acid

no. of molecules in 1 gm acid

44) MxOy
77.78 gm 22.22 gm 56x 16y

atomic wt. of metal = 56

M2O3

45) P-2, Q-1, R-4, S-3

46)
 Ans. - 3

0
47) Mn+2 = [Ar]3d54s
0
Zn+2 = [Ar]3d104s
Mn+2 = 5 unpaired electron
Zn+2 = 0 unpaired electron

48) Explain the Question : Find molarity of HNO3.

Concept : This question is based on concentration term.
Solution :
100 gm soln → 63 gm HNO3

→ 1 mole HNO3

Molarity =
Final Answer : 14

49) 2Al + O2 Al2O3

1 ml ml

= × 102 = 51 gm

50) λ = , λ ∝ m–1/2 T–1/2

MATHEMATICS

51) (logyx)3 + (logzy)3 + (logxz)3 = 3 (logyx)(logzy) (logzy)

logyx + logzy + logx2 = 0
(logyx) (logzx) + (logzy) (logzx) = –1

52)
10 – 2 = 8

53)

Question Explanation:

We have to find number of natural number 'n' for which given expression is a natural numbers.

Concept:
 This question is based on Number system.

Solution:

must be an integer
⇒ n = 1,2,3,4,6,12

Final Answer:
The correct option is (4).

54) Explain Question: Compute the total sum when the product of pairs from symmetrical
numbers is taken two at a time.
Concept: Sum of Products Taken Two at a Time and Sum of Squares of First Natural
Numbers.
Solution:

2 (required sum) = (1 – 1 + 2 – 2 + .... + n – n)2 – (12 + 12 + 22 + 22+....+n2 + n2)

Final Answer: (C)

55)

Question Explanation: Determining the count of positive integers satisfying the rational
inequality.

Concept: Solving Rational Inequalities with sign analysis.

Solution:

Here (x2 – 3x + 4) > 0, x∈R

(as D < 0, a > 0)
2
So, –(x – 3x + 4) < 0, x ∈ R
⇒

Number of positive integral solution = 1

Final Answer: option (2)

56) x =
x=

x=
x + 1 = 51/16
(x+1)48 = 53 = 125

57)

∴ only one solution.

58) (a1 + a2n) = (a2 + a2n–1) = ..... = (an + an+1) = (a + b)

g1g2n = g2g2n–1 = ..... = gngn+1 = (ab)

59) Conceptual.

60) Conceptual.

61)

x2 + px + 2 = 0
⇒ α + β = – p , αβ = 2
& 2x2 + 2qx + 1 = 0

⇒ ,

62) α,β are root of eq. ⇒ α2 – 2α – 20 = 0

⇒ α20– 2α19– 20α18 = 0
So by newton's formula;
⇒ a20 – 2a19 – 20a18 = 0

63) Let
⇒

vertex has x-coordinate

D<0

64)

Let f(x) = x2 + bx + d
f(0) = d
point C (0, d)

now B(d, 0), A

roots of f(x) = 0 are & d.

product of roots ×d=d ⇒

Roots are 1, 2

65)

x2 – 3x + 2 = (x – 2) (x – 1)
⇒ x = 2 & x = 1 are roots x4 – px2 + q
16 – 4p + q = 0
1–p+q=0
– + –
___________________
15 – 3p = 0
p=5
now q = 4

66)

G2 = A.H.

67) AM ≥ G.M.

≥ (abc)1/3
1 ≥ (abc)1/3
abc ≤ 1 a2b2c2 ≤ 1

68) 2(41) = 32 + x + 32 – x
82 = 9.3x + 9.3–x
Let 3x = t
82 = 9t + 9/t
9t2 – 82t + 9 = 0
9t2 – 81t – t + 9 = 0
9t(t – 9) – 1(t – 9) = 0
t=9 or t = 1/9

3x = 9
x = 2 or

69) Sum of all means = (7 + 49) = 364

(56) = 364
n = 13

A3 = a + 3d = 7 + 3(3) = 16
A6 = a + 6d = 7 + 6(3) = 25
GM of A3 & A6 =
=
= 20
=K

70) Tn = (3n – 2)·(3n + 1)·(3n + 4)

using vn method sum.

= [(3n – 2) (3n + 1) (3n + 4) (3n + 7) + 56]

= [(9n2 – 3n – 2) (9n2 + 33n + 28) + 56]

= [81n4 + 270n3 + 135n2 – 150n]

= [27n4 + 90n3 + 45n2 – 50n]

71) ∵ all the terms of LHS are greater than or equal to zero
∴ to hold the equation
and and |z – 3| = 0
⇒ x = 1 and y = 2 and z = 3
∴x+y+z=1+2+3=6

72)

∴ log4x = 2, x = 16

73) (3x)2 – 3x – 6 = 0
⇒ Put 3x = y
∴ y2 – y – 6 = 0
⇒ y = 3, –2
But 3x > 0
∴ 3x = 31
⇒

74)

x2 – nx + 2014 = 0

Now,
= 2 × 1007 or (–2) × (–1007)
= 19 × 106 or (–19) × (–106)
= 38 × 53 or (–38) × (–53)
Least possible value of
n=α+β
= 38 + 53
= 91

75)

Question Explanation: Finding the number of arithmetic means inserted between two given
numbers.

Concept: Arithmetic Mean (A.M.) and properties of Arithmetic Progressions (A.P.).

Solution:

A. Let the sequence be . Total terms n = m + 2.

B. The number (A7) is .

The number is .

C. Given ratio

Final Answer: 14