Chapter 2
Chapter 2
2.1 Introduction
A good engineering project is generally a trade-off between a robust and effective design
and the cost of the final product. This involves the solution of a complex optimisation
problem, where the objective function is twofold: minimise the cost and maximise the
efficiency; the constraints are the equations that describe the physical behaviour of the
system; and inequalities, often binding, are technical and security limits.
CI-ESSs are, of course, no exception to this general procedure. In 2013, Stephen
Berberich of the California ISO, referring to the difficulties in building out grid-scale
energy storage, said: ‘It’s good stuff, but it’s expensive, and we have to find business
cases.’1 In the last 5 years the situation has substantially evolved and the number of
grid-scale projects has grown to a level at which it is safe to say that CI-ESSs are not just
an emerging trend but a solid market for the next decade(s). The illustrative examples
presented at the end of Chapter 3 strongly support this statement.
ESSs have an additional feature with respect to standard engineering projects and
products. There is, in fact, a sort of social acceptance of such systems, which goes be-
yond the mere economic benefit. This is so probably because energy storage is typically
coupled to eco-friendly renewable sources; or because trendy companies such as Tesla
are betting on this technology at many levels, such as electric vehicles (EVs), smart
houses and, lately, power electric systems. It is also true that any technology is expen-
sive when it is in its early stage and CI-ESSs are, de facto, still in their infancy. It is
unfair to judge energy storage technologies based on their current production costs. Our
attitude, as will be clear in the remainder of this chapter, is thus to assign a very small
weight, if any at all, to the part of the aforementioned ‘objective function’ that weights
cost minimisation.
This chapter focuses on technical and economic aspects related to ESSs. Section
2.2 discusses the technical applications of ESSs when included in transmission and/or
distribution networks and indicates the time scales of each application. The emphasis
is on the applications for dynamic analysis considered in Part III. Section 2.3 outlines
economic aspects of conventional and new energy storage technologies. This is the only
section of the book dedicated to economics. A motivation for this choice is also given
in this section.
Technical features, much more than cost and other economic considerations, allow a
proper classification of storage devices. With adequate incentives or long term invest-
ments, it is always possible to make a new technology worthwhile, but technical con-
straints are based on physics and, hence, not subject to the mood of the market. This
section explores in particular the main properties and specifications that quantitatively
characterise any storage technology (Section 2.2.1) and the services that the power grid
expects from energy storage (Section 2.2.2). In Section 2.2.2, the services for which
CI-ESSs are particularly suited are also highlighted.
[Link] Capacity
Capacity is defined as the amount of energy available in the storage device when fully
charged. The energy retrieved when discharging the device is lower than the energy
stored in the device due to incomplete discharge and inevitable losses. It is thus con-
venient to distinguish between capacity, intended as the total energy required to fully
charge the storage device, Ech , and operational energy that can be utilised in practice,
Eop . The following relationship holds:
Ech ≥ Eop . (2.1)
These two quantities are energies and thus, in SI units, should be expressed in Joules.
However, it is more common to measure the capacity in Wh or multiples of it, e.g. kWh
and MWh. For batteries, it is also common to express the capacity in Amperes per hour
(Ah), i.e. in terms of the amount of storable electric charge. Eop is constrained by the
depth of discharge (see Section [Link]).
The ratio of Eop to Ech is not constant as Eop depends on the operation of the storage
device. A fast dynamic process (e.g. quick charge/discharge), can lower the efficiency of
some technologies (e.g. because of heating), thus leading to considerably decreased Eop .
In steady state, Eop decreases if the self-discharge is not null. Note also that, for some
technologies, Ech can change over time due to ageing or other factors. For example, the
capacity of a reservoir can decrease due to the accumulation of sediments.
where E is the amount of available energy stored in the device at a given time. For
batteries and electrochemical storage, it is more common to use the notation State of
Charge (SoC), which is effectively the potential energy of a battery.
The complement of the SoE (or SoC) is the Depth of Discharge (DoD), namely:
Eop − E
DoD = 1 − SoE = . (2.3)
Eop
For some technologies, the measure of the SoE or SoC is straightforward, e.g. for
flywheels, one just needs to know the inertia constant and the measure of the angular
speeds (see also Section 3.2.2). For other technologies, the determination of the SoE can
be involved and, as a consequence, not accurate. For batteries, for example, commonly
utilised methods are the voltage method (based on the discharge curve); the chemical
method (only for liquid electrolytes); and the
R current integration method, i.e. the indirect
measure of the electric charge as qe (t) = t i(r) dr. Kalman filtering is also utilised but
requires a precise model and, hence, precise parameters of the battery.
±2%
100
pn [%(MW)] T resp
T meas
T cont
T ramp
0
to Time [s]
PHES
Days
Flow battery
C-CAES
Discharge time
Hours
NaS
MSTES
Ultrabattery CAES
LAES
Lithium ion
Minutes
FES
Lead acid
NiCd
NiMH
Seconds
SMES
ECES
10 kW 100 kW 1 MW 10 MW 100 MW 1 GW
Power rate
Figure 2.2 Power rate vs discharge time of a variety of energy storage technologies. The meaning
of the acronyms is given in the notation section in the preamble of the book as well as in Chapter 3.
[Link] Efficiency
The round-trip efficiency or, simply, efficiency, is defined as the ratio of the operational
usable energy to the stored energy when the storage device is fully charged:
Eop
η= . (2.5)
Emax
The efficiency is a key parameter of any storage technology as it heavily impacts on
its economic viability. The calculation of the efficiency is often not straightforward
36 Technical and Economic Aspects
because Eop is a function, as discussed above, of the operating conditions, duty cy-
cle and dynamic response of the storage device. In the long term, self-discharge and
ageing also modify the efficiency. All these factors suggest that the efficiency is a time-
dependent quantity that should be defined per cycle and that there is a discharge time
and a charge/discharge power that maximise the efficiency [119]. The calculation of
such an optimum is a relevant aspect that should be taken into account in the economic
appraisal of storage devices for grid applications.
Let us consider a simple example. The energy needed to pump a water volume V to a
height h is:
ρghV
Epump = , (2.6)
ηpump
where ρ is the density of the water, g is the gravitation acceleration and ηpump is the
efficiency of the pump. On the other hand, the energy obtained from the water stored in
the reservoir through the turbine is:
Eturb = ρ g h V ηturb , (2.7)
where ηturb is the efficiency of the energy generation. Assuming no leakages, the round-
trip efficiency of the energy storage system is thus:
Eturb
η= = ηturb ηpump . (2.8)
Epump
For pumped hydroelectric energy storage, η falls in the range from 70 to 85%. Indeed, a
similar expression can be obtained for all storage technologies, i.e. the overall efficiency
is given by the product of the efficiencies of the charging and discharging processes,
namely:
η = ηch ηdis . (2.9)
In some cases, e.g. batteries and supercapacitors, energy leakage (i.e. self-discharge)
is not negligible and Equation (2.9) must take into account the time during which the
energy is stored and the self-discharge energy. Table 2.4 later on in this chapter provides
data on the efficiency of most relevant storage technologies.
[Link] Autonomy
Autonomy is defined as the maximum period of time during which a storage device can
continuously release energy, as follows:
Eop
Ta = , (2.10)
pdis
where pdis is the average power during the discharge. The autonomy is conceptually
very similar to the discharge time, and differs from it because pdis , pn , in general.
Autonomy is particular relevant for applications where the storage device has to operate
disconnected from the grid, such as EVs, and when coupled with intermittent energy re-
sources. Particularly relevant for grid applications is the combination of thermal storage
with solar power plants (see the real-world examples described in Section 3.7).
is quantified as the State of Health (SoH) of the ESS, especially referred to batteries.
SoH does not generally refer to a specific physical quantity. It is determined heuristically
(and often treated as a trade secret) based on a combination of several parameters such
as internal resistance, self-discharge, and the number of completed cycles.
[Link] Self-discharge
Self-discharge is the quota of energy that is dissipated after charging an ESS during the
time the system is not utilised. Depending on the technology, the self-discharge can be
negligible or even null, e.g. an energy system based on potential energy (see for example
the solid-masses ESS described in Section 3.7), or substantial, such as electrochemical
capacitors with non-negligible internal resistance.
[Link] Ageing
Ageing is the deterioration of the performance and efficiency due to time. This affects
all systems (both mechanical and organic) and energy storage devices are no excep-
tion. Mechanical energy storage ages mainly due to fatigue and wear, chemical storage
because of oxidation and electromagnetic storage because of the deterioration of the
insulation, e.g. thermal degradation of the polymers or partial discharges.
In any case, ageing is related to the cycling capacity, the average SoE and the energy
per cycle. Since it is based on statistical evaluations, the lifetime of a device can be
defined only approximately.
plants. Others, in particular RoCoF control, off-grid utilisation and integration of inter-
mittent resources, are recent developments and mostly based on CI-ESS. The latter is
also a crucial aspect of the microgrid and smart house concepts (see Section 4.5.2).
Typical energy storage applications are shown in Table 2.1, which is mainly based on
data collected by the International Energy Agency [130]. Figure 2.3 shows the typical
time scales and capacities of the grid applications for different energy storage technolo-
gies.
Table 2.1 Relevant parameters of power system applications of energy storage systems
(Source: International Energy Agency).
Capacity Discharge
Application Cycles T resp
(MW) duration
Months
Seasonal
storage
Days
Offgrid
Black start
T&D relief & deferral Spinning
and
non-spinning
Variable supply reserve
resource
Minutes
integration
Primary frequency control Secondary
frequency control
Seconds
10 kW 100 kW 1 MW 10 MW 100 MW 1 GW
Capacity
Figure 2.3 Power requirement versus discharge duration for power system applications.
[Link] Arbitrage
Arbitrage refers to the energy trade among energy markets and consists in acquiring
and storing energy in periods of low price (overnight and weekends) and then selling
the energy in periods when the energy has a high price (daytime of weekdays). An ex-
ample of systematic arbitrage is the utilisation of pumped hydroelectric storage in Italy,
which stores the cheap energy produced in France by nuclear power plants overnight
and resells the energy to France at peak hours. The time scales involved in arbitrage
are days and weeks, and the technologies are the same as those discussed for seasonal
storage above.
hydroelectric and conventional compressed air ESSs, but also with large battery banks
and converter-interfaced compressed and liquid air ESSs.
and it thus typically requires hybrid solutions that mix together ESSs with fast response
time (e.g. electrochemical capacitor, superconducting magnetic and flywheel ESSs) and
others with longer response time (e.g. battery ESS).
ESSs are generally costly. Except for pumping hydroelectric power plants, which have
been exploited since the 1930s (see Figure 3.2) and very peculiar and rather unique stor-
age solutions (see Section [Link]), energy storage has never really been economically
viable. It is also undeniable that energy storage is the solution to most power system
problems as thoroughly discussed in the motivations and technical challenges earlier in
this chapter. As a matter of fact, if a consistent amount of fast-controlled large-capacity
ESSs were installed in a power system, most stability and operational problems would
be finally solved.
It is a matter of research and investment to find economically viable energy storage
systems.2 Actually, in hindsight, it is strange that the research on cheap storage sys-
tems has not begun earlier. The reason is, likely, the profound conservatism of system
operators, which has had to drastically change in recent years due to deregulation first,
and then to the strong social and political pressure for the reduction of pollution. As
discussed in Section 2.2, without the trigger of the high penetration of renewable re-
sources, and if such resources were not mostly stochastic, the time for energy storage
would have very likely waited a long while.
On the other hand, in many, even non-technical news media, energy storage – batter-
ies, in particular – is seen as the holy grail of power systems and the key for moving
towards the long sought goal of fully clean energy.3 The cost to store a kWh of electric
energy is key. If this cost is low enough to make it more convenient to install storage
devices than additional generators to cope with the instantaneous power balance, then
the operation of the power system will change forever (for the technicalities, the reader
can refer to Section 2.2). It is also worth noticing at this point that the drastic reduction
in battery costs and increase in performance are expected to continue in the near future,
at least for batteries based on lithium ion, sulphur and vanadium [133]. This will be
achieved by increasing the energy density of the batteries.
So, given that the cost of a kWh is the deal-breaker at this time for a massive pen-
etration of converter-interfaced energy storage devices, the remainder of this section
provides some figures to illustrate the trend of the most important technologies and the
projections (inevitably tentative) for the next decade.
At this time, a 100 $/kWh is assumed to be the threshold below which batteries will be
more competitive than internal combustion engines and, thus, the entire industry of EVs
would be revolutionised. In 2013, Tony Seba, entrepreneur and solar power expert from
Stanford University, stated: The tipping point for the mass market to move from internal
combustion engines to EVs is between 250 and 300 $/kWh. Once it gets to 100 $/kWh,
it is all over. I think we will get to 250 $/kWh by 2020. By 2030, when batteries are
2 In 2016, the US Energy Department was funding 75 projects focusing on the development of energy
storage devices, including research groups from MIT, Harvard, Stanford, and Lawrence Livermore and
Oak Ridge National Laboratories. (Source: The Telegraph, 10 August 2016).
3 The New York Times was among the first to utilise the expression ‘holy grail’ referred to energy storage, in
an article of 6 November 2010, available at: [Link]/2010/11/07/us/[Link].
44 Technical and Economic Aspects
at 100 $/kWh, gasoline vehicles will be obsolete. Not on their way out, obsolete.4 This
statement also assumes that the price per kWh of combustion engines is not expected to
decrease in the future.
The threshold value for power electric systems is not a straightforward quantity to
be computed, as technologies are very diverse, and cost is not always the primary pa-
rameter to be taken into account. For example, one of the cheapest, most reliable and,
in many aspects, cleanest way to produce electricity is through nuclear fission but, in
most developed countries, especially Western culture ones, this technology is not an
option anymore.5 In any case, while a threshold value is not attempted to be defined in
this book, it is a fact that the installation of grid-connected energy storage devices other
than PHES ones has more than quadrupled in the last decade (see Figure 3.3), which is a
clear sign that there is a strong interest in energy storage for power system applications.
A widely accepted quantity to estimate and compare diverse technologies related to
energy generation is the Levelised Cost of Electricity (LCoE), or Levelised Energy Cost
(LEC), which is a measure of lifetime costs divided by energy production. The LCoE is
utilised as an approximated estimation of the average price that a given technology has
to obtain in a market to break even over its lifetime. Lifetime costs typically include the
total investment, operations and maintenance, fuel, decommissioning and treatment of
waste.
Since the LCoE is a cost normalised with respect to the unit of energy produced
by the power plant, it allows comparing diverse technologies (e.g. wind, natural gas,
battery) of diverse life spans, size, capital cost, risk, return and capacities. The LCoE is
calculated over the design lifetime of a plant, which is usually 20 to 40 years, and given
in the units of currency per kWh or multiples of it.6
A simple expression for the LCoE is the following [131]:
PT
(it + mt + ft + wt ) · Et · (1 + %)−t
LCoE = t=1 PT , (2.13)
t=1 E t · (1 + %)
−t
where:
The quantity (1 + %)t is the discount factor or time-value for money in year t.
Several variants of (2.13) have been proposed. In [45], the formula also includes the
4 See full article at: [Link]
5 A noteworthy, well-known exception is UK, where EDF is currently building a new nuclear power station
at Hinkley Point C in Somerset.
6 An interactive web-based LCoE calculator is available at: [Link]/analysis/[Link]
2.3 Economic Aspects 45
depreciation schedule rt and the salvage value st of any physical assets at the end of
life-cycle:
PT
(it + mt + ft + wt − rt ) · Et · (1 + %)−t − st · Et · (1 + %)−T
LCoE = t=1 PT . (2.14)
t=1 E t · (1 + %)
−t
The calculation of the LCoE is illustrated with a simple numerical example. Consider
a nuclear power plant with net capacity Pnet = 1, 400 MW, and assume the following
values based on [131]:
%= 3% ;
T= 60 years ;
it = 30.75 $/MWh ;
mt = 11.0 $/MWh ;
ft = 11.33 $/MWh ;
wt = 1.26 $/MWh ;
rt = St = 0 .
The electrical energy generated in a year is the average hourly power production, ph ,
multiplied by the number of hours in a year:
Et = ph · 8,760 . (2.15)
Since nuclear power plants are operated in such a way that the production is as con-
stant and as close as possible to the rated power of the plant, it can be assumed that
ph ≈ pnet , hence:
Et ≈ pnet · 8,760 ≈ const., ∀t = 1, . . . , n . (2.16)
Then, since all costs are constant, (2.13) simply becomes:
LCoE = it + mt + ft + wt , (2.17)
and, substituting the values of the example:
LCoE = 30.75 + 11.0 + 11.33 + 1.26 = 54.34 $/MWh .
Calculations given in [131] are based on (2.17) rather than on (2.13) or (2.14). The
costs and the power production, in fact, are assumed constant for all technologies and
are thus independent of the net capacity of the technology and of the discount rate %.
In [131], the LCoE varies as % varies because it and mt are different for different %.
The calculation of lifetime costs might be biased by several external and often non-
technical factors, e.g. taxes or subsidies, and other, more sophisticated versions of (2.13)
have been proposed. Some of them are specific for ESSs, e.g. [224], which includes the
relations between storage and PV generation. The financial advisory and asset man-
agement firm Lazard conducts an annual evaluation of the Levelised Cost of Storage
(LCoS) which includes most operational parameters of battery storage systems.7 More-
over, the numerical example above shows that, even assuming that the LCoE formula
7 The studies are available at: [Link].
46 Technical and Economic Aspects
is accurate, it is quite difficult to have a precise estimation of the costs through the life-
time of the power plant. Very often the LCoE is thus calculated only based on present
information and extrapolating it to the next decades.
The standard definition of LCoE does not take into account operational aspects either.
Among these, we cite dynamic response, i.e. the ability to follow fast varying demand or
to match the demand at all. This is a major aspect of all stochastic renewable generation,
which may lead to a need for extra generation backup. In [289], the authors conclude
that replacing nuclear power with wind-based generation would lead, at least in Sweden,
to double costs and emissions. The intermittency and volatility of wind and solar power
have a significant associated ‘cost’, which should not be neglected when evaluating the
actual LCoE.
Other authors believe that the intermittency can be smoothed (statistically) if a suf-
ficiently large and geographically extended network is considered (see for example,
Chapter 2 of [2]). This argument, however, is not convincing. In a small system, where
distances are short, it is unlikely that weather conditions are so uniformly distributed
that the average wind and/or solar power production is constant. In Ireland, for exam-
ple, the volatility of wind power generation is quite high even in a short time, and it is
not uncommon to have days during which the wind power production is null. On the
other hand, for large systems, the statistical argument given in [2] does not take into
account the location of the generation. For example, considering the European inter-
connected system, ENTSO-E, it is not the same to have all power generated by solar
power plants, say, in Spain, while the rest of continental Europe is under the clouds, as
compared with the same amount of generation being evenly distributed everywhere in
the system. Statistical considerations have still to satisfy the Kirchhoff laws of the elec-
tric network and stability constraints. In any case, whatever one’s belief, cost effective
and fast responding ESSs are to be sought.
There is another and deeper reason that justifies why the LCoE should be utilised with
caution. As any quantity that mixes a cost or a price with an actual physical quantity –
in this case, energy – the LCoE embeds an intrinsic arbitrariness. The costs that appear
in (2.13) are, in fact, decided based on criteria that do not follow physical principles or
technical constraints but, rather, political and social situations. As such, the LCoE does
not have an absolute significance. Only indexes that are exclusively based on physical
quantities, e.g. the efficiency, can provide valuable and consistent information. If the
price of an object, in fact, were defined as the amount of energy required to make it
and were measured in joules, there would be no market speculation or uncertainty. It is
the ‘human’ – artistic, sentimental, speculative, etc. – value attributed to an object that
makes prices and, hence, market dynamics largely unpredictable.
The LCoE ability to indicate the relative significance of different technologies is
doubtful, as political and social beliefs tend to change in time, and do not always follow
a rational economic criterion.8 The huge international effort to reduce CO2 emissions
and pollution is a good example of that and, ultimately, the reason why energy storage
devices have suddenly become so relevant in the last decade, despite their high costs.
8 The tulip mania that occurred in the Netherlands in the seventeenth century should always be kept in mind.
2.3 Economic Aspects 47
With the caveats above in mind, Table 2.2 shows the expected LCoEs of most relevant
generation types for power plants commissioned in 2020, as published by the Interna-
tional Energy Agency (IEA) and Nuclear Energy Agency (NEA) in 2015 [131]. The
LCoEs included in the table consider 19 OECD (namely, Organisation for Economic
Co-operation and Development) and three non-OECD countries.
The estimation of cost depends on many factors which can be weighted differently
by different agencies. Table 2.3, shows the estimated LCoEs for new generation re-
sources commissioned in 2022 as published by the US Energy Information Administra-
tion (EIA) in 2017 [279]. The values in the table only refer to the United States. Note,
for example, the different figures for nuclear power in Tables 2.2 and 2.3.
The figures for conventional and renewable generation types serve as a comparison
base for better understanding the cost of energy storage technologies. Table 2.4 shows
typical ranges of the power rate (pn ), efficiency (η), lifetime (T ) and LCoE of most
common energy storage technologies in 2017 as provided online by Enipedia.9
Table 2.2 Expected LCoE ranges in $/MWh of commissioning most relevant generation tech-
nologies in 2020 at 3% discount rate (Source: IEA and NEA).
Low High
Technology
($/MWh) ($/MWh)
Natural gas-fired CCGT 61 133
Coal 66 95
Nuclear 29 64
PV solar – residential 96 218
PV solar – commercial 69 142
PV solar – large, ground-mounted 54 181
Onshore wind 33 135
Offshore wind 98 214
Table 2.3 Expected LCoE ranges in $/MWh of commissioning most relevant generation tech-
nologies in 2022 (Source: EIA).
Table 2.4 Power rate, efficiency, lifetime and LCoE of most common energy storage tech-
nologies in 2017 (Source: Enipedia, TU Delft).
pn η T LCoE
Technology
(MW) (%) (years) ($/kWh)