19-07-2026

1001CJA101021260019 JA

PART-1 : MATHEMATICS

SECTION-I (i)

1) The value of the definite integral equals :

(A)

(B)

(C)

(D)

2) =

(A)

(B)

(C)

(D)

3) The equation of a curve passing through (1, 0) for which the product of the abscissa of a point P
and the intercept made by a normal at P on the x-axis equals twice the square of the radius vector of
the point P, is

(A) x2 + y2 = x4
(B) x2 + y2 = 2x4
(C) x2 – y2 = 4x4
(D) x2 – y2 = x4

4) The line y = mx bisects the area enclosed by the lines x = 0, y = 0, x = and the curve y = 1 + 4x
– x2. Find m.

(A)

(B)
(C)

(D)

SECTION-I (ii)

1) Let f(x) = for all x ∈ (0, ∞), then :

(A) f has a local maximum at x = 4 and a local minimum at x = 3

(B) f is decreasing on (3, 4) ∪ (5, ∞) and increasing on (0, 3) ∪ (4, 5)
(C) There exist atleast two c1, c2 ∈ (0, ∞) such that f ″ (c1) = 0 and f ″ (c2) = 0
(D) There exists some c ∈ (0, ∞) such that f ′″ (c) = 0

2) Let f(x) be a differentiable function satisfying = 2x4 – 2x3, for all x ∈ R

then which of the following is/are correct ?

Minimum value of f(x) is equal to

(A)

(B) f(|x|) is non-derivable at exactly one value of x

(C) Area bounded by y = f(x) and x-axis is equal to 2

(D)
exist and is equal to 3

3) A function y = f(x) satisfying the differential equation .sinx – ycosx + = 0 is such that, y →
0 as x → ∞, then the correct statement(s) is(are) :

(A)

(B)
is less than

(C)
is greater than unity
(D) f(x) is an odd function

4) The area bounded by a curve, the axis of co-ordinates and the ordinate of some point of the curve
is equal to the length of the corresponding arc of the curve. If the curve passes through the point
P(0, 1) then the equation of this curve can be
(A)

(B)

(C) y = 1

(D)

SECTION-I (iii)

1) The functions in List-I satisfies the differential equations in List-II.

List-I List-II
3
(P) y = x tan (x + 2) (1) xdx = 2(y – y ) dy

(Q) (2) y′ + 2xy = 2x3y3

y= tan (log 2x)

(R) (3) (x2 + y2 + y)dx = xdy

(S) x2 = y2(2 – y2) (4) (1 – xy + x2y2)dx = x2dy

(5) (x + y)dy = dx
(A) P → 3;Q → 4;R → 2;S → 1
(B) P → 1;Q → 2;R → 3;S → 4
(C) P → 2;Q → 3;R → 1;S → 4
(D) P → 3;Q → 5;R → 1;S → 2

2)

List-I List-II

The equation of tangent to the

(P) ellipse which cuts off equal intercepts on axes is x – y = (1)
a where |a| equal to

The normal y = mx – 2am – am2 to the parabola y2 = 4ax

(Q) (2)
subtends a right angle at the vertex if |m| equal to

The equation of the common tangent to parabola y2 =

(R) (3)
2
4x and x = 4y is x + y + = 0, then k is equal to

An equation of common tangent to parabola y2 = 8x and

(S) (4)
the hyperbola 3x2 – y2 = 3 is 4x – 2y + = 0, then k is
equal to

(5) 2
(A) P → 1;Q → 1;R → 4;S → 2
(B) P → 4;Q → 1;R → 2;S → 3
(C) P → 1;Q → 2;R → 3;S → 5
(D) P → 4;Q → 3;R → 1;S → 3

3) Match the following statement in List-I with the values in List-II

List-I List-II

Let f : R → R be a differentiable function

(P) (1) 6
which satisfies f(x) = .
If (α, β) is a point of inflection of f(x),
then α + β can be

If g(x) is inverse function of f(x) and domain

of f(x) is [2, 8] where f(2) = 5 and f(8) = 2,
(Q) (2) 4

then the value of is

f(x) = |9 – x2| – |x – a|, then for a = 8

(R) (3) 0
number of distinct real roots of f(x) = 0 is

f(x) = |9 – x2| – |x – a|, then for a = 3

(S) (4) 3
number of distinct real roots of f(x) = 0 is

(5) 5
(A) P → 4;Q → 2;R → 1;S → 3
(B) P → 3;Q → 1;R → 2;S → 4
(C) P → 1;Q → 2;R → 5;S → 4
(D) P → 1;Q → 3;R → 2;S → 5

4) Let the foci of the hyperbola be the vertices of the ellipse and the foci of
the ellipse be the vertices of the hyperbola. Let the eccentricities of the ellipse and hyperbola be e1
and e2 respectively.

List-I List-II

(P) (1) 1

(Q) e1 + e2 can not be equal to (2) 2

If the angle between the asymptotes of the hyperbola

(R) (3) 3
is , then 2e1 ≤
 If e1 = and (x, y) is point of intersection of ellipse
(S) (4) 4

and hyperbola, then =

(5) 5
(A) P → 2;Q → 3;R → 1;S → 5
(B) P → 1;Q → 3,4;R → 1;S → 5
(C) P → 3;Q → 4;R → 2;S → 1
(D) P → 1;Q → 1,2;R → 1,2,3,4,5;S → 4

SECTION-II

1) Let y = f(x) be a real-valued differentiable function on R (the set of all real numbers) such that f(1)
= 1. If f(x) satisfies x f ′ (x) = x2 + f(x) – 2 then find the area enclosed by f(x) with x-axis between
coordinates x = 0 and x = 3.

2) Let A = [aij], aij ∈ Z ∩ [0, 4], 1 ≤ i, j ≤ 2. The number of matrices A such that the sum of all entries
is a prime number p ∈ (2, 13) is (where Z denotes integers)

3) Suppose a matrix A satisfies A2 – 5A + 7I = 0. If A8 = aA + bI, then a/253 is equal to

4) If the solution of satisfies y(0) = 1, then the value of is

PART-2 : PHYSICS

SECTION-I (i)

1) A rod of mass m and length L is hinged at its one end and carries a block of same mass m at its
lower end. Two springs of same force constant k are installed at distances a = L/2 and b = L/4
respectively as shown in the figure. If the whole arrangement lies in the vertical plane, the

frequency of small vibration is :

(A)
(B)

(C)

(D)

2) The circuit shown in the diagram extends to the right into infinity. Each battery has the
electromotive force V (unknown) and the internal resistance r (known). Each resistor has the
resistance 4r. The reading of the ideal ammeter shown in the diagram is I. Find the value of V in

terms of I and r.

(A)

(B)

(C) V = 4.5 Ir
(D) V = 3.0 Ir

3) In the figure shown below, the maximum and minimum possible unknown resistance (X), that can
be measured by the post office box are Xmax and Xmin respectively. Then the ratio of these two
resistances is : (In this experiment, we take out only one plug in arm AB and only one plug in arm

BC, but in arm AD we can take any no. of plugs):

(A) 3 × 105
(B) 5 × 105
(C) 7 × 105
(D) 9 × 105

4) A wire abc is carrying current i. It is bent as shown in fig and is placed in a uniform magnetic field
of magnetic induction . Length ab = ℓ and ∠abc = 45°. The ratio of force on ab and on bc is
(A)

(B)
(C) 1

(D)

SECTION-I (ii)

1) To measure capacitance of a parallel plate capacitor it is first charged to a potential V0 =1350 V.

It is then connected in parallel to an uncharged capacitor of identical geometry but filled with
dielectric of dielectric constant k. As a result the voltage of 1st capacitor become 450 volt and charge
on 2nd capacitor become 18 mC. Choose the correct option(s).

(A) Initial charge on 1st capacitor is 27 mC

(B) Dielectric constant k = 2
(C) Charge on 1st capacitor after connection is 18 mC
(D) Heat loss is zero in this process.

2) In the adjacent circuit diagram, initially switch S is opened and the circuit is in steady state. At
time t = 0, the switch S is closed and the new steady state is reached. Choose the correct options (s).

(A) Current in the inductor when the circuit reaches the new steady state is 4A.
(B) The net change in the magnetic flux in the inductor is 1.5 Wb
The potential difference across the inductor is 9 volt when the circuit reaches the new steady
(C)
state
(D) The charge stored in the capacitor in the new steady state is 1.2 mC

0
3) Two moles of O2 at temperature T and three moles of CO2 at temperature 2T
are allowed to mix together in a rigid closed adiabatic vessel. The resulting mixture finally comes in
thermal equilibrium. Then,
(A)
final temperature of the mixture is

(B)
final temperature of the mixture is

(C)
adiabatic exponent of the mixture formed is

(D)
adiabatic exponent of the mixture formed is

4) An insulating cylinder contains equal volumes of He and O2 separated by a massless freely moving
adiabatic piston as shown. The gas is compressed slowly by moving the insulating piston so that

volume of He becomes half. Select the correct alternative(s).

(A) Pressure in He chamber will be equal to pressure in O2 chamber

(B) Pressure in He chamber will be less then pressure in O2 chamber
(C) Volume of He chamber will be equal to volume of O2 chamber

(D)
Volume of O2 chamber will be .

SECTION-I (iii)

1) List–I gives certain situations in which capacitance of a capacitor is changed by different means.
List–II gives resulting effect under different conditions. In which of the following case statements in
list–I are INCORRECTLY matched to corresponding statements in list–II.

List–I List–II

The plates of a plane parallel

capacitor are slowly pulled apart. Increases if the capacitor is
(P) (1)
Then the magnitude of electric maintained at constant charge.
field intensity inside the capacitor.

The plates of a plane parallel plate

capacitor are slowly pulled apart. Decreases if the capacitor is
(Q) (2)
Then the potential energy stored maintained at constant charge
in the capacitor.

The capacitance of an air filled Increases if the capacitor is

(R) plane parallel plate capacitor on (3) maintained at constant potential
insertion of dielectric. difference.

A dielectric slab is inserted inside

Decreases if the capacitor is
an air filled plane parallel plate
(S) (4) maintained at constant potential
capacitor. The potential energy
difference.
stored in the capacitor.
 Remain same if the capacitor is
(5)
maintained at constant charge
(A) P → 1;Q → 3;R → 2;S → 4
(B) P → 1;Q → 5;R → 1;S → 4
(C) P → 4;Q → 5;R → 1;S → 2
(D) P → 4;Q → 5;R → 1;S → 4

2) List–I shows the cylindrical region of radius r where a downward magnetic field exists, and is

increasing at the rate of . A conducting rod PQ is placed in different situation as shown. Match
the list–I with the correct statement in List–II regarding the induced e.m.f. in rod.

List-I List-II

Induced e.m.f. in rod PQ is

(P) (1)

Induced e.m.f. in rod PQ is less

(Q) (2)
than

End P is positive with respect to

(R) (3)
point Q

End Q is positive with respect to

(S) (4)
point P

(5) End P and Q are at same potential

(A) P → 3,4;Q → 5;R → 1,5;S → 1,4
(B) P → 2,3;Q → 4;R → 1,5;S → 2,5
(C) P → 2,4;Q → 1,3;R → 1,4;S → 2,3
(D) P → 2,3;Q → 1,4;R → 1,3;S → 2,4
3) Answer the following by appropriately matching the lists based on the information given
in the list.
An ideal monatomic gas undergoes a process as shown in figure. ΔU, Q and W represents the
change in internal energy, amount of heat exchange and work done by gas respectively for the gas

either for single process or for complete cycle. .

List-I List-II
(P) In process AB (1) ΔU > 0, W > 0, Q > 0
(Q) In process DA (2) ΔU > 0, W = 0, Q > 0
(R) In cyclic process ABCDA (3) ΔU < 0, W < 0, Q < 0
(S) In process CD (4) ΔU = 0, W > 0, Q > 0
(5) ΔU = 0, W < 0, Q < 0

Correctly match among the following is :

(A) P → 1;Q → 4;R → 1;S → 2
(B) P → 1;Q → 4;R → 5;S → 3
(C) P → 1;Q → 3;R → 1;S → 4
(D) P → 3;Q → 1;R → 4;S → 1

4) List-I contains four distinct thermodynamic scenarios. List-II contains five calculated values.
Match the scenario in List-I with the single correct numerical or algebraic result in List-II.

List-II
List-I
(Calculated
(Thermodynamic Scenario)
Result)

An irreversible heat engine (efficiency η = 0.8 ×

ηCarnot) operates between 600 K and 300 K. It
absorbs 1000 J of heat. The work output W from
this engine is used to drive a reversible (Carnot)
(P) (1) Rℓn2
refrigerator operating between 250 K and 300
K. Calculate the total heat Qdumped (in J) rejected
into the 300 K reservoir by both the engine and
the refrigerator.

Two identical blocks (mass m, specific heat C)

are at initial temperatures T1 = 300 K and T2 =
500 K. They are brought into thermal contact in
(Q) an isolated system and reach a final common (2) 3000 J
temperature. Calculate the total change in
entropy ΔSuniv for this irreversible process. (Let
k = mC).
 A Carnot heat pump maintains a room at 27°C
(300 K) when the outside temperature is –3°C
(270 K). The heat loss from the room to the
(R) (3)
outside is 20 kW. Calculate the minimum
electrical power Pin (in kW) required to operate
the pump.

One mole of an ideal gas undergoes an

irreversible free adiabatic expansion into a
(S) vacuum, doubling its volume (Vf = 2Vi). (4) 2.0 kW
Calculate the total change in universal entropy
ΔSuniv for this process.

(5) 0
(A) P → 2;Q → 3;R → 4;S → 1
(B) P → 2;Q → 4;R → 1;S → 4
(C) P → 3;Q → 2;R → 4;S → 1
(D) P → 2;Q → 4;R → 1;S → 3

SECTION-II

1) One solenoid is centered inside another. The outer one has a length of 50.0 cm and contains 6750
turns, while the coaxial inner solenoid is 3.0 cm long and π cm2 in area and contains 150 turns. The
current in the outer solenoid is changing at 3000 A/s. Find the emf induced (in V) in the inner
solenoid. (Take : π2 = 10)

2) A straight conducting wire MN of length 4m is rotated in a uniform magnetic field Tesla

about point O with angular speed ω = 10 rad/s as shown in the figure. The axis of rotation is
parallel to . Find the potential difference (in volt) between point M and point N.

3) One mole of ideal monoatomic gas is taken along a cyclic process as shown in the figure.
Process 1 → 2 shown is 1/4th part of a circle as shown by dotted lines, process 2 → 3 is isochoric

while 3 → 1 is isobaric. Calculate efficiency in percentage of the given cycle.

4) Two parallel wires in the plane of the paper are distance X0 apart. A point charge is moving with
speed u between the wires in the same plane at a distance X1 from one of the wires. When the wires
carry current of magnitude l in the same direction, the radius of curvature of the path of the point
charge is R1. In contrast, if the currents i in the two wires have directions opposite to each other, the

radius of curvature of the path is R2. If , the value of is

PART-3 : CHEMISTRY

SECTION-I (i)

1) The efficiency of a Carnot engine is . When the temperature of sink decreases by 65 K, the

efficiency becomes .
Which of the following statements is correct ?

(A) The source temperature lies between 350 K and 400 K.

(B) The sink temperature is less than 300 K.
(C) The ratio TH / TC is greater than 1.5.
(D) The difference between source and sink temperatures is greater than 100 K.

2) Geometry, hybridization, and magnetic moment of the

ions , and respectively are :

(A) Tetrahedral, square planar,octahedral: sp3, dsp2, sp3d2: 5.9, 0, 4.9

(B) Tetrahedral, square planar,octahedral: dsp2, sp3, sp3d2: 0, 5.9, 4.9
(C) Square planar, tetrahedral, octahedral: dsp2, sp3, d2sp3 : 5.9, 4.9, 0
(D) Square planar, tetrahedral, octahedral: dsp2, sp3, sp3d2: 0, 5.9, 4.9

3) Select option having both correct statements regarding CoBr3.4NH3 -

(a) complex can show geometrical isomerism
(b) Three Br– ions are counter ion
(c) Two Br– satisfied primary valency as well as secondary valency
(d) Complex is diamagnetic and an inner orbital complex in nature.

(A) a,b
(B) b, c
(C) b, d
(D) a, d

4)

CH3–C≡C–CH3
Which of the following is incorrect combination.
(A) X = H2–Pd-BaSO4, Z = D2/Ni, P = Meso compound
(B) X = H2–Pd-BaSO4, Z = Baeyer's reagent, P = Meso compound
(C) X = Na/Liq NH3, Z = Br2/CCl4, P = Meso compound
(D) X = Na/Liq NH3, Z = mCPBA/H2O, P = Enantiomeric compound

SECTION-I (ii)

1) 100 ml 0.4 M HCl (strong acid) is neutralised with 200 ml 0.2M NH4OH (weak base) in a constant
pressure Calorimeter which results in temperature rise of 1.4°C. If heat capacity of Calorimeter is
1.5 kJ/°C. Which statement is/are correct
Given : ΔHneutralisation for strong acid and strong base is –57 kJ/mol.

(A) Enthalpy of neutralisation of NH4OH with HCl will be – 52.5 kJ/mol

(B) Enthalpy of dissociation (ionization) of NH4OH is 4.5 kJ/mol
(C) Enthalpy of dissociation of NH4OH is 9 kJ/mol
+
(D) ΔH for 2H2O(ℓ) → 2H (aq.) + 2OH¯(aq.) is 114 kJ

2) Which of the following do NOT represent the correct sequence of indicated properties ?

+3 +3
(A) [Co(NH3)6] > [Co(en)3] : Wave length of light absorbed
3– 3+
(B) [Fe(CN)6] < [Fe(NH3)6] : Wave number of light absorbed
(C) Be+2 < Ca+2 : Complex formation ability
(D) F2 > Cl2 > Br2 > I2 : Homo - Lumo gap

3) Which of the following statement(s) is/are incorrect

(A) [Mabcd]n± tetrahedral complex can not show optical isomersism

n±
(B) [M(AA)3] can show optical isomarism.
(C) [Mabcdef]n± has 15 optically active isomers.
n±
(D) [Ma3b3] has two stereoisomers

4)
Which of the following reaction is correct to get X is a major product.

(A)

(B)
(C)

(D)

SECTION-I (iii)

1) Match the List -

List-I List-II

(P) Froth floatation (1) Based upon thermal decomposition reaction

(Q) Roasting (2) Oxidation of the ore takes place

(R) Calcination (3) Adsorption is associated

(S) Hydrometallurgical reduction (4) Metal displacement reaction takes place

(5) High temperature is associated

The correct option is :
(A) P → 3;Q → 5;R → 1,5;S → 4
(B) P → 3;Q → 4;R → 2;S → 1,4
(C) P → 2;Q → 4;R → 1,3;S → 5
(D) P → 3;Q → 2;R → 1,3;S → 4,5

2)

List-I List-II

(P) Reversible adiabatic compression (1) ΔSsystem > 0

(Q) Reversible vapourisation of a liquid (2) ΔSsystem < 0

Adiabatic free expansion of ideal gas in

(R) (3) ΔSsurrounding < 0
vacuum

(S) Dissociation of CaCO3(s) → CaO(s) + CO2(g) (4) ΔSsurrounding = 0

(5) ΔSsystem = 0
The correct option is :
(A) P → 4, 5;Q → 1, 3;R → 1, 4;S → 1, 3
(B) P → 2, 3;Q → 4, 5;R → 1, 3;S → 1, 4
(C) P → 1, 3;Q → 1, 4;R → 2, 3;S → 4, 5
(D) P → 1, 4;Q → 2, 3;R → 3, 5;S → 1, 5

3) Match the list-

List-I List-II
 (P) (1)

Major product

(Q) (2)

Major product

(R) (3)

Major product

(S) (4)

Major product

(5)

(A) P → 3;Q → 1;R → 2;S → 4

(B) P → 5;Q → 3;R → 4;S → 2
(C) P → 2;Q → 3;R → 1;S → 5
(D) P → 4;Q → 3;R → 2;S → 1

4) Match the list-

List-I (Reaction) List-II (Major product)

(P) Major organic (1) Ethanoic acid

product

(Q) Isobutane Major organic product (2) 2-Methylpropan-2-ol

(R) (3) 2-Methylpropane-2-Methylpropane

Methane Major organic product

(S) Methane Major organic (4) Formaldehyde

product

(5) Methanol
(A) P → 1;Q → 2;R → 4;S → 5
(B) P → 5;Q → 4;R → 2;S → 1
(C) P → 3;Q → 4;R → 1;S → 2
(D) P → 4;Q → 3;R → 1;S → 5

SECTION-II

1) 1 mole of monoatomic ideal gas subjected to irreversible adiabatic expansion against constant
external pressure of 2 atm starting from initial pressure of 5 atm and initial temperature of 300 K till

the final pressure is 2 atm. If the final temperature (in K) in the process is Tf then find ? (Given :
R = 2 cal/mol K).

2) Consider the following reaction of inversion of sugar

S→G+F
If an aqueous solution of 0.025 moles of sugar in 200 gm of water shows depression in freezing point
of 0.372ºC, then what is the degree of dissociation of sugar. (Given : Kf(H2O) = 1.86 K kg mol–1)

3) Among [Zn(CN)4]2–, [Co(CO)3(NO)], XeF4, [PCl4]+, SF4 , [ICl4]–, [Cu(CN)4]3– , [Ni(CO)4] , [CdCl4]2– ,
C2H4 and P4 the total number of species with tetrahedral geometry is ______.

4)

What is the sum of double bond equivalence of X, Y and Z.

 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I (i)

Q. 1 2 3 4
A. D B A C

SECTION-I (ii)

Q. 5 6 7 8
A. A,C,D A,B,D A,B,C B,C

SECTION-I (iii)

Q. 9 10 11 12
A. A B B D

SECTION-II

Q. 13 14 15 16
A. 6.00 204.00 5.00 4.00

PART-2 : PHYSICS

SECTION-I (i)

Q. 17 18 19 20
A. D B D C

SECTION-I (ii)

Q. 21 22 23 24
A. A,B A,B A,D A,D

SECTION-I (iii)

Q. 25 26 27 28
A. A D B A

SECTION-II

Q. 29 30 31 32
A. 2.43 4.80 3.70 to 3.80 3.00

PART-3 : CHEMISTRY
 SECTION-I (i)

Q. 33 34 35 36
A. A D D D

SECTION-I (ii)

Q. 37 38 39 40
A. A,B,D B,C A,C A,B,C

SECTION-I (iii)

Q. 41 42 43 44
A. A A A A

SECTION-II

Q. 45 46 47 48
A. 11.40 0.60 7.00 3.00
 SOLUTIONS

PART-1 : MATHEMATICS

1)
Apply king property & add

2)

3) Y–y = (X – x)

X–int = x + y
 ,C=0
2 2 4
y +x =x

4)

5)

Minima at x = 3, 5
& Maxima at x = 4
f ″ (x) = 0 at atleast two point (Rolle's theorem)
f ′″ (x) = 0 at atleast one point (Rolle's theorem)

6)

f(2x).2 = 24x2 – 12x

f(2x) = 12x2 – 6x
f(x) = 3x2 – 3x
f ′ (x) = 64 – 3

, fmin. =
7)
I.F. =

[Link] =

ycosecx =

C = 0,

,1<

8)

Arc length =

9) (P) x dx = 2(y – y3) dy

x2 = y2(2 – y2) + 2C
(Q) y′ + 2xy = 2x3y3

, y–2 = t
 I.F. =

2 2
(R) (x + y + y)dx = xdy
2 2
(x + y )dx = xdy – ydx

⇒x=C= ⇒ y = xtan(x + C)

(S) (1 – xy + x2y2) =

C + ℓnx = tan–1(xy) ⇒ xy = tan(C + ℓnx)

10) (P)
equation of tangent with slope 1

(Q) y = mx – 2am – am3

it passes through (4a, 0)
2am = am3
(R) y2 = 4x & x2 = 4y

y = mx + , y = mx – am2

= –m2 ⇒ m = –1
x + y = –1,

(S) y2 = 8x,

y = mx + ,

⇒ m4 – 3m2 – 4 = 0
m=±2
y = 2x + 1
4x – 2y + 2 = 0,

11) (P) f ′ (x) + f(x) = x if x ≥ f(x)

f ′ (x) – f(x) = –x if x ≤ f(x)
 point of inflection (0, 0)
α+β=0

(Q)

(R) for
f(x) = 0 has 4 real roots.

(S) for
for 1 = 0 has 3 real roots.

12) (P) ,
,
a = A + B , A = a 2 – b2 ⇒ B = b
2 2 2 2

, ,

(R)

2e1 = 1

(S)

A2 = a2 – b2 = b2
A2 = b2

equation of hyperbola :

equation of ellipse :
 2
13) x f ′ (x) = x + f(x) – 2

I.F. =

f(x) = y = x2 + 2 + cx
f(x) = x2 + 2 – 2x

A= =
=6

14) As given a + b + c + d = 3 or 5 or 7 or 11
∴ Total matrices = 20 + 52 + 80 + 52 = 204

15) A4 = (5A – 7I)2

= 25A2 – 70A + 49I
= 25(5A – 7I) – 70A + 49I
= 55A – 126I
A8 = 3025A2 – 13860A + 15876I
= 3025(5A – 7I) – 13860A + 15876I
= 1265A – 5299I
a/253 = 5

16) x dy = (y – (x2 + y2)) dx

(x2 + y2) dx = y dx – x dy

dx =

dx =

x = tan–1 +c, c=0

PART-2 : PHYSICS

17) Question Explanation:

Frequency of small oscillations for a hinged rod-spring system.
Concept:
Angular Simple Harmonic Motion (SHM).
Solution:

The frequency is determined by the restoring torque acting on the system when it is displaced
by a small angle θ. The total restoring torque comes from both the springs and gravity.

Moment of Inertia (I): Rod + Block = .

Restoring Torque :

Due to gravity: .
Due to springs: .

Given .

Total Torque: .

Frequency (f): .
Final Answer:
Option (4)

18) Explain question: Find the value of V in terms of i and R.

Concept: Ohm's law.

Solution:
 ⇒ R2 – 4rR – 4r2 = 0

⇒
Resistance can not be negative, so

Final answer: option 2 is correct

19)

20) Question Explanation:

A current carrying wire abc is bent as shown and placed in a uniform magnetic field of
magnetic induction B directed horizontally. Length ab = ℓ and ∠abc = 45°. The same current
flows through both segments. Find the ratio of magnetic force on ab and on bc.

Concept:
Magnetic force on a straight current carrying conductor in a uniform magnetic field

Formula :
F = B | L sinθ
where θ is the angle between the conductor and magnetic field.

Solution:

For segment ab :
ab is vertical, while B is horizontal
So, θ1 = 90°
Fab = Biℓ sin 90°
Fab = Biℓ

For segment bc
bc makes an angle of 45° with ab (vertical), hence it makes 45° with the horizontal magnetic field B.

Length of bc
Since triangle is right angle with angle 45°
bc = / cos 45°
Force on bc

Fbc =
Fbc =

Thus
Fab = Fbc = (Biℓ) / (Biℓ) = 1

Final Answer: Option (3)

21) Question Explanation: The question asks to find capacitor parameters after parallel
connection.
Concept: Charge conservation and parallel combination of capacitors.
Solution:

Let initial capacitance be C. Common potential .

Find k : 450 = ⇒1+k=3⇒k=2 .

Find C : Charge on second capacitor
q2 = (kC)V ⇒18×10–3 = (2C) × 450 ⇒ C = 20μF.

C. Initial charge Q0 : Q0 = CV0 = 20µF × 1350V = 27mC.

D. Final charge on 1st capacitor q1 : q1 = CV = 20µF × 450 V = 9mC.

Final Answer: Options (1) and (2) are correct.

22) At t < 0 ; IL = = 1A

At t >> 0 ; IL = = 4A
∴ |f| = L|if – ii| = 500 × 10–3 × 3 = 1.5 Wb
∴ (A) & (B)

23) (i) n1 T1 + n2 T2 = (n1 + n2) CvT

0 0
2 T + 3 (3R) 2T = 5 Cv T

0
RT = CvT
(ii)

Cp = R

γ= ; Put in (i) Cv = R

0
T= T

24) We know

γHe = ,
γ
PV = const.

PHe (LA)5/3 =
(2)5/3 ... (1)
7/5 7/5
(LA) = (L′A)

... (2)
Now ⇒

⇒ ⇒

So volume of O2 = L′A =

25) when plates are pulled apart C ↓

on insertion of dielectric C

26)

27) ΔU = nRΔT
W = Area under P-V curve
ΔQ = ΔU + W

28) I → Q
1. Engine :

• Carnot efficiency
• Actual efficiency η = 0.8 × ηCarnot = 0.8 × 0.5 = 0.4
• Work output W = η × QH = 0.4 × 1000 J = 400 J
• Heat dumped by engine QC, eng = QH – W = 1000 – 400 = 600 J
2. Refrigerator :
• It is a reversible (Carnot) refrigerator.

•
• The work input is the 400 J from the engine : Win = 400 J

• Heat dumped by refrigerator QH,ref = Win + QC,ref. We also know .

• QC,ref = COP × Win = 5 × 400 = 2000 J
• QH,ref = 400 J + 2000 J = 2400 J
3. Total :
• Both QC,eng and QH,ref are dumped into the 300 K reservoir.
• Qdumped = QC,eng + QH,ref = 600 J + 2400 J = 3000 J
II → R :-
1. Final temperature : Since the system is isolated and the blocks are identical, the final
equilibrium temperature Tf is the average :

•
2. Entropy Change : This is an irreversible process.

Let k = mC

• Block 1 (Hot) :

• Block 2 (Cold) :
3. Total :

•
• Using ℓn(a) + ℓn(b) = ℓn(ab)

• (Note : , as required for an irreversible process).

III → S
1. System : This is a heat pump, as its goal is to deliver heat QH to the hot reservoir (the
room).
2. Power : The heat loss QH is 20 kW. The power Pin is the work rate W.
3. COP (Heat pump) : For a reversible (Carnot) pump, the COPHP is maximum :

•
4. Work Rate : The definition of COPHP is (Heat delivered) / Work Input).

•
 IV → P
1. Process : Free adiabatic expansion is irreversible, Q = 0, W = 0.
2. First Law : ΔU = Q – W = 0.
3. Ideal Gas : Since ΔU = 0 and U depends only on T for an ideal gas, ΔT = 0. The initial and
final temperatures are identical (Tf = Ti = T).
4. Entropy Change : Entropy is a state function. We cannot use ΔS = Q/T because the
process is irreversible. We must calculate ΔS for a reversible path that connects the same
initial state (T, Vi) and final state (T, 2Vi).
5. Reversible Path : The simplest reversible path is an isothermal expansion.
• For a reversible isothermal process, ΔU = 0, so Qrev = Wrev = PdV.

•
6. System & Universe :

•
• Given n = 1, ΔSsystem = Rℓn(2).
• Since the original process was adiabatic (Q = 0), the surroundings exchanged no heat :
ΔSsurr = 0.
• ΔSuiv = ΔSsystem + ΔSsurr = Rℓn(2) + 0 = Rℓn(2).

29)

Explanation Question: We have to find the emf induced (in V) in the inner solenoid. (Round
off to nearest integer) if the outer one has a length of 50.0 cm and contains 6750 coils, while
the coaxial inner solenoid is 3.0 cm long and π cm2 in area and contains 150 coils. The current
in the outer solenoid is changing at 3000 A/s
Concept: This question is based on self inductance.
Solution:
Induced emf will be

= 1800 × 10–7 × 13500 = 2.43 V

30)

31)

= 3.76%
 32)

⇒ ....(1)
Now in second case

⇒ ....(2)
Dividing equation (1) by (2)

PART-3 : CHEMISTRY

33)

TC =

3TC – 195 = 2TH TH – 195 = 2TH

TH = 390 K
 TC =

34) Explain Question: Finding out geometry, hybridization and magnetic moment of ions

respectively.

Concept : Based on C.F.T.

:strong ligand; Br- & F-;weak ligands

2+ 2
Ni [Link].4, will be dsp [Link]; No unpaired
2+ 3
Mn [Link].4, will give sp Tetrahedral;
5 unpaired ;
Fe3+ [Link] 6, will give sp3d2 Octahedral;
4 unpaired

Final Answer The correct option is (D)

35)

[Co(NH3)4 Br2]Br

36) The correct answer is option (D)

37)

The correct answer is option (A, B, D)

38)

Question Explanation : Finding correct sequence.

Concept: This question is based on magnetic moments, stability constant, basic character,
colur.
Solution:
1. [FeF₆]³⁻ > [NiF₆]³⁻ : Magnetic moment
Fe³⁺ (d⁵, 5 unpaired) vs Ni³⁺ (d⁷, 3 unpaired).
Magnetic moment of Fe complex greater → Correct sequence
2. [Fe(CN)₆]³⁻ < [Fe(NH₃)₆]³⁺ : Stability constant
CN⁻ is a much stronger ligand than NH₃.
Stability: [Fe(CN)₆]³⁻ ≫ [Fe(NH₃)₆]³⁺.
Given order is incorrect
3. Be+2 < Ca+2 : Complex formation ability
4.
Colour intensity increases down the group due to lower HOMO-LUMO gap.
Given order is correct
Final Answer : Option (B) and (C)
39) (A) Tetrahedral complex can show optical isomerism.
n±
(B) [M(AA)3] does not show geometrical isomerism.
n±
(C) [Mabcdef] has 30 optically active isomers
(D) Ma3b3 :–

40) The correct answer is option (A), (B), (C)

41) Question Explanation:

Match the correct options of list-I and list-II in given table.

Concept:
Information based.

Solution:
(P) Froth floatation - (3)
(Q) Roasting - (2), (5)
(R) Calcination - (1), (5)
(S) Hydrometallurgy - (2), (4)

Final Answer:
The correct option is (1).

42) Theory based.

43) The correct answer is option (A)

44) The correct answer is option (A)

45) 1 × (T2 – 300) = – Pext

1.5 (T2 – 300) = – 2

1.5 T2 – 450 = – T2 + (60 × 2)
T2 = 228 K

46) Molality = = 0.125m

Hence 0.372 = i × 1.86 × 0.125
α = 0.6

47)

Question Explanation: Count the number of chemical species from the given list that have a
tetrahedral geometry.
Concept: Hybridization and coordination geometry determination.
Solution: The geometry of each species is determined by its hybridization or coordination
number (C.N.):
2– 3
• [Zn(CN)4] undergoes sp hybridization. → Tetrahedral
3
• undergoes sp hybridization. → Tetrahedral
• XeF4 : Has 4 bond pairs and 2 lone pairs . → Square Planar
• : Central P has 4 bond pairs and 0 lone pairs Tetrahedral
• SF4 : Has 4 bond pairs and 1 lone pair See-saw
• : Has 4 bond pairs and 2 lone pairs . → Square Planar
3
• undergoes sp hybridization. → Tetrahedral
• undergoes sp3 hybridization. → Tetrahedral
• undergoes sp3 hybridization. → Tetrahedral
• C2H4 : Carbon atoms are sp2 hybridized. → Planar
• : Contains a cage-like network structure with atoms at four vertices. → Tetrahedral
The 7 species with tetrahedral geometry are
, and P4.
Final Answer: 7

48) The correct answer is 3.00