19-07-2026

5001CJA101024360001 JA

PHYSICS

SECTION-I(i)

1) The electrostatic potential V at a point on the circumference of a thin non–conducting disk of

radius r and uniform charge density σ is given by equation V = 4σr. Which of the following
expression correctly represents electrostatic energy stored in the electric field of a similar charged
disk of radius R?

(A)

(B)

(C)

(D) None of these

2) A circular disc of radius R carries surface charge density σ(r) = σ0 , where σ0 is a constant
and r is the distance from the center of the disc. Assume that the disc is in xz plane and its axis is y

axis. We have a sphere of radius R and centre at . What is the flux of electric field

through this sphere?

(A)

(B)

(C)

(D)

3) A mercury barometer has a cylindrical capillary tube of radius mm inverted vertically on

the mercury in the trough. Atmospheric pressure is 76 cm of mercury but the level of mercury in
the capillary is 75cm. The portion of the tube without mercury is 10cm in length. Considering that
this region is occupied by ideal gasses, the number of moles of the ideal gas will be :
[Given : Density of mercury = 13.6 g/cc, surface tension of mercury = 0.5 N/m, temperature =
37°C, g = 10 m/s2, universal gas constant = R, angle of contact of mercury on tube = 135°]
(A)

(B)

(C)

(D)

4) For a concave mirror, graph of and u for real object is drawn. What is the value of .

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) As shown in figure, two large, parallel, vertical conducting plates separated by distance 'd' are
charged to their potential +V0 and –V0. A small conducting ball of mass m and radius R(R<<d) hangs
midway between the plates. The thread of length 'L' supporting the ball is conducting wire,
connected to earth, so the potential of ball is fixed at V = 0. The ball hangs straight down in
equilibrium. (Given ].

For small horizontal displacement (x) of ball (x << L) along electric field, modulus of charge on
(A)
ball is
For small horizontal displacement (x) of ball (x << L) along electric field, modulus of charge on
(B)
ball is

(C)
equilibrium of ball is stable if

(D)
equilibrium of ball is stable if

2) A narrow smooth tunnel of L-shapes is made into earth up to centre as shown in the figure. A
small ball which just fits in tunnel is released from 'A'. The collision of ball is perfectly inelastic. (g is

acceleration due to gravity on surface of planet) :-

(A)
Time to fall from A to B is
Time to fall from B to O is
(B)

(C)
Speed just before hitting B is

(D)
Speed just before hitting O is

3) Little Jai is sitting on a seat of merry-go-round moving with constant angular velocity. At t = 0, Jai
is at position A shown in figure.
Which of the graphs shown in figure are correct? All graphs are sinusoidal.

(A)

Fy is the j-component of the force keeping Jai moving in a circle

(B)
x is the x component of Jai's position.

(C)

is the angle that Jai's position vector makes with positive x-axis.

(D)
is the x component of Jai's velocity

4) A ray of light is incident on the surface of a sphere of refractive index . Another half of the
sphere is silvered. After refraction it is reflected and then refracted out of the sphere again such that
the total deviation is minimum. (sin 41° = ))

(A) The angle of incidence of the ray is 41°

(B) The angle of incidence of the ray is 60°
(C) Total deviation of the ray is 146°
(D) Total deviation of the ray is 126°

SECTION-I(iii)

1) A semi-circular wire with radius R has uniform linear charge density –λ. Consider at a point (0, 0,
z) on the “axis” of the semicircle (the line through the centre, perpendicular to the pane of the
semicircle, as shown in figure) i.e. the z-axis. Then match List-I to List-II.

List-I List-II

Magnitude of x-component of electric field at the

(P) (1)
point (0, 0, z) v/s z graph.

Magnitude of z component of electric field at the

(Q) (2)
point (0, 0, z) v/s z graph.

The electric field at a point (0, 0, z) point towards a

(R) (3)
point (x, y, 0) in xy plane then x v/s z graph is

The electric field at a point (0, 0, z) point towards a

(S) (4) None of these
point (x, y, 0) in xy plane then y v/s z graph is
(A) P → 2;Q → 1;R → 3;S → 4
(B) P → 1;Q → 2;R → 2;S → 3
(C) P → 2;Q → 1;R → 1;S → 4
(D) P → 2;Q → 2;R → 3;S → 4

2) A steel rope (density d, length L, area of cross section A. Young's modulus Y) is subjected to
operations as described in List-I. Discover the correct value of x in the expressions and match.

List-I List-II

The rope is hanging from a ceilling in

equilibrium. The elastic potential energy per
(P) unit volume at a point L/3 from the ceilling (1) 3

is
 The rope is vertical and moves under the

application of vertical force acting

at its upper end upwards. The strain at a
(Q) (2) 4

point at a distance from the lower end is

The rope is rotating at angular speed in

gravity free space about its one fixed end.
(R) (3) 5
The stress at a point from the fixed end is

A circular ring is formed from the rope. This

ring is made to rotate with angular
speed in its own plane in gravity free space.
(S) (4) 6

Tension in the rope is

(5) None of these

(A) P → 4;Q → 2;R → 1;S → 5
(B) P → 2;Q → 4;R → 5;S → 3
(C) P → 1;Q → 3;R → 2;S → 4
(D) P → 3;Q → 2;R → 4;S → 5

3) A satellite of massm is taken to a point P at a heightR (= the radius of the earth) from the surface
of the earth and given a velocity perpendicular to the line OP (where O is the center of
the earth). Match the quantities in Column I with those in Column II

Column-I Column-II

(P) Reciprocal of eccentricity of its trajectory (1) 6

(Q) Furthest distance of satellite from the center of the earth (as a multiple ofR) (2) 3

(R) Time period (as a multiple of ) (3) 4

whereE is its total energy (the reference for potential energy

(S) (4)
being taken at infinity)
(A) P → 2;Q → 4;R → 3;S → 1
(B) P → 4;Q → 3;R → 2;S → 1
(C) P → 2;Q → 3;R → 1;S → 4
(D) P → 2;Q → 3;R → 4;S → 1

SECTION-II

1) A manufacturer wants to produce crude benzene models for the chemistry department. The
manufacturer plans to do this by punching regular hexagons out of steel; such that edge length and
thickness are in ratio 1000 : 1. Steel ruptures at shear stress greater than 4 × 108 N m–2. If total
shearing force applied is 6 × 105 N, then find maximum value of thickness of the hexagonal plane (in
mm)

2) Drops of water are thrown tangentially from the horizontal rim of a rotating wet umbrella. The
rim is 3 ft in diameter and is held 4 ft above the ground and makes 14 revolutions in 33 seconds.
Drops of water will meet the ground on a circle of diameter (in ft). (g = 32 ft/s2)

3) A portion of a straight glass rod of diameter 3 cm and refractive index 1.8 is bent into an arc of
radius R cm and a parallel beam of light is incident on its as shown in figure. Find the smallest R, in
cm, which permits all the light to pass around the arc.

4) A narrow capillary tube of radius 0.5 mm contains some water in it. When tube is held vertical,
the water remains inside the tube as shown. Find the radius of curvature (in mm) of the lower water

surface. (Surface tension s = 0.075 N/m, contact angle = 0°, g = 10 m/s2).

5) A right angled prism is placed with air all around it. A horizontal incident ray strikes the face PQ
of prism normally, then undergoes total internal reflection twice as shown and exists the prism from

face PR horizontally. The refractive index of prism is μ and angle θ = 15º. If the value of μ is
then find n ?

6) An electric dipole having dipole moment (4 × 10–9) C-m is placed at origin along x-axis. What
uniform electric field (in N/m) should be applied along x-axis so that we get a equipotential spherical
surface of radius 3m centred at origin?

CHEMISTRY

SECTION-I(i)

1) Which of the following compound CANNOT act as a Lewis base?

(A) NF3
(B) PCl5
(C) SF4
(D) ClF3

2) Correct electronic configuration of 'Nb'.

(A) [Kr] 5s2 4d3

(B) [Kr] 5s1 4d4
(C) [Kr] 5s2 4d4
(D) [Kr] 5s1 4d5

3) Incorrect statement among the following :

(A) Photoiodination is reversible phenomenon

(B) Photobromination is more selective than photochlorination
(C) During Kolbe's electrolysis CO2 gas evolved as cathode
If R(Alkyl group) is tertiary during Kolbe's electrolysis of sodium carboxylate the major
(D)
product will be ester

4)

Column-I Column-II
 Eq. wt. of underlined species =
(P) (1) When oxidises into and

Eq. wt. of underlined species =

When oxidises into
(Q) (2)

Eq. wt. of underlined species =

When oxidizes into
(R) (3)

Eq. wt. of underlined species =

(S) (4) When oxidise into

(A) P-1, Q-3, R-2, S-4

(B) P-2, Q-1, R-4, S-3
(C) P-3, Q-2, R-1, S-4
(D) P-4, Q-1, R-3, S-2

SECTION-I(ii)

1) A 5 gm sample containing Fe3O4 (FeO + Fe2O3) and an inert impurity is treated with excess of KI
solution in the presence of dilute H2SO4. The entire iron converted to ferrous ion along with
formation of iodine. The resulting solution is diluted to 100 ml. 20 ml of the diluted solution
requires 10 ml of 0.5 M Na2S2O3 solution to reduce the iodine present. Among the following select
correct statement.

(A) Percentage of inert impurity in sample is 42%

(B) Percentage of Fe2O3 in sample is 40%
(C) Percentage of FeO in sample is 28%
(D) Percentage of inert impurity in sample is 32%

2) Which complex(es) follow Sidwick's EAN rule.

(A) [V(CO)6]
(B) Co2(CO)8
(C) Mn2(CO)10
(D) Cr(CO)6

3) Which of the following statements is/are correct?

(A)
(B)

(C) (singlet) > (triplet) (stability order)

(D) (Basic strength in water)

4) Which of the following pair of isomers are correctly matched with their relationship

(A)
Geometrical isomers

(B)
Position isomers

(C)
Functional group isomers

(D)
Chain isomers

SECTION-I(iii)

1)

List-I (Order) List-II (Properties)

(P) CH3F < CH3Cl < CH3Br (1) dipole moment of the molecule
(Q) CH3F > CH3Cl > CH3Br (2) bond length (carbon-halogen)
difference in electronegativity of C and X
(R) CH3F < CH3Cl > CH3Br (3)
(halogen)
(S) CH3F = CH3Cl = CH3Br (4) No of lone pairs
(A) P → 2;Q → 3;R → 1;S → 4
(B) P → 2;Q → 1;R → 3;S → 4
(C) P → 4;Q → 2;R → 1;S → 3
(D) P → 3;Q → 1;R → 4;S → 2

2) Match the electronic configurations in List-I with appropriate metal complex ions in List-II and
choose the correct option.
[Atomic Number: Fe = 26, Mn = 25, Co = 27]

List-I List-II
 2+
(P) (1) [Fe(H2O)6]
2+
(Q) (2) [Mn(H2O)6]
3+
(R) (3) [Co(NH3)6]
–
(S) (4) [FeCl4]
2–
(5) [CoCl4]
(A) P → 1;Q → 4;R → 2;S → 3
(B) P → 1;Q → 2;R → 4;S → 5
(C) P → 3;Q → 2;R → 5;S → 1
(D) P → 3;Q → 2;R → 4;S → 1

3)

List-I List-II
(Molecule) (Property)

(P) (1) Meso compound

Compound having even

(Q) (2)
number of chiral centres.

Optically active
(R) (3)
compound

Compound having odd

(S) (4)
number of chiral centres.

(5) Achiral
(A) P → 2;Q → 3,4;R → 3,4,5;S → 1,2
(B) P → 1;Q → 2,3;R → 3,5;S → 1,2,3
(C) P → 2,3;Q → 3,4;R → 2,3;S → 1,2,5
(D) P → 2,4;Q → 3,4,5;R → 1,2,3;S → 1

SECTION-II

1) 250 ml of 1 M I2 is separately reacted with 0.5 M Cu2S solution, 0.5 M CuS solution, causing
production of Cu+2 and in both of the cases along with iodide ions. If volume of CuS and Cu2S
consumed in both the reactions are 'x' ml and 'y' ml. Calculate (x + y) is.

2) How many of the following elements have either half filled or fully filled 4f subshell.
Eu, Gd, Tm, Yb, Lu, Cm, Lr, Sm

3) Find the number of molecules in which atleast two d-orbitals are involved in hybridisation :-
XeF5–, SF4, XeF6 , SO3F–, CF4 , SO3 , , IF7

4) Degree of unsaturation in the major product is

X then (X–2)

5)

Total number of alkenes obtained in the given reaction are :

6) Number of compounds which are more reactive than toward SN2 reaction :

MATHEMATICS

SECTION-I(i)
1) Let , x ≠ 0 and f(0) = 1. The value of a and b so that f is a
continuous function are -

(A)

(B)

(C)

(D) None of these

2) Let ƒ : → be a real valued function such that ƒ(10 + x) = ƒ(10 – x) ∀ x ∈

and ƒ(20 + x) = –ƒ(20 – x) ∀ x ∈ . Then which of the following statements is true

(A) ƒ(x) is odd and periodic

(B) ƒ(x) is odd and aperiodic
(C) ƒ(x) is even and periodic
(D) ƒ(x) is even and aperiodic

3) For any positive integer n, define fn : (0, ∞) → ℝ as

for all x ∈ (0, ∞).

(Here, the inverse trigonometric function tan–1x assume values in .)

Then, which of the following statement(s) is (are) TRUE ? [JEE(Advanced)-2018]

(A)

(B)

(C)
For any fixed positive integer n,

(D) For any fixed positive integer n,

4) equals -

(A) 1

(B)

(C) e
(D)

SECTION-I(ii)
1) Let f be a function given by . Then,

(A) f is continuous on R

f is differentiable on R and equals

(B)

(C) f is not differentiable at x = 0

f is differentiable on R and equals

(D)

2) , is equal to

(A)

(B)

(C)

(D)

3) Let be differentiable functions such that f(x) = x3 + 3x + 2, g(f(x)) =

x and h(g(g(x))) = x for all . Then- [JEE Advanced 2016]

(A)

(B) h'(1) = 666

(C) h(0) = 16
(D) h(g(3)) = 36

0
4) If for all n ∈ N and f (x) = x, then is equal to

(A)

(B)
(C)
(D) None of these

SECTION-I(iii)

1) Match List-I with List-II and select the correct answer using the code given below the list.
 List-I List-II

(I) sin–1sin10 + cos–1cos3 + tantan–1(–3) is equal to (P)

(II) (Q) 3π – 10
is equal to

(III) (R)
is equal to

(IV) (S)
is equal to

(T) 2π
(A) I → Q;II → R;III → P;IV → S
(B) I → R;II → Q;III → S;IV → P
(C) I → Q;II → R;III → P;IV → P
(D) I → Q;II → R;III → S;IV → P

2) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(P) If then absolute value of difference of let and right limit (1) 4
is

Let ƒ(x) = x2 – 4x + 1, then the number of points where |ƒ(|x|)| is non-

(Q) (2) 5
differentiable is

(R) (3) 1
If is continuous at x = 0, then
ƒ'(0) is (where [.] represents greatest integer function)

(S) (4) 2
Let , the is
(where [.] represents greatest integer function)

(5) 8
(A) P → 3;Q → 2;R → 4;S → 1
(B) P → 4;Q → 2;R → 3;S → 1
(C) P → 1;Q → 4;R → 3;S → 2
(D) P → 4;Q → 1;R → 2;S → 3

3) Match the following

List – I List – II
 Let f be a real valued differentiable function on f such that f'(1)

(I) (p) 4
= 6 and f'(2) = [Link] is
equal to

For a > 0, let f:[–4a, 4a] → R be an even function

such that f(x) = f (4a –x) ∀ x ∈ [2a, 4a] and
(II) (q) 5
then is equal
to

Suppose f is a differentiable function on R. Let F(x) = f(ex) and

(III) (r) 3
G(x) = ef(x), If f'(1) = e3 and f(0) = f'(0) = 3, then is equal
to

Let f(x) = Max. (cos x, x, 2x – 1) where x ≥ 0. Then number of

(IV) (s) 2
points of non – differentiability

(t) 1

(u) 6
(A) I → p;II → p;III → r;IV → u
(B) I → p;II → s;III → r;IV → s
(C) I → p;II → p;III → r;IV → u
(D) I → p;II → p;III → u;IV → q

SECTION-II

1) If ex+y = y2 and then is

2) Value of is

3) Let the function ƒ : [0, 1] → be defined by .

Then the value of is______

4) Let ƒ : R → R be an even function satisfying ƒ(x) = ƒ(x + 6) ∀ x ∈ R such that

. The value of ƒ(8) + ƒ(–3) is

5) If is K then find 23 K
6) Let f(x) = ax3 + bx2 + cx + d, satisfying , then (a + c) equals
 ANSWER KEYS

PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. A C A A

SECTION-I(ii)

Q. 5 6 7 8
A. B,C A,C A,B,C,D B

SECTION-I(iii)

Q. 9 10 11
A. A B D

SECTION-II

Q. 12 13 14 15 16 17
A. 0.50 5.00 6.75 1.50 0.75 1.33 to 1.34

CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21
A. B B C B

SECTION-I(ii)

Q. 22 23 24 25
A. A,B B,C,D A,B,D C,D

SECTION-I(iii)

Q. 26 27 28
A. A D C

SECTION-II

Q. 29 30 31 32 33 34
A. 225.00 4 3.00 9.00 5.00 5.00

MATHEMATICS
 SECTION-I(i)

Q. 35 36 37 38
A. C A D D

SECTION-I(ii)

Q. 39 40 41 42
A. A,B A,B,C,D B,C A,C

SECTION-I(iii)

Q. 43 44 45
A. D B B

SECTION-II

Q. 46 47 48 49 50 51
A. 0.50 1.00 19.00 5.00 11.50 2.00
 SOLUTIONS

PHYSICS

1) Charge in layer of width dr

dq = 2πrdrσ

Work to bring dq = dU=Vdq

dU = 4σr· 2πrdrσ = 8πσ2r2dr

2) Question Explanation: Calculating electric flux through a sphere by determining the

charge enclosed from a non-uniform charged disc.
Concept: Gauss's Law and Flux Calculation.
Solution: According to Gauss's Law, the net electric flux through any closed surface is

. We must find the portion of the charged disc that lies inside the sphere.
Step-by-step Calculation:

A. Identify the Intersection: * The disc lies in the xz-plane (y=0).

B. The sphere is centered at with radius R.

C. To find the intersection, set y=0 in the sphere's equation: .

D. .

E. This means the sphere encloses a smaller circular region of the disc with radius .
F. Calculate Enclosed Charge ( ):
G. Flux ( ):
Final Answer: (Option 3)

3)
Let the pressure at the top of mercury be P

P = 76 cm of Hg – 75 cm of Hg

= 860 N/m2
No of moles of gas

4) Question Explanation: Finding the ratio b/a based on the graph of versus u for a
concave mirror, where u is the object distance and v is the image distance.

Concept: 1. Mirror Formula: .

2. Analysis of the Graph: The graph plots against x = u. From the mirror formula,

. Therefore:

Solution:

A. Find value of a: As (at the horizontal asymptote), the term 1/u becomes 0.
 B.

C. Thus, .
D. Find value of b: From the graph, b is the value of when u = R.

E.

F. Thus, .
G. Calculate the ratio b/a:

H.

Final Answer: Option (1)

5)

or

For vertical equal

T = mg
For unstable equilibrium

If (unstable equilibrium)
For critical
6)

Time to fall from A to B =

Where

T= ;t=
Apply energy cons. from A to B

;V=
Energy cons. from B to O

;V=

7)
8)

µ=
S ⇒ (i – r) + (π – 2r) + i – r
⇒ π + 2i – 4r ...(1)
sin i = µ sin r ...(2)
For δmin

9)

10)

(P)

(Q)

(R)

(S)

11) ANSWER: 4

12) Question Explanation:

We need to find the maximum thickness (t) of a hexagonal steel plate that can be successfully
punched out given a specific shearing force and the material's rupture stress.

Concept:
Shear Stress and Shearing Area of a regular polygon.

Solution:
Relationship between length and thickness:
Given ratio : t = 1000 : 1, so the edge length = 1000 t.
Total Shearing Area (A):
For a hexagon being punched, the force acts along its perimeter.

Substituting = 1000 t :

Condition for Rupture (Punching):

The applied shear stress (σ) must be at least equal to the rupture stress for the material to fail
and the shape to be punched out.

Calculating t :

Conversion to mm:

Final Answer: 0.50.

13)

Let the drop is thrown off from point A. The velocity V = rω

The drop will describe the parabolic path

The time take by drop to strike the ground ⇒ s

∴ The horizontal distance

NB

i.e., diameter = 5 ft.

14)
For this ray, let α be the angle of incidence, then we observe that

where d is the diameter of tube

For TIR,

Since, µ =1.5 and d = 4 cm, so we get

R = 12 cm
Hence, the least radius required is 12 cm

15)

r' = 1.5 mm

16)
In ΔABC,
θ + 90 – x + 2 (x + θ) = 180
∴ x = 90 – 3θ
⇒ μsinx = sin(90 – θ)

μ=
 =
∴ n = 0.75

17)
Consider a point on circumference at angular position θ.
For surface to be equipotential net E.F. at A should be perpendicular to A.

CHEMISTRY

18) Explain Question:

Identify the compound which cannot act as a lewis base.

Concept:
Lewis base theory.

Solution:
Lewis base : Chemical species which has capability to donate electron pair.
In NF3, SF4, ClF3 central atom (i.e. N, S, Cl) having lone pair therefore act as lewis base.
In PCl5 central atom (P) does not have lone pair therefore does not act as lewis base.

Final answer: Option (2)

19)

Question Explanation : Correct electronic configuration of 'Nb'.

Concept: Electronic configuration
Solution:
The electronic configuration of Niobium (Nb), atomic number 41, is one of the "exceptions" in
the periodic table.
Instead of following the standard Aufbau principle, one electron from the 5s orbital is
promoted to the 4d orbital to achieve a more stable state.
Final Answer: Option (2)

20) During kolbe's electrolysis H2 gas evolved at cathode

21)
n = 3 + 8 × 3 = 27

n = 1 + (8 + 0 + 8) × 2 = 33

n = 8 + 8 + 0 + 8 = 24

n = 2 × 2 + 8 × 3 = 28

22) Let mass of Fe3O4 is x.

equivalent of Fe2O3 = equivalent of KI = equivalent of I2 = equivalent of Na2S2O3
2x = 0.025
x = 0.0125 mole of Fe2O3
mass of Fe2O3 = 0.125 × 160 = 2 gm

% of Fe2O3 = × 100 = 40%

23)

(B) Co2(CO)8
(C) Mn2(CO)10
(D) Cr(CO)6

24) Explanation Question:

Asking about the correct orders for the given species

Concept:
This question Based on application of electronic displacement efects

Solution:

(1) Acdic strength (Ka) ∝ Stability of conjugate base ∝

(2) Stability of carbocations ∝ .

(3) Stability of carbene ; Triplet > singlet

(4) Basic strength (Kb): (in polar solvent) : 2° amine > 1° amine 3° amine > NH3 ; (1 alkyl
group is methyl)
According to above concepts except option (singlet) > (triplet) (stability order) all
other options are correct.

Final Answer: The correct option is (1), (2) and (4).

26)

(P)- 2; (Q)- 3; (R)- 1; (S)- 4

27) 1.

2.

3.

4.

5.
29) 1 × 250 × 2 = 0.5 × V × 10 ⇒ V =

1 × 250 × 2 = 0.5 × V × 8 ⇒ V =

30) Theory

31)

XeF5 → sp3d3
SF4 → sp3d

XeF6 → sp3d3
→ sp3
CF4 → sp3
SO3 → sp2
→
sp3d

IF7 → sp3d3

32)

33)

34)

Question Explanation:
The question asks us to identify the total number of compounds from the provided list that
 react faster than isopropyl chloride (H3​C−CH(Cl)−CH3) in an SN2 reaction.

Concept:
This question is based on S N 2 Reaction Mechanism, Steric Hindrance, Leaving Group
Ability, Electronic Effects, Alkyl Halides.

Solution :
Factors affecting SN2 reactivity:

A. Steric hindrance: Methyl > 1° > 2° >> 3°

B. Leaving group ability: I⁻ > Br⁻ > Cl⁻ > F⁻

C. Electronic effects: An adjacent carbonyl group or –M group enhances S N 2 by

stabilizing the transition state.

D. Constraints: Aryl halides and bridgehead halides do not undergo S N 2 due to

geometric/electronic restrictions.

Comparison with isopropyl chloride:

A. (CH3)3CF (tert-butyl fluoride): Less reactive (3°, F⁻ poor Leaving group).

B. (CH3)2CHBr (isopropyl bromide): More reactive (same steric, better Leaving group).

C. (CH3)3CCl (tert-butyl chloride): Less reactive (3°, severe steric hindrance).

D. CH3COCH2Cl (α-chloroacetone): More reactive (1°, carbonyl activation).

E. CH3CH2Br (ethyl bromide): More reactive (1°, Br⁻).

F. CH3CH2I (ethyl iodide): More reactive (1°, I⁻ best Leaving group).

G. CH3Cl (methyl chloride): More reactive (methyl, least hindrance).

H. Chlorobenzene: Less reactive (aryl halide).

I. 1-Chlorobicyclo[2.2.1]heptane: Less reactive (bridgehead halide).

Final Answer: 5
MATHEMATICS

35)

Final Answer : Option (3)

36) Solution :
ƒ:R→R
ƒ(10 + x) = ƒ(10 – x)
Let 10 – x = t
ƒ(t) = ƒ(20 – t)
& ƒ(20+t) = –ƒ(20 – t)
⇒ ƒ(20+t) = –ƒ(t)
Replace t by t + 20
⇒ ƒ(20+t+20) = –ƒ(t+20)
⇒ ƒ(40+t) = ƒ(t)
⇒ Periodic with Period '40'
Also,
ƒ(20 + x) = –ƒ(20 – x)
20 – x = a
ƒ(a) = –ƒ(40 – a)
ƒ(a) = –ƒ(–a)
⇒ odd function.
Final Answer : Option (1)

37)

fn(x) = tan–1(x + n) – tan–1x

∴ tan(fn(x)) = tan[tan–1(x + n) – tan–1x]

tan(fn(x)) =

tan(fn(x)) =
∴ sec2(fn(x)) = 1 + tan2(fn(x))
sec2(fn(x)) =

38)
 39)

40)

Question Explanation: Conversion of inverse cosine into other inverse functions for x < 0.

Concept: Inverse Trigonometric Function Conversions

Solution:

Let
Final Answer: Options (1), (2), (3), and (4) are all correct.

41)

Ans. (B, C)
Given
g(f(x))=x

⇒ g'(f(x)) · f'(x) = 1 ⇒ g'(f(x)) =

⇒ g'(x3 + 3x + 2)=

put x = 0 we get
option A is wrong
* h(g(g(x))) = x; given
Put x = f(x)
⇒ h(g(g(f(x))))=f(x); given
⇒ …(1)
3
put x = 3 h(g(3)) = f(3)=3 + 3 × 3 + 2 ⇒
put x = f(x) in eq. (1)

⇒
⇒

⇒
⇒ h'(x) = f'(f(x))·f'(x)
⇒ h'(x)=f'(x3 + 3x + 2)·(3x2 + 3)
put x = 1
⇒ h'(1) = f'(6)·6
⇒ h'(1) = 111 × 6
⇒

42) and f0(x) = x

f1(x) = ex
f2(x) =
f3(x) =
Now

43) (I) sin–1sin10 + cos–1cos3 + tan tan–1(–3)

= (3π – 10) + 3 – 3 = 3π – 10

(II)

(III)

(IV) =

44) (P)
Jump = 2

(Q)

(R)
ƒ(0) = ƒ(0 + h) = ƒ(0 – h) ⇒ b = 0

ƒ'(0+) = ƒ'(0–) = 1

(S)

45)
(Q) f'(2a+)

Now f'(–2a+)

( f is even function)

f(x) = f (4a – x) ∀ x ∈ [2a, 4a]

Put x = 2a + h, we get f (2a + h) = f (2a – h)
(R) We have F(x) = f(ex)
⇒ F'(x) = ex f' (ex)
And G(x) = ef(x)
⇒ G'(x) = ef(x)f'(x)

=
(S) ∴ Number of points of non – differentiability = 2

46) ex + y = y2
x+y=
∴k=2

47) Using :

= |–1| = 1

48)

Question Explanation:
Evaluating a series using the symmetry property of a function.
Concept:
Symmetry property f(x) + f(1–x) = 1
Solution:
The f(x) satisfies a specific property where the sum of terms at equidistant positions from the
ends of the series equals1. We pair terms like f(1/40) and f(39/40) to simplify the summation.
Calculation:
First, verify the property:

The given expression is:

S=
Since there are 39 terms in the first part of the sequence:
• There are 19 pair that sum to 1.
• The middle term is f(20/40) = f(1/2).

Final Answer: (19)

49) ƒ(–x) = ƒ(x) .... (1)

and ƒ(x) = ƒ(x + 6)
Now ƒ(8) + ƒ(–3)
= ƒ(2) + ƒ(3)
= (5 – 2) + (5 – 3) = 5

50)
and so on

Applying limit then

51)

⇒
⇒ a = 2, b = –2, c = 0, d = 0