MOLE CONCEPT :

EXERCISE - 1
Section (A) : Units, Atoms, Molecules, Atomic mass, Molecular mass, Gram atomic
mass, Gram molecular mass, RAM, Average atomic

1. Torr is unit of :
(1) Temperature (2) Pressure (3) Volume (4) Density

2. Centigrade and Fahrenheit scales are related as :

C F  32 C F  32 C F  32
(1)  (2)  (3)  (4) None of these
5 9 9 5 8 5

3. Which the following is not equal to 10–2 atm :

(1) 0.76 cm of Hg (2) 7.6 torr (3) 0.076 dm of Hg (4) 0.0076 torr

4. Which is not a basic postulate of Dalton’s atomic theory ?

(1) Atoms are neither created nor destroyed in a chemical reaction.
(2) Different elements have different types of atoms.
(3) Atoms of an element may be different due to presence of isotopes.
(4) Each element is composed of extermely small particles called atoms.

5. The modern atomic weight scale is based on :

(1) 12C (2) 16O (3) 1H (4) 18O

6. 1 amu is equal to
1 1
(1) of C  12 (2) of O  16 (3) 1 g of H2 (4) 1.66 × 10–23 kg
12 14

7. Avogadro number is :
(1) Number of atoms in one gram of the element
(2) Number of mililitre which one mole of a gaseous substance occupies at NTP (1 atm & 0ºC)
(3) Number of molecules present in one gram molecular mass of a substance.
(4) All are correct

8. If we consider that 1/6, in place of 1/12 mass of carbon atom is taken to be the relative atomic mass
unit, the mass of one mole of a substance will :
(1) decrease twice
(2) increase two fold
(3) remain unchanged
(4) be a function of the molecular mass of the substance

Section (B) : Relation between Mole, Mass and Gaseous volume.

1. If the atomic mass of Sodium is 23, the number of moles in 46 g of sodium is :

(1) 1 (2) 2 (3) 2.3 (4) 4.6

2. Which of the following would contain 1 mole of particles?

(1) 0.5 mole of H2 (2) 2 g of H-atoms (3) 16 g of O-18 (4) 16 g of methane

3. How many atoms are there in 100 amu of He ?

(1) 25 (2) 50 (3) 75 (4) 100
4. Number of molecules of water in a drop of water weighing 0.09 g are :
(1) 3.01 × 1021 (2) 6.02 × 1021 (3) 3.01 × 1022 (4) 3.01 × 1020

5. The largest number of molecules is present in 1 g of

(1) CO2 (2) H2O (3) C2H5OH (4) N2O5.

6. The total number of g-molecules of SO2Cl2 in 13.5 g of sulphuryl chloride is

(1) 0.1 (2) 0.2 (3) 0.3 (4) 0.4

7. The number of sodium atoms in 2 moles of sodium ferrocyanide (Na4[Fe(CN)6]) is :

(1) 12 × 23 (2) 26 × 1023 (3) 34 × 1023 (4) 48 × 1023

8. Total number of atoms in 196 amu H2SO4 are :

(1) 14 NA (2) 14 (3) 7 NA (4) 7

9. The number of molecules of CO2 present in 44 g of CO2 is :

(1) 6.0  1023 (2) 3  1023 (3) 12  1023 (4) 3  1010

10. The number of mole of ammonia in 4.25 g of ammonia is :

(1) 0.425 (2) 0.25 (3) 0.236 (4) 0.2125

11. One mole of P4 molecules contain :

(1) 1 molecule (2) 4 molecules
1
(3)  6.022  1023 atoms (4) 24.088 × 1023 atoms
4

12. Number of atoms in 560 g of Fe (atomic mass 56 gmol–1) is :

(1) Twice that in 70 g N (2) Half that in 20 g H (3) Both (1) and (2) (4) None of these

13. Which has maximum number of atoms :

(1) 24 g of C (12) (2) 56 g of Fe (56) (3) 27 g of Al (27) (4) 108 g Ag (108)
12
14. The total number of protons, electrons and neutrons in 12 g of 6 C is :
(1) 1.084 × 10 25
(2) 6.022 × 10 23
(3) 6.022×10 22
(4) 18

15. 1.0 g of hydrogen contains 6×1023 atoms. The atomic weight of helium is 4. It follows that the number of
atoms in 1 g of He is :
1
(1)  6  1023 (2) 4 × 6 × 1023 (3) 6 × 1023 (4) 12 × 1023
4

16. A sample of aluminium has a mass of 54.0 g. What is the mass of the same number of magnesium
atoms? (At. wt. Al = 27, Mg = 24)
(1) 12 g (2) 24 g (3) 48 g (4) 96 g.

17. The number of atoms in 558.5 g of Fe (at wt.= 55.85) is :

(1) Twice that in 60 g carbon (2) 6.022 × 1022
(3) Half in 8 g He (4) 558.5 × 6.023 × 1023
18. The total number of electrons present in 8.0 g of methane is
(1) 4.8 × 1024 (2) 3.01 × 1024 (3) 4.8 × 1025 (4) 3.01 × 1023.

19. The weight of 1  1022 molecules of CuSO4. 5H2O is :

 (1) 41.59 g (2) 415.9 g (3) 4.159 g (4) None of these

20. How many moles of electron weigh one kilogram :

1 6.023 1
(1) 6.023 × 1023 (2) × 1031 (3) × 1054 (4) × 108
9.108 9.108 9.108  6.023

21. Under the same conditions, two gases have the same number of molecules. They must
(1) be noble gases (2) have equal volumes
(3) have a volume of 22.4 dm each
3
(4) have an equal number of atoms

22. 5.6 litre of oxygen at STP contains :

(1) 6.02 × 1023 atoms (2) 3.01 × 1023 atoms (3) 1.505 × 1023 atoms (4) 0.7525 × 1023 atoms

23. If V ml of the vapours of substance at NTP weight W g. Then molecular weight of substance is :
V W 1
(1) (W/V) × 22400 (2) × 22.4 (3) (W–V) × 22400 (4)
W V  22400

24. If 1 dm3 of a gas weights 2.5 g at STP, its gram-molecular weight is :

(1) 56 g (2) 11.2 g (3) 22.4 g (4) 224 g

25. 16 g of an ideal gas SOx occupies 5.6 L. at STP. The value of x is

(1) x = 3 (2) x = 2 (3) x = 4 (4) none of these

Section (C) : Density and Vapour density

1. Vapour density of a gas if its density is 0.178 g/L at NTP is :

(1) 0.178 (2) 2 (3) 4 (4) 0.089

2. A gas is found to have the formula (CO)x. It’s VD is 70 the value of x must be :
(1) 7 (2) 4 (3) 5 (4) 6

3. Number of electrons in 1.8 mL of H2O() is about :

(1) 6.02 × 1023 (2) 3.011 × 1023 (3) 0.6022 × 1021 (4) 60.22 × 1020

Section (D) : Percentage composition and Molecular formula

1. The percentage value of nitrogen in urea is about

(1) 46 (2) 85 (3) 18 (4) 28

2. A hydrocarbon contains 75% of carbon. Then its molecular formula is :

(1) CH4 (2) C2H4 (3) C2H6 (4) C2H2

3. The empirical formula of a compound of molecular mass 120 is CH 2O. The molecular formula of the
compound is :
(1) C2H4O2 (2) C4H8O4 (3) C3H6O3 (4) all of these

4. The number of atoms of Cr and O in a compound are 4.8 × 10 10 & 9.6  1010 respectively. Its empirical
formula is–
(1) Cr2O3 (2) CrO2 (3) Cr2O4 (4) None
5. The percentages of C, H and N in an organic compound are 40%, 13.3% and 46.7%. The empirical
formula of this compound is
(1) CH2N (2) CH4N (3) CH5N (4) C3H9N3.

6. The simplest formula of a compound containing 50% of element ‘A’ (Atomic weight = 10) and 50% of
element ‘B’ (Atomic weight = 20) is
(1) AB (2) A 2B (3) A2B2 (4) A2B3

7. Insulin constans 3.4% sulphur. The minimum mol. wt. of insulin is –

(1) 941.176 (2) 944 (3) 945.27 (4) None

Section (E) : Balanced chemical equation analysis

1. For the reaction 2P + Q  R, 8 mol of P and excess of Q will produce :

(1) 8 mol of R (2) 5 mol of R (3) 4 mol of R (4) 13 mol of R

2. If 1.5 moles of oxygen combine with Al to form Al2O3, the weight of Al used in the reaction is :
(1) 27 g (2) 40.5 g (3) 54g (4) 81 g

3. How many moles of potassium chlorate need to be heated to produce 11.2 litre oxygen at N.T.P.
1 1 1 2
(1) mol (2) mol (3) mol (4) mol
2 3 4 3

4. What volume of CO2 will be liberated at NTP if 12 g of carbon is burnt in excess of oxygen ?
(1) 11.2 L (2) 22.4 L (3) 2.24 L (4) 1.12 L

5. For the complete combustion of 4 litre ethane, how much oxygen is required ?
(1) 14 litre (2) 4 litre (3) 8 litre (4) 12 litre

6. The volume of oxygen necessary for the complete combusion of 20 litre of propane is :
(1) 40 litre (2) 60 litre (3) 80 litre (4) 100 litre

7. The equation :
3
2Al(S) + O (g) Al2O3(S) show that
2 2
3 7
(1) 2 mole of Al reacts with mole of O2 to produce mole of Al2O3
2 2
3
(2) 2g of Al reacts with g of O2 to produce one mole of Al2O3
2
3
(3) 2g mole of Al reacts with litre of O2 to produce 1 mole of Al2O3
2
3
(4) 2 mole of Al reacts with mole of O2 to produce 1 mole of Al2O3
2

8. The number of moles of oxygen obtained by the electrolytic decomposition of 90 g water is :

2H2O  2H2+O2
(1) 2.5 (2) 5 (3) 7.5 (4) 10

9. Volume of CO2 obtained at STP by the complete decompoisition of 9.85 g. BaCO 3 is –

 (At. wt. of Ba = 137)
(1) 2.24 lit (2) 1.12 lit (3) 0.84 lit (4) 0.56 lit

10. The moles of O2 required for reacting with 6.8 g of ammonia

(......NH3 + ....... O2  ...... NO + ..... H2O) is
(1) 5 (2) 2.5 (3) 1 (4) 0.5

11. At same temperature and pressure the volume of oxygen required for complete combustion of 20 ml of
ethene is
(1) 30 ml (2) 60 ml (3) 40 ml (4) 50 ml

12. The volume of gas at NTP produced by 100g of CaC2 with water
CaC2 + H2O 
 Ca(OH)2+ C2H2
(1) 70 litre (2) 35 litre (3) 17.5 litre (4) 22.4 litre

13. The weight of lime obtained by heating 200 kg of 95% pure lime stone is :
(1) 98.4 kg (2) 106.4 kg (3) 112.8 kg (4) 122.6 kg

14. 20 gm. CaCO3 on decomposition gives CO2 at STP if yield of reaction is 75% only
(1) 3.36 litre (2) 22.4 litre (3) 2.24 litre (4) None of these

Section (F) : Principle of atomic conversation

1. X g of Ag was dissolved in HNO3 and the solution was treated with excess of NaCl. When 2.87 g of
AgCl was precipeted the value of X is
(1) 1.08 g (2) 2.16 g (3) 2.70 g (4) 1.62 g

2. When 100g of ethylene polymerises entirely to polyethene, the weight of polyethene formed as per the
equation n(C2H4)  (CH2CH2)n is :
n(C2H4)  (CH2CH2)n.
(1) (n/2)g (2) 100g (3) (100/n)g (4) 100ng

3. 10 g of a sample of a mixture of CaCl2 and NaCl is treated to precipitate all the calcium as CaCO 3. This
Ca CO3 is heated to convert all the Ca to CaO and the final mass of CaO is 1.62 g . The percent by
mass of CaCl2 in the original mixture is.
(1) 32.1 % (2) 16.2 % (3) 21.8 % (4) 11.0 %

4. 500 ml of a gaseous hydrocarbon when burnt in excess of O 2 gave 2.5 litre of CO2 and 3.0 litre of water
vapours under same conditions. Molecular formula of the hydrocarbon is :
(1) C4H8 (2) C4H10 (3) C5H10 (4) C5H12

Section (G) : Limitting reagent

1. For the reaction 2P + Q  R, 8 mol of P and 5 mol of Q will produce

(1) 8 mol of R (2) 5 mol of R (3) 4 mol of R (4) 13 mol of R

2. For the reaction : A + 2B  C

5 mole of A and 8 mole of B will produce :
 (1) 5 mole of C (2) 4 mole of C (3) 8 mole of C (4) 12 mole of C

3. 4 g of hydrogen is ignited with 4 g of oxygen, the amount of water formed is ?

(1) 2.5 g (2) 0.5 g (3) 4.5 g (4) 8 g

4. Calculate the amount of H2 which is left unreacted in the given reaction :

2H2 + O2 
 2H2O
If 8 g of H2 is mixed with 16 g O2 ?
(1) 3 g (2) 6 g (3) 1 g (4) 4 g

5. If 30 ml of H2 and 20 ml of O2 react to form water, what is left at the end of the reaction?
(1) 10 ml of H2 (2) 5 ml of H2 (3) 10 ml of O2 (4) 5 ml of O2

6. How many mole of Zn(FeS2) can be made from 2 mole zinc, 3 mole iron and 5 mole sulphur.
(1) 2 mole (2) 3 mole (3) 4 mole (4) 5 mole

Section (H) : Concentration terms

1. 500 mL of a glucose solution contains 90 g of glucose. The concentration of the solution is

(1) 0.1 M (2) 1.0 M (3) 0.2 M (4) 2.0 M

2. 500 mL of a glucose solution contains 6.02 × 1022 molecules. The concentration of the solution is
(1) 0.1 M (2) 1.0 M (3) 0.2 M (4) 2.0 M

3. What volume of a 0.8 M solution contains 100 milli moles of the solute?
(1) 100 mL (2) 125 mL (3) 500 mL (4) 62.5 mL

4. Which of the following solutions are unimolar solutions ?

(1) 4.6 g of C2H5OH in 10 mL of solution (2) 110.98 g of CaCI2 in 1000 mL of solution
(3) 0.23 g of CH3OH in 100 mL of solution (4) 5.88 g of NaCI in 1000 mL of solution.

5. The amount of salt required to prepare 10 dm 3 of decimolar solution is :

(1) 0.05 mole (2) 0.02 mole (3) 0.01 mole (4) 1.00 mole

M
6. A solution of FeCl3 is its molarity for Cl– ion will be :
30
M M M M
(1) (2) (3) (4)
90 30 10 5

7. 11.1 g CaCl2 is used to prepare a 500 mL solution then molarity of Cl– in solution will be :
M
(1) 0.4 M (2) (3) 0.1 M (4) 0.2 M
30

8. 0.01 mole of a non-electrolyte is dissolved in 10 g of water. The molality of the solution is :

(1) 0.1 m (2) 0.5 m (3) 1.0 m (4) 0.18 m

9. The molality of a sulphuric acid solution is 0.2. Calculate the total weight of the solution having
1000 gm of solvent.
(1) 1000 g (2) 1098.6 g (3) 980.4 g (4) 1019.6g

10. The mole fraction of water in a solution containing 117 g sodium chloride and 900 g of water is ?
 (1) 0.0632 (2) 0.038 (3) 0.9615 (4) 1.000

11. Which of the following concentration factor is affected by change in temperature ?

(1) Molarity (2) Molality (3) Mole fraction (4) Weight fraction

Section (I) : Dilution, Mixting of solutions, Interconversion of concentration terms and

Acid base reactions

1. If 500 ml of 1 M solution of glucose is mixed with 500 ml of 3 M solution of glucose final molarity of
solution will be :
(1) 1 M (2) 0.5 M (3) 2 M (4) 1.5 M

2. 250 ml of 0.5 M KCl is diluted with water to 500 ml of solution, the number of chloride ions in the
resulting solution are
(1) 6.02 × 1023 (2) 7.5 × 1022 (3) 1 × 1024 (4) 3.76 × 1023

3. 300 ml of 3.0 M NaCl is added to 200 ml of 4.0 M BaCl 2 solution. The concentration of Cl¯ ions in the
resulting solution is
(1) 7 M (2) 1.6 M (3) 1.8 M (4) 5 M

4. The molarity of the solution containing 2.8% w/v solution of KOH is

(1) M/10 (2) M/2 (3) M/5 (4) 1 M

5. The molality of the solution containing 20% w/w solution of NaOH is :

(1) 4.5 m (2) 6.25 m (3) 0.3 m (4) 1 m

6. Mole fraction of A in H2O is 0.2. The molality of A in H2O is :

(1) 13.9 (2) 15.5 (3) 14.5 (4) 16.8

7. The molarity of 20% w/w sulphuric acid of density 1.14 g cm –3 is

(1) 2.32 (2) 2.02 (3) 2.12 (4) 2.22

8. 36.5 % w/w HCl has density equal to 1.20 g mL–1. The molarity (M) and molality (m), respectively, are
(1) 15.7, 15.7 (2) 12, 12 (3) 15.7, 12 (4) 12, 15.7

9. An aqueous solution of ethanol has density 1.025 g/mL and it is 2M. What is the molality of this solution ?
(1) 1.79 (2) 2.143 (3) 1.951 (4) None of these.

10. 3.0 litre of water are added to 2.0 litre of 5 M HCl. What is the molarity of HCl (in M) the resultant
solution ?
(1) 2 (2) 3 (3) 4 (4) 5
 ANSWER KEY
SECTION (A)
1. (2) 2. (1) 3. (4) 4. (3) 5. (1) 6. (1) 7. (3)
8. (3)
SECTION (B)
1. (2) 2. (4) 3. (1) 4. (1) 5. (2) 6. (1) 7. (4)
8. (2) 9. (1) 10. (2) 11. (4) 12. (3) 13. (1) 14. (1)
15. (1) 16. (3) 17. (1) 18. (2) 19. (3) 20. (4) 21. (2)
22. (2) 23. (1) 24. (1) 25. (2)
SECTION (C)
1. (2) 2. (3) 3. (1)
SECTION (D)
1. (1) 2. (1) 3. (2) 4. (2) 5. (2) 6. (2) 7. (1)
SECTION (E)
1. (3) 2. (3) 3. (2) 4. (2) 5. (1) 6. (4) 7. (4)
8. (1) 9. (2) 10. (4) 11. (2) 12. (2) 13. (2) 14. (1)
SECTION (F)
1. (2) 2. (2) 3. (1) 4. (4)
SECTION (G)
1. (3) 2. (2) 3. (3) 4. (2) 5. (4) 6. (1)
SECTION (H)
1. (2) 2. (3) 3. (2) 4. (2) 5. (4) 6. (3) 7. (1)
8. (3) 9. (4) 10. (3) 11. (1)
SECTION (I)
1. (3) 2. (2) 3. (4) 4. (2) 5. (2) 6. (1) 7. (1)
8. (4) 9. (2) 10. (1)

SACHIN KHURANA SIR