PYQ Sourabh Raina

SOLUTIONS

questious CI Moalis)
Very short answer type
c o m f o r t a b l e in cold
h y s p e c ies are ? m o r e
W than warm water
a q u a t i c
in
(2018)
water
e a s e s w i t h i ncrease in
u b i l i t y o f o x y gen decr
Ans s o l e r . Hence aq u a t i c s p e c i e s are
u r e o f w a l Solubilityx
lemperat e in wld waber
comfort abl f g a s T e m p e rate
v a n t a g e of L
ma i n a d
teation?
22 stale thaelity over molarity as the unct of loC2ni01 en4)
mol m peralure
ch an ge in l e
Ans Mo N
lality does not change wi th
use
while mo larity decreases with rise intemperat
n
Mola lity=n
ult of solvent
Molatiky" Told soinlulittireón Cm)
inkg
 added pure ethanol
23 What happens when acetone is to
(2020)
ethanol of
Ans When acetone is added to ,some

t h a n o l m o l e c u l es break down
he e
H-bond beween t .
v a p o u r p r e s s u r e o f mixtire
resulling in ahnowinpcorseiatsive deviation from Raonlt's law
e in
The mixtume s
o w i n g (2014)
Def i n e e f o l l tсет
ant (kb)
point
t h n s t
Bu
Mol al eleva
tio n c o
t i o n i n b o i l ing
eva
ST6=Eollality
кох т
Ans дть m=m
b o i l i n g i nt
=

i o n p o
as elevat
i n
I t i s d e fi m e d
o l u t i o n is unity
when the mol al
ity o f t h e s
Unut → Kkgm
oe-
85 Give reason for the following o d is preferred
p r e s s u r e m e t h
Measurement of osmot molar mass of macromolecules
ic

r m i n a tion of
fo t h e d e t e r
y m e r s ? . (2018) g n i t u d e
suc h a s p r o t e i n a n d p o l
v e properti e s
e s , i t s m a
to o t h e r w l l i g a i p e r ature.
s c o m p a r e d o m t e m
Ans A solution a t 2 o
l y a ble
is large even
fo r v e r y d i l u t e
i n are nnoott gene r a l s t
such p r o t e u b i l ity
Macc o m o l e c u l e s a s
p o o r s o l
p o l y m e r s have
b a t d
ume antion? (2014)
at
e r t e m p e r
high tonie sol
u
pressure
so
86 What are
s m o t i c
o
ns having sam e
Ans Tụo solutio e ratue
ag i v e n t e m p ns
at we en these lmo solutio
→ No O
smosis bet
 Sourabh Raina

87 Gwereason for the following m kil solution is

a t i o n o f b o i l i n g p oint of i 018e)-
El e v
u g a o l t i
r s kcl →kt+c
i o n ? . ( 2
l e a n I M s
mearly doub
Дтb=
k
Kb m
tion i=2
Ans kcl solu
e=1 (Msoungar
Suga r soluthon l u t i o n i s d ouble Han
soluti
ать оf iмкие so
z e o t r o p e s .What are
mixing for m a
S o m e l q u id o 2014) n
9B
az eotro
pes?. ( i o n that
n a r y m i x t i r e of r o l u t
y t he bi q u i ' d a nd
Ans The
a r e n l i
c o m p osclion i
have the s
a m e
s t a n t l e m p e ratme
d b o i l sat con
Vaponr pphas
e a n
 Identafy which liquid will have a higler
vapor
89
bo il in g po in t of l u s li qu id A
pressure at goc if the sp ec ti ve ly : (20Zоc
are 140c an d 1 8 0 c re
and B
[Link]
h e l i q u i d w i th a lower boiling B o i l i n oint
gp
Ans T
g h e r v a p o m pressure.
point has a A has higher vapom pressur
h i
c t ed
H e n c e l i q u i d l v e n t a f f e
p r e s s u r e of a so ' i t ? . (2014)
is th e v a p o u r
sol v e d i n
ole How ute is dis
e n non vol
at i l e s o l
t h e s o lvent
wh a
o l ute is add
e d t o
a t i l e s
W h e n non vol e s l ower than
A n s c o m ure
u r e o f s o l ution be e t e nm p e r a t
s
vapone pres e з o l v e n t at sam
e s s и r е o f риr
vapone pr

Puse solvent Solution

@!! Define the following terт 2017)
Abnormal molar mass

higher
which is either lower
or
Ans The molar mass
normal value
than expected or
Dissociation
Association or
n
c e t h e b l o od cell
n whenwepla
What happe olution) Give reason (2015
912
walerc h
ypotonie s lecul e s m o ve in b
lood
er mo
Ans
Due to osmosis, wal a n d m a y even
swel l
resnlt b lood cell
cell. As a
buest.
 Shovt answer type I questions (2morks)
913 State Henry's law. u Why
an is diluled with
helium inthe tank used by scuba divers?
Ans The partialpressure
of the gar in vapome phareluCplion
f r a t t o n of gas (X)in so
is proportional to mole
r y ' s l a w c o nstant
H e n
p=kHX kH =
as the lo
жic
as well
in theblood
b e n d s
oid
→To av
t r ation of Nitrogen
ig h o n c e n
effect of h
c
m e c a n s e o f lower
uted with Heliu b
n
Air is del
solubility in blood tha nitroger
 Sourabh Raina

814
Calculate the molarity of 9.8. CW/W) solution of
lution is 1.02gml".CMolar ma
s of
H₂SOu. if the density of so H₂Sou= 98g mol"!

= 9.8g s olu te
Ans Mass of H₂ sou
Molar i t y = n
o l u t i o ncеs
=100g vol fs
Mass of solution
Mass
moles of H2SO4 =
0.1
Molar mass
98
= 9.8=0.1 1000
१४
1000
=0.1x
98
Density= Mass me
Volu =100 -1.02M
-86
100
m e of s o lution = 1.02
volu
= 98ml
015 Write tuo difference between ideal solution and
non ideal solution?. 12017)
Ans Ideal solution Non-Edeal solution
onot obey Raou
lt's
1. D
Obey Raoult's law a l l E e m p erature
.
re and l a w a t
at all temperatu and conc
entra tion
concentration
P Px
P, =PiX
2. AVmLx 0
2. Vmix=0
DH mcx ≠ o
AHmlx=0
816 Calculate the freezing point of a solution
containing 60g of glucose Cmolarmass= 180g mol")
r (k f o& wa te r= 1. 86 kk gm ol "( (2018)
in 250g of wate
ol-
Ans Mass of glucose= 60g
(M) M2=180gm
1000
60,
Mass of water =250g 1.86 x
250
CW)
=
180
mo -l-
K¢ = 1.86 k kg mое ь 2.48 K
А т =

kf m solulion
ATf
Freezing o .48
=
=273-2
x1000
ATf= Kfx !W2
270.52k
M₂xW
817 Give reason

① 0.1Mkcl hashigher boiling pomt than 0.1M glucose?

er ve d for lo ng er by sa lt in g (2020)
Meat is pres ti me

Ans O Дть = і ком

kt+le
alucose i=1
g a x N o o f p a r t iiles
kll
tion ofboil
in
1 =2 Elev a
pomt
f r o m m e a t b y process
water
① Salt removes
ce there no water
is
khown as osmosis. Sin
s m are unabl
e to
m i c r o o r g a n i
left in meat, r e fo r l o ngee lime
o
eminate. This help to
s t m e a t
ge
 Sourabh Raina

What is by positive deviation from Raoult's

918 meant
gn fa ДmixH
ex a m p l e W
. h a t is th e si
law? Ave an
n? 2015(
fr positive deviatio an A-A and 13-B
weakker th
Ans A-B interactions are

sure incueases
vapone pres
interattion.Dục to
this u l t ' s law.
d e v i a tion f r o m R a o
p o s i t i v e
which result in
ceto ne
eg Ethanol+ A

∆Hmx = +ve
 of шеа смolarmass
=60g/mok)
a19 For a 5%% solution 00k oe)
ue at 3 mk m
alculate the osmot
ic pressumeе 082 1 2 a l
C CR=0. (2020)
Ans 0nl of solution
Mass of Uhea 5g in 10
21x 300
T 5 x0.08
A=CR =

00
60x 1 0
RT 100
T=n 0
8 21X30
RТ = 1x0.0
m 12 0.1
지 =
MV m
= 20.51 at
G20
Defi ne az eo tr op e. Wh at ty pe of azeotropes
f r o m R a o u l e 's law0?15)
is formed by po
sttive d e v i a t i o n C2
aire an example? or
f e o t r o p e s is f ormed by
e o p e . W hat type o a z
n examp
le?
Defin a z e o t r
om Raoult's
law? a i v e a

negatve dev
iation fr
h a n ol+ W aler
e g E t
Ans
b o c l i n g a zeotrope b y v o l ume)
Min i m u m C9 5 % o
e
30

u i + W a t r
e o r o p e e g Nitr a n d
u mb o i l i n g a z C 6 8 % by mass)
Maxim
821 Blood cells are isotonic with 0.9% sodium chloride.

solution. What happen if we plaved blood cell in

(2016)
a solution containing
1.2%. Nall solution
tion
0.4%. Nacl solu
Ans b o n h y p e r t o n i c with respeit to
2%% Na l l s o l u is
l and cell
①1. o f c e l
will flow o n t th e
blood cell, [Link]
shr
would
i c w i t h t e s p e itto
l u t i o n i s hypoton and it would
l o
① 0.4%l%,Nwaalter will flow ento ce
s ll
bloodcel
swell.
 is Va w' t Ho ff fa ct or ? W h a t ty pe of value
822 What
the solutron the Cso lu te
can it have if in forming 2 0 1 4 )
molecule undergo
Lis Dusociation Association
a k o o f e x p e r i mental value
Ans
d as the r е of
It is def me c a l c u l a t e d vaвл
p r o p e to the
rty
l l i g a t i v e
of the o perty rty
co l l i g a t i v e p r o wll i g a t i v e p r o p e
observed p erty
i=
Cal culate
d weligative pro

O Dissoc iaton i1
n ici
Associatio
 Short answer type II questions 3 marks)
823 Some ethylene glywl HOCH, CH,OH is added to
your al on g wi th 5k g of [Link] the
cooling sy
car co st em
g l y w l so lu ti on is -1 5° C. What is
freezing pomt of watluerti-on CKb= 0.52 kkgmol , kf=1.86 k liguo
boling pome of the so 15°c =x W2x1000
1.86
Ang ATF = 15°c 62 x5000

W2 =? W₂=15x62
x5

а с н о с ц е н ом) = 62
1.86
М
IN= 5 kg
INlz=2500g
m дть = кыт
Tf =kf
W₂ x1 0001 Дть=кь W2x 1000
ATF= kfx M W
M₂XW
-0.52x2500x1000 =4.19k
62 500
Tb=373+4.19 =377.19k
 Sourabh Raina

224 At 300k, 3од of glucose presontt in a litre of its

solution has an osmotirpressune of 4.98 bar. If tthe
at the
osmoticpressure of a glucose solution is 1.52 bartio n?. (2019)
te mp er at ue , wh at wo ul d be its concentra
same
Ans
= C, RT T2=C2RT T=300k
,
RT
xRT 1.52 = C2
4.98= m
MxV
1.52= C2
RT
0x RT
4.98=3 80xi
1

RT
4.98=1 T
6 XC R
1.52
=152
=1.52
4.98x6 29.88
0.051 mo
le-!
=
825 Calculate the boiling point elevation for a

solution prepared by adding 1og of cacl2 to200g of water

скьваwaler= a52kkg mol",Molar mass of Call|gmue") =
(2017)
Ans
Call2 Ca²++2ce
= 3

к
Ать і
т

W₂ x1000
i kbx
MxW
=

1000
10 y 0.702k
52x
=

= 3x 0. 111 200
826 3.9g of benzoic acid dissolved in 49 g of benzene
3.99
shows a depression in in freezing pomt of 1.62k. ature
t the n
Calculate the van't Hoff factos and pre dut
Molar mass of benzo0
0
di ss oc ia te d) . Gu ve n
of so lute (associated aud-12 2g/mol)
or
к6 =4.9 kkgmol-!.
Ans
ATf= iкь m
2 2 x49
2 x 1
i=1.6 004.9
STf = i k& x W₂ x1000
3. 9 x 1 0
MxW
7
00 i=0.50
4 . 9 x 3.9x10
x
1.62= i 49 n
122
icI associatio
827
When 19.5 g of F-CH-coOн (Mola mass = 78gml"!)
is dissolved in 50og of [Link] adepress eon of freezing
point is obsewed to be [Link] degiee of dissociation
F-CH ₂-COOH. (kfofwater = 1.86 k kgmol ")(
Ans W₂=195g M2=78gтое- i= 78
9.5x2
W1=500g 1.86x1
i = 1.075
STf = ik f m
+H+
COo
O O H Z F-CH
F-CH- C
1000
A Tf = i kf W₂
x degreeg
M W
i=1+Ch-1) dissouation
→Nog
paracle
1.86x19.5x
1000 -1)
ix 1.075:14C2 dissociater
1 =
78 500 +α
1.075=1
x=1.075-1
= 0.075 = 7.5%
828 30g of Urea (M=60gmol")
!") is dissolved in 840g
of [Link] the vapor pressure of watier
for this
solution if vapome pressure of pime (water
2017)at 298k
23.8 mmHg?
Ans W₂ 30g
=

kl,= 846 g PA= PAXXA

nwate
Nurea= 30 =0.5 23.8x
=
nurea
60 nwatert
23.8x 47
n water = 846-47 =
47.5
18
= 23.8x0.99
Hg
= 23. Smm
329 When 2.56g of sulphur was dissolved in 100g
ofCs2, the freezingpoint is lowered by 0.383k
a Ck fo f CS₂ 3. 83 kk g moе -1) a s sgs
Calculate form ul of Sx =
atom i c m
mol
(2016) = 32g
Ans IN₂ =2.56g W,=100g X100ь
2.56
M₂=? M= 3.83X 0
0-383x10

ATf= kf
Mz=2569тое-
xm

x W₂x 1000
ss ofS
x
Tf= kf a r
olecul
m a
W
M2 M xx32
=2 56

.83x 2.56x1000 23526=8

0.383=3
x =
M2 100

Formula= S8
830
A 4 % solution CW/W) of sucsose CM=34гдтое
m freezing point of 271.15 K. Calcul)al
water has
m
e
w a l es73.15
glui os e ( M = 18 0g m o e "
the freezing pomt of 3 % o n t o f p u re wa0ter)=2
Ans
CW₂) "(Freezing p 2 19 C
of Surose = 4g
Mass
a l u c w s )= 5g
e CW₂
Mas s o f
0-4
Mass of INater = 10 g C W , ) =100-5
CW) = 96 Mars of INa t e r
= 95g
TF= kf x m
ATf= kf xm
W₂ x 1000
kfx W₂ 1000 DTf=kFx
- 2 7 1.15= M2 W
27 3 . 1 5 M M
x 1000
l000
=15.55x5 95
4 x 180
2=kfxx Tf =4.54c
96
342
.145
27.35
nt-=4
15.55 kkgmol Freezing po-
Kf =
=268.61k
831 The vapour pressureof pure liquid x and pure liquidY
at 25'c are 120mm of Hg and 160 mm of Hg respectively.
l moles of xa nd y ar e mi xe d to fo rm an ideal solution.
If equa 3)
of th e so lu ti on? (2202
ur pr es su re M arks
Caloulate the vapo
Noof moles of x and Y =x ưdX CPX)
Ans V. P &f pure leq mmmHg
Mole fraction of x = x
x+x
= 2 1200m
= 12

V. P of pu re liquid Y CPY)
Mole n f Y=
fracto =
160 mmHg
ution
Ideal sol
s u r e = Pu
+Py
a w
Total p r e s Py+ fy
Raoult's l
= PxxXx+

= 120 + 160x

= 60+80
mmgHg.
=
140
832 Owhy is the value of van't Hoff factor for ethanoic
benzene close to 0.5?
on prepared
acid in
of a soluti
t e rm i n e t h e mo ti c pr es su re
t i o n a t 25c,
De 22 of so
os u
l
k ₂ i n (2023)
by dissolving 2. 32 x1
x1 0
0 ² g o f S O u
t e d ? . 3Marks
plet e l y d i s o c i a
assuming kzsoy is ccom c acid assoi
ate.
the ethanoi
Ans uo molecules of
① In benzene t
to form dimer. Coo
2CH COOH
r t i c olution
les in s
of s o l u t e p a
i= Number
r of solunt
e particles
numbe
Theoretical
1 =0.5
032 0why is the value of van't Hoff factor fr ethanoic
acid in benzene close to O.S?
su re of a solution pr
epared25c,
n e e osmotic pr es o l u t ion at
De t e r m i t h o f s
*g of k₂ sou in
2 l (2023)
by dissolving x10-2
is
2.32
c o m p l e t e l y d isociated? 3Marks
assuming kzsoy T= =25+273
25°C Molar mass k2s04
W= 2.32 x 102 g =298k 6x4
An = 39x2+32+1
2k+ Sou² =1749moe-1
v= 2l
k2s04
¿=3

Rт
A= iC
im RT
RT =i
= ?2 MxV
V
8 4.8 x103 atm
x0.082x29
2 =

= 3 x 2 . 3 2 X 1 0
174 x2
833 A solution is prepared by dissobving 10g of nonvolatile
solute in 200g of [Link] has a vapour pressure of
s of the solute
31.84 mm Hg at 308k. Calculate the molar ma 2 mm Hg)
ewater at 3081c =3
(Vapour presure of pure (2023)
2Marks
Ans W₂= 10g
p₁ = 32 mm Hgд M, = 18gImol
M2 =?.
W=200g P,= 31.84mm д

nitn2 (dilute s
olution)
Pi M 777
12

Pi-Pi こ

32-31.84 = 10 x. 18
mi
P 32 Mz 20ь

M, =18x32
Pi-Pi = IN2xM, 0.16 =1x 18
20 0.16x20
32 M₂
pi M₂xM'
=180g/mel
аз4 solution mose
O W hy is the boiling point of IM Nall
than that of IM glucose solution
@A non volatile solute XC Molar ma
rs= 50sogmal)
re du ce d it s v a p our pressure
when dissolved in
78g of benzen e
to 90%. Calculate the mars
of x dissolved tion.
inthe so lu 3)(202
3Markes

lonie and completely

com dissociate to
possible in
Ans Nace is
leculé which is not
give 2 2ons pr mo
glucose ce and it i
s I for glucose
fаctor i s f o r N a
-

van't Hoff 2
ать скът
=

se for Nacl than

Incre ase in boiling point will be mo alucose
 more

O W hy is the boiling point of IMNall solution

34

than that of IM glucose so lution

①A non volatile solute sogmal1)
XC Molar mars = 5

of en e re du ce d is vapour presure
when dissolved in 78 g be nz
lc ul at e th e ma rs of x di ss ol ve d nthe solution. (2023)
%. Ca
to 90 3Marks

An M² = ? M2 = 50gmoe CM₁) = C6 H6 = 12x6+6x1

mass of benzene 78gIe 1
M=78 g Molar =

[Link] benzene Cp1)=

pl
90%.g f1
V.P & solntion Cp₁)= = 0.9 pi P-0.9Pi= W₂x7788 50
이
P
P-Pi =M2 = N₂xM 0.1P1=W₂
Mz W' 50
Pi

W₂=5g