14-06-2026

9610WJA802544260008 JA

PHYSICS

SECTION-I (i)

1) An object starts moving from rest with an acceleration of 2 m/s2 at t = 0. Which of the following is
correct?

(A) Velocity of the object at t = 2 seconds is 4 m/s

(B) Velocity of the object at t = 2 seconds is 6 m/s
(C) Displacement of the object in 2 seconds is 6 m
(D) Displacement of the object in 2 seconds is 4 m

2) A particle is projected with speed 40 m/s such that at maximum height its speed is 20 m/s, then :

(A) Angle of projection is 60°

(B) Time of flight is sec.
(C) Range is m.
(D) Maximum height is 60 m.

3) For which of the following continuous charge system magnitude of electric field at point P is

0
where λ is linear charge density?

(A)

(B)
(C)

(D)

4) Electric field in a region is given as . A charge particle of mass 5kg and charge
Q (= 1C) is released from origin at rest and free to move in given electric field. Then choose the
CORRECT option(s) (Neglect gravity) :-

(A) Motion of charge particle is Oscillatory.

(B) Maximum displacement of charge particle from origin is 4 SI units.
(C) Maximum velocity gain by charge particle is 2 SI units.
(D) The position of charge particle, when velocity gained by particle is maximum, is 2 SI units.

5) In x-y coordinate system a particle P of charge –q and mass m enters with negligible velocity as
shown in figure. In this region potential varies as V = ax2, a = +ve constant. Which of the following
graphs representing the variation of particle’s velocity and acceleration along x - axis.

(A)
(B)

(C)

(D)

6) A point charge q is placed at origin. Let , and be the electric field at three points A(1, 2,
3), B(1, 1, –1) and C (2, 2, 2) respectively due to charge q, then :

(A)

(B) (EA perpendicular to EB)

(C) (EA is parallel to EC)

(D)

7) The curve represents distribution of potential along a line joining two charges q1 and q2
(separated by distance ℓ) then which of the following statements are incorrect ?

(A) |q1| < |q2|

(B) q1 is negative in nature
(C) A and B are equilibrium points
(D) C is point of unstable equilibrium
8) Two point objects of masses m and 4m are at rest at an infinite separation. They move towards
each other under mutual gravitational attraction. If G is the universal gravitational constant, then at
a separation r.

(A) the total mechanical energy of the two objects is zero

(B)
their relative velocity is

(C)
the total kinetic energy of the objects is
(D) their relative velocity is zero

SECTION-I (ii)

Common Content for Question No. 1 to 2

Answer question 1,2 by appropriately matching the information given in the two columns of the
following table.
Figure shows total charge given to a conductor. Here, Column 1 represents arrangement of
conductors.
Column 2 represent charge on surface -1 and charge on surface -2.

Column -1 Column -2

(I) (i) +Q charge on surface I

(II) (ii) –Q charge on surface I

 (III) (iii) +Q/2 charge on surface I

(IV) (iv) –Q/2 charge on surface I

(v) +Q charge on surface II

(vi) +Q/2 charge on surface II

1) For part (I) the correct combination is

(A) (I) (i) (v)

(B) (I) (ii) (v)
(C) (I) (iii) (v)
(D) (I) (iii) (vi)

2) For part (II) the correct combination is

(A) (II) (i) (v)

(B) (II) (iii) (vi)
(C) (II) (iii) (v)
(D) (II) (i) (vi)

Common Content for Question No. 3 to 4

Position of a particle moving along any one of x, y or z axis is given w.r.t time in List-I. Where
(a, b, c > 0)

List-I List-II

(P) a + bt + ct2 (1) An accelerating body

(Q) bt – ct2 (2) It can be a body projected vertically up under gravity

(R) a – ct2 (3) A body which starts from origin

(S) ct2 (4) Initial velocity is zero

(5) Acceleration is constant

(6) Acceleration is variable

3) Choose correct option

(A) P-1,2,5
(B) Q-1,2,3,5
(C) R-1,6
(D) S-2,3

4) Choose correct option

(A) P-4,5
(B) P-3,5
(C) R-1,4,6
(D) S-1,3,4,5

SECTION-II

1) The work done in carrying a charge of 5μC from a point to a point in an electric field is 10 mJ.
The potential difference (VB – VA) is K volts. Find the value of K.

2) A particle is projected radially outwards from the surface of a planet with an initial speed of 4.0
km/s. Maximum height attained by the particle is h = 900 km from the planet’s surface. Find the
radius R (in km) of the planet taking g = 10 m/s2 on the surface of the planet. Fill R/900.

3) A Nurture student of Allen was standing at Kota platform in front of 3rd coach (start) of Rajdhani
Express. If train starts moving with constant acceleration 3rd coach crosses the student in 5 sec.
Then which coach will pass the student after 10 sec from start.

4) A man jumps from a stationary helicopter which is situated at a height of 100 m. The man opens
the parachute after falling a distance 80 m and finally reaches the ground at 10 m/s. If net

retardation of man after opening parachute is a (in m/s2) find .

5) Three very large identical metal plates are given charges as shown. The final charge on left

surface of IInd plate is found to be NQ. Find out the value of N.

6) A point charge q is placed at distance 3R from center of a neutral conducting sphere as shown in

the figure. Find the potential of point A (in V) if = 18 V:

CHEMISTRY

SECTION-I (i)

1) In a galvanic cell , the salt bridge -

(A) Does not participate chemically in the cell reaction

(B) Stops the diffusion of ions from one electrode to another
(C) Is necessary for the occurence of the cell reaction
(D) Ensures mixing of the two electrolytic solutions

2) Which of the following is correct order of electronegativity :

(A) Cs > Rb > Na

(B) Li < Be < B
(C) C < N < O
(D) Cl > F > Br

3) Select the correct order according to their giver properties.

(A) F > Cl > Br > I [Order of Electronegativity]

(B) F– > Cl– > Br– > I– [Order of Hydrated radii]
(C) F– > Cl– > Br– > I– [Order of Ionic radii]
(D) F– > I– > Cl– > Br– [Order of Electrical Conductivity]

4) Which of the following statements are correct for an electron that has the quantum number n = 4
and m = 2 ?

(A)
The electron may have the quantum number, ms = +
(B) The electron may have the quantum number, =2
(C) The electron may have the quantum number, m = 2
(D) The electron may have the quantum number, = 0, 1, 2.

5) For a first order reaction : A(g) → 2B(g)

(A) Half life of reaction is 10 sec
(B) Value of rate constant for reaction is 6.93 × 10–3 sec–1
(C) Total pressure at t = 50 sec will be 126 mm of Hg
(D) Reaction must be a complex reaction

6) An aqueous solution of hydrazine (N2H4) is electrochemically oxidized by O2, thereby releasing

chemical energy in the form of electrical energy. One of the products generated from the
electrochemical reaction is N2(g).
Choose the correct statement(s) about the above process :

OH– ions react with N2H4 at the anode to form N2(g) and water, releasing 4 electrons to the
(A)
anode.
At the cathode, N2H4 breaks to N2(g) and nascent hydrogen released at the electrode reacts with
(B)
oxygen to form water.
(C) At the cathode, molecular oxygen gets converted to OH–.
(D) Oxides of nitrogen are major by-products of the electrochemical process.

7) For a solution formed by mixing liquids L and M, the vapour pressure of L plotted against the
mole fraction of M in solution is shown in the following figure, here XL and XM represent mole
fractions of L and M, respectively, in the solution. the correct statement(s) applicable to this system
is(are)

Attractive intramolecular interactions between L–L in pure liquid L and M–M in pure liquid M
(A)
are stronger than those between L–M when mixed in solution
The point Z represents vapour pressure of pure liquid M and Raoult's law is obeyed when
(B)
XL → 0
(C) The point Z represents vapour pressure of pure liquid L and Raoult's law is obeyed when XL → 1
The point Z represents vapour pressure of pure liquid M and Raoult's law is obeyed from XL = 0
(D)
to XL = 1

8) Which of the following complexes is/are an example of homoleptic complex ?

2⊝
(A) [PtCl4]
(B) K3[Fe(CN)6]
(C) [Cr(NH3)3Cl3]
 ⊕
(D) [CoBr2(en)2]

SECTION-I (ii)

Common Content for Question No. 1 to 2

List-I List-II
(Electrolysis using inert electrode) (Product at anode or cathode.)

(P) Aqueous solution of sodium acetate (1) H2

(Q) Aqueous solution of sodium formate (2) CO2

(R) Concentrated aqueous solution of NaCl (3) Cl2

(S) Dilute aqueous solution of HCl (4) C2H6

(5) O2

(6) Na

1) Identify the correct option

(A) P → 1, 3
(B) Q → 1, 4
(C) R → 1, 3
(D) S → 4, 6

2) The correct option is

(A) P → 1, 6
(B) Q → 2, 5
(C) R → 3, 4
(D) S → 1, 5

Common Content for Question No. 3 to 4

Match the following:

Column–I (Orbital) Column–II (Property)

(P) s (1) Have electron density at all three axes

(Q) px (2) YZ plane is nodal plane

(R) dxy (3) dumbell shape

(S) (4) have azimuthal quantum no. ℓ = 2

(5) xy plane is nodal plane

(6) double dumbell shape

3) Find the correct option

(A) P → 1, 2
(B) Q → 2, 3, 5
(C) R → 2, 4, 6
(D) S → 1, 4, 5

4) Identify the correct option

(A) P → 1, 5
(B) Q → 2, 3
(C) R → 2, 5
(D) S → 4, 5

SECTION-II

1) Two moles of AgCl get precipitated when one mole of an octahedral co-ordination compound with
empirical formula CrCl3.3NH3.3H2O reacts with excess of silver nitrate. The number of chloride ions
satisfying only the primary valency of the metal ion is________ .

2)

The oxidation state of iron in Na4[Fe(CN)5(NOS)] is :

3) For how much time in seconds a current of 2A has to be passed through a solution of AgNO3 to
coat a metal surface of 80 cm2 with 5 μm thick layer? Density of silver = 10.8g cm–3.

4) Dal lake has water 8.2 ×1012 litre approximately. A power reactor produces electricity at the rate
of 1.5 × 106 coulomb per second at an appropriate voltage. How many million years would it take to
electrolyse the lake?
[1 million = 106]

5) The half life time for the first order decomposition of a substance dissolved in CCl4 is 2.5 hour at
30ºC. How much of the substance will be left (in gram) after 10 hours, if the initial weight of the
substance is 160 gm

6) The cryoscopic constant for acetic acid is 3.6 K kg/mol. A solution of 1 g of a hydrocarbon (CXHY)
in 100 g of acetic acid freezes at 16.14°C instead of the usual 16.60°C. The hydrocarbon contains
92.3% carbon. Find value of (X + Y) ?
[Give your answer as sum of digits till you get single digit number]

MATHEMATICS

SECTION-I (i)
1) Let L be the number of digits in 340 before decimal and M be the number of zeroes in 3–40 after
decimal before significant digit, then
[Use-log10(3) = 0.4771]

(A) L + M = 39
(B) L – M = 2
(C) L – M = 1
(D) L + M = 38

2) If logax = b for permissible values of a and x, then identify the statement(s) which can be correct

(A) If a and b are two irrational numbers, then x can be rational

(B) If a is rational and b is irrational, then x can be rational
(C) If a is irrational and b is rational, then x can be rational
(D) If a is rational and b is rational, then x can be rational

3) If = ℓ (finite real number) then -

(A) ℓ = 4
(B) C = –6
(C) C = 4
(D) C ∈ R

4)

If log0.3 (x – 1) > log0.09 (x – 1) then x ∊ (a, b), then a + b is

(A) odd integer

(B) prime number
(C) negative integer
(D) positive integer

5) If , , ,
then

(A)

(B)

(C)

(D)
6) If , then

Maximum value of x2 + y2 is
(A)

(B) Maximum value of x2 + y2 is 4

(C)
Minimum value of x2 + y2 is
(D) Minimum value of x2 + y2 is 3

7)

Which of the following is/are correct ?

(A)
If , then

(B)
If , then x > 6

(C)
If , then x < 6

(D)
If , then x is a rational number

8) On the set of real numbers, let R be a relation aRb iff is an irrational no, then R is

(A) not symmetric relation

(B) not reflexive relation
(C) not transitive relation
(D) equivalence relation.

SECTION-I (ii)

Common Content for Question No. 1 to 2

Appropriately matching the lists based on the information given in the paragraph.

List-I List-II

Let f : R → R and the roots of equation

(I) which also satisfy equation f(x) = x (P) 1
will be

(II) Let f : [5, 10] onto [4,17], the integers in the range of is/are (Q) 5

Let f(x) = 8cot–1(cot x) + 5sin–1(sin x) + 4tan–1(tan x) – sin (sin–1x), then

(III) (R) 10
possible integral values which f(x) can take
 Let 'a' denotes the roots of equation

(IV) (S) 15
then possible values of where[.] denotes the greatest integer function
will be

(T) –3

(U) 0

1) Which of following is correct combination?

(A) (I) (P) (R)

(B) (I) (Q) (R)
(C) (II) (Q) (R) (S)
(D) (II) (P) (S)

2) Which of following is correct combination?

(A) (III) (P) (Q) (T) (U)

(B) (III) (P) (Q) (R) (U)
(C) (IV) (P) (R)
(D) (IV) (Q) (S)

Common Content for Question No. 3 to 4

Appropriately matching the lists based on the information given in the paragraph.

List-I List-II

Let ƒ(x) be an even function satisfying for every x ∈ R and

(I) (P) 0

Find value of ƒ(–89) – ƒ(–67) + ƒ(46)

Let ƒ(x) be a function such that 2ƒ(x) + ƒ(–x) = cosx for every real number x. The
(II) (Q) 1
value of |3ƒ(π)| is

(III) (R) 2
If , then is equal to

(IV) (S) 4
where 1 < x < 2, then ƒ(x) is tending towards

3) Which of the following options is the only CORRECT combination ?

(A) I S
(B) II P
(C) III R
(D) IV Q
4) Which of the following options is the only CORRECT combination ?

(A) I P
(B) II Q
(C) III R
(D) IV P

SECTION-II

1) Number of integers in the domain of ƒ

2) then λ is equal to

3) Consider ƒ(x) = sin–1[2x] + cos–1([x] –1) (where [.] denotes greatest integer function.) If domain of

ƒ(x) is [a,b) & the range of ƒ(x) is {c,d} then a + b + is equal to (where c < d).

4) The least integral value of 'λ' for which the expression (λx2 – 4x + 3λ + 1) is positive for all x ∈ R,
is

5) If x2 – 9αx – 10β = 0 have roots γ and δ, x2 – 9γx – 10δ = 0 have roots α and β. (α, β, γ, δ are

distinct real numbers), then the value of is

6)

The graph of the function y = f(x) is shown below.

If
then find the value of
[Note: [K] denotes greatest integer less than or equal to K]
 ANSWER KEYS

PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6 7 8
A. A,D A,B,C,D A,B A,B,C,D B,D B,D A,B,C A,B,C

SECTION-I (ii)

Q. 9 10 11 12
A. B B B D

SECTION-II

Q. 13 14 15 16 17 18
A. 2000.00 8.00 6.00 3.00 2.00 6.00

CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24 25 26
A. A,C B,C A,B A,B,C A,C A,C A,C A,B

SECTION-I (ii)

Q. 27 28 29 30
A. C D C B

SECTION-II

Q. 31 32 33 34 35 36
A. 2.00 2.00 193.00 1.84 to 1.87 10.00 3.00

MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42 43 44
A. A,C A,B,C,D A,B A,B,D B,C,D A,C A,C,D A,B,C

SECTION-I (ii)

Q. 45 46 47 48
A. C C A B
 SECTION-II

Q. 49 50 51 52 53 54
A. 5.00 1.50 4.00 2.00 3.00 8.00
 SOLUTIONS

PHYSICS

1) Explain Question: An object starts from rest with constant acceleration of 2 m/s² and
statements about velocity and displacement after 2 seconds are asked.
Concept: Use kinematic equations.
Solution:
v = at

s = ut + at2
Final Answer: (A,D)

2)

Question Explanation:
A particle is projected with speed 40 m/s.
At maximum height its speed becomes 20 m/s.
Check the correct statements.

Concept:
At maximum height, vertical velocity becomes zero, so speed equals the horizontal component.

Solution:

Vertical component:

Time of flight:

Range:

Maximum height:

Final Answer: (A,B,C,D)

3) Explain Question: Different continuous charge distributions are given and electric field at
point P is compared.
Concept: Use electric field expressions for charge distributions.
Solution:
Electric field at ∴

E|| =

and for charged circular arc E = Final Answer: (A,B)

4) Explain Question: A charged particle is released in a position-dependent electric field.

Concept: Convert electric force into equation of motion and identify SHM.
Solution:

m = 5kg

(a) F ∝ – x
so motion of charge particle is oscillatory
(b) F = 0 at x = 2
oscillation about x = 2
so maximum displacement is 4
F = 10 – 5x

a=
a=2–x
a = – (x – 2)
so ω2 = 1
ω=1
(c) vmax = Aω
A=2
ω=1
vmax = 2
(d) velocity at mean position
at x = 2
Final Answer: (A,B,C,D)

5) Explain Question: A charged particle moves in a region where electric potential varies as
V=ax².
Concept: Relate potential, field, acceleration and velocity.
Solution:

v = ax2 ⇒ E =
E = –2ax
F = ma
E × q = max
2axq = max
ax ∝ x
ax = kx

vx = kx

vx = ±kx
vx ∝ x
Final Answer: (B,D)

6) Explain Question: Electric fields due to a point charge are given at different coordinates.
Concept: Use vector form of electric field.
Solution:

Final Answer: (B,D)

7) Explain Question: A potential-position graph for two charges is given.

Concept: Use slope of potential graph to analyze field.
Solution:
q1 > 0 and q2 < 0 ;
But let x = –∞ potential is positive
So. |q1| > |q2|
At A and B points the electric field is not zero, so they are not equilibrium points.
At point C, and it is unstable equilibrium
Final Answer: (A,B,C)

8)
Question Explanation: Two masses m and 4m start from rest at infinite separation and move
toward each other under mutual gravitational attraction. We are asked about their total
mechanical energy, total kinetic energy, and relative velocity at a separation r.
Concept: This question is based on conservation of mechanical energy and conservation of
linear momentum.
Solution:
1. Total Mechanical Energy: Initial at r → ∞: Ui = 0, Ki = 0 → Ei = 0
By energy conservation, total mechanical energy at any separation r: E = 0
Option 1 correct.
2. Linear Momentum:
Total momentum = 0 → m v₁ + 4m v₂ = 0 → v₁ = −4 v₂
3. Total Kinetic Energy:
At separation r: Uf = −4 G m² / r
Kf + Uf = 0 → Kf = 4 G m² / r
Option 3 correct.
4. Relative Velocity:
Kf = ½ m v₁² + ½ (4m) v₂² = ½ m (16 v₂²) + 2 m v₂² = 10 m v₂²
10 m v₂² = 4 G m² / r → v₂ = √(2 G m / 5 r)
v₁ = 4 v₂ → relative velocity vrel = |v₁| + |v₂| = 5 v₂ = √(10 G m / r)
Option 2 correct.
Final Answer: Option (1), (2) and (3)

9) Explain Question: Conductors with charges are given and matching of induced charges is
asked.
Concept: Conductors
Solution:
Charge induced on surface -1 is –Q, so charge on surface -2 is +Q.
Final Answer: (B)

10) Explain Question: Grounded conductors with charge distribution are given and correct
matching is asked.
Concept: Conductors
Solution:

Since inner conductor is grounded, charge on this inner conductor would be .

So charge on surface -1 will be and charge on surface will be . (Since total charge on
outer conductor is +Q.)
Final Answer: (B)

11) Explain Question: Position-time equations are given and correct motion statements are
asked.
Concept: Motion with variable acceleration
Solution:
(P) x = a + bt + ct2

v= → (1, 5)
At t = 0
 a= x = a & v = b. & velocity will never zero
(Q) x = bt–ct2

v= → (1,2,3,5)
at t = 0

a= x = 0 velocity may be zero

v=b
(R) x = a – ct2
→ (1,4,5)

v= At t = 0
x=a

a= v=0
(S) x = ct2

v= → (1,3,4,5)
At t = 0

a= x=0
v=0
Final Answer: (B)

12) Explain Question: Different position equations are given and correct matching is asked.
Concept: Motion with variable acceleration
Solution:
(P) x = a + bt + ct2

v= → (1, 5)
At t = 0

a= x = a & v = b. & velocity will never zero

(Q) x = bt–ct2

v= → (1,2,3,5)
at t = 0

a= x = 0 velocity may be zero

v=b
(R) x = a – ct2
→ (1,4,5)

v= At t = 0
x=a

a= v=0
(S) x = ct2
 v= → (1,3,4,5)
At t = 0

a= x=0
v=0
Final Answer: (D)

13) Explain Question: Find the potential difference

Concept: Wext = qΔV
Solution:
Work done

Final Answer: (2000.00)

14) Question Explanation:

Finding the radius of a planet from projectile motion data.

Concept:
Conservation of Mechanical Energy.

Solution:

(R + 900 × 103) × 8 × 106 = 10 × R × 900 × 103

R = 72 × 105 m ⇒ 7200 km .

Final Answer:
Correct answer is 8.

15) Explain Question: Coach number passing a student is required..

Concept: Use uniformly accelerated motion.
Solution:
Length of 3rd coach

=
length crossing after 10 sec.

ℓ1 =
= 50a
= 4ℓ
= 4 coaches (including 3rd)
= 6th coach
Final Answer: (6)

16) Explanation: The problem describes a man jumping from a stationary helicopter at 100
m. He opens a parachute after falling 80 m and reaches the ground at 10 m/s. we need to find

the net retardation due to the porachute 'a' and then calculate
Concept:
Kinematics, free fall, Retardation.

Solution:
Velocity of man after falling 80 m under gravity (free fall)
V2 = 0 + 2 × (-10) (-80)
V = 40 m/s
downwards
Now the man travels next 20 m with
retardatioon due to parachute
Final velocity = 10 m/s, uinitial = 40 m/s
(–10)2 = (–40)2 + 2 × (a) (–20)
40a = 1600-100 = 1500

a= = m/s2

So value of

Final answer : 3

17) Explain Question: Final charge on conducting plates is required.

Concept: Use charge redistribution.
Solution:
Charge on two end surfaces will be

Charge distribution

Final Answer: (2)

18) Explain Question: Potential near a conducting sphere is required.

Concept: Use conductor potential properties.
Solution:

0
V = VA = = 6V
 Final Answer: (6)

CHEMISTRY

19) Question Explanation:

Find correct option about salt bridge.
Concept:
galvanic cell.
Solution:
Salt bridge electrolytes are inert and do not participate chemically in the cell reaction (1).
It completes the internal circuit and maintains electrical neutrality, making it necessary for the
occurrence of the cell reaction (3).
Final Answer:
Option 1 & 3

20)

Question Explanation : Identify the correct electronegativity trends.

Concept : Periodic trends in electronegativity.
Solution :
Electronegativity increases across a period from left to right due to increased nuclear charge
and decreases down a group as atomic size increases.

A. Option 2: Li,Be, and B are in the same period; electronegativity increases as we move right
(Li<Be<B).
B. Option 3: C,N, and O are in the same period; electronegativity increases as we move right
(C<N<O).
C. Options 1 and 4 are incorrect because electronegativity decreases down the group
(Na>Rb>Cs and F>Cl>Br).

Final Answer : Option (2) and (3)

21) Explain Question: Identify the correct order according to their giver properties
Concept: Properties of Halogens
Solution:
F > Cl > Br > I [Order of Electronegativity]
F– > Cl– > Br– > I– [Order of Hydrated radii]
Final Answer: (AB)

22)

Question Explanation: Select correct statement for electron having n = 4 and m = 2.

Concept: This question is based on Quantum number.
Solution:

n ℓ m s may be + or –
4 0 0
1 –1, 0, +1
 2 –2, –1, 0, +1, +2
3 –3, –2, –1, 0, +1, +2, +3
Therefore all statements are correct.
Final Answer: (ABC).

23)

Explain Question: Identify the correct relation

Concept: First order kinetics
Solution:

A → 2B
t=0 64
t=t (64–x) 2x

t=∞ 0 2×64

PTotal = 64–x + 2x
= 64 + x
t = 20 : x = 48
t = 40 : x = 60

k=
at t = 50 sec

⇒ 5ln 2 = ln

⇒ ⇒ 64 - x = 2
x = 62
⇒ So, at t = 50 sec
PT = 64 + 62 = 126 mm of Hg
Final Answer: (AC)

24)

Explain Question: Choose the correct statement(s) about the above process :
Concept: Electrolysis of aqueous N2H4
Solution:
Anode : N2H4(aq) + 4OH–(aq) → N2(g) + 4H2O(l) + 4e–
Cathode : 2H2O(l) + O2(g) + 4e– → 4OH–(aq)
Final Answer: (AC)

25)

Explain Question: Identify the correct statement(s) applicable to this system is(are)
Concept: Characterstics of solution shows positive deviation form Raoult’s law.
Solution:
 → solution showing positive deviation from Raoult's law
∴ L-M interactions are weaker than L-L & M-M interactions.
Final Answer: (AC)

26)

Explain Question: Identify the correct example of homoleptic complex

Concept: Heteroleptic complex have different ligands.
Solution:
Homoleptic complexes are those in which all ligands are identical in coordination sphere.
Final Answer: (AB)

27)

Explain the question: The goal is to match each electrolysis process listed in List-I with the
corresponding chemical products formed at the cathode or anode listed in List-II.
Concept: Electrolysis of aqueous solutions depends on the preferential discharge of ions
based on their reduction/oxidation potentials and concentrations, as well as specific reactions
like Kolbe's electrolysis for organic salts.
Solution:

A. (P) Aqueous solution of sodium acetate (CH3COONa) :

A. At cathode: H2O is more easily reduced than Na+, yielding H2 (1).
B. At anode: Kolbe's electrolysis occurs: 2CH3COO → C2H6 + 2CO2 + 2e–. Products are
CO2 (2) and C2H6 (4).
C. Matches: 1, 2, 4.
B. (Q) Aqueous solution of sodium formate (HCOONa):
A. At cathode: Water reduction gives H2 (1).
B. At anode: Kolbe's electrolysis for formate is 2HCOO– → H2 + 2CO2 + 2e–. Products are
H2 (1) and CO2 (2).
C. Matches: 1, 2.
C. (R) Concentrated aqueous solution of NaCl (Brine):
A. At cathode: Water reduction gives H2 (1).
B. At anode: High concentration of chloride ions allows Cl oxidation over water due to
overpotential effects. Product is Cl2 (3).
C. Matches: 1, 3.
D. (S) Dilute aqueous solution of HCl:
A. At cathode: H+ ions are reduced to H2 (1).
B. At anode: In dilute solution, the low concentration of Cl means water is oxidized
preferentially to produce oxygen gas, O2 (5).
C. Matches: 1, 5.

Final Answer: (C)

28)

Explain the question: The goal is to match each electrolysis process listed in List-I with the
corresponding chemical products formed at the cathode or anode listed in List-II.
Concept: Electrolysis of aqueous solutions depends on the preferential discharge of ions
 based on their reduction/oxidation potentials and concentrations, as well as specific reactions
like Kolbe's electrolysis for organic salts.
Solution:

A. (P) Aqueous solution of sodium acetate (CH3COONa) :

A. At cathode: H2O is more easily reduced than Na+, yielding H2 (1).
B. At anode: Kolbe's electrolysis occurs: 2CH3COO → C2H6 + 2CO2 + 2e–. Products are
CO2 (2) and C2H6 (4).
C. Matches: 1, 2, 4.
B. (Q) Aqueous solution of sodium formate (HCOONa):
A. At cathode: Water reduction gives H2 (1).
B. At anode: Kolbe's electrolysis for formate is 2HCOO– → H2 + 2CO2 + 2e–. Products are
H2 (1) and CO2 (2).
C. Matches: 1, 2.
C. (R) Concentrated aqueous solution of NaCl (Brine):
A. At cathode: Water reduction gives H2 (1).
B. At anode: High concentration of chloride ions allows Cl oxidation over water due to
overpotential effects. Product is Cl2 (3).
C. Matches: 1, 3.
D. (S) Dilute aqueous solution of HCl:
A. At cathode: H+ ions are reduced to H2 (1).
B. At anode: In dilute solution, the low concentration of Cl means water is oxidized
preferentially to produce oxygen gas, O2 (5).
C. Matches: 1, 5.

Final Answer: (D)

29) Question Explanation: Match the column

Concept: This question is based on shape of orbitals
Solution:

orbital electron density at all three axis Nodal plane

s at all three axis zero

px at x - axis yz

dxy in xy plane yz, xz

at x and y axis two angular nodal plane

2 2
For dx –y & dxy orbitals value of ℓ = 2
Final Answer: (C)

30) Question Explanation: Match the column

Concept: This question is based on shape of orbitals
Solution:

orbital electron density at all three axis Nodal plane

s at all three axis zero

px at x - axis yz
 dxy in xy plane yz, xz

at x and y axis two angular nodal plane

For dx2–y2 & dxy orbitals value of ℓ = 2
Final Answer : (B)

31) Explain Question: Calculate the number of chloride ions satisfying only the primary
valency of the metal ion
Concept: Werner's Theory
Solution:
Mole of AgCl precipitated is equal the mole of Cl– present in ionization sphere.

Since one Cl– is present in the co-ordination sphere. Therefore answer is two.
Final Answer: (2.00)

32)

Question Explanation: Find the oxidation state of iron in Sodium Nitroprusside.

Concept: Oxidation State Calculation
Solution: In we sum the charges of the cations, central metal, and
ligands to equal zero.

Final Answer: 2.00

33) Question Explanation: Question is asking about time to deposit silver

Concept: This question is based on Faraday's law
Solution:
Ag+ + e → Ag(s)

V.f = 1,

or, ( W = d × V)

or, A = Area in cm2

d = density in g/ml. x = thickness in cm
x = 5 × 10–6 m = 5 × 10–4 cm

or,
or,
= 2 × 96.5 sec = 193 sec.

Final Answer: (193.00)

34) Question Explanation: Question is asking about number of million years would it take to
electrolyse the lake
Concept: This question is based on Faraday's law
Solution:
H2O(ℓ) = 8.2 × 1012L = 8.2 × 1015 ml = 8.2 × 1015g
∵ d = 1g(ml)
i = 1.5 × 106 C/sec

n = 2(1– 0) = 2 ∴

or, = 5.86 × 1013 sec.

= years = 1.86 × 106 yrs.

= 1.858 M years
Final Answer: 1.84-1.87

35)

Question Explanation: Find How much of the substance will be left (in gram) after 10 hours
Concept: First order reaction
Solution:
Given: Half-life (t1/2) = 2.5 hours, Initial amount (N0) = 160 gm, Total time (t) = 10 hours.

Number of half-lives

The amount of substance left (Nt) for a first-order reaction is given by .

After 10 hours, 10 gm of the substance will be left.

Final Answer: (10.00)

36) Question Explanation: Find value of (X + Y)

Concept: This question is based on cryoscopy.
Solution:
Kf(CH3COOH) = 3.6 K–kg/mol; mass of hydrocarbon = 1g; mass of CH3COOH = 100 g = 0.1
kg;
ΔTf = 16.6 – 16.14 = 0.46 °C
If the molecular mass of hydrocarbon (CxHy) = M; then applying the formula of depression in
freezing point;
 ΔTf = Kf × m × i ⇒ 0.46 = 3.6 ×

wt. of carbon in hydrocarbon =

⇒ moles of
⇒ wt. of hydrogen in the hydrocarbon = 78.26 – 72.23 = 6.03
⇒ moles of hydrogen = 6.03
⇒ Molecular formula of hydrocarbon = C6H6
Compare with (CxHy) so X = 6 and Y = 6
So, X + Y = 12 ⇒ 1 + 2 = 3
Final Answer: (3.00)

MATHEMATICS

37) Explain the Question : We are given 2 numbers we need to find number of digits &
number of zeff after decimal respectively.
Concept : This question is based on characteristic and mantissa.
Solution :
Let A = 340
⇒ log10A = 40log103
= 40 × 0.4771
= 19.084
∴ L = number of digits = 20
& B = 3–40
⇒ log10B = –40 × 0.4771
= –19.084
∴ M = number of zeros after decimal = 19
L + M = 39 & L–M = 1
Final Answer: (A,C)

38) Explain Question: Determine the correctness of statements regarding the nature
(rational or irrational) of x when given the logarithmic relationship across different
rational/irrational combinations of base a and exponent b.
Concept: Logarithmic definitions, conversion to exponential forms (x = ab), and properties of
rational or irrational exponentiation.
Solution:

(A) For which is rational.

(B) For which is rational
(C) For and b = 2; x = 2
(D) The option is obviously correct.
Final Answer: (A, B, C, D)

39) Explain Question: Find the value of the unknown constant C and the final finite real limit
value l for the given rational function as x approaches 3.
Concept: Limits of indeterminate forms (0/0 form), polynomial factorization, and evaluation of
continuous functions.
Solution:
For the limit to be a finite real number, the numerator must be zero at x = 3 because the
denominator becomes zero.
Numerator at .
With C = -6, numerator is .

.
Final Answer: (A, B)

40) Explain Question: Solve the logarithmic inequality to find the interval (a, b) for x, and
classify the sum of the boundary values a + b.
Concept: Logarithmic inequalities with bases between 0 and 1, base-change formula, domain
of logarithmic functions, and properties of numbers.
Solution:

Final Answer: (A, B, D)

41) Explain Question: Given log x and log y, evaluate the mathematical relationship between
two multi-layered inverse trigonometric logarithmic expressions M and N.
Concept: Properties of logarithms and simplification of composite inverse trigonometric
identities (such as arcsin, arccos, and arctan).
Solution:

Final Answer: (B, C, D)

42) Explain Question: Given an inverse trigonometric equation containing x and y, find the
maximum and minimum possible values for the expression x2 + y2.
Concept: Domain restrictions of inverse trigonometric functions, geometric/algebraic
simplification of , and optimization of multivariate functions.
Solution:

⇒
 ⇒
⇒

Max. value of x2 + y2 is

Min. value of x2 + y2 is
Final Answer: (A, C)

43) Explain Question: Evaluate the validity of separate algebraic options involving
logarithmic systems, properties of reciprocal bases, and nested logarithmic inequalities.

Concept: Rationalization inside logarithms, change-of-base rule ( ), logarithmic

addition, and solving simple nested log equations.
Solution:

(A)
(C) log27 + log29 = x ⇒ log263 = x
∴ x<6
(D) log3(log1/2x) = 0
⇒ log1/2x = 1

Final Answer: (A, C, D)

44) Explain Question: Analyze whether a relation defined on the set of real numbers where
is reflexive, symmetric, transitive, or an equivalence relation.
Concept: Definitions and testing conditions for reflexive, symmetric, and transitive relations
using counterexamples involving rational/irrational bounds.
Solution:
Take

, does not irrational number

Final Answer: (A, B, C)

45) Explain Question: Identify the correct match combination between a set of
functional/algebraic equations in List-I and their corresponding solution outcomes listed in
List-II.
Concept: Composite functions ( , function range mapping (onto functions), greatest
integer constraints, and inverse trigonometric function behaviors.
Solution:
(I) f2(x) = f(f(x)) = f(x) = x
 f3(x) = f(f2(x) = f(x)) = x
⇒ x3 – 25x2 + 175x – 375 = 0
(x – 5) (x2 – 20x +75) = 0
(x – 5)2 (x – 15) = 0
⇒ x = 5, 15 ⇒ Q, S
(II) Range of f(f(f(x))) is [4, 17] ⇒ Q, R, S
Domain of f(x) is [–1, 1]
(III) if x ∈ [–1, 0), f(x) = 8(x + π) + 5x + 4x – x = 16x + 8π
f(x) ∈ [8π – 16, 8π]
If x ∈ (0, 1], f(x) = 8x + 5x + 4x – x = 16x
f(x) ∈ (0, 16] ⇒ P, Q, R, S
(IV) x ∈ [–1, 0]

x ∈ [0, 1]

1 + x2 = 2x ⇒ x = 1 ⇒ |10a| = 10

⇒ P, R
Final Answer: (C)

46) Explain Question: Identify another uniquely correct match combination for the same
paragraph list items linking functional equations to their respective numerical outputs.
Concept: Piecewise functional domains, composite limits, solving radical transcendental
equations, and greatest integer function computations ( ).
Solution:
(I) f2(x) = f(f(x)) = f(x) = x
f3(x) = f(f2(x) = f(x)) = x
⇒ x3 – 25x2 + 175x – 375 = 0
(x – 5) (x2 – 20x +75) = 0
(x – 5)2 (x – 15) = 0
⇒ x = 5, 15 ⇒ Q, S
(II) Range of f(f(f(x))) is [4, 17] ⇒ Q, R, S
Domain of f(x) is [–1, 1]
(III) if x ∈ [–1, 0), f(x) = 8(x + π) + 5x + 4x – x = 16x + 8π
f(x) ∈ [8π – 16, 8π]
If x ∈ (0, 1], f(x) = 8x + 5x + 4x – x = 16x
f(x) ∈ (0, 16] ⇒ P, Q, R, S
(IV) x ∈ [–1, 0]
 x ∈ [0, 1]

1 + x2 = 2x ⇒ x = 1 ⇒ |10a| = 10

⇒ P, R
Final Answer: (C)

47) Explain Question: Determine the correct matching pair linking a functional or limit
property item from List-I to its precise answer option in List-II.
Concept: Periodic functions ( ), even/odd adjustments, solving functional system
equations, piecewise limits, and infinite logarithmic products.
Solution:
(I) ƒ(x) = ƒ(x + 8)
⇒ Periodic function with period 8

ƒ(–89) – ƒ(–67) + ƒ(46)

= ƒ(–1) – ƒ(–3) + ƒ(–2)
=3–1+2=4
(II) 2ƒ(x) + ƒ(–x) = cosx ...I
replace x by –x
2ƒ(–x) + ƒ(x) = cosx ...II

solving I & II
|3ƒ(π)| = 1

(III)
(IV) (log2x) (log2x) .....∞ = 0 for 1 < x < 2
⇒ ƒ(x) = 4
Final Answer: (A)

48) Explain Question: Choose the only correct combination linking a separate functional
property sequence from List-I to its valid calculation value from List-II.
Concept: Periodic function reductions, continuous functional substitutions, evaluation of
composite limit loops, and infinite series evaluation.
Solution:
(I) ƒ(x) = ƒ(x + 8)
⇒ Periodic function with period 8

ƒ(–89) – ƒ(–67) + ƒ(46)

= ƒ(–1) – ƒ(–3) + ƒ(–2)
=3–1+2=4
(II) 2ƒ(x) + ƒ(–x) = cosx ...I
replace x by –x
2ƒ(–x) + ƒ(x) = cosx ...II

solving I & II
|3ƒ(π)| = 1

(III)
(IV) (log2x) (log2x) .....∞ = 0 for 1 < x < 2
⇒ ƒ(x) = 4
Final Answer: (B)

49) Explain Question: Find the total count of valid integers that lie within the permissible
mathematical domain of the provided square-root function containing inverse trigonometric
expressions.
Concept: Domain constraints for square roots ( ) and inverse functions
(), alongside decreasing behavior properties of .
Solution:

Final Answer: (5.00)

50) Explain Question: Solve an infinite summation of an inverse tangent series to determine
the exact equivalent value of the parameter .
Concept: Telescoping series expansion utilizing the inverse trigonometric identity

.
Solution:

Final Answer: (1.50)

51) Explain Question: For a given function containing nested greatest integer operations,
determine its domain and distinct range elements to evaluate the value of the expression

.
Concept: Greatest Integer Function ( ) property constraints, fundamental domain parameters
for and , and range evaluation.
Solution:
ƒ(x) = sin–1[2x] + cos–1([x] – 1)
–1 < [2x] < 1 & –1 < [x] – 1 < 1
⇒ –1 < 2x < 2 & 0 < [x] < 2

⇒ & 0<x<3
⇒ 0 < x < 1 Domain
⇒ [x] = 0 ⇒ 0 < 2x < 2
⇒ [2x] = 0 or 1
Now ƒ(x) = sin–1[2x] + cos–1(–1)

= π or

⇒
Final Answer: (4.00)

52) Question Explanation: In this question we have to find least integral value of 'λ' for
which given expression is positive for all x ∈ R.

Concept: ax2 + bx + c > 0 ∀ x ∈ R ⇒ a > 0 & D < 0 (Here a ≠ 0, b, c ∈ R)

Solution: Given λx2 – 4x + 3λ + 1 = 0 ∀ x ∈ R

⇒ λ > 0 and D < 0 ... (1)
⇒ (–4)2 – 4(λ) (3λ + 1) < 0
⇒ 16 – 12λ2 – 4λ < 0
⇒ 3λ2 + λ – 4 > 0
⇒ (3λ + 4)(λ – 1) > 0
By wavy curve method

... (2)
∴ (1) (2) ⇒ λ ∈ (1, ∞)
∴ least integral value of λ = 2

Final answer: 2

53) Explain Question: Calculate the requested value from two interlocking quadratic
equations whose roots are cross-linked permutations of distinct real numbers and .
Concept: Relations between roots and coefficients of quadratic equations (sum and product of
roots) and algebraic system solving.
Solution:

γ + δ = 9α
γδ = –10β
α + β = 9γ
αβ = –10δ
αβγδ = 100βδ
αγ = 100
α + β + γ + δ = 9(α + γ) ...(1)
⇒ γ2 – 9αγ – 10β = 0
α2 – 9αγ – 10δ = 0
add α2 + γ2 – 18αγ – 10(β + δ) = 0
(α + γ)2 – 20αγ – 80(α + γ) = 0
(α + γ)2 – 80(α + γ) – 2000 = 0
α + γ = 100 ...(2)
⇒ α + β + γ + δ = 900.
Final Answer: (3.00)

54) Question Explanation: Finding the value of an expression based on graphical limits and
GIF.
Concept: Left-hand and right-hand limits from a graph.
Solution:
∴

=
Final Answer : (8)