21-06-2026

1001CJA101016260013 JA

PART-1 : MATHEMATICS

SECTION-I (i)

1) If the data given to construct a triangle ABC is a = 5, b = 7, sinA = , then it is possible to

construct -
[All symbols used have usual meanings in ΔABC]

(A) only one triangle

(B) two triangles
(C) infinitely many triangle
(D) no triangle

2) Number of integral values of x satisfying

4cos2x – 8cosx + 3 > 0, 0 < x < 2π is -

(A) 2
(B) 3
(C) 4
(D) 5

3) Set of all values of such that x2 – kx + 4 = 0 has one root less than 1 and the other root is
greater than 1 is

(A)
(B)
(C)
(D)

4) sin8435° – cos8435° is -

(A)

(B)

(C)

(D)

SECTION-I (ii)
1) Value of x in satisfying the equation , is -

(A)

(B)

(C)

(D)

2) Let f(x) = sin2(x + α) + sin2(x + β) – 2cos(α – β) sin(x + α) sin(x + β). Which of the following is/are
TRUE ?

(A) f(x) is independent of x

(B) f(x) is independent of α
(C) f(x) is dependent on β
(D) f(x) is dependent on α

3) Let and , then the value of (P + Q) is greater than or

equal to

(A) 5048
(B) 5049
(C) 5050
(D) 5051

4) Let A,G,H be arithmetic, geometric and harmonic mean between two given positive numbers x
and y. Then -

(A) A2, AG, AH are in G.P.

(B) Quadratic Ax2 + Gx + H = 0 has imaginary roots
(C) Quadratic Ax2 + Gx + H = 0 has real roots
(D) A > G > H

5) If the equation log2|x| = log4(x2 – 4x + 4) has root x = α and the equation has root
x = β, then

(A) αβ = 8

(B)

(C)

(D)
 SECTION-II (i)

Common Content for Question No. 1 to 2

Let an–1(n–1) = an(n + 1) for n > 2 such that (where n ∈ N).

1) If , then n is equal to -

2) is equal to -

Common Content for Question No. 3 to 4

For the equation

3) If the sum of solution(s) in [0, π] is kπ, then the value of k is

4) The number of solution(s) in is

SECTION-II (ii)

1)

If the equation 2ksinx + 7 = 4k – cos2x possesses a solution for k ∈ [a, b], then (a + b) is equal to

2) Let λ1, λ2 ∈ [0,π] are the solutions of the equation , then

8(sin2λ1 + sin2λ2) is equal to

3) If x = 30°, then the sum of series 1 + cos2x + cos22x + cos32x + ... upto infinite terms is

4) Sum of all the integral roots of , is λ then is

5) If the sides of a triangle are p, q and then the greatest angle is radian where
3k =

PART-2 : PHYSICS
 SECTION-I (i)

1) Which of the following statements is false for a particle moving in a circle with a constant angular
speed ?

(A) The velocity vector is tangent to the circle.

(B) The acceleration vector is tangent to the circle.
(C) The velocity and acceleration vectors are perpendicular to each other.
(D) The acceleration vector points to the centre of circle.

2) The position of a body of mass 2 kg varies with time t as x = t2 + 2t, where x is in meters and t is
in seconds. The work done by all the forces acting on the body during the time interval [2s, 4s] is :

(A) 36 J
(B) 64 J
(C) 100 J
(D) 120 J

3) Consider the system shown in figure. The wall is smooth, but the surfaces of blocks A and B in

contact are rough. The friction on B due to A in equilibrium is :-

(A) upward
(B) downward
(C) zero
(D) the system can not remain in equilibrium.

4) Find acceleration of the lower block :

(A) 4 m/s2
(B) 5 m/s2
(C) 0 m/s2

(D)
m/s2

SECTION-I (ii)

1) A particle is performing circular motion of radius 1m. Its speed is v = (2t2) m/s. Then at t = 1s :
(A) Angular speed is nearly 19.1 rpm
2
(B) Centripetal acceleration, ac = 4m/s
(C) Net acceleration, m/s2
(D) Tangential acceleration,

2) Calculate the following for the situation shown:

(A) Speed at D is .
(B) Normal reaction at D is 3mg.

(C)
Height H is .
(D) Normal reaction at D is 4mg.

3) Refer the system shown in the figure. Block is sliding down the wedge. All surface are frictionless.

Find the correct statement(s)

(A) Acceleration of block is g sinθ

(B) Acceleration of block is g cosθ
(C) Tension in the string is mg cos 2θ
(D) Tension in the string is mg sin θ.cosθ

4) Chose the correct option(s) for the given figure. Assume the pulleys and string to be ideal and
neglect any friction.(aA = acceleration of A, aB = acceleration of B)

2
(A) aB = 1.56 m/s
2
(B) aA = 3.12 m/s
2
(C) aA = 2.34 m/s
2
(D) aB = 4.68 m/s

5) Two particles projected from the same point with same speed u at angles of
projection and strikes the horizontal ground at the same point. If and are the maximum
heights attained by the projectile , R is the range for both and t1 and t2 are their times of flights,
respectively, then

(A)

(B)

(C)

(D)

SECTION-II (i)

Common Content for Question No. 1 to 2

Initially system is in equilibrium. At t = 0 spring connecting 2 kg and 5 kg to be cut. Just after

cutting the spring, answer the following questions. (g = 10 m/s2)

1) Acceleration (in m/s2) of 5 kg block just after cutting the spring :-

2) What is tension (in N) in string just after cutting the spring?

Common Content for Question No. 3 to 4

Consider the following figure.

3) The maximum F (in N) which will not cause motion of any of the blocks is :-

4) The acceleration (in m/s2) of 10 kg block when F = 30 N is :-

SECTION-II (ii)
1) The figure shows two wires tied to a sphere which revolves in a horizontal circle at constant

speed. The mass of the sphere is . At this particular speed the tension is same in both

the wires. The value of tension (in N) is T . is equal to :

2)

The potential energy (in joules) function of a particle in a region of space is given as :

U = (2x2 + 3y3 + 2z) Here x, y and z are in metres. Find the magnitude of x component of force (in
newton) acting on the particle at point P (1m, 2m, 3m).

3) Consider the situation shown in figure. Initially the spring is undeformed when the system is
released from rest. Assuming no friction in the pulley, the maximum elongation of the spring is

xmg/k. Find x?

4) What will be closest distance (in m) of approach between A and B :-

5) A ladder is resting on two mutually perpendicular walls. If ladder starts to slide and velocity of
point B at a certain point when θ is 37°, is 3 m/sec then velocity (in m/s) of point A at this moment is
 PART-3 : CHEMISTRY

SECTION-I (i)

1) Select the CORRECT order of bond angle ?

(A)

(B)
(C) PCl3 > PBr3 > PI3
(D) OH2 < OF2

2) Which among the following can NOT show hydrogen bonding?

(A) HCN
(B) Salicylaldehyde
(C) Chloral hydrate
(D) Para-dichlorobenzene

3) How many moles of neutrons are present in 3.011 × 1022 molecules of H2O2 ?
[Given the elements are and ]

(A) 8
(B) 0.90
(C) 0.80
(D) 0.4

4) Which of the following is NOT CORRECT.

(A) HF > HCl > HBr > HI (Acidic nature)

(B) HF > HI > HBr > HCl (Boiling point)
(C) HF > HCl > HBr > HI (Bond strength)
(D) HF > HCl > HBr > HI (Thermal stability)

SECTION-I (ii)

1) Which of the following statement is / are CORRECT :

(A) On increasing s-character hybrid orbital's energy decreases
(B) Bond angle is generally unaffected due to presence of lone pair
(C) On increasing s-character hybrid orbital's length decreases
(D) Valence shell electron pairs play important role to decide the shape of a molecule

2)

Select the CORRECT order(s) of bond length.

(A)
(B)
(C)
(D)

3)

Which of the following order is/are CORRECT with respect to the given property ?

(A) XeF4 > XeF2 ; dipole moment order

(B) NH3 > PH3 : bond angle
(C) 2p - 2p > 2s - 2p : σ bond strength
(D) NF3 > NH3 : Dipole moment

4) In 2.6 kg of FeSO4 .6H2O (At. wt. of Fe = 56)

(A) Number of atoms of O are 100 × NA

(B) Moles of H-atoms are 120 × NA
(C) Molecules of water of crystallisation are 60 × NA
– 2–
(D) Moles of e present in SO4 are 500

5) Select the process which is / are definitely exothermic (Energy is released):

(A)
(B)
(C)
(D) where A is any element

SECTION-II (i)

Common Content for Question No. 1 to 2

Dithionic acid is sulfur oxyacid that is only known in aqueous solution (in which it behaves as a
strong acid) or in the form of salts containing the dithionate, [S2O6]2–, ion.

1) Oxidation state of S in [S2O6]2– are :

2) Total number of lone pairs present in dithionate are :

Common Content for Question No. 3 to 4

Bent's rule is consistent with Gillespie's VSEPR model, and may provide alternative rationalization
for effect of electronegativity. So it is stated as : 'more electronegative atom not only prefers to stay
in the orbital having more p character but also can increase the p character in its attached orbital
from the central atom depending on the circumstance'. The rule can be applied to explain the effect
of electronegativity on bond angle and bond length.

3) • Consider the following molecules.

PF2Cl3, SF4, XeOF4, SOF4
• If x is number of molecules having two different bond lengths between same pair of atoms.
• y is number of molecules having at least 4 atoms in single plane.

Calculate the value of .

4) Consider the following order against mentioned property

(i) B(OH)3 < B(OH)4– : Bond length (B-O)
(ii) CH3F < CH4 : Bond length (C-H)
(iii) SO2Cl2 > SO2F2 : Bond length (S=O)
(iv) CO < CO2 : Bond length (C-O)
(v) (Cl-F(ax)) = (Cl-F(eq.)) : Bond length in ClF3

SECTION-II (ii)

1) The number of moles of all atoms present in 3 × 1023 molecules of ammonia (NH3) is-
[Given NA = 6 × 1023]

2) How many of the following pairs have dipole-dipole interactions ?

(Na+, H2O) ; (Na+, CCl4) ; (NF3, NCl3) ; (NH3, H2O) ; (BF3, BCl3) ; (HCl, HCl)

3)

If 5.6 litre of O2 gas is taken at 1 atm, 273 K, then no. of oxygen atoms are .........× 1023 (NA = 6 ×
1023)

4) Consider the following molecules :-

x = number of polar species
y = species having atleast one pπ-dπ bond
Find the value of (x × y)

5) Among the following, find out total number of species having planar as well as each bond length is
identical.
SF4, ClF3, , SCl2, PCl5, IF4
 ANSWER KEYS

PART-1 : MATHEMATICS

SECTION-I (i)

Q. 1 2 3 4
A. D C A C

SECTION-I (ii)

Q. 5 6 7 8 9
A. A,D A,C,D A,B,C A,B,D A,C,D

SECTION-II (i)

Q. 10 11 12 13
A. 10.00 0.50 2.00 4.00

SECTION-II (ii)

Q. 14 15 16 17 18
A. 4.00 6.00 2.00 1.50 2.00

PART-2 : PHYSICS

SECTION-I (i)

Q. 19 20 21 22
A. B B D C

SECTION-I (ii)

Q. 23 24 25 26 27
A. A,B A,C,D A,D A,C A,B,C,D

SECTION-II (i)

Q. 28 29 30 31
A. 10.00 0.00 10.00 2.00

SECTION-II (ii)

Q. 32 33 34 35 36
A. 2.00 4.00 4.00 6.00 4.00

PART-3 : CHEMISTRY
 SECTION-I (i)

Q. 37 38 39 40
A. B D C A

SECTION-I (ii)

Q. 41 42 43 44 45
A. A,C,D A,B,C B,C A,C,D A,B,C

SECTION-II (i)

Q. 46 47 48 49
A. 5.00 14.00 1.50 4.00

SECTION-II (ii)

Q. 50 51 52 53 54
A. 2.00 3.00 3.00 18.00 3.00
 SOLUTIONS

PART-1 : MATHEMATICS

1) Question Explanation: In this question, we have to construct a possible triangle using

given values.

Concept: This question is based on sine rule.

Solution: Given a = 5, b = 7,

Using sine rule

⇒
Since –1 < sin B < 1
So, sin B out of range.
∴ No triangle possible.

Final answer: The correct option is (D).

2) Question Explain: We have to find no. of integral values of 'x' from the given inequation,
for 0 ≤ x ≤ 2π

Concept: This question is based on Trigonometric inequalities

Solution: Given
4cos2x – 8cosx + 3 > 0
(2cosx – 3)(2cosx – 1) ≥ 0
as cosx ∈ [–1, 1]

cosx ≥ not possible.

So, 2cosx – 1 ≤ 0

cosx ≤

integral values of x = 2, 3, 4, 5, in

Final Answer: Option (C)

3)
Question Explanation: Find the range of k such that 1 lies between the roots.
Concept: Location of Roots for Quadratic Equations.
Solution: For a quadratic f(x) = ax2 + bx + c with a > 0, if a value d lies between the roots,
the function value at that point must be negative (f(d) < 0).
Given f(x) = x2 – kx + 4 = 0
Condition: f(1) < 0
12 – k(1) + 4 < 0
1–k+4<0
5–k<0 ⇒k>5
k ∈ (5, ∞)
Final Answer: Option (A)

4)

(sin475° – cos475°) (sin475° + cos475°)

– (cos150°) (1 – 2sin275° cos275°)

– (cos150°)

5)

or

6) f(x) = 1 – cos2(x + α) + sin2 (x + β) – 2cos(α – β) sin(x + α) sin(x + β)

= 1 – cos(2x + α + β) cos(α – β) – 2cos(α – β) sin(x + α) sin(x + β)
= 1 – cos(α – β) [cos(2x + α + β) – cos(2x + α + β) + cos(α – β)]
= sin2 (α – β)
a constant function

7)

8) (A) A, G, H are in G.P.

⇒ A2, AG, AH are in G.P.
(B) D = G2 – 4AH = (G2 – AH) – 3AH
= –ve – ve = –ve
(D) AM > GM > HM
9) log2|x| =
⇒ |x| = |x – 2| ⇒ x=1=α
⇒x–3=5 ⇒ x=8=β
So α = 1, β = 8

10) Question Explanation: We have to find value of 'n' when a recurrence relation for an and
an equation involving sum of cubes of ten natural numbers is given.

Concept: This question is based on special sequence.

Solution: Given

Now,

Since

Now,

From question

13 + 23 + 23 +.....+ 103 =

n = 10

Final answer: The correct option is (2).

11) Question Explanation: We have to find value of when a recurrence relation for
an is given.

Concept: This question is based on special sequence.

Solution: Given
Since n ≥ 2

Now,

12) log1/2|[Link]| = 2 ⇒ |sinx cosx| =

or

sum of solution =
= 2π

13) log1/2|[Link]| = 2 ⇒ |sinx cosx| =

or

⇒ Number of solution = 4

14)

⇒ –cos2x – 2ksinx + 4k – 7 = 0
⇒ –1 + 2sin2x – 2ksinx + 4k – 7 = 0
⇒ 2sin2x – 2k sinx + 4k – 8 = 0
⇒ sin2x – k sinx + 2k – 4 = 0
sin2x – 4 – k(sinx – 2) = 0
(sinx – 2) [sinx + 2 – k] = 0
sinx ≠ 2
⇒ sinx = k – 2
⇒ –1 ≤ k – 2 ≤ 1
⇒1≤k≤3
⇒ k ∈ [1,3]

15)

cosx = 2 cos2x – 1
2cos2x – cosx – 1 = 0
2 cos2x – 2cosx + cosx–1 = 0

cosx = 1, cosx =

λ1 = 0,

sin2λ1 + sin2λ2 = 0

16) Put x = 30°

17)
Let log5x = t
t2 + t3 + 1 – t = 1 + t
t3 + t2 – 2t = 0
t = 0, t2 + t – 2 = 0
t = 1, t = –2
log5x = 0, log5x = 1, log5x = –2

x=1 x=5
sum = 6

18) Explain question:

Find the greater angle of the triangle.

Concept:
Apply cosine Law.
 Solution:

Largest side is If largest angle is

then

Final Answer: 2

PART-2 : PHYSICS

19) We have to choose the incorrect option (s) for a particle moving in a circle with a constant
angular speed.
This question is based on kinematics of uniform circular motion.

Uniform angular velocity, so tangential acceleration = 0.

Only centripetal acceleration

20)

x = t2 + 2t

= 2t + 2
Time interval from t = 2s to 4s
At t = 2s, vi = 2(2) + 2 = 6 m/s
At t = 4s, vf = 2(4) + 2 = 10 m/s
using work-energy theorem

wall = ΔKE = KEf – KEi =

= (2)(10)2 – (2)(6)2
= 100 – 36 = 64 J
The work done by all the force acting on the body during the time intervals [2S, 4S] is 64J

21) First Diagram

Second Diagram

For B to be in equilibrium friction of B must be in upward direction. And same for A. Which not
possible. Therefore system can not be in equilibrium.

22)

a50 = 0

23)

∴ tangential acceleration

= ; at = 4t
then at t = 1 sec; at = 4 m/s2

and centripetal acceleration 4 m/s2

Net acceleration =

24)

Correct Answer is (A,C,D)

25)

at t = 0, a = 9 m/sec2
t = 2 sec, a = 9 – 4 = 5 m/sec2
μ(ma) = mg

mg = 100
m = 10 kg

acceleration of block in horizontal direction

acceleration of block in vertical direction

26)

Here

∴ 2T = 70 ×
300 – 3T = 35aB
Solving we get

27) or

and

and

28)
Just after cutting the spring, extension is spring does not instantaneously becomes zero. So,
spring still everts 80 N force on 5 kg block, but tension force can change.

Acceleration of system =
Thus, acceleration of 5 kg block, a = 0 m/s2
29) After cutting, only 5 kg and 3 kg remain connected.
Total weight
Total mass
Acceleration:
Thus both masses move downward with a = g
For
Substitute
Hence the string becomes slack just after cutting

30)

Correct Answer is 10

31)
Max friction between blocks
= 0.1 × 10g = 10N
Max. friction from ground
= 0.3 × 15 g = 45 N

Hence for F ≤ 10N neither upper nor lower block will start sliding. Once F crosses this value
10N friction between blocks becomes kinetic and upper block start slipping on lower block.
But this 10N friction on lower block can not compete with 45N friction on ground, so lower

block will never slide, but upper block will slide with acceleration .

32)
T sin 60° + T sin 30° = mg

33)

U = (2x2 + 3y3 + 2z)

 × compount = 4

34)

Correct Answer is 4

35)

;
In ΔADP

;
⇒ DP = 40 m
⇒ BP = DP – DB = 40 – 30 = 10 m
In ΔBGP

⇒ BG = =6m

36) x2 + y2 = ℓ2

xvB + yvA = 0
xvB =–yvA

|vA| = 4 m/s
PART-3 : CHEMISTRY

37) Explain question:

Correct order of bond Angle.

Concept:

BA EN of CA

Solution:
(1) > > → Incorrect have one lp while have zero lp so >
(2) > CH4 > CH3– → correct
(3) PCI3 > PBr3 > PI3 → Incorrect
(4) OH2< OF2 → Incorrect

Final Answer: Option (B)

38)

The correct answer is option (D)

39)

The correct answer is option (C)

40) Question Explanation: Analyzing periodic trends of hydrides of Group 17 elements.

Concept: Properties of Halogen Hydrides
Solution: Down the group, the size of the halogen atom increases, which weakens the H-X
bond. This makes it easier to release H+ ions, meaning acidic strength actually increases from
HF to HI.
(1) HI > HBr > HCl > HF [Acidic Nature]
(2) HF > HI > HBr > HCl (Boiling point)
(3) HF > HCl > HBr > HI [Bond strength]
(4) HF > HCl > HBr > HI [Thermal stability]
Final Answer: HF > HCl > HBr > HI (Acidic nature) (Option 1 is incorrect)

41) Question Explanation: Evaluating statements regarding hybrid orbitals and molecular
shapes. Concept: Chemical Bonding Principles. Solution: Increasing s-character stabilizes
the orbital (lower energy) and makes it shorter and stronger. Additionally, valence shell
electron pairs (VSEPR) determine the actual shape of a molecule. Statement 1: Correct
(Lower energy). Statement 3: Correct (Shorter length). Statement 4: Correct (Decides
shape). Final Answer: (A), (C), (D)

42)
 Question Explanation : Identify all correct orders of bond length.
Concept : Bond Order and Repulsion. Bond length is inversely proportional to bond order
(BO). Higher BO leads to shorter bonds.
Solution :

1. SO2 > SO3 :

• SO2 has a bond order of 2 .
• SO3 has a bond order of 2 due to resonance.
• However, greater bond pair-bond pair repulsion in SO3 makes its bonds shorter than in SO2.
Statement 1 is correct.

2. H2O2 >O2F2 :
• In O2 F2, the highly electronegative Fluorine pulls electron density away, shortening the O–O bond
to ≈ 1.22Å.
• In , the bond is longer at ≈1.48Å. Statement 2 is correct.

3. P–Cl(eq.) > P–F(ax.)

A. in SF4 :
B. SF4 has a see-saw geometry (trigonal bipyramidal base).
C. Axial bonds experience more repulsion from lone pairs and are typically longer than equatorial
bonds. Statement 4 is incorrect.

Final Answer : Option (A) (B) and (C)

43)

The correct answer is option (B),(C)

44)

n(FeSO4.6H2O) =
number of O-atom = 10 × 10 × NA
moles of H-atom = 10 × 12
molecules of H2O = 10 × 6 × NA
moles of electron in SO42– = 10 × 1 × 50

45) (A)(B) and (C) are exothermic

46)
47)
Total lone pairs = 14

48) x = 2 { SF4, SOF4}

y = 3 {All except SF4}

49) (i), (ii), (iii), (iv)

50) The correct answer is 2

51) Question Explanation:

This question is about identifying dipole-dipole interactions.

Concept: Intermolecular Forces.

Solution:
Dipole-dipole interactions occur between polar molecules (molecules with a permanent net
dipole moment).
(Na+, H2O): Ion-dipole.
(Na+, CCl4): Ion-induced dipole.
(NF3, NCl3): Both are polar. Dipole-dipole.
(NH3, H2O): Both are polar. Dipole-dipole (specifically hydrogen bonding).
(BF3, BCl3): Both are nonpolar. London dispersion forces only.
(HCl, HCl): HCl is polar. Dipole-dipole.
There are 3 such pairs.

Final Answer: 3

52) Question Explanation: Calculate the total number of atoms in a gas sample.
Concept: Mole to Atom Conversion
Solution: First determine moles of gas using molar volume at STP. Multiply moles by
Avogadro's number and the atomicity of the molecule to find the total atoms.

Final Answer: 3.00

53)

Explanation Question:
Find the value of (x + y)
Concept:
This question is based on Dipole moment
Solution:
x = 6(XeO3, SO2, , IF3, BrF5, NH3
y = 3(XeO3, SO2, XeO3F2)
Final Answer: 18.00

54) Question Explain: Find out total number of species having planar as well as each bond
length is identical.

Concept: This question is based on VSEPR theory

Solution:
SCl2, – Bent Planar
, – Linear Planar
IF4–, – Square planar Planar
Final Answer: (3.00)